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The crystal structure of the title complex, [Cu(CN)(C12H8N2)2][C(CN)3].2H2O, is formed by discrete [Cu(phen)2(CN)]+ cations, tcm anions and uncoordinated water molecules [phen = 1,10-phenanthroline, tcm = tricyanomethanide, C(CN)3-]. The Cu atom is coordinated by four N atoms (from two phen molecules) and by one C atom (from the cyanide group in the equatorial plane) in the form of a distorted trigonal bipyramid.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks ft3a, global

hkl

Structure factor file (CIF format)
Contains datablock ft3a

CCDC reference: 126222

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