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The hexa­lithium ethyl­enedi­amine octa­selenido tetra­ferrate was synthesized in solution, to be the first lithium-containing compound with chalcogenido tetra­ferrate cluster anions.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S205698902201060X/jq2021sup1.cif
Contains datablock I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S205698902201060X/jq2021Isup2.hkl
Contains datablock I

CCDC reference: 2217266

Computing details top

Data collection: APEX4 (Bruker, 2021); cell refinement: SAINT (Bruker, 2016); data reduction: SAINT (Bruker, 2016); program(s) used to solve structure: SHELXT2018/2 (Sheldrick, 2015a); program(s) used to refine structure: SHELXL (Sheldrick, 2015b); molecular graphics: Olex2 (Dolomanov et al., 2009); software used to prepare material for publication: Olex2 (Dolomanov et al., 2009).

Poly[[tricosa(µ-ethylenediamine)dodecalithium] bis[octaselenidotetraferrate(II/III)]] top
Crystal data top
[Li6(C2H8N2)11.5][Fe4Se8]Z = 2
Mr = 1587.91F(000) = 1570
Triclinic, P1Dx = 1.824 Mg m3
a = 11.495 (2) ÅMo Kα radiation, λ = 0.71073 Å
b = 11.665 (3) ÅCell parameters from 9368 reflections
c = 22.233 (5) Åθ = 2.4–25.4°
α = 92.885 (8)°µ = 6.06 mm1
β = 92.383 (7)°T = 100 K
γ = 103.510 (7)°Block, dark black
V = 2890.9 (11) Å30.8 × 0.6 × 0.4 mm
Data collection top
Bruker APEXII CCD
diffractometer
9144 reflections with I > 2σ(I)
Radiation source: sealed X-ray tubeRint = 0.081
φ and ω scansθmax = 25.5°, θmin = 2.2°
Absorption correction: multi-scan
(SADABS; Krause et al., 2015)
h = 1313
Tmin = 0.323, Tmax = 0.745k = 1414
178309 measured reflectionsl = 2626
10708 independent reflections
Refinement top
Refinement on F2Primary atom site location: dual
Least-squares matrix: fullHydrogen site location: mixed
R[F2 > 2σ(F2)] = 0.030H atoms treated by a mixture of independent and constrained refinement
wR(F2) = 0.059 w = 1/[σ2(Fo2) + 11.5642P]
where P = (Fo2 + 2Fc2)/3
S = 1.10(Δ/σ)max = 0.002
10708 reflectionsΔρmax = 0.65 e Å3
752 parametersΔρmin = 0.64 e Å3
193 restraints
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Se10.23309 (3)0.31834 (3)0.82278 (2)0.00859 (8)
Se20.51559 (3)0.44704 (3)0.80634 (2)0.01022 (8)
Se30.47570 (3)0.02579 (3)0.62160 (2)0.01098 (8)
Se40.36270 (3)0.31909 (3)0.66142 (2)0.00930 (8)
Se50.28008 (3)0.02291 (3)0.88460 (2)0.01085 (8)
Se60.51956 (3)0.09741 (3)0.78576 (2)0.00885 (8)
Se70.19676 (3)0.08788 (3)0.71572 (2)0.00948 (8)
Se80.00915 (3)0.41635 (3)0.67346 (2)0.01008 (8)
Fe10.42062 (4)0.30404 (5)0.77046 (2)0.00816 (11)
Fe20.18670 (4)0.29485 (5)0.71569 (2)0.00838 (11)
Fe30.39696 (4)0.11194 (5)0.69146 (2)0.00849 (11)
Fe40.30805 (4)0.11068 (5)0.80853 (2)0.00818 (11)
N10.4973 (3)0.8434 (3)0.94248 (15)0.0136 (7)
H1A0.448 (3)0.892 (3)0.9340 (18)0.016*
H1B0.490 (4)0.802 (3)0.9063 (10)0.016*
N20.6222 (3)0.8083 (3)0.57712 (14)0.0126 (7)
H2A0.591 (3)0.873 (2)0.5816 (18)0.015*
H2B0.571 (3)0.757 (3)0.5986 (16)0.015*
N30.5391 (3)0.2755 (3)0.90791 (14)0.0138 (7)
H3A0.534 (4)0.3467 (19)0.8947 (18)0.017*
H3B0.4601 (13)0.238 (3)0.9060 (19)0.017*
N40.0699 (3)0.8309 (3)0.61730 (15)0.0139 (7)
H4A0.026 (3)0.891 (2)0.6417 (15)0.017*
H4B0.039 (3)0.772 (3)0.6314 (18)0.017*
N50.1591 (3)0.5663 (3)0.52773 (15)0.0157 (7)
H5A0.223 (2)0.534 (3)0.5327 (19)0.019*
H5B0.146 (4)0.585 (4)0.5667 (7)0.019*
N70.3681 (3)0.5696 (3)0.94751 (15)0.0156 (7)
H7A0.425 (3)0.562 (4)0.9216 (15)0.019*
H7B0.313 (3)0.594 (4)0.9239 (16)0.019*
N80.2417 (3)1.0029 (3)0.32400 (15)0.0135 (7)
H8A0.3213 (12)1.006 (4)0.3250 (19)0.016*
H8B0.205 (3)0.982 (4)0.2869 (9)0.016*
N90.1297 (3)0.7187 (3)0.40169 (14)0.0118 (7)
H9A0.0574 (19)0.734 (4)0.4077 (18)0.014*
H9B0.110 (3)0.6404 (12)0.3901 (18)0.014*
N100.1535 (3)0.5881 (3)0.81593 (15)0.0135 (7)
H10A0.2307 (14)0.574 (4)0.8008 (17)0.016*
H10B0.101 (3)0.591 (4)0.7863 (13)0.016*
N120.0773 (3)0.1331 (3)0.78714 (17)0.0180 (8)
H12A0.134 (3)0.111 (4)0.8107 (16)0.022*
H12B0.063 (4)0.084 (3)0.7533 (12)0.022*
N130.2564 (3)0.3522 (3)0.86096 (15)0.0153 (7)
H13A0.290 (3)0.290 (3)0.8659 (19)0.018*
H13B0.317 (3)0.413 (3)0.8513 (19)0.018*
N140.0117 (3)0.4141 (3)0.79762 (15)0.0134 (7)
H14A0.000 (4)0.448 (3)0.7626 (11)0.016*
H14B0.064 (3)0.468 (3)0.8216 (15)0.016*
N150.4007 (3)0.7894 (3)0.49376 (15)0.0146 (7)
H15A0.409 (4)0.824 (3)0.5317 (8)0.018*
H15B0.425 (4)0.849 (3)0.4688 (16)0.018*
N160.0241 (3)0.7795 (3)0.91254 (15)0.0146 (7)
H16A0.077 (3)0.8511 (19)0.9124 (19)0.018*
H16B0.064 (3)0.736 (3)0.8897 (16)0.018*
N170.1663 (3)0.8433 (3)0.55308 (15)0.0163 (7)
H17A0.234 (2)0.898 (3)0.5658 (18)0.020*
H17B0.150 (4)0.802 (3)0.5863 (12)0.020*
N180.7145 (3)0.7742 (3)0.89574 (16)0.0162 (7)
H18A0.685 (4)0.810 (4)0.8649 (13)0.019*
H18B0.659 (3)0.705 (2)0.8959 (19)0.019*
N190.2420 (3)0.7809 (3)0.99544 (16)0.0174 (7)
H19A0.248 (4)0.814 (4)0.9592 (10)0.021*
H19B0.240 (4)0.842 (3)1.0221 (15)0.021*
N200.0885 (4)0.1079 (3)0.80260 (17)0.0193 (8)
H20A0.019 (4)0.115 (4)0.789 (2)0.023*
H20B0.142 (4)0.108 (4)0.775 (2)0.023*
N210.7131 (3)0.6615 (3)0.68026 (14)0.0129 (7)
H21A0.784 (2)0.657 (4)0.6988 (17)0.015*
H21B0.650 (2)0.646 (4)0.7040 (15)0.015*
N220.4619 (3)0.2194 (3)0.77482 (15)0.0156 (7)
H22A0.416 (3)0.152 (2)0.7881 (18)0.019*
H22B0.433 (4)0.280 (3)0.7899 (18)0.019*
N230.5410 (3)0.3981 (3)0.67015 (15)0.0141 (7)
H23A0.489 (3)0.425 (4)0.6460 (16)0.017*
H23B0.542 (4)0.438 (3)0.7062 (10)0.017*
C10.6909 (3)0.5686 (3)0.63090 (17)0.0123 (8)
H1C0.7625640.5809500.6066200.015*
H1D0.6233100.5792310.6044160.015*
C20.6124 (3)0.7679 (4)0.51350 (17)0.0177 (9)
H2C0.6619280.7097420.5076130.021*
H2D0.6451660.8359940.4893970.021*
C30.2137 (3)0.3794 (4)0.92042 (18)0.0173 (9)
H3C0.1764910.3039720.9378630.021*
H3D0.1503010.4229830.9143530.021*
C40.5863 (3)0.2379 (4)0.79921 (17)0.0136 (8)
H4C0.6281530.3209330.7941290.016*
H4D0.6265670.1869160.7747970.016*
C50.1255 (3)0.6950 (4)0.99522 (18)0.0180 (9)
H5C0.1131720.6685701.0365830.022*
H5D0.1287430.6250570.9687810.022*
C60.6203 (3)0.9169 (3)0.95251 (17)0.0140 (8)
H6A0.6272670.9637980.9914280.017*
H6B0.6372590.9727220.9201020.017*
C70.0182 (3)0.7406 (4)0.97419 (18)0.0175 (9)
H7C0.0553470.6772520.9766730.021*
H7D0.0118570.8076421.0019540.021*
C80.0500 (3)0.8437 (4)0.55319 (18)0.0155 (8)
H8C0.1082370.8855110.5360730.019*
H8D0.0666620.7640260.5324320.019*
C90.0345 (4)0.1159 (4)0.8184 (2)0.0183 (9)
H9C0.0983900.1277960.7898210.022*
H9D0.0241730.1778120.8516630.022*
C110.1833 (4)0.7927 (3)0.35333 (17)0.0151 (8)
H11A0.1360810.7659710.3148230.018*
H11B0.2659870.7839630.3481700.018*
C120.6014 (3)0.2127 (3)0.86527 (16)0.0121 (8)
H12C0.5720220.1267660.8691370.015*
H12D0.6879530.2338090.8773190.015*
C130.0556 (3)0.4759 (3)0.50163 (17)0.0119 (8)
H13C0.0416530.4066520.5266900.014*
H13D0.0727000.4494220.4606230.014*
C140.1363 (4)0.4963 (3)0.85624 (17)0.0143 (8)
H14C0.2110550.4690100.8773470.017*
H14D0.0722240.5326400.8872390.017*
C150.1040 (3)0.3892 (3)0.82603 (18)0.0143 (8)
H15C0.1025450.3305530.8565640.017*
H15D0.1677340.3527950.7948770.017*
C160.0761 (3)0.9104 (3)0.53955 (18)0.0153 (8)
H16C0.0772910.9276220.4963950.018*
H16D0.0969340.9867400.5637070.018*
C170.4843 (4)0.7115 (4)0.48997 (19)0.0207 (9)
H17C0.4857770.6835820.4472830.025*
H17D0.4532120.6414050.5130200.025*
C180.6626 (3)0.4420 (3)0.64901 (17)0.0132 (8)
H18C0.6731240.3902640.6139660.016*
H18D0.7215790.4347510.6814760.016*
C190.0765 (4)0.0038 (4)0.8445 (2)0.0218 (9)
H19C0.0195290.0093230.8781980.026*
H19D0.1552640.0070290.8616020.026*
C200.7115 (3)0.8423 (3)0.95328 (17)0.0142 (8)
H20C0.7919110.8944700.9632000.017*
H20D0.6936410.7866260.9856730.017*
C220.3085 (4)0.4515 (4)0.96621 (18)0.0179 (9)
H22C0.2703390.4610471.0046610.021*
H22D0.3701990.4065160.9739090.021*
C230.1855 (3)0.9217 (3)0.36872 (18)0.0134 (8)
H23C0.1022210.9293840.3727730.016*
H23D0.2293330.9459970.4083130.016*
Li10.7577 (5)0.8246 (6)0.6421 (3)0.0141 (14)
Li20.4064 (6)0.7262 (6)1.0017 (3)0.0162 (14)
Li50.2141 (5)0.7278 (6)0.4896 (3)0.0129 (13)
Li60.1309 (5)0.7527 (6)0.8581 (3)0.0154 (14)
Li40.1373 (6)0.3128 (6)0.7847 (3)0.0170 (14)
N60.2336 (6)0.3899 (6)0.71564 (18)0.0195 (9)0.935 (8)
H6C0.3101 (18)0.383 (4)0.721 (2)0.023*0.935 (8)
H6D0.239 (4)0.4674 (15)0.725 (2)0.023*0.935 (8)
C100.2073 (5)0.3661 (4)0.64990 (19)0.0177 (10)0.935 (8)
H10C0.2777230.4053880.6281820.021*0.935 (8)
H10D0.1388890.3992500.6373140.021*0.935 (8)
C210.1775 (4)0.2355 (4)0.6335 (2)0.0198 (11)0.935 (8)
H21C0.1063290.1967340.6548490.024*0.935 (8)
H21D0.1573300.2215810.5896340.024*0.935 (8)
N240.2752 (4)0.1837 (4)0.6490 (3)0.0335 (13)0.935 (8)
H24A0.276 (5)0.186 (5)0.6897 (6)0.040*0.935 (8)
H24B0.271 (5)0.1061 (15)0.640 (2)0.040*0.935 (8)
Li30.4551 (6)0.2192 (6)0.6823 (3)0.0170 (14)
N6A0.221 (8)0.375 (8)0.7090 (15)0.020 (4)0.065 (8)
H6AA0.2358800.4549900.7117340.024*0.065 (8)
H6AB0.2930280.3549760.7088730.024*0.065 (8)
C10A0.155 (6)0.332 (7)0.6506 (16)0.021 (3)0.065 (8)
H10E0.0820520.2710920.6582740.025*0.065 (8)
H10F0.1293970.3981550.6326690.025*0.065 (8)
C21A0.224 (4)0.280 (5)0.6064 (18)0.022 (3)0.065 (8)
H21E0.1669010.2353140.5741210.026*0.065 (8)
H21F0.2782370.3456600.5876200.026*0.065 (8)
N24A0.294 (4)0.203 (5)0.629 (3)0.025 (3)0.065 (8)
H24C0.3069510.1619160.5952300.030*0.065 (8)
H24D0.2400960.1506780.6490500.030*0.065 (8)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Se10.00745 (17)0.01009 (19)0.00859 (18)0.00206 (14)0.00235 (13)0.00248 (14)
Se20.00890 (18)0.01060 (19)0.01223 (19)0.00395 (15)0.00204 (14)0.00199 (15)
Se30.01273 (18)0.01107 (19)0.01146 (18)0.00579 (15)0.00575 (14)0.00452 (15)
Se40.00803 (17)0.01185 (19)0.00829 (18)0.00278 (14)0.00216 (13)0.00026 (14)
Se50.01063 (18)0.0120 (2)0.00995 (18)0.00294 (15)0.00167 (14)0.00080 (15)
Se60.00723 (17)0.00982 (19)0.00919 (18)0.00113 (14)0.00079 (13)0.00152 (14)
Se70.00895 (17)0.01200 (19)0.00890 (18)0.00486 (15)0.00133 (14)0.00209 (15)
Se80.00716 (17)0.0118 (2)0.01137 (18)0.00250 (15)0.00047 (14)0.00072 (15)
Fe10.0070 (2)0.0093 (3)0.0088 (3)0.0025 (2)0.0019 (2)0.0016 (2)
Fe20.0068 (2)0.0102 (3)0.0083 (3)0.0021 (2)0.0010 (2)0.0007 (2)
Fe30.0081 (2)0.0097 (3)0.0083 (3)0.0029 (2)0.0020 (2)0.0020 (2)
Fe40.0081 (2)0.0090 (3)0.0078 (3)0.0023 (2)0.0014 (2)0.0015 (2)
N10.0103 (16)0.0163 (19)0.0150 (17)0.0044 (14)0.0014 (13)0.0031 (14)
N20.0105 (16)0.0159 (18)0.0134 (17)0.0074 (14)0.0009 (13)0.0005 (14)
N30.0100 (16)0.0203 (19)0.0124 (17)0.0060 (14)0.0001 (13)0.0021 (14)
N40.0136 (17)0.0142 (18)0.0149 (17)0.0045 (14)0.0004 (13)0.0041 (14)
N50.0135 (17)0.0185 (19)0.0142 (17)0.0022 (14)0.0012 (14)0.0010 (15)
N70.0177 (18)0.0172 (19)0.0129 (17)0.0050 (15)0.0022 (14)0.0036 (14)
N80.0129 (16)0.0155 (18)0.0126 (17)0.0041 (14)0.0004 (13)0.0034 (14)
N90.0103 (16)0.0101 (17)0.0144 (17)0.0009 (14)0.0015 (13)0.0028 (14)
N100.0093 (16)0.0172 (18)0.0171 (18)0.0081 (14)0.0031 (13)0.0045 (14)
N120.0160 (18)0.0123 (18)0.028 (2)0.0057 (15)0.0062 (15)0.0043 (15)
N130.0128 (17)0.0168 (19)0.0176 (18)0.0045 (14)0.0067 (14)0.0053 (15)
N140.0099 (16)0.0141 (18)0.0169 (18)0.0031 (14)0.0019 (13)0.0055 (14)
N150.0120 (16)0.0206 (19)0.0119 (17)0.0044 (14)0.0017 (13)0.0032 (14)
N160.0079 (16)0.0178 (19)0.0180 (18)0.0027 (14)0.0013 (13)0.0015 (15)
N170.0138 (17)0.023 (2)0.0137 (17)0.0068 (15)0.0013 (14)0.0022 (15)
N180.0081 (16)0.0187 (19)0.0211 (19)0.0029 (14)0.0002 (14)0.0029 (15)
N190.0148 (17)0.021 (2)0.0158 (18)0.0020 (15)0.0009 (14)0.0042 (15)
N200.025 (2)0.0123 (18)0.021 (2)0.0047 (16)0.0019 (16)0.0015 (15)
N210.0092 (16)0.0157 (18)0.0143 (17)0.0036 (14)0.0017 (13)0.0028 (14)
N220.0154 (17)0.0153 (19)0.0153 (18)0.0018 (14)0.0009 (14)0.0044 (14)
N230.0164 (17)0.0138 (18)0.0118 (17)0.0029 (14)0.0005 (14)0.0003 (14)
C10.0104 (18)0.014 (2)0.0123 (19)0.0033 (16)0.0016 (15)0.0011 (16)
C20.0113 (19)0.029 (2)0.014 (2)0.0075 (18)0.0002 (16)0.0001 (18)
C30.014 (2)0.020 (2)0.019 (2)0.0035 (17)0.0080 (16)0.0029 (17)
C40.0127 (19)0.015 (2)0.014 (2)0.0040 (16)0.0027 (15)0.0009 (16)
C50.018 (2)0.020 (2)0.015 (2)0.0017 (18)0.0015 (16)0.0050 (17)
C60.016 (2)0.013 (2)0.0120 (19)0.0021 (16)0.0002 (15)0.0010 (16)
C70.014 (2)0.024 (2)0.014 (2)0.0031 (17)0.0062 (16)0.0004 (17)
C80.015 (2)0.014 (2)0.019 (2)0.0056 (17)0.0013 (16)0.0001 (17)
C90.016 (2)0.011 (2)0.028 (2)0.0025 (17)0.0021 (17)0.0045 (18)
C110.019 (2)0.014 (2)0.012 (2)0.0027 (17)0.0023 (16)0.0026 (16)
C120.0121 (19)0.014 (2)0.0126 (19)0.0078 (16)0.0002 (15)0.0007 (16)
C130.0121 (19)0.012 (2)0.0115 (19)0.0013 (16)0.0025 (15)0.0016 (15)
C140.019 (2)0.011 (2)0.015 (2)0.0054 (16)0.0036 (16)0.0024 (16)
C150.0102 (18)0.014 (2)0.019 (2)0.0027 (16)0.0039 (15)0.0031 (17)
C160.017 (2)0.013 (2)0.017 (2)0.0044 (17)0.0036 (16)0.0052 (17)
C170.016 (2)0.032 (3)0.015 (2)0.0097 (19)0.0016 (16)0.0083 (18)
C180.0135 (19)0.013 (2)0.0132 (19)0.0050 (16)0.0014 (15)0.0001 (16)
C190.025 (2)0.013 (2)0.029 (2)0.0053 (18)0.0082 (19)0.0025 (18)
C200.0130 (19)0.015 (2)0.015 (2)0.0037 (16)0.0010 (15)0.0009 (16)
C220.021 (2)0.018 (2)0.014 (2)0.0029 (18)0.0031 (16)0.0046 (17)
C230.0102 (18)0.013 (2)0.017 (2)0.0028 (16)0.0012 (15)0.0023 (16)
Li10.009 (3)0.017 (4)0.018 (3)0.006 (3)0.001 (3)0.004 (3)
Li20.015 (3)0.020 (4)0.013 (3)0.002 (3)0.001 (3)0.003 (3)
Li50.011 (3)0.016 (3)0.010 (3)0.001 (3)0.001 (2)0.000 (3)
Li60.007 (3)0.015 (4)0.023 (4)0.002 (3)0.000 (3)0.003 (3)
Li40.011 (3)0.014 (4)0.025 (3)0.001 (3)0.001 (3)0.002 (3)
N60.020 (2)0.019 (3)0.0166 (19)0.0016 (17)0.0021 (17)0.0056 (17)
C100.013 (2)0.020 (2)0.021 (2)0.0058 (18)0.0039 (17)0.0005 (18)
C210.019 (2)0.020 (2)0.021 (2)0.0077 (18)0.0066 (18)0.0024 (18)
N240.015 (2)0.015 (2)0.072 (3)0.0062 (17)0.001 (2)0.007 (2)
Li30.017 (3)0.016 (4)0.020 (4)0.008 (3)0.001 (3)0.002 (3)
N6A0.017 (6)0.019 (6)0.022 (5)0.002 (6)0.002 (5)0.002 (5)
C10A0.017 (5)0.019 (5)0.025 (4)0.004 (5)0.005 (4)0.003 (5)
C21A0.016 (5)0.017 (5)0.034 (5)0.007 (4)0.004 (5)0.001 (5)
N24A0.018 (6)0.017 (6)0.041 (6)0.006 (5)0.004 (6)0.005 (6)
Geometric parameters (Å, º) top
Se1—Fe12.4674 (7)N21—H21A0.909 (10)
Se1—Fe22.4611 (8)N21—H21B0.908 (10)
Se1—Fe42.4157 (8)N21—C11.473 (5)
Se2—Fe12.3502 (7)N21—Li12.084 (7)
Se3—Fe32.3456 (7)N22—H22A0.905 (10)
Se3—Li32.634 (7)N22—H22B0.907 (10)
Se4—Fe12.4739 (8)N22—C41.471 (5)
Se4—Fe22.4629 (7)N22—Li32.055 (8)
Se4—Fe32.4108 (8)N23—H23A0.906 (10)
Se5—Fe42.3251 (8)N23—H23B0.906 (10)
Se6—Fe12.4133 (8)N23—C181.477 (5)
Se6—Fe32.4531 (8)N23—Li32.126 (8)
Se6—Fe42.4752 (8)C1—H1C0.9900
Se7—Fe22.3899 (8)C1—H1D0.9900
Se7—Fe32.4608 (8)C1—C181.516 (5)
Se7—Fe42.4414 (7)C2—H2C0.9900
Se8—Fe22.3262 (7)C2—H2D0.9900
Fe1—Fe22.9327 (9)C2—C171.524 (5)
Fe1—Fe32.9702 (9)C3—H3C0.9900
Fe1—Fe42.9566 (9)C3—H3D0.9900
Fe2—Fe32.9154 (9)C3—C221.524 (6)
Fe2—Fe42.9556 (9)C4—H4C0.9900
Fe3—Fe42.8362 (9)C4—H4D0.9900
N1—H1A0.907 (10)C4—C121.523 (5)
N1—H1B0.908 (10)C5—H5C0.9900
N1—C61.474 (5)C5—H5D0.9900
N1—Li22.079 (7)C5—C71.519 (5)
N2—H2A0.907 (10)C6—H6A0.9900
N2—H2B0.907 (10)C6—H6B0.9900
N2—C21.460 (5)C6—C201.511 (5)
N2—Li12.049 (7)C7—H7C0.9900
N3—H3A0.909 (10)C7—H7D0.9900
N3—H3B0.909 (10)C8—H8C0.9900
N3—C121.476 (5)C8—H8D0.9900
N3—Li2i2.082 (7)C8—C161.527 (5)
N4—H4A0.906 (10)C9—H9C0.9900
N4—H4B0.907 (10)C9—H9D0.9900
N4—C81.463 (5)C9—C191.519 (5)
N4—Li1ii2.065 (7)C11—H11A0.9900
N5—H5A0.908 (10)C11—H11B0.9900
N5—H5B0.908 (10)C11—C231.521 (5)
N5—C131.470 (5)C12—H12C0.9900
N5—Li52.077 (7)C12—H12D0.9900
N7—H7A0.907 (10)C13—C13vi1.513 (7)
N7—H7B0.908 (10)C13—H13C0.9900
N7—C221.477 (5)C13—H13D0.9900
N7—Li22.085 (8)C14—H14C0.9900
N8—H8A0.907 (10)C14—H14D0.9900
N8—H8B0.906 (10)C14—C151.518 (5)
N8—C231.471 (5)C15—H15C0.9900
N8—Li1iii2.111 (8)C15—H15D0.9900
N9—H9A0.906 (10)C16—H16C0.9900
N9—H9B0.910 (10)C16—H16D0.9900
N9—C111.476 (5)C17—H17C0.9900
N9—Li52.133 (7)C17—H17D0.9900
N10—H10A0.909 (7)C18—H18C0.9900
N10—H10B0.910 (7)C18—H18D0.9900
N10—C141.474 (5)C19—H19C0.9900
N10—Li62.049 (8)C19—H19D0.9900
N12—H12A0.905 (10)C20—H20C0.9900
N12—H12B0.908 (10)C20—H20D0.9900
N12—C91.464 (5)C22—H22C0.9900
N12—Li42.052 (8)C22—H22D0.9900
N13—H13A0.908 (10)C23—H23C0.9900
N13—H13B0.908 (10)C23—H23D0.9900
N13—C31.474 (5)Li1—H2B2.26 (4)
N13—Li42.097 (8)Li2—H7B2.31 (4)
N14—H14A0.908 (10)Li4—H14B2.30 (4)
N14—H14B0.902 (10)Li4—N62.051 (8)
N14—C151.469 (5)Li4—N6A2.05 (2)
N14—Li42.088 (7)N6—H6C0.907 (10)
N15—H15A0.909 (10)N6—H6D0.903 (10)
N15—H15B0.909 (10)N6—C101.479 (6)
N15—C171.470 (5)C10—H10C0.9900
N15—Li52.094 (7)C10—H10D0.9900
N16—H16A0.909 (10)C10—C211.504 (6)
N16—H16B0.908 (10)C21—H21C0.9900
N16—C71.465 (5)C21—H21D0.9900
N16—Li62.064 (7)C21—N241.431 (6)
N17—H17A0.907 (10)N24—H24A0.902 (10)
N17—H17B0.908 (10)N24—H24B0.906 (10)
N17—C161.468 (5)N24—Li32.107 (8)
N17—Li52.080 (7)Li3—H24A2.01 (6)
N18—H18A0.909 (10)Li3—N24A2.12 (2)
N18—H18B0.907 (10)N6A—H6AA0.9100
N18—C201.477 (5)N6A—H6AB0.9100
N18—Li6iv2.058 (7)N6A—C10A1.48 (2)
N19—H19A0.910 (10)C10A—H10E0.9900
N19—H19B0.907 (10)C10A—H10F0.9900
N19—C51.472 (5)C10A—C21A1.48 (2)
N19—Li22.133 (7)C21A—H21E0.9900
N20—H20A0.89 (5)C21A—H21F0.9900
N20—H20B0.85 (5)C21A—N24A1.44 (2)
N20—C191.469 (6)N24A—H24C0.9100
N20—Li6v2.070 (7)N24A—H24D0.9100
Fe2—Se1—Fe173.03 (2)C18—C1—H1D108.1
Fe4—Se1—Fe174.52 (2)N2—C2—H2C108.9
Fe4—Se1—Fe274.60 (2)N2—C2—H2D108.9
Fe3—Se3—Li398.63 (15)N2—C2—C17113.6 (3)
Fe2—Se4—Fe172.89 (2)H2C—C2—H2D107.7
Fe3—Se4—Fe174.89 (2)C17—C2—H2C108.9
Fe3—Se4—Fe273.47 (2)C17—C2—H2D108.9
Fe1—Se6—Fe375.23 (2)N13—C3—H3C108.3
Fe1—Se6—Fe474.42 (2)N13—C3—H3D108.3
Fe3—Se6—Fe470.27 (2)N13—C3—C22115.9 (3)
Fe2—Se7—Fe373.87 (2)H3C—C3—H3D107.4
Fe2—Se7—Fe475.43 (2)C22—C3—H3C108.3
Fe4—Se7—Fe370.70 (2)C22—C3—H3D108.3
Se1—Fe1—Se4105.83 (3)N22—C4—H4C108.4
Se1—Fe1—Fe253.39 (2)N22—C4—H4D108.4
Se1—Fe1—Fe397.87 (2)N22—C4—C12115.7 (3)
Se1—Fe1—Fe451.944 (18)H4C—C4—H4D107.4
Se2—Fe1—Se1108.31 (2)C12—C4—H4C108.4
Se2—Fe1—Se4117.08 (3)C12—C4—H4D108.4
Se2—Fe1—Se6119.59 (3)N19—C5—H5C108.5
Se2—Fe1—Fe2138.02 (3)N19—C5—H5D108.5
Se2—Fe1—Fe3153.78 (3)N19—C5—C7115.1 (3)
Se2—Fe1—Fe4143.63 (3)H5C—C5—H5D107.5
Se4—Fe1—Fe253.381 (17)C7—C5—H5C108.5
Se4—Fe1—Fe351.589 (19)C7—C5—H5D108.5
Se4—Fe1—Fe498.75 (2)N1—C6—H6A109.3
Se6—Fe1—Se1103.23 (2)N1—C6—H6B109.3
Se6—Fe1—Se4101.23 (2)N1—C6—C20111.5 (3)
Se6—Fe1—Fe2102.13 (2)H6A—C6—H6B108.0
Se6—Fe1—Fe353.00 (2)C20—C6—H6A109.3
Se6—Fe1—Fe453.75 (2)C20—C6—H6B109.3
Fe2—Fe1—Fe359.189 (18)N16—C7—C5113.9 (3)
Fe2—Fe1—Fe460.25 (2)N16—C7—H7C108.8
Fe4—Fe1—Fe357.18 (2)N16—C7—H7D108.8
Se1—Fe2—Se4106.37 (2)C5—C7—H7C108.8
Se1—Fe2—Fe153.582 (17)C5—C7—H7D108.8
Se1—Fe2—Fe399.46 (2)H7C—C7—H7D107.7
Se1—Fe2—Fe452.00 (2)N4—C8—H8C108.6
Se4—Fe2—Fe153.73 (2)N4—C8—H8D108.6
Se4—Fe2—Fe352.44 (2)N4—C8—C16114.7 (3)
Se4—Fe2—Fe499.03 (2)H8C—C8—H8D107.6
Se7—Fe2—Se1101.70 (2)C16—C8—H8C108.6
Se7—Fe2—Se4104.06 (2)C16—C8—H8D108.6
Se7—Fe2—Fe1103.32 (2)N12—C9—H9C108.4
Se7—Fe2—Fe354.18 (2)N12—C9—H9D108.4
Se7—Fe2—Fe453.076 (19)N12—C9—C19115.6 (3)
Se8—Fe2—Se1116.00 (2)H9C—C9—H9D107.4
Se8—Fe2—Se4112.40 (3)C19—C9—H9C108.4
Se8—Fe2—Se7115.01 (3)C19—C9—H9D108.4
Se8—Fe2—Fe1141.65 (3)N9—C11—H11A109.6
Se8—Fe2—Fe3144.53 (3)N9—C11—H11B109.6
Se8—Fe2—Fe4148.55 (3)N9—C11—C23110.4 (3)
Fe1—Fe2—Fe460.28 (2)H11A—C11—H11B108.1
Fe3—Fe2—Fe161.05 (2)C23—C11—H11A109.6
Fe3—Fe2—Fe457.77 (2)C23—C11—H11B109.6
Se3—Fe3—Se4118.26 (3)N3—C12—C4115.6 (3)
Se3—Fe3—Se6114.85 (3)N3—C12—H12C108.4
Se3—Fe3—Se7108.75 (2)N3—C12—H12D108.4
Se3—Fe3—Fe1150.72 (3)C4—C12—H12C108.4
Se3—Fe3—Fe2143.27 (3)C4—C12—H12D108.4
Se3—Fe3—Fe4137.92 (3)H12C—C12—H12D107.4
Se4—Fe3—Se6101.90 (2)N5—C13—C13vi110.8 (4)
Se4—Fe3—Se7103.50 (2)N5—C13—H13C109.5
Se4—Fe3—Fe153.52 (2)N5—C13—H13D109.5
Se4—Fe3—Fe254.084 (19)C13vi—C13—H13C109.5
Se4—Fe3—Fe4103.67 (2)C13vi—C13—H13D109.5
Se6—Fe3—Se7108.66 (3)H13C—C13—H13D108.1
Se6—Fe3—Fe151.778 (19)N10—C14—H14C108.3
Se6—Fe3—Fe2101.62 (2)N10—C14—H14D108.3
Se6—Fe3—Fe455.23 (2)N10—C14—C15115.8 (3)
Se7—Fe3—Fe1100.50 (2)H14C—C14—H14D107.4
Se7—Fe3—Fe251.95 (2)C15—C14—H14C108.3
Se7—Fe3—Fe454.331 (17)C15—C14—H14D108.3
Fe2—Fe3—Fe159.76 (2)N14—C15—C14114.8 (3)
Fe4—Fe3—Fe161.17 (2)N14—C15—H15C108.6
Fe4—Fe3—Fe261.83 (2)N14—C15—H15D108.6
Se1—Fe4—Se6102.93 (2)C14—C15—H15C108.6
Se1—Fe4—Se7101.53 (2)C14—C15—H15D108.6
Se1—Fe4—Fe153.54 (2)H15C—C15—H15D107.5
Se1—Fe4—Fe253.40 (2)N17—C16—C8112.3 (3)
Se1—Fe4—Fe3102.80 (2)N17—C16—H16C109.1
Se5—Fe4—Se1117.39 (3)N17—C16—H16D109.1
Se5—Fe4—Se6114.88 (3)C8—C16—H16C109.1
Se5—Fe4—Se7110.38 (3)C8—C16—H16D109.1
Se5—Fe4—Fe1148.27 (3)H16C—C16—H16D107.9
Se5—Fe4—Fe2144.99 (3)N15—C17—C2115.0 (4)
Se5—Fe4—Fe3139.68 (3)N15—C17—H17C108.5
Se6—Fe4—Fe151.836 (18)N15—C17—H17D108.5
Se6—Fe4—Fe299.98 (2)C2—C17—H17C108.5
Se6—Fe4—Fe354.502 (17)C2—C17—H17D108.5
Se7—Fe4—Se6108.57 (3)H17C—C17—H17D107.5
Se7—Fe4—Fe1101.35 (2)N23—C18—C1115.2 (3)
Se7—Fe4—Fe251.50 (2)N23—C18—H18C108.5
Se7—Fe4—Fe354.97 (2)N23—C18—H18D108.5
Fe2—Fe4—Fe159.48 (2)C1—C18—H18C108.5
Fe3—Fe4—Fe161.652 (19)C1—C18—H18D108.5
Fe3—Fe4—Fe260.40 (2)H18C—C18—H18D107.5
H1A—N1—H1B99 (4)N20—C19—C9116.5 (4)
C6—N1—H1A108 (3)N20—C19—H19C108.2
C6—N1—H1B109 (3)N20—C19—H19D108.2
C6—N1—Li2126.1 (3)C9—C19—H19C108.2
Li2—N1—H1A105 (3)C9—C19—H19D108.2
Li2—N1—H1B106 (3)H19C—C19—H19D107.3
H2A—N2—H2B100 (4)N18—C20—C6114.0 (3)
C2—N2—H2A109 (3)N18—C20—H20C108.8
C2—N2—H2B111 (3)N18—C20—H20D108.8
C2—N2—Li1131.7 (3)C6—C20—H20C108.8
Li1—N2—H2A108 (3)C6—C20—H20D108.8
Li1—N2—H2B92 (3)H20C—C20—H20D107.7
H3A—N3—H3B100 (4)N7—C22—C3114.5 (3)
C12—N3—H3A111 (3)N7—C22—H22C108.6
C12—N3—H3B109 (3)N7—C22—H22D108.6
C12—N3—Li2i114.9 (3)C3—C22—H22C108.6
Li2i—N3—H3A116 (3)C3—C22—H22D108.6
Li2i—N3—H3B104 (3)H22C—C22—H22D107.6
H4A—N4—H4B98 (4)N8—C23—C11114.3 (3)
C8—N4—H4A114 (3)N8—C23—H23C108.7
C8—N4—H4B111 (3)N8—C23—H23D108.7
C8—N4—Li1ii115.7 (3)C11—C23—H23C108.7
Li1ii—N4—H4A102 (3)C11—C23—H23D108.7
Li1ii—N4—H4B114 (3)H23C—C23—H23D107.6
H5A—N5—H5B101 (4)N2—Li1—H2B23.6 (5)
C13—N5—H5A110 (3)N2—Li1—N4iv119.8 (3)
C13—N5—H5B109 (3)N2—Li1—N8iii97.3 (3)
C13—N5—Li5121.3 (3)N2—Li1—N21102.0 (3)
Li5—N5—H5A109 (3)N4iv—Li1—H2B136.0 (10)
Li5—N5—H5B105 (3)N4iv—Li1—N8iii105.9 (3)
H7A—N7—H7B103 (4)N4iv—Li1—N21101.7 (3)
C22—N7—H7A109 (3)N8iii—Li1—H2B103.6 (11)
C22—N7—H7B106 (3)N21—Li1—H2B81.1 (7)
C22—N7—Li2126.1 (3)N21—Li1—N8iii132.1 (3)
Li2—N7—H7A115 (3)N1—Li2—N3i123.8 (4)
Li2—N7—H7B93 (3)N1—Li2—N7100.6 (3)
H8A—N8—H8B113 (4)N1—Li2—H7B92.4 (10)
C23—N8—H8A109 (3)N1—Li2—N1996.7 (3)
C23—N8—H8B111 (3)N3i—Li2—N7119.6 (3)
C23—N8—Li1iii106.9 (3)N3i—Li2—H7B138.6 (9)
Li1iii—N8—H8A101 (3)N3i—Li2—N19109.5 (3)
Li1iii—N8—H8B115 (3)N7—Li2—H7B23.1 (5)
H9A—N9—H9B103 (4)N7—Li2—N19102.7 (3)
C11—N9—H9A107 (3)N19—Li2—H7B82.3 (7)
C11—N9—H9B113 (3)N5—Li5—N9109.6 (3)
C11—N9—Li5122.9 (3)N5—Li5—N15112.6 (3)
Li5—N9—H9A105 (3)N5—Li5—N17102.1 (3)
Li5—N9—H9B105 (3)N15—Li5—N9114.8 (3)
H10A—N10—H10B112 (4)N17—Li5—N9115.7 (3)
C14—N10—H10A112 (3)N17—Li5—N15101.2 (3)
C14—N10—H10B108 (3)N10—Li6—N16106.0 (3)
C14—N10—Li6114.3 (3)N10—Li6—N18ii111.6 (3)
Li6—N10—H10A101 (3)N10—Li6—N20vii115.3 (3)
Li6—N10—H10B109 (3)N16—Li6—N20vii101.4 (3)
H12A—N12—H12B108 (4)N18ii—Li6—N16118.9 (4)
C9—N12—H12A109 (3)N18ii—Li6—N20vii103.7 (3)
C9—N12—H12B107 (3)N12—Li4—N13101.3 (3)
C9—N12—Li4105.0 (3)N12—Li4—N14117.0 (3)
Li4—N12—H12A104 (3)N12—Li4—H14B132.6 (10)
Li4—N12—H12B123 (3)N12—Li4—N6A117 (3)
H13A—N13—H13B105 (4)N13—Li4—H14B84.9 (7)
C3—N13—H13A106 (3)N14—Li4—N13105.8 (3)
C3—N13—H13B110 (3)N14—Li4—H14B23.1 (5)
C3—N13—Li4120.5 (3)N6—Li4—N12122.4 (4)
Li4—N13—H13A109 (3)N6—Li4—N13105.0 (3)
Li4—N13—H13B106 (3)N6—Li4—N14103.6 (4)
H14A—N14—H14B107 (4)N6—Li4—H14B100.2 (11)
C15—N14—H14A107 (3)N6A—Li4—N13111 (2)
C15—N14—H14B108 (3)N6A—Li4—N14104 (4)
C15—N14—Li4131.9 (3)N6A—Li4—H14B104 (3)
Li4—N14—H14A108 (3)Li4—N6—H6C108 (3)
Li4—N14—H14B92 (3)Li4—N6—H6D102 (3)
H15A—N15—H15B106 (4)H6C—N6—H6D103 (4)
C17—N15—H15A108 (3)C10—N6—Li4128.5 (4)
C17—N15—H15B108 (3)C10—N6—H6C104 (3)
C17—N15—Li5123.7 (3)C10—N6—H6D109 (3)
Li5—N15—H15A98 (3)N6—C10—H10C109.5
Li5—N15—H15B112 (3)N6—C10—H10D109.5
H16A—N16—H16B99 (4)N6—C10—C21110.7 (4)
C7—N16—H16A109 (3)H10C—C10—H10D108.1
C7—N16—H16B110 (3)C21—C10—H10C109.5
C7—N16—Li6119.8 (3)C21—C10—H10D109.5
Li6—N16—H16A117 (3)C10—C21—H21C109.3
Li6—N16—H16B98 (3)C10—C21—H21D109.3
H17A—N17—H17B102 (4)H21C—C21—H21D107.9
C16—N17—H17A106 (3)N24—C21—C10111.8 (4)
C16—N17—H17B112 (3)N24—C21—H21C109.3
C16—N17—Li5122.6 (3)N24—C21—H21D109.3
Li5—N17—H17A107 (3)C21—N24—H24A103 (4)
Li5—N17—H17B105 (3)C21—N24—H24B121 (4)
H18A—N18—H18B102 (4)C21—N24—Li3144.7 (4)
C20—N18—H18A110 (3)H24A—N24—H24B101 (5)
C20—N18—H18B108 (3)Li3—N24—H24A72 (4)
C20—N18—Li6iv124.2 (3)Li3—N24—H24B94 (4)
Li6iv—N18—H18A98 (3)Se3—Li3—H24A100.9 (15)
Li6iv—N18—H18B112 (3)N22—Li3—Se3117.6 (3)
H19A—N19—H19B104 (4)N22—Li3—N23100.7 (3)
C5—N19—H19A109 (3)N22—Li3—N24109.6 (4)
C5—N19—H19B108 (3)N22—Li3—H24A84.5 (5)
C5—N19—Li2121.3 (3)N22—Li3—N24A123 (2)
Li2—N19—H19A100 (3)N23—Li3—Se3129.2 (3)
Li2—N19—H19B113 (3)N23—Li3—H24A115.6 (17)
H20A—N20—H20B114 (4)N24—Li3—Se388.4 (3)
C19—N20—H20A113 (3)N24—Li3—N23109.9 (3)
C19—N20—H20B109 (3)N24—Li3—H24A25.2 (4)
C19—N20—Li6v103.1 (3)N24A—Li3—Se386.1 (15)
Li6v—N20—H20A103 (3)N24A—Li3—N23100.3 (16)
Li6v—N20—H20B114 (3)Li4—N6A—H6AA108.3
H21A—N21—H21B114 (4)Li4—N6A—H6AB108.3
C1—N21—H21A104 (3)H6AA—N6A—H6AB107.4
C1—N21—H21B107 (3)C10A—N6A—Li4116 (3)
C1—N21—Li1107.9 (3)C10A—N6A—H6AA108.3
Li1—N21—H21A103 (3)C10A—N6A—H6AB108.3
Li1—N21—H21B119 (3)N6A—C10A—H10E108.6
H22A—N22—H22B107 (4)N6A—C10A—H10F108.6
C4—N22—H22A110 (3)H10E—C10A—H10F107.5
C4—N22—H22B107 (3)C21A—C10A—N6A115 (3)
C4—N22—Li3110.9 (3)C21A—C10A—H10E108.6
Li3—N22—H22A112 (3)C21A—C10A—H10F108.6
Li3—N22—H22B109 (3)C10A—C21A—H21E108.2
H23A—N23—H23B104 (4)C10A—C21A—H21F108.2
C18—N23—H23A108 (3)H21E—C21A—H21F107.3
C18—N23—H23B105 (3)N24A—C21A—C10A116 (3)
C18—N23—Li3126.5 (3)N24A—C21A—H21E108.2
Li3—N23—H23A105 (3)N24A—C21A—H21F108.2
Li3—N23—H23B107 (3)Li3—N24A—H24C102.7
N21—C1—H1C108.1Li3—N24A—H24D102.7
N21—C1—H1D108.1C21A—N24A—Li3138 (3)
N21—C1—C18116.6 (3)C21A—N24A—H24C102.7
H1C—C1—H1D107.3C21A—N24A—H24D102.7
C18—C1—H1C108.1H24C—N24A—H24D105.0
N1—C6—C20—N1862.8 (4)Li5—N9—C11—C2367.9 (4)
N2—C2—C17—N1560.7 (5)Li5—N15—C17—C2161.3 (3)
N4—C8—C16—N1769.1 (4)Li5—N17—C16—C890.2 (4)
N9—C11—C23—N8177.8 (3)Li6—N10—C14—C15157.0 (3)
N10—C14—C15—N1463.8 (5)Li6—N16—C7—C5144.6 (4)
N12—C9—C19—N2053.8 (5)Li6iv—N18—C20—C6139.2 (4)
N13—C3—C22—N760.9 (5)Li6v—N20—C19—C9174.9 (3)
N19—C5—C7—N1659.9 (5)Li4—N12—C9—C19160.7 (4)
N21—C1—C18—N2374.6 (4)Li4—N13—C3—C22157.0 (3)
N22—C4—C12—N354.0 (5)Li4—N14—C15—C14148.6 (4)
Li1—N2—C2—C17150.7 (4)Li4—N6—C10—C2148.1 (9)
Li1ii—N4—C8—C16149.4 (3)Li4—N6A—C10A—C21A128 (6)
Li1iii—N8—C23—C11176.9 (3)N6—C10—C21—N2461.0 (6)
Li1—N21—C1—C18177.2 (3)C10—C21—N24—Li35.6 (10)
Li2—N1—C6—C2067.1 (5)Li3—N22—C4—C12166.9 (3)
Li2i—N3—C12—C4165.5 (3)Li3—N23—C18—C1166.7 (3)
Li2—N7—C22—C3136.6 (4)N6A—C10A—C21A—N24A43 (9)
Li2—N19—C5—C7164.6 (3)C10A—C21A—N24A—Li374 (8)
Li5—N5—C13—C13vi57.2 (5)
Symmetry codes: (i) x+1, y+1, z+2; (ii) x1, y, z; (iii) x+1, y+2, z+1; (iv) x+1, y, z; (v) x, y1, z; (vi) x, y+1, z+1; (vii) x, y+1, z.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
N1—H1A···Se5vii0.91 (1)2.94 (1)3.837 (3)169 (4)
N1—H1B···Se6vii0.91 (1)2.98 (3)3.594 (3)127 (3)
N2—H2A···Se3vii0.91 (1)2.60 (2)3.483 (3)163 (3)
N2—H2B···Se4vii0.91 (1)2.81 (2)3.646 (3)155 (3)
N3—H3B···Se50.91 (1)2.86 (2)3.665 (4)148 (3)
N4—H4A···Se7vii0.91 (1)2.94 (3)3.600 (3)131 (3)
N4—H4B···Se8vii0.91 (1)2.60 (1)3.493 (3)170 (4)
N5—H5B···Se4vii0.91 (1)3.15 (4)3.696 (3)121 (3)
N5—H5B···Se8vii0.91 (1)2.90 (2)3.751 (3)156 (4)
N7—H7A···Se2vii0.91 (1)2.81 (2)3.647 (3)154 (3)
N7—H7B···Se1vii0.91 (1)2.73 (2)3.573 (3)155 (3)
N8—H8A···Se3viii0.91 (1)2.68 (2)3.514 (3)152 (3)
N9—H9B···Se8ix0.91 (1)2.92 (2)3.786 (3)161 (3)
N10—H10A···Se2x0.91 (1)2.88 (2)3.725 (3)156 (3)
N10—H10B···Se8vii0.91 (1)2.86 (1)3.749 (3)165 (3)
N12—H12A···Se50.91 (1)2.71 (1)3.611 (4)173 (4)
N12—H12B···Se70.91 (1)2.91 (4)3.532 (3)127 (3)
N13—H13A···Se50.91 (1)3.14 (2)3.973 (4)153 (3)
N13—H13B···Se2vii0.91 (1)2.74 (2)3.628 (3)166 (4)
N14—H14A···Se8vii0.91 (1)2.59 (1)3.479 (3)166 (4)
N14—H14B···Se1vii0.90 (1)2.77 (3)3.539 (3)144 (3)
N15—H15A···Se3vii0.91 (1)2.94 (2)3.785 (4)154 (3)
N15—H15B···Se3viii0.91 (1)2.68 (2)3.560 (3)163 (4)
N16—H16A···Se5vii0.91 (1)2.82 (2)3.679 (3)159 (4)
N16—H16B···Se1vii0.91 (1)2.67 (2)3.537 (3)160 (4)
N17—H17A···Se3vii0.91 (1)3.01 (2)3.897 (4)166 (4)
N17—H17B···Se7vii0.91 (1)3.07 (4)3.649 (3)124 (3)
N18—H18A···Se6vii0.91 (1)2.96 (2)3.837 (3)162 (3)
N18—H18B···Se2vii0.91 (1)2.80 (3)3.491 (3)134 (3)
N19—H19A···Se5vii0.91 (1)2.98 (2)3.801 (3)151 (4)
N20—H20A···Se70.89 (5)2.98 (5)3.841 (4)163 (4)
N21—H21A···Se8xi0.91 (1)2.98 (3)3.729 (3)141 (3)
N21—H21B···Se2vii0.91 (1)2.91 (2)3.763 (3)157 (3)
N22—H22A···Se50.91 (1)2.97 (2)3.785 (3)150 (4)
N22—H22B···Se2vii0.91 (1)3.10 (3)3.818 (4)138 (3)
N23—H23B···Se2vii0.91 (1)2.60 (1)3.505 (3)173 (4)
C1—H1C···Se8xi0.993.143.702 (4)118
C6—H6A···Se5i0.992.903.734 (4)143
C12—H12C···Se60.993.053.838 (4)137
C13—H13D···Se8ix0.993.073.929 (4)146
N6—H6D···Se4vii0.90 (1)3.01 (4)3.659 (5)130 (4)
C10—H10D···Se8vii0.992.993.816 (5)142
N24—H24B···Se30.91 (1)2.77 (5)3.327 (4)121 (4)
N24—H24B···Se70.91 (1)2.88 (4)3.507 (5)128 (4)
N6A—H6AA···Se4vii0.912.993.79 (7)147
C10A—H10F···Se8vii0.992.953.74 (5)137
N24A—H24D···Se70.913.173.94 (6)145
Symmetry codes: (i) x+1, y+1, z+2; (vii) x, y+1, z; (viii) x+1, y+1, z+1; (ix) x, y, z+1; (x) x1, y+1, z; (xi) x+1, y+1, z.
 

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