Carbonylchloro[2-(diphenylphosphino)thiophenolato-P,S]hydrido(triphenylphosphine-P)iridium(III)-Dichloromethane Solvate (4/1)

In the title complex, [IrH(Cl)(C₁₈H₁₄PS)(C₁₈H₁₅P)(CO)].0.25CH₂Cl₂, the two P donors, the chloro and thiolato functions, and the carbonyl and hydride ligands are bonded in mutually trans positions. The five-membered chelate ring has an envelope conformation with the metal atom deviating from the plane defined by the P and S donors and the two bridging phenylene C atoms.

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