1,1′-Bis(diisobutyl­phosphino)cobalto­cenium hexa­fluorido­phosphate

Hou, J.-G.; Li, D.-B.; Qiu, M.-Z.

doi:10.1107/S1600536808017194

1,1′-Bis(diisobutylphosphino)cobaltocenium hexafluoridophosphate

In the title compound, [Co(C₁₃H₂₂P)₂]PF₆, the Co^III atom is sandwiched between two (diisobutylphosphino)cyclopentadienenyl ligands. The two diisobutylphophine units are trans to each other with respect to the Co^III metal center. The PF₆⁻ anion links the cobaltocenium cations via weak C—H

F hydrogen bonds into a chain running along the b axis. The chains are further linked by C—H

F hydrogen bonds, forming a layer extending parallel to the (10 $\overline{1}$ ) plane.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536808017194/is2295sup1.cif Contains datablocks I, global
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536808017194/is2295Isup2.hkl Contains datablock I

CCDC reference: 696433

checkCIF report

Key indicators

Single-crystal X-ray study
T = 298 K
Mean (C-C) = 0.006 Å
R factor = 0.057
wR factor = 0.147
Data-to-parameter ratio = 20.2

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.12 Ratio
PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.38 Ratio
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for         C7
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C11
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C20
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C24
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for         P3

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   7 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   5 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

Comment top

Cobaltocene derivatives have been applied as catalysts in cross-coupling reactions (Mathews et al., 2000). As part of our investigations of new catalysts, we have focused our attention on cobaltocenium compounds. Some complexes, such as 1,1'-bis(diphenylphosphino)cobaltocenium tetrafluoridoborate, have been obtained and reported (Hou et al., 2007). Herein, we report the structure of the title compound, (I) (Fig. 1). The molecular structure of the title complex consists of the [(η₅-(i-C₄H₉)₂PC₅H₄)₂Co]⁺ cation and the PF₆^- anion, which is very similar to the compounds 1,1'-bis(diphenylphosphino)cobaltocenium tetrafluoridoborate (Hou et al., 2007) and 1,1'-bis(diphenylphosphino)cobaltocenium hexafluorophosphate with different substituents (Brasse et al., 2000). The two (i-C₄H₉)₂P substituents are trans to each other with respect to the Co^III metal center, and the two substituted Cp rings staggered and are essentially parallel with a dihedral angle of 1.8 (2)°. The Co1···Cg1 and Co1···Cg2 distances are 1.6429 (15) and 1.6430 (3) Å, respectively, and the Cg1···Co1···Cg2 angle is 179.13 (8)° (Cg1 and Cg2 are the centroids of the two cyclopentadienyl) The hydrogen bonds of C—H···F play a key role of the stabilization of crystal structure of the title compound. As shown in Fig. 2, there are extensive nonclassical hydrogen bonds formed by C—H···F (Table 2). There are not only intramolecular but also intermolecular hydrogen bonds between the cation and anion, thus, two-dimensional layers extending parallel to the (101) plane were formed.

Related literature top

For background to cobaltocene derivatives applied as catalysts, see: Mathews et al. (2000). For the structures of closely related compounds, see: Brasse et al. (2000); Hou et al. (2007).

Experimental top

The title compound was obtained by anion exchange of 1,1'-bis(di-isobutylphosphino)cobaltocenium chloride with ammonium hexaflurophosphate. Crystals appropriate for data collection were obtained by slow diffusion of hexane into a solution of the title compound in dichloromethane at 293 K.

Computing details top

Data collection: SMART (Bruker, 2001); cell refinement: SAINT (Bruker, 2001); data reduction: SAINT (Bruker, 2001); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXS97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top

	Fig. 1. The molecular structure of (I), showing ellipsoids at 30% probability level.
	Fig. 2. The packing diagram of two-dimensional sheet with hydrogen bonds shown as dashed lines. H atoms not involved in the hydrogen bonds have been omitted for clarity.

1,1'-Bis(diisobutylphosphino)cobaltocenium hexafluorophosphate top

Crystal data top

[Co(C₁₃H₂₂P)₂]·PF₆	F(000) = 1304
M_r = 622.45	D_x = 1.340 Mg m⁻³
Monoclinic, P2₁/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 3150 reflections
a = 16.7733 (3) Å	θ = 2.3–19.9°
b = 10.4660 (2) Å	µ = 0.76 mm⁻¹
c = 18.5105 (4) Å	T = 298 K
β = 108.288 (1)°	Needle, yellow
V = 3085.38 (10) Å³	0.40 × 0.04 × 0.02 mm
Z = 4

Data collection top

Bruker SMART CCD area-detector diffractometer	6733 independent reflections
Radiation source: fine-focus sealed tube	3878 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.083
ϕ and ω scans	θ_max = 27.0°, θ_min = 1.4°
Absorption correction: multi-scan (SADABS; Sheldrick, 2004)	h = −21→21
T_min = 0.750, T_max = 0.985	k = −13→13
33818 measured reflections	l = −23→22

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.056	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.147	H-atom parameters constrained
S = 0.97	w = 1/[σ²(F_o²) + (0.0731P)²] where P = (F_o² + 2F_c²)/3
6733 reflections	(Δ/σ)_max = 0.001
333 parameters	Δρ_max = 0.47 e Å⁻³
0 restraints	Δρ_min = −0.34 e Å⁻³

Crystal data top

[Co(C₁₃H₂₂P)₂]·PF₆	V = 3085.38 (10) Å³
M_r = 622.45	Z = 4
Monoclinic, P2₁/n	Mo Kα radiation
a = 16.7733 (3) Å	µ = 0.76 mm⁻¹
b = 10.4660 (2) Å	T = 298 K
c = 18.5105 (4) Å	0.40 × 0.04 × 0.02 mm
β = 108.288 (1)°

Data collection top

Bruker SMART CCD area-detector diffractometer	6733 independent reflections
Absorption correction: multi-scan (SADABS; Sheldrick, 2004)	3878 reflections with I > 2σ(I)
T_min = 0.750, T_max = 0.985	R_int = 0.083
33818 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.056	0 restraints
wR(F²) = 0.147	H-atom parameters constrained
S = 0.97	Δρ_max = 0.47 e Å⁻³
6733 reflections	Δρ_min = −0.34 e Å⁻³
333 parameters

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Co1	0.66580 (3)	0.34637 (4)	0.07609 (2)	0.04054 (16)
C1	0.6975 (2)	0.3487 (3)	−0.02171 (18)	0.0413 (8)
C2	0.6752 (2)	0.2221 (3)	−0.00492 (18)	0.0480 (9)
H2	0.7119	0.1470	0.0038	0.058*
C3	0.5916 (2)	0.2239 (4)	−0.0027 (2)	0.0560 (10)
H3	0.5608	0.1507	0.0081	0.067*
C4	0.5606 (2)	0.3499 (4)	−0.01797 (19)	0.0542 (10)
H4	0.5047	0.3794	−0.0193	0.065*
C5	0.6254 (2)	0.4270 (3)	−0.02941 (18)	0.0468 (9)
H5	0.6215	0.5189	−0.0402	0.056*
C6	0.7928 (2)	0.5658 (3)	−0.0360 (2)	0.0558 (10)
H6A	0.7526	0.5870	−0.0849	0.067*
H6B	0.7717	0.5993	0.0033	0.067*
C7	0.8757 (3)	0.6294 (4)	−0.0295 (3)	0.0740 (13)
H7	0.8998	0.5880	−0.0655	0.089*
C8	0.9371 (3)	0.6159 (6)	0.0495 (3)	0.126 (2)
H8A	0.9162	0.6608	0.0850	0.189*
H8B	0.9904	0.6511	0.0507	0.189*
H8C	0.9439	0.5271	0.0630	0.189*
C9	0.8631 (3)	0.7712 (4)	−0.0501 (3)	0.1105 (19)
H9A	0.8379	0.8127	−0.0164	0.166*
H9B	0.8270	0.7798	−0.1016	0.166*
H9C	0.9164	0.8099	−0.0451	0.166*
C10	0.7851 (2)	0.3465 (4)	−0.1272 (2)	0.0562 (10)
H10A	0.7344	0.3882	−0.1586	0.067*
H10B	0.8316	0.3803	−0.1419	0.067*
C11	0.7776 (3)	0.2041 (4)	−0.1449 (2)	0.0694 (12)
H11	0.7300	0.1710	−0.1306	0.083*
C12	0.7589 (3)	0.1826 (5)	−0.2301 (3)	0.1059 (18)
H12A	0.8042	0.2160	−0.2458	0.159*
H12B	0.7077	0.2256	−0.2573	0.159*
H12C	0.7530	0.0928	−0.2409	0.159*
C13	0.8552 (4)	0.1312 (4)	−0.1000 (3)	0.1079 (19)
H13A	0.8506	0.0440	−0.1170	0.162*
H13B	0.8603	0.1337	−0.0469	0.162*
H13C	0.9039	0.1695	−0.1077	0.162*
C14	0.6338 (2)	0.3542 (3)	0.17449 (18)	0.0406 (8)
C15	0.7006 (2)	0.2654 (3)	0.18142 (18)	0.0470 (9)
H15	0.6989	0.1739	0.1921	0.056*
C16	0.7687 (2)	0.3305 (4)	0.16930 (19)	0.0576 (10)
H16	0.8224	0.2923	0.1706	0.069*
C17	0.7466 (2)	0.4595 (4)	0.15524 (19)	0.0574 (10)
H17	0.7821	0.5269	0.1450	0.069*
C18	0.6640 (2)	0.4751 (3)	0.15777 (18)	0.0493 (9)
H18	0.6323	0.5554	0.1492	0.059*
C19	0.5497 (2)	0.3896 (3)	0.28119 (19)	0.0528 (9)
H19A	0.5086	0.3520	0.3018	0.063*
H19B	0.6046	0.3598	0.3120	0.063*
C20	0.5469 (3)	0.5333 (4)	0.2898 (2)	0.0699 (12)
H20	0.5877	0.5708	0.2680	0.084*
C21	0.4615 (4)	0.5887 (5)	0.2477 (3)	0.114 (2)
H21A	0.4208	0.5578	0.2702	0.171*
H21B	0.4455	0.5632	0.1953	0.171*
H21C	0.4640	0.6803	0.2510	0.171*
C22	0.5730 (3)	0.5705 (5)	0.3741 (2)	0.0917 (15)
H22A	0.5717	0.6618	0.3786	0.138*
H22B	0.6288	0.5401	0.3993	0.138*
H22C	0.5348	0.5329	0.3973	0.138*
C23	0.5366 (2)	0.1557 (3)	0.2033 (2)	0.0605 (10)
H23A	0.5477	0.1120	0.1612	0.073*
H23B	0.5842	0.1405	0.2484	0.073*
C24	0.4590 (3)	0.0970 (4)	0.2154 (3)	0.0708 (12)
H24	0.4482	0.1431	0.2575	0.085*
C25	0.3822 (3)	0.1080 (5)	0.1483 (3)	0.115 (2)
H25A	0.3907	0.0632	0.1060	0.172*
H25B	0.3711	0.1964	0.1352	0.172*
H25C	0.3354	0.0714	0.1602	0.172*
C26	0.4769 (3)	−0.0421 (4)	0.2402 (4)	0.113 (2)
H26A	0.4304	−0.0761	0.2538	0.169*
H26B	0.5269	−0.0464	0.2832	0.169*
H26C	0.4846	−0.0910	0.1990	0.169*
F1	0.63466 (15)	0.7385 (2)	0.03501 (14)	0.0871 (8)
F2	0.75008 (15)	0.7617 (2)	0.13489 (16)	0.0953 (9)
F3	0.71730 (17)	0.9112 (3)	0.04222 (16)	0.0973 (8)
F4	0.70793 (18)	0.9559 (2)	0.15705 (15)	0.1059 (10)
F5	0.59126 (16)	0.9334 (2)	0.05722 (17)	0.1051 (9)
F6	0.62383 (18)	0.7849 (3)	0.14848 (15)	0.0981 (8)
P1	0.80124 (6)	0.39039 (9)	−0.02673 (5)	0.0469 (3)
P2	0.52962 (6)	0.32919 (9)	0.18315 (5)	0.0476 (3)
P3	0.67083 (6)	0.84835 (9)	0.09545 (6)	0.0561 (3)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Co1	0.0484 (3)	0.0352 (3)	0.0388 (3)	−0.0031 (2)	0.0149 (2)	−0.0013 (2)
C1	0.0513 (19)	0.0361 (19)	0.0372 (17)	−0.0008 (16)	0.0150 (15)	−0.0037 (15)
C2	0.069 (2)	0.033 (2)	0.044 (2)	−0.0023 (17)	0.0203 (17)	−0.0092 (16)
C3	0.066 (2)	0.052 (3)	0.052 (2)	−0.0226 (19)	0.0213 (19)	−0.0142 (19)
C4	0.048 (2)	0.063 (3)	0.045 (2)	−0.0019 (19)	0.0064 (16)	−0.0064 (19)
C5	0.053 (2)	0.044 (2)	0.0401 (19)	0.0021 (17)	0.0109 (16)	0.0053 (16)
C6	0.061 (2)	0.043 (2)	0.067 (2)	−0.0035 (18)	0.0257 (19)	0.0008 (18)
C7	0.078 (3)	0.057 (3)	0.094 (3)	−0.019 (2)	0.036 (3)	−0.011 (2)
C8	0.089 (4)	0.107 (4)	0.150 (5)	−0.031 (3)	−0.008 (4)	−0.014 (4)
C9	0.123 (4)	0.060 (3)	0.148 (5)	−0.031 (3)	0.041 (4)	0.010 (3)
C10	0.066 (2)	0.062 (3)	0.047 (2)	−0.0002 (19)	0.0268 (18)	0.0003 (19)
C11	0.083 (3)	0.068 (3)	0.072 (3)	−0.021 (2)	0.046 (2)	−0.022 (2)
C12	0.129 (4)	0.121 (5)	0.081 (4)	−0.029 (4)	0.051 (3)	−0.042 (3)
C13	0.163 (5)	0.062 (3)	0.101 (4)	0.027 (3)	0.046 (4)	−0.014 (3)
C14	0.055 (2)	0.0317 (19)	0.0366 (18)	0.0033 (15)	0.0173 (15)	−0.0004 (15)
C15	0.060 (2)	0.043 (2)	0.0408 (19)	0.0072 (17)	0.0193 (17)	0.0054 (16)
C16	0.051 (2)	0.076 (3)	0.043 (2)	0.005 (2)	0.0113 (17)	0.001 (2)
C17	0.067 (3)	0.065 (3)	0.041 (2)	−0.022 (2)	0.0178 (18)	−0.0124 (19)
C18	0.074 (3)	0.034 (2)	0.041 (2)	−0.0064 (17)	0.0211 (18)	−0.0087 (16)
C19	0.063 (2)	0.052 (2)	0.047 (2)	0.0069 (18)	0.0228 (18)	0.0029 (17)
C20	0.094 (3)	0.054 (3)	0.072 (3)	−0.013 (2)	0.041 (2)	−0.013 (2)
C21	0.167 (5)	0.066 (3)	0.091 (4)	0.056 (4)	0.015 (4)	−0.008 (3)
C22	0.105 (4)	0.093 (4)	0.078 (3)	−0.014 (3)	0.030 (3)	−0.035 (3)
C23	0.075 (3)	0.040 (2)	0.074 (3)	−0.0032 (19)	0.034 (2)	0.004 (2)
C24	0.077 (3)	0.052 (3)	0.087 (3)	−0.014 (2)	0.030 (2)	0.004 (2)
C25	0.087 (4)	0.119 (5)	0.116 (4)	−0.041 (3)	0.001 (3)	0.011 (4)
C26	0.109 (4)	0.053 (3)	0.186 (6)	−0.014 (3)	0.061 (4)	0.024 (3)
F1	0.0994 (18)	0.0704 (17)	0.0828 (17)	−0.0229 (14)	0.0160 (14)	−0.0294 (14)
F2	0.0789 (16)	0.0622 (16)	0.120 (2)	0.0124 (13)	−0.0038 (15)	0.0095 (15)
F3	0.105 (2)	0.089 (2)	0.103 (2)	−0.0209 (16)	0.0388 (16)	0.0105 (16)
F4	0.142 (3)	0.0577 (16)	0.096 (2)	−0.0114 (16)	0.0059 (17)	−0.0290 (15)
F5	0.0843 (18)	0.0725 (18)	0.139 (2)	0.0210 (14)	0.0074 (17)	0.0211 (17)
F6	0.128 (2)	0.0788 (19)	0.105 (2)	0.0015 (17)	0.0616 (18)	0.0080 (16)
P1	0.0508 (5)	0.0438 (6)	0.0477 (5)	−0.0007 (4)	0.0179 (4)	−0.0006 (4)
P2	0.0546 (5)	0.0429 (6)	0.0472 (5)	0.0024 (4)	0.0188 (4)	0.0008 (4)
P3	0.0628 (6)	0.0361 (6)	0.0614 (6)	−0.0009 (5)	0.0081 (5)	−0.0028 (5)

Geometric parameters (Å, º) top

Co1—C16	2.028 (3)	C13—H13B	0.9600
Co1—C2	2.028 (3)	C13—H13C	0.9600
Co1—C18	2.033 (3)	C14—C15	1.430 (4)
Co1—C17	2.034 (3)	C14—C18	1.433 (4)
Co1—C15	2.036 (3)	C14—P2	1.823 (3)
Co1—C5	2.038 (3)	C15—C16	1.407 (5)
Co1—C1	2.041 (3)	C15—H15	0.9800
Co1—C3	2.045 (3)	C16—C17	1.403 (5)
Co1—C4	2.053 (3)	C16—H16	0.9800
Co1—C14	2.056 (3)	C17—C18	1.410 (5)
C1—C5	1.431 (5)	C17—H17	0.9800
C1—C2	1.437 (4)	C18—H18	0.9800
C1—P1	1.824 (3)	C19—C20	1.515 (5)
C2—C3	1.415 (5)	C19—P2	1.850 (3)
C2—H2	0.9800	C19—H19A	0.9700
C3—C4	1.413 (5)	C19—H19B	0.9700
C3—H3	0.9800	C20—C21	1.515 (6)
C4—C5	1.421 (5)	C20—C22	1.532 (5)
C4—H4	0.9800	C20—H20	0.9800
C5—H5	0.9800	C21—H21A	0.9600
C6—C7	1.513 (5)	C21—H21B	0.9600
C6—P1	1.845 (4)	C21—H21C	0.9600
C6—H6A	0.9700	C22—H22A	0.9600
C6—H6B	0.9700	C22—H22B	0.9600
C7—C8	1.508 (6)	C22—H22C	0.9600
C7—C9	1.530 (6)	C23—C24	1.519 (5)
C7—H7	0.9800	C23—P2	1.850 (4)
C8—H8A	0.9600	C23—H23A	0.9700
C8—H8B	0.9600	C23—H23B	0.9700
C8—H8C	0.9600	C24—C25	1.487 (6)
C9—H9A	0.9600	C24—C26	1.527 (6)
C9—H9B	0.9600	C24—H24	0.9800
C9—H9C	0.9600	C25—H25A	0.9600
C10—C11	1.523 (5)	C25—H25B	0.9600
C10—P1	1.851 (4)	C25—H25C	0.9600
C10—H10A	0.9700	C26—H26A	0.9600
C10—H10B	0.9700	C26—H26B	0.9600
C11—C13	1.512 (6)	C26—H26C	0.9600
C11—C12	1.526 (5)	F1—P3	1.586 (2)
C11—H11	0.9800	F2—P3	1.585 (2)
C12—H12A	0.9600	F3—P3	1.579 (3)
C12—H12B	0.9600	F4—P3	1.584 (2)
C12—H12C	0.9600	F5—P3	1.576 (2)
C13—H13A	0.9600	F6—P3	1.585 (3)

C16—Co1—C2	109.48 (15)	C11—C12—H12A	109.5
C16—Co1—C18	68.21 (15)	C11—C12—H12B	109.5
C2—Co1—C18	176.26 (14)	H12A—C12—H12B	109.5
C16—Co1—C17	40.40 (14)	C11—C12—H12C	109.5
C2—Co1—C17	135.80 (16)	H12A—C12—H12C	109.5
C18—Co1—C17	40.57 (14)	H12B—C12—H12C	109.5
C16—Co1—C15	40.50 (13)	C11—C13—H13A	109.5
C2—Co1—C15	112.05 (14)	C11—C13—H13B	109.5
C18—Co1—C15	68.31 (14)	H13A—C13—H13B	109.5
C17—Co1—C15	68.08 (15)	C11—C13—H13C	109.5
C16—Co1—C5	141.94 (15)	H13A—C13—H13C	109.5
C2—Co1—C5	68.72 (14)	H13B—C13—H13C	109.5
C18—Co1—C5	111.10 (14)	C15—C14—C18	105.9 (3)
C17—Co1—C5	113.26 (15)	C15—C14—P2	130.1 (3)
C15—Co1—C5	177.38 (13)	C18—C14—P2	124.0 (3)
C16—Co1—C1	111.52 (14)	C15—C14—Co1	68.81 (18)
C2—Co1—C1	41.36 (12)	C18—C14—Co1	68.62 (18)
C18—Co1—C1	136.13 (13)	P2—C14—Co1	126.59 (17)
C17—Co1—C1	109.39 (14)	C16—C15—C14	108.8 (3)
C15—Co1—C1	141.09 (13)	C16—C15—Co1	69.44 (19)
C5—Co1—C1	41.07 (13)	C14—C15—Co1	70.28 (18)
C16—Co1—C3	136.09 (16)	C16—C15—H15	125.6
C2—Co1—C3	40.66 (14)	C14—C15—H15	125.6
C18—Co1—C3	143.01 (15)	Co1—C15—H15	125.6
C17—Co1—C3	175.89 (16)	C17—C16—C15	108.4 (3)
C15—Co1—C3	110.47 (15)	C17—C16—Co1	70.0 (2)
C5—Co1—C3	68.35 (15)	C15—C16—Co1	70.07 (19)
C1—Co1—C3	69.14 (13)	C17—C16—H16	125.8
C16—Co1—C4	176.30 (16)	C15—C16—H16	125.8
C2—Co1—C4	68.30 (14)	Co1—C16—H16	125.8
C18—Co1—C4	114.16 (15)	C16—C17—C18	108.1 (3)
C17—Co1—C4	143.21 (16)	C16—C17—Co1	69.6 (2)
C15—Co1—C4	136.99 (15)	C18—C17—Co1	69.65 (19)
C5—Co1—C4	40.65 (13)	C16—C17—H17	126.0
C1—Co1—C4	68.97 (14)	C18—C17—H17	126.0
C3—Co1—C4	40.35 (14)	Co1—C17—H17	126.0
C16—Co1—C14	68.80 (14)	C17—C18—C14	108.8 (3)
C2—Co1—C14	141.54 (13)	C17—C18—Co1	69.8 (2)
C18—Co1—C14	41.02 (12)	C14—C18—Co1	70.36 (18)
C17—Co1—C14	68.82 (14)	C17—C18—H18	125.6
C15—Co1—C14	40.91 (12)	C14—C18—H18	125.6
C5—Co1—C14	137.02 (13)	Co1—C18—H18	125.6
C1—Co1—C14	177.04 (13)	C20—C19—P2	116.2 (3)
C3—Co1—C14	112.82 (14)	C20—C19—H19A	108.2
C4—Co1—C14	110.91 (14)	P2—C19—H19A	108.2
C5—C1—C2	106.3 (3)	C20—C19—H19B	108.2
C5—C1—P1	130.4 (3)	P2—C19—H19B	108.2
C2—C1—P1	123.3 (3)	H19A—C19—H19B	107.4
C5—C1—Co1	69.38 (19)	C19—C20—C21	112.4 (4)
C2—C1—Co1	68.86 (18)	C19—C20—C22	110.6 (4)
P1—C1—Co1	124.48 (16)	C21—C20—C22	110.4 (4)
C3—C2—C1	108.7 (3)	C19—C20—H20	107.8
C3—C2—Co1	70.3 (2)	C21—C20—H20	107.8
C1—C2—Co1	69.78 (18)	C22—C20—H20	107.8
C3—C2—H2	125.6	C20—C21—H21A	109.5
C1—C2—H2	125.6	C20—C21—H21B	109.5
Co1—C2—H2	125.6	H21A—C21—H21B	109.5
C4—C3—C2	108.2 (3)	C20—C21—H21C	109.5
C4—C3—Co1	70.16 (19)	H21A—C21—H21C	109.5
C2—C3—Co1	69.06 (19)	H21B—C21—H21C	109.5
C4—C3—H3	125.9	C20—C22—H22A	109.5
C2—C3—H3	125.9	C20—C22—H22B	109.5
Co1—C3—H3	125.9	H22A—C22—H22B	109.5
C3—C4—C5	108.0 (3)	C20—C22—H22C	109.5
C3—C4—Co1	69.49 (19)	H22A—C22—H22C	109.5
C5—C4—Co1	69.10 (18)	H22B—C22—H22C	109.5
C3—C4—H4	126.0	C24—C23—P2	115.0 (3)
C5—C4—H4	126.0	C24—C23—H23A	108.5
Co1—C4—H4	126.0	P2—C23—H23A	108.5
C4—C5—C1	108.7 (3)	C24—C23—H23B	108.5
C4—C5—Co1	70.25 (19)	P2—C23—H23B	108.5
C1—C5—Co1	69.55 (18)	H23A—C23—H23B	107.5
C4—C5—H5	125.6	C25—C24—C23	113.7 (4)
C1—C5—H5	125.6	C25—C24—C26	111.2 (4)
Co1—C5—H5	125.6	C23—C24—C26	109.4 (4)
C7—C6—P1	112.9 (3)	C25—C24—H24	107.4
C7—C6—H6A	109.0	C23—C24—H24	107.4
P1—C6—H6A	109.0	C26—C24—H24	107.4
C7—C6—H6B	109.0	C24—C25—H25A	109.5
P1—C6—H6B	109.0	C24—C25—H25B	109.5
H6A—C6—H6B	107.8	H25A—C25—H25B	109.5
C8—C7—C6	111.5 (4)	C24—C25—H25C	109.5
C8—C7—C9	109.4 (4)	H25A—C25—H25C	109.5
C6—C7—C9	110.8 (4)	H25B—C25—H25C	109.5
C8—C7—H7	108.4	C24—C26—H26A	109.5
C6—C7—H7	108.4	C24—C26—H26B	109.5
C9—C7—H7	108.4	H26A—C26—H26B	109.5
C7—C8—H8A	109.5	C24—C26—H26C	109.5
C7—C8—H8B	109.5	H26A—C26—H26C	109.5
H8A—C8—H8B	109.5	H26B—C26—H26C	109.5
C7—C8—H8C	109.5	C1—P1—C6	101.32 (16)
H8A—C8—H8C	109.5	C1—P1—C10	98.64 (16)
H8B—C8—H8C	109.5	C6—P1—C10	99.83 (17)
C7—C9—H9A	109.5	C14—P2—C23	99.00 (16)
C7—C9—H9B	109.5	C14—P2—C19	98.79 (16)
H9A—C9—H9B	109.5	C23—P2—C19	99.08 (18)
C7—C9—H9C	109.5	F5—P3—F3	89.92 (16)
H9A—C9—H9C	109.5	F5—P3—F4	90.45 (15)
H9B—C9—H9C	109.5	F3—P3—F4	89.63 (15)
C11—C10—P1	115.8 (3)	F5—P3—F6	89.95 (16)
C11—C10—H10A	108.3	F3—P3—F6	179.69 (17)
P1—C10—H10A	108.3	F4—P3—F6	90.65 (16)
C11—C10—H10B	108.3	F5—P3—F2	178.99 (18)
P1—C10—H10B	108.3	F3—P3—F2	91.09 (16)
H10A—C10—H10B	107.4	F4—P3—F2	89.53 (14)
C13—C11—C10	112.2 (4)	F6—P3—F2	89.04 (16)
C13—C11—C12	110.9 (4)	F5—P3—F1	90.58 (15)
C10—C11—C12	110.1 (4)	F3—P3—F1	90.94 (15)
C13—C11—H11	107.8	F4—P3—F1	178.83 (16)
C10—C11—H11	107.8	F6—P3—F1	88.78 (14)
C12—C11—H11	107.8	F2—P3—F1	89.44 (14)

C16—Co1—C1—C5	−146.7 (2)	C15—Co1—C14—C18	117.8 (3)
C2—Co1—C1—C5	117.9 (3)	C5—Co1—C14—C18	−64.6 (3)
C18—Co1—C1—C5	−66.2 (3)	C3—Co1—C14—C18	−146.8 (2)
C17—Co1—C1—C5	−103.5 (2)	C4—Co1—C14—C18	−103.2 (2)
C15—Co1—C1—C5	177.7 (2)	C16—Co1—C14—P2	−162.0 (3)
C3—Co1—C1—C5	80.6 (2)	C2—Co1—C14—P2	−67.1 (3)
C4—Co1—C1—C5	37.2 (2)	C18—Co1—C14—P2	117.2 (3)
C16—Co1—C1—C2	95.4 (2)	C17—Co1—C14—P2	154.5 (3)
C18—Co1—C1—C2	175.9 (2)	C15—Co1—C14—P2	−125.0 (3)
C17—Co1—C1—C2	138.6 (2)	C5—Co1—C14—P2	52.6 (3)
C15—Co1—C1—C2	59.8 (3)	C3—Co1—C14—P2	−29.6 (3)
C5—Co1—C1—C2	−117.9 (3)	C4—Co1—C14—P2	14.0 (2)
C3—Co1—C1—C2	−37.3 (2)	C18—C14—C15—C16	0.0 (4)
C4—Co1—C1—C2	−80.6 (2)	P2—C14—C15—C16	179.5 (2)
C16—Co1—C1—P1	−21.2 (3)	Co1—C14—C15—C16	58.9 (2)
C2—Co1—C1—P1	−116.6 (3)	C18—C14—C15—Co1	−58.9 (2)
C18—Co1—C1—P1	59.3 (3)	P2—C14—C15—Co1	120.6 (3)
C17—Co1—C1—P1	22.0 (3)	C2—Co1—C15—C16	94.6 (2)
C15—Co1—C1—P1	−56.8 (3)	C18—Co1—C15—C16	−81.4 (2)
C5—Co1—C1—P1	125.5 (3)	C17—Co1—C15—C16	−37.5 (2)
C3—Co1—C1—P1	−153.9 (3)	C1—Co1—C15—C16	56.5 (3)
C4—Co1—C1—P1	162.8 (2)	C3—Co1—C15—C16	138.3 (2)
C5—C1—C2—C3	0.2 (4)	C4—Co1—C15—C16	175.9 (2)
P1—C1—C2—C3	177.9 (2)	C14—Co1—C15—C16	−120.1 (3)
Co1—C1—C2—C3	59.7 (2)	C16—Co1—C15—C14	120.1 (3)
C5—C1—C2—Co1	−59.6 (2)	C2—Co1—C15—C14	−145.4 (2)
P1—C1—C2—Co1	118.2 (2)	C18—Co1—C15—C14	38.66 (19)
C16—Co1—C2—C3	139.5 (2)	C17—Co1—C15—C14	82.5 (2)
C17—Co1—C2—C3	176.9 (2)	C1—Co1—C15—C14	176.6 (2)
C15—Co1—C2—C3	96.2 (2)	C3—Co1—C15—C14	−101.6 (2)
C5—Co1—C2—C3	−81.1 (2)	C4—Co1—C15—C14	−64.0 (3)
C1—Co1—C2—C3	−119.7 (3)	C14—C15—C16—C17	0.4 (4)
C4—Co1—C2—C3	−37.3 (2)	Co1—C15—C16—C17	59.8 (2)
C14—Co1—C2—C3	59.4 (3)	C14—C15—C16—Co1	−59.4 (2)
C16—Co1—C2—C1	−100.8 (2)	C2—Co1—C16—C17	139.3 (2)
C17—Co1—C2—C1	−63.4 (3)	C18—Co1—C16—C17	−37.6 (2)
C15—Co1—C2—C1	−144.14 (19)	C15—Co1—C16—C17	−119.3 (3)
C5—Co1—C2—C1	38.55 (19)	C5—Co1—C16—C17	59.2 (3)
C3—Co1—C2—C1	119.7 (3)	C1—Co1—C16—C17	95.0 (2)
C4—Co1—C2—C1	82.4 (2)	C3—Co1—C16—C17	176.8 (2)
C14—Co1—C2—C1	179.09 (19)	C14—Co1—C16—C17	−81.8 (2)
C1—C2—C3—C4	0.0 (4)	C2—Co1—C16—C15	−101.5 (2)
Co1—C2—C3—C4	59.4 (2)	C18—Co1—C16—C15	81.7 (2)
C1—C2—C3—Co1	−59.4 (2)	C17—Co1—C16—C15	119.3 (3)
C16—Co1—C3—C4	178.5 (2)	C5—Co1—C16—C15	178.5 (2)
C2—Co1—C3—C4	−119.6 (3)	C1—Co1—C16—C15	−145.7 (2)
C18—Co1—C3—C4	59.2 (3)	C3—Co1—C16—C15	−63.9 (3)
C15—Co1—C3—C4	140.0 (2)	C14—Co1—C16—C15	37.4 (2)
C5—Co1—C3—C4	−37.5 (2)	C15—C16—C17—C18	−0.6 (4)
C1—Co1—C3—C4	−81.7 (2)	Co1—C16—C17—C18	59.2 (2)
C14—Co1—C3—C4	95.9 (2)	C15—C16—C17—Co1	−59.8 (2)
C16—Co1—C3—C2	−61.9 (3)	C2—Co1—C17—C16	−62.0 (3)
C18—Co1—C3—C2	178.8 (2)	C18—Co1—C17—C16	119.4 (3)
C15—Co1—C3—C2	−100.4 (2)	C15—Co1—C17—C16	37.6 (2)
C5—Co1—C3—C2	82.1 (2)	C5—Co1—C17—C16	−144.8 (2)
C1—Co1—C3—C2	37.9 (2)	C1—Co1—C17—C16	−100.7 (2)
C4—Co1—C3—C2	119.6 (3)	C4—Co1—C17—C16	178.7 (2)
C14—Co1—C3—C2	−144.5 (2)	C14—Co1—C17—C16	81.8 (2)
C2—C3—C4—C5	−0.2 (4)	C16—Co1—C17—C18	−119.4 (3)
Co1—C3—C4—C5	58.5 (2)	C2—Co1—C17—C18	178.6 (2)
C2—C3—C4—Co1	−58.7 (2)	C15—Co1—C17—C18	−81.8 (2)
C2—Co1—C4—C3	37.6 (2)	C5—Co1—C17—C18	95.8 (2)
C18—Co1—C4—C3	−145.5 (2)	C1—Co1—C17—C18	139.8 (2)
C17—Co1—C4—C3	176.7 (2)	C4—Co1—C17—C18	59.3 (3)
C15—Co1—C4—C3	−62.0 (3)	C14—Co1—C17—C18	−37.7 (2)
C5—Co1—C4—C3	119.7 (3)	C16—C17—C18—C14	0.6 (4)
C1—Co1—C4—C3	82.1 (2)	Co1—C17—C18—C14	59.7 (2)
C14—Co1—C4—C3	−101.0 (2)	C16—C17—C18—Co1	−59.1 (2)
C2—Co1—C4—C5	−82.2 (2)	C15—C14—C18—C17	−0.4 (4)
C18—Co1—C4—C5	94.8 (2)	P2—C14—C18—C17	−179.9 (2)
C17—Co1—C4—C5	57.0 (3)	Co1—C14—C18—C17	−59.4 (2)
C15—Co1—C4—C5	178.3 (2)	C15—C14—C18—Co1	59.0 (2)
C1—Co1—C4—C5	−37.6 (2)	P2—C14—C18—Co1	−120.5 (2)
C3—Co1—C4—C5	−119.7 (3)	C16—Co1—C18—C17	37.4 (2)
C14—Co1—C4—C5	139.2 (2)	C15—Co1—C18—C17	81.2 (2)
C3—C4—C5—C1	0.3 (4)	C5—Co1—C18—C17	−101.6 (2)
Co1—C4—C5—C1	59.1 (2)	C1—Co1—C18—C17	−61.4 (3)
C3—C4—C5—Co1	−58.8 (2)	C3—Co1—C18—C17	176.8 (3)
C2—C1—C5—C4	−0.3 (4)	C4—Co1—C18—C17	−145.6 (2)
P1—C1—C5—C4	−177.8 (2)	C14—Co1—C18—C17	119.7 (3)
Co1—C1—C5—C4	−59.5 (2)	C16—Co1—C18—C14	−82.3 (2)
C2—C1—C5—Co1	59.2 (2)	C17—Co1—C18—C14	−119.7 (3)
P1—C1—C5—Co1	−118.3 (3)	C15—Co1—C18—C14	−38.56 (19)
C16—Co1—C5—C4	175.8 (2)	C5—Co1—C18—C14	138.70 (19)
C2—Co1—C5—C4	81.1 (2)	C1—Co1—C18—C14	178.82 (18)
C18—Co1—C5—C4	−103.0 (2)	C3—Co1—C18—C14	57.0 (3)
C17—Co1—C5—C4	−146.9 (2)	C4—Co1—C18—C14	94.6 (2)
C1—Co1—C5—C4	119.9 (3)	P2—C19—C20—C21	61.7 (5)
C3—Co1—C5—C4	37.2 (2)	P2—C19—C20—C22	−174.4 (3)
C14—Co1—C5—C4	−63.5 (3)	P2—C23—C24—C25	61.3 (5)
C16—Co1—C5—C1	56.0 (3)	P2—C23—C24—C26	−173.6 (3)
C2—Co1—C5—C1	−38.82 (19)	C5—C1—P1—C6	4.9 (3)
C18—Co1—C5—C1	137.2 (2)	C2—C1—P1—C6	−172.2 (3)
C17—Co1—C5—C1	93.2 (2)	Co1—C1—P1—C6	−86.4 (2)
C3—Co1—C5—C1	−82.7 (2)	C5—C1—P1—C10	−97.0 (3)
C4—Co1—C5—C1	−119.9 (3)	C2—C1—P1—C10	85.8 (3)
C14—Co1—C5—C1	176.62 (19)	Co1—C1—P1—C10	171.7 (2)
P1—C6—C7—C8	−67.0 (5)	C7—C6—P1—C1	171.4 (3)
P1—C6—C7—C9	171.0 (3)	C7—C6—P1—C10	−87.7 (3)
P1—C10—C11—C13	−59.7 (5)	C11—C10—P1—C1	−70.1 (3)
P1—C10—C11—C12	176.3 (3)	C11—C10—P1—C6	−173.2 (3)
C16—Co1—C14—C15	−37.1 (2)	C15—C14—P2—C23	−0.1 (3)
C2—Co1—C14—C15	57.9 (3)	C18—C14—P2—C23	179.4 (3)
C18—Co1—C14—C15	−117.8 (3)	Co1—C14—P2—C23	92.0 (2)
C17—Co1—C14—C15	−80.5 (2)	C15—C14—P2—C19	100.6 (3)
C5—Co1—C14—C15	177.6 (2)	C18—C14—P2—C19	−79.9 (3)
C3—Co1—C14—C15	95.4 (2)	Co1—C14—P2—C19	−167.2 (2)
C4—Co1—C14—C15	139.0 (2)	C24—C23—P2—C14	179.3 (3)
C16—Co1—C14—C18	80.7 (2)	C24—C23—P2—C19	78.8 (3)
C2—Co1—C14—C18	175.7 (2)	C20—C19—P2—C14	81.0 (3)
C17—Co1—C14—C18	37.3 (2)	C20—C19—P2—C23	−178.3 (3)

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
C3—H3···F5ⁱ	0.98	2.44	3.237 (5)	138
C15—H15···F4ⁱ	0.98	2.39	3.278 (4)	150
C17—H17···F2	0.98	2.51	3.188 (5)	126
C18—H18···F6	0.98	2.41	3.305 (4)	152
C19—H19B···F2ⁱⁱ	0.97	2.54	3.494 (4)	167

Symmetry codes: (i) x, y−1, z; (ii) −x+3/2, y−1/2, −z+1/2.

Experimental details

Crystal data
Chemical formula	[Co(C₁₃H₂₂P)₂]·PF₆
M_r	622.45
Crystal system, space group	Monoclinic, P2₁/n
Temperature (K)	298
a, b, c (Å)	16.7733 (3), 10.4660 (2), 18.5105 (4)
β (°)	108.288 (1)
V (Å³)	3085.38 (10)
Z	4
Radiation type	Mo Kα
µ (mm⁻¹)	0.76
Crystal size (mm)	0.40 × 0.04 × 0.02

Data collection
Diffractometer	Bruker SMART CCD area-detector diffractometer
Absorption correction	Multi-scan (SADABS; Sheldrick, 2004)
T_min, T_max	0.750, 0.985
No. of measured, independent and observed [I > 2σ(I)] reflections	33818, 6733, 3878
R_int	0.083
(sin θ/λ)_max (Å⁻¹)	0.639

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.056, 0.147, 0.97
No. of reflections	6733
No. of parameters	333
H-atom treatment	H-atom parameters constrained
Δρ_max, Δρ_min (e Å⁻³)	0.47, −0.34

Computer programs: SMART (Bruker, 2001), SAINT (Bruker, 2001), SHELXS97 (Sheldrick, 2008), SHELXTL (Sheldrick, 2008).