metal-organic compounds
The crystal structure of the title complex, [Cu(CN)(C12H8N2)2][C(CN)3].2H2O, is formed by discrete [Cu(phen)2(CN)]+ cations, tcm anions and uncoordinated water molecules [phen = 1,10-phenanthroline, tcm = tricyanomethanide, C(CN)3-]. The Cu atom is coordinated by four N atoms (from two phen molecules) and by one C atom (from the cyanide group in the equatorial plane) in the form of a distorted trigonal bipyramid.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 126222