Temperature dependence of the silver distribution in the crystal structure of natural pearceite, (Ag,Cu)16(As,Sb)2S11

Bindi, L.; Evain, M.; Menchetti, S.

doi:10.1107/S010876810600108X

Temperature dependence of the silver distribution in the crystal structure of natural pearceite, (Ag,Cu)₁₆(As,Sb)₂S₁₁

The crystal structure of the mineral pearceite, (Ag,Cu)₁₆(As,Sb)₂S₁₁, has been solved and refined at 300, 120 and 15 K. At room temperature pearceite crystallizes with trigonal symmetry, space group P $\bar 3$ m1; the refinement of the structure leads to a residual factor of R = 0.0464 for 1109 independent observed reflections and 92 variables. The crystal structure consists of sheets stacked along the c axis. The As atoms form isolated (As,Sb)S₃ pyramids, which typically occur in sulfosalts, copper cations link two S atoms in a linear coordination, and the silver cations are found in a fully occupied position and in various sites corresponding to the most pronounced probability density function locations (modes) of diffusion-like paths. These positions correspond to low-coordination (2, 3 and 4) sites, in agreement with the preference of silver for such environments. d¹⁰ silver-ion distribution has been determined by means of a combination of a Gram–Charlier description of the atomic displacement factors and a split-atom model. To analyse the crystal chemical behaviour of the silver cations as a function of temperature, a structural study was carried out at 120 K (R = 0.0450). The refinement indicates that the mineral exhibits the same structural arrangement as the room-temperature structure (space group $P\overline 3m1$ ) and shows that the silver cations are still highly disordered. In order to investigate a possible ordering scheme for the silver cations, a data collection at ultra-low temperature (15 K) was performed. The structural skeleton was found to be similar to that of the room-temperature and 120 K atomic structures, but the best solution was achieved with a fully split-atom model of five silver positions, giving an R value of 0.0449 for 651 observed reflections and 78 parameters. Although the silver cation densities condense into better defined modes, the joint probability density function still exhibits a strong overlapping of neighbouring sites.

Keywords: temperature dependence; silver-ion distribution; pearceite.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S010876810600108X/lc5042sup1.cif Contains datablocks global, 300K, 120K, 15K
	Structure factor file (CIF format) https://doi.org/10.1107/S010876810600108X/lc5042300Ksup2.hkl Contains datablocks global, (I)
	Structure factor file (CIF format) https://doi.org/10.1107/S010876810600108X/lc5042120Ksup3.hkl Contains datablocks global, (I)
	Structure factor file (CIF format) https://doi.org/10.1107/S010876810600108X/lc504215Ksup4.hkl Contains datablock 15K

Computing details top

For all compounds, program(s) used to refine structure: (Jana2000; Petricek and Dusek, 2000); software used to prepare material for publication: (Jana2000; Petricek and Dusek, 2000).

Figures top

(300K) top

Crystal data top

Ag_13.034As_1.179Cu_2.966S₁₁Sb_0.821	F(000) = 955
M_r = 2135.4	D_x = 6.309 Mg m⁻³
Trigonal, P3m1	Mo Kα radiation, λ = 0.71069 Å
Hall symbol: -P 3;-2"	µ = 17.51 mm⁻¹
a = 7.3876 (4) Å	T = 300 K
c = 11.8882 (7) Å	Prism, black
V = 561.89 (5) Å³	0.15 × 0.15 × 0.04 mm
Z = 1

Data collection top

Nonius KappaCCD diffractometer	1109 reflections with I > 2σ(I)
ω scans	R_int = 0.048
Absorption correction: gaussian (Jana2000; Petricek, Dusek & Palatinus, 2000)	θ_max = 40.0°, θ_min = 6.5°
T_min = 0.197, T_max = 0.727	h = −13→13
20965 measured reflections	k = −12→12
1352 independent reflections	l = −21→21

Refinement top

Refinement on F²	Weighting scheme based on measured s.u.'s w = 1/[σ²(I) + 0.001936I²]
R[F² > 2σ(F²)] = 0.046	(Δ/σ)_max = 0.0003
wR(F²) = 0.127	Δρ_max = 1.41 e Å⁻³
S = 1.89	Δρ_min = −1.00 e Å⁻³
1352 reflections	Extinction correction: B-C type 1 Gaussian isotropic (Becker & Coppens, 1974)
92 parameters	Extinction coefficient: 0.294979

Crystal data top

Ag_13.034As_1.179Cu_2.966S₁₁Sb_0.821	Z = 1
M_r = 2135.4	Mo Kα radiation
Trigonal, P3m1	µ = 17.51 mm⁻¹
a = 7.3876 (4) Å	T = 300 K
c = 11.8882 (7) Å	0.15 × 0.15 × 0.04 mm
V = 561.89 (5) Å³

Data collection top

Nonius KappaCCD diffractometer	1352 independent reflections
Absorption correction: gaussian (Jana2000; Petricek, Dusek & Palatinus, 2000)	1109 reflections with I > 2σ(I)
T_min = 0.197, T_max = 0.727	R_int = 0.048
20965 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.046	92 parameters
wR(F²) = 0.127	Δρ_max = 1.41 e Å⁻³
S = 1.89	Δρ_min = −1.00 e Å⁻³
1352 reflections

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
As	0.333333	0.666667	0.40748 (5)	0.02317 (18)	0.590 (13)
Sb	0.333333	0.666667	0.407476	0.02317 (18)	0.410 (13)
Ag1	0.3009 (2)	0.15043 (12)	0.38526 (11)	0.0528 (7)	0.672 (18)
Cu1	0.300867	0.150434	0.385264	0.0528 (7)	0.328 (18)
Ag2	0.3566 (4)	0.240 (3)	0.1233 (2)	0.345 (10)	0.366 (4)
Ag3	0.2921 (9)	0.3808 (8)	0.1174 (3)	0.119 (2)	0.384 (4)
Cu2	0	0	0	0.0282 (3)
S1	0	0	0.18164 (12)	0.0267 (4)
S2	0.01656 (16)	0.50828 (8)	0.31324 (9)	0.0269 (3)
S3	0.666667	0.333333	0.0174 (2)	0.0428 (6)
S4	0	0	0.5	0.114 (3)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
As	0.0242 (2)	0.0242 (2)	0.0211 (3)	0.01210 (12)	0	0
Sb	0.0242 (2)	0.0242 (2)	0.0211 (3)	0.01210 (12)	0	0
Ag1	0.0676 (10)	0.0404 (7)	0.0596 (9)	0.0338 (5)	−0.0021 (5)	−0.0011 (2)
Cu1	0.0676 (10)	0.0404 (7)	0.0596 (9)	0.0338 (5)	−0.0021 (5)	−0.0011 (2)
Ag2	0.0388 (9)	0.62 (2)	0.0447 (7)	−0.082 (5)	0.0064 (7)	−0.018 (5)
Ag3	0.194 (4)	0.110 (2)	0.0490 (13)	0.072 (2)	−0.0287 (14)	0.0002 (12)
Cu2	0.0350 (4)	0.0350 (4)	0.0148 (4)	0.0175 (2)	0	0
S1	0.0324 (5)	0.0324 (5)	0.0154 (5)	0.0162 (3)	0	0
S2	0.0219 (4)	0.0251 (3)	0.0325 (5)	0.0109 (2)	0.0009 (3)	0.00045 (16)
S3	0.0437 (7)	0.0437 (7)	0.0411 (10)	0.0219 (4)	0	0
S4	0.157 (4)	0.157 (4)	0.028 (3)	0.0787 (18)	0	0

Geometric parameters (Å, º) top

As—Sb	0	Ag2—Ag3	1.35 (2)
As—S2	2.3157 (10)	Ag2—Ag3^v	2.881 (5)
As—S2ⁱ	2.3157 (12)	Ag2—Ag3^iv	2.23 (2)
As—S2ⁱⁱ	2.3157 (10)	Ag2—Ag3^vi	2.658 (18)
Sb—S2	2.3157 (10)	Ag2—Cu2	2.750 (4)
Sb—S2ⁱ	2.3157 (12)	Ag2—S1	2.428 (4)
Sb—S2ⁱⁱ	2.3157 (10)	Ag2—S2ⁱ	2.836 (11)
Ag1—Cu1	0	Ag2—S3	2.393 (5)
Ag1—S2ⁱ	2.4459 (14)	Ag3—Ag3ⁱⁱ	2.417 (6)
Ag1—S2ⁱⁱⁱ	2.446 (2)	Ag3—Ag3^vi	1.502 (12)
Ag1—S4	2.3592 (15)	Ag3—Cu2	2.906 (4)
Cu1—S2ⁱ	2.4459 (11)	Ag3—S1	2.661 (4)
Cu1—S2ⁱⁱⁱ	2.4459 (11)	Ag3—S2ⁱ	2.664 (4)
Cu1—S4	2.3592	Ag3—S3^vii	2.545 (6)
Ag2—Ag2ⁱⁱ	2.980 (14)	Cu2—S1	2.1594 (15)
Ag2—Ag2^iv	0.91 (3)	Cu2—S1^viii	2.1594 (15)

Sb—As—S2	0	Ag3^ix—Cu2—Ag3^xv	106.7 (2)
Sb—As—S2ⁱ	0	Ag3^ix—Cu2—S1	61.31 (8)
Sb—As—S2ⁱⁱ	0	Ag3^ix—Cu2—S1^viii	118.69 (8)
S2—As—S2ⁱ	98.57 (4)	Ag3^x—Cu2—Ag3	81.12 (17)
S2—As—S2ⁱⁱ	98.57 (3)	Ag3^x—Cu2—Ag3^viii	98.88 (17)
S2ⁱ—As—S2	98.57 (4)	Ag3^x—Cu2—Ag3^ix	180
S2ⁱ—As—S2ⁱⁱ	98.57 (4)	Ag3^x—Cu2—Ag3^xi	150.0 (2)
S2ⁱⁱ—As—S2	98.57 (3)	Ag3^x—Cu2—Ag3^v	30.0 (2)
S2ⁱⁱ—As—S2ⁱ	98.57 (4)	Ag3^x—Cu2—Ag3^xii	81.1 (2)
As—Sb—S2	0	Ag3^x—Cu2—Ag3^xiii	98.9 (2)
As—Sb—S2ⁱ	0	Ag3^x—Cu2—Ag3^iv	62.43 (15)
As—Sb—S2ⁱⁱ	0	Ag3^x—Cu2—Ag3^xiv	117.57 (15)
S2—Sb—S2ⁱ	98.57 (3)	Ag3^x—Cu2—Ag3^vi	106.7 (2)
S2—Sb—S2ⁱⁱ	98.57 (3)	Ag3^x—Cu2—Ag3^xv	73.3 (2)
S2ⁱ—Sb—S2	98.57 (3)	Ag3^x—Cu2—S1	118.69 (8)
S2ⁱ—Sb—S2ⁱⁱ	98.57 (4)	Ag3^x—Cu2—S1^viii	61.31 (8)
S2ⁱⁱ—Sb—S2	98.57 (3)	Ag3^xi—Cu2—Ag3	117.57 (12)
S2ⁱⁱ—Sb—S2ⁱ	98.57 (4)	Ag3^xi—Cu2—Ag3^viii	62.43 (12)
Cu1—Ag1—S2ⁱ	0	Ag3^xi—Cu2—Ag3^ix	30.0 (2)
Cu1—Ag1—S2ⁱⁱⁱ	0	Ag3^xi—Cu2—Ag3^x	150.0 (2)
Cu1—Ag1—S4	0	Ag3^xi—Cu2—Ag3^v	180
S2ⁱ—Ag1—S2ⁱⁱⁱ	104.86 (6)	Ag3^xi—Cu2—Ag3^xii	73.3 (2)
S2ⁱ—Ag1—S4	127.57 (7)	Ag3^xi—Cu2—Ag3^xiii	106.7 (2)
S2ⁱⁱⁱ—Ag1—S2ⁱ	104.86 (6)	Ag3^xi—Cu2—Ag3^iv	98.88 (16)
S2ⁱⁱⁱ—Ag1—S4	127.57 (4)	Ag3^xi—Cu2—Ag3^xiv	81.12 (16)
Ag1—Cu1—S2ⁱ	0	Ag3^xi—Cu2—Ag3^vi	98.88 (17)
Ag1—Cu1—S2ⁱⁱⁱ	0	Ag3^xi—Cu2—Ag3^xv	81.12 (17)
Ag1—Cu1—S4	0	Ag3^xi—Cu2—S1	61.31 (7)
S2ⁱ—Cu1—S2ⁱⁱⁱ	104.86 (3)	Ag3^xi—Cu2—S1^viii	118.69 (7)
S2ⁱ—Cu1—S4	127.57 (2)	Ag3^v—Cu2—Ag3	62.43 (12)
S2ⁱⁱⁱ—Cu1—S2ⁱ	104.86 (3)	Ag3^v—Cu2—Ag3^viii	117.57 (12)
S2ⁱⁱⁱ—Cu1—S4	127.57 (2)	Ag3^v—Cu2—Ag3^ix	150.0 (2)
Ag2ⁱⁱ—Ag2—Ag2^iv	120.0 (5)	Ag3^v—Cu2—Ag3^x	30.0 (2)
Ag2ⁱⁱ—Ag2—Ag3	77.9 (7)	Ag3^v—Cu2—Ag3^xi	180
Ag2ⁱⁱ—Ag2—Ag3^v	84.4 (2)	Ag3^v—Cu2—Ag3^xii	106.7 (2)
Ag2ⁱⁱ—Ag2—Ag3^iv	130.7 (6)	Ag3^v—Cu2—Ag3^xiii	73.3 (2)
Ag2ⁱⁱ—Ag2—Ag3^vi	100.2 (7)	Ag3^v—Cu2—Ag3^iv	81.12 (16)
Ag2ⁱⁱ—Ag2—Cu2	143.3 (4)	Ag3^v—Cu2—Ag3^xiv	98.88 (16)
Ag2ⁱⁱ—Ag2—S1	155.2 (7)	Ag3^v—Cu2—Ag3^vi	81.12 (17)
Ag2ⁱⁱ—Ag2—S2ⁱ	58.3 (3)	Ag3^v—Cu2—Ag3^xv	98.88 (17)
Ag2ⁱⁱ—Ag2—S3	51.5 (3)	Ag3^v—Cu2—S1	118.69 (7)
Ag2^iv—Ag2—Ag2ⁱⁱ	120.0 (5)	Ag3^v—Cu2—S1^viii	61.31 (7)
Ag2^iv—Ag2—Ag3	161.8 (4)	Ag3^xii—Cu2—Ag3	98.88 (16)
Ag2^iv—Ag2—Ag3^v	95.9 (5)	Ag3^xii—Cu2—Ag3^viii	81.12 (16)
Ag2^iv—Ag2—Ag3^iv	10.8 (3)	Ag3^xii—Cu2—Ag3^ix	98.9 (2)
Ag2^iv—Ag2—Ag3^vi	139.8 (4)	Ag3^xii—Cu2—Ag3^x	81.1 (2)
Ag2^iv—Ag2—Cu2	80.5 (4)	Ag3^xii—Cu2—Ag3^xi	73.3 (2)
Ag2^iv—Ag2—S1	79.2 (5)	Ag3^xii—Cu2—Ag3^v	106.7 (2)
Ag2^iv—Ag2—S2ⁱ	121.5 (4)	Ag3^xii—Cu2—Ag3^xiii	180
Ag2^iv—Ag2—S3	79.0 (5)	Ag3^xii—Cu2—Ag3^iv	29.96 (17)
Ag3—Ag2—Ag3^v	82.3 (4)	Ag3^xii—Cu2—Ag3^xiv	150.04 (17)
Ag3—Ag2—Ag3^iv	151.0 (3)	Ag3^xii—Cu2—Ag3^vi	117.57 (15)
Ag3—Ag2—Ag3^vi	22.3 (2)	Ag3^xii—Cu2—Ag3^xv	62.43 (15)
Ag3—Ag2—Cu2	82.8 (3)	Ag3^xii—Cu2—S1	61.31 (10)
Ag3—Ag2—S1	84.5 (3)	Ag3^xii—Cu2—S1^viii	118.69 (10)
Ag3—Ag2—S2ⁱ	68.8 (5)	Ag3^xiii—Cu2—Ag3	81.12 (16)
Ag3—Ag2—S3	114.1 (7)	Ag3^xiii—Cu2—Ag3^viii	98.88 (16)
Ag3^v—Ag2—Ag3	82.3 (4)	Ag3^xiii—Cu2—Ag3^ix	81.1 (2)
Ag3^v—Ag2—Ag3^iv	94.5 (4)	Ag3^xiii—Cu2—Ag3^x	98.9 (2)
Ag3^v—Ag2—Ag3^vi	86.0 (4)	Ag3^xiii—Cu2—Ag3^xi	106.7 (2)
Ag3^v—Ag2—Cu2	62.09 (10)	Ag3^xiii—Cu2—Ag3^v	73.3 (2)
Ag3^v—Ag2—S1	110.69 (14)	Ag3^xiii—Cu2—Ag3^xii	180
Ag3^v—Ag2—S2ⁱ	136.1 (6)	Ag3^xiii—Cu2—Ag3^iv	150.04 (17)
Ag3^v—Ag2—S3	56.80 (14)	Ag3^xiii—Cu2—Ag3^xiv	29.96 (17)
Ag3^iv—Ag2—Ag3	151.0 (3)	Ag3^xiii—Cu2—Ag3^vi	62.43 (15)
Ag3^iv—Ag2—Ag3^v	94.5 (4)	Ag3^xiii—Cu2—Ag3^xv	117.57 (15)
Ag3^iv—Ag2—Ag3^vi	129.0 (3)	Ag3^xiii—Cu2—S1	118.69 (10)
Ag3^iv—Ag2—Cu2	70.5 (3)	Ag3^xiii—Cu2—S1^viii	61.31 (10)
Ag3^iv—Ag2—S1	69.5 (4)	Ag3^iv—Cu2—Ag3	73.3 (2)
Ag3^iv—Ag2—S2ⁱ	126.5 (4)	Ag3^iv—Cu2—Ag3^viii	106.7 (2)
Ag3^iv—Ag2—S3	87.1 (6)	Ag3^iv—Cu2—Ag3^ix	117.57 (15)
Ag3^vi—Ag2—Ag3	22.3 (2)	Ag3^iv—Cu2—Ag3^x	62.43 (15)
Ag3^vi—Ag2—Ag3^v	86.0 (4)	Ag3^iv—Cu2—Ag3^xi	98.88 (16)
Ag3^vi—Ag2—Ag3^iv	129.0 (3)	Ag3^iv—Cu2—Ag3^v	81.12 (16)
Ag3^vi—Ag2—Cu2	64.98 (19)	Ag3^iv—Cu2—Ag3^xii	29.96 (17)
Ag3^vi—Ag2—S1	62.9 (2)	Ag3^iv—Cu2—Ag3^xiii	150.04 (17)
Ag3^vi—Ag2—S2ⁱ	79.5 (4)	Ag3^iv—Cu2—Ag3^xiv	180
Ag3^vi—Ag2—S3	131.8 (6)	Ag3^iv—Cu2—Ag3^vi	98.9 (2)
Cu2—Ag2—S1	48.81 (9)	Ag3^iv—Cu2—Ag3^xv	81.1 (2)
Cu2—Ag2—S2ⁱ	139.8 (4)	Ag3^iv—Cu2—S1	61.31 (10)
Cu2—Ag2—S3	112.1 (3)	Ag3^iv—Cu2—S1^viii	118.69 (10)
S1—Ag2—S2ⁱ	99.0 (2)	Ag3^xiv—Cu2—Ag3	106.7 (2)
S1—Ag2—S3	153.3 (7)	Ag3^xiv—Cu2—Ag3^viii	73.3 (2)
S2ⁱ—Ag2—S3	105.4 (2)	Ag3^xiv—Cu2—Ag3^ix	62.43 (15)
Ag2—Ag3—Ag2^v	95.3 (4)	Ag3^xiv—Cu2—Ag3^x	117.57 (15)
Ag2—Ag3—Ag2^iv	7.3 (3)	Ag3^xiv—Cu2—Ag3^xi	81.12 (16)
Ag2—Ag3—Ag2^vi	118.0 (6)	Ag3^xiv—Cu2—Ag3^v	98.88 (16)
Ag2—Ag3—Ag3ⁱⁱ	102.1 (5)	Ag3^xiv—Cu2—Ag3^xii	150.04 (17)
Ag2—Ag3—Ag3^vi	137.8 (5)	Ag3^xiv—Cu2—Ag3^xiii	29.96 (17)
Ag2—Ag3—Cu2	69.9 (3)	Ag3^xiv—Cu2—Ag3^iv	180
Ag2—Ag3—S1	65.2 (3)	Ag3^xiv—Cu2—Ag3^vi	81.1 (2)
Ag2—Ag3—S2ⁱ	83.1 (3)	Ag3^xiv—Cu2—Ag3^xv	98.9 (2)
Ag2—Ag3—S3^vii	137.1 (3)	Ag3^xiv—Cu2—S1	118.69 (10)
Ag2^v—Ag3—Ag2	95.3 (4)	Ag3^xiv—Cu2—S1^viii	61.31 (10)
Ag2^v—Ag3—Ag2^iv	93.3 (3)	Ag3^vi—Cu2—Ag3	30.0 (2)
Ag2^v—Ag3—Ag2^vi	84.9 (4)	Ag3^vi—Cu2—Ag3^viii	150.0 (2)
Ag2^v—Ag3—Ag3ⁱⁱ	95.6 (2)	Ag3^vi—Cu2—Ag3^ix	73.3 (2)
Ag2^v—Ag3—Ag3^vi	84.1 (4)	Ag3^vi—Cu2—Ag3^x	106.7 (2)
Ag2^v—Ag3—Cu2	56.75 (12)	Ag3^vi—Cu2—Ag3^xi	98.88 (17)
Ag2^v—Ag3—S1	101.96 (18)	Ag3^vi—Cu2—Ag3^v	81.12 (17)
Ag2^v—Ag3—S2ⁱ	157.4 (3)	Ag3^vi—Cu2—Ag3^xii	117.57 (15)
Ag2^v—Ag3—S3^vii	51.90 (15)	Ag3^vi—Cu2—Ag3^xiii	62.43 (15)
Ag2^iv—Ag3—Ag2	7.3 (3)	Ag3^vi—Cu2—Ag3^iv	98.9 (2)
Ag2^iv—Ag3—Ag2^v	93.3 (3)	Ag3^vi—Cu2—Ag3^xiv	81.1 (2)
Ag2^iv—Ag3—Ag2^vi	110.8 (5)	Ag3^vi—Cu2—Ag3^xv	180
Ag2^iv—Ag3—Ag3ⁱⁱ	109.3 (3)	Ag3^vi—Cu2—S1	61.31 (8)
Ag2^iv—Ag3—Ag3^vi	130.7 (3)	Ag3^vi—Cu2—S1^viii	118.69 (8)
Ag2^iv—Ag3—Cu2	63.15 (16)	Ag3^xv—Cu2—Ag3	150.0 (2)
Ag2^iv—Ag3—S1	58.73 (16)	Ag3^xv—Cu2—Ag3^viii	30.0 (2)
Ag2^iv—Ag3—S2ⁱ	87.6 (2)	Ag3^xv—Cu2—Ag3^ix	106.7 (2)
Ag2^iv—Ag3—S3^vii	139.2 (2)	Ag3^xv—Cu2—Ag3^x	73.3 (2)
Ag2^vi—Ag3—Ag2	118.0 (6)	Ag3^xv—Cu2—Ag3^xi	81.12 (17)
Ag2^vi—Ag3—Ag2^v	84.9 (4)	Ag3^xv—Cu2—Ag3^v	98.88 (17)
Ag2^vi—Ag3—Ag2^iv	110.8 (5)	Ag3^xv—Cu2—Ag3^xii	62.43 (15)
Ag2^vi—Ag3—Ag3ⁱⁱ	139.8 (6)	Ag3^xv—Cu2—Ag3^xiii	117.57 (15)
Ag2^vi—Ag3—Ag3^vi	19.9 (5)	Ag3^xv—Cu2—Ag3^iv	81.1 (2)
Ag2^vi—Ag3—Cu2	59.0 (4)	Ag3^xv—Cu2—Ag3^xiv	98.9 (2)
Ag2^vi—Ag3—S1	54.3 (4)	Ag3^xv—Cu2—Ag3^vi	180
Ag2^vi—Ag3—S2ⁱ	115.78 (19)	Ag3^xv—Cu2—S1	118.69 (8)
Ag2^vi—Ag3—S3^vii	89.0 (4)	Ag3^xv—Cu2—S1^viii	61.31 (8)
Ag3ⁱⁱ—Ag3—Ag3^vi	120.0 (4)	S1—Cu2—S1^viii	180
Ag3ⁱⁱ—Ag3—Cu2	148.8 (2)	S1^viii—Cu2—S1	180
Ag3ⁱⁱ—Ag3—S1	159.0 (3)	Ag2—S1—Ag2^ix	112.2 (5)
Ag3ⁱⁱ—Ag3—S2ⁱ	63.02 (13)	Ag2—S1—Ag2^xi	130.4 (5)
Ag3ⁱⁱ—Ag3—S3^vii	61.65 (18)	Ag2—S1—Ag2^xii	112.2 (6)
Ag3^vi—Ag3—Ag3ⁱⁱ	120.0 (4)	Ag2—S1—Ag2^iv	21.6 (6)
Ag3^vi—Ag3—Cu2	75.0 (2)	Ag2—S1—Ag2^vi	92.1 (5)
Ag3^vi—Ag3—S1	73.6 (3)	Ag2—S1—Ag3	30.2 (5)
Ag3^vi—Ag3—S2ⁱ	112.1 (3)	Ag2—S1—Ag3^ix	136.5 (3)
Ag3^vi—Ag3—S3^vii	72.8 (3)	Ag2—S1—Ag3^xi	146.22 (16)
Cu2—Ag3—S1	45.38 (8)	Ag2—S1—Ag3^xii	83.8 (5)
Cu2—Ag3—S2ⁱ	140.7 (2)	Ag2—S1—Ag3^iv	51.7 (5)
Cu2—Ag3—S3^vii	102.95 (14)	Ag2—S1—Ag3^vi	62.8 (5)
S1—Ag3—S2ⁱ	97.80 (13)	Ag2—S1—Cu2	73.41 (7)
S1—Ag3—S3^vii	139.1 (2)	Ag2^ix—S1—Ag2	112.2 (5)
S2ⁱ—Ag3—S3^vii	116.19 (19)	Ag2^ix—S1—Ag2^xi	92.1 (5)
Ag2—Cu2—Ag2^viii	180	Ag2^ix—S1—Ag2^xii	112.2 (5)
Ag2—Cu2—Ag2^ix	94.2 (4)	Ag2^ix—S1—Ag2^iv	130.4 (5)
Ag2—Cu2—Ag2^x	85.8 (4)	Ag2^ix—S1—Ag2^vi	21.6 (5)
Ag2—Cu2—Ag2^xi	106.5 (4)	Ag2^ix—S1—Ag3	83.8 (4)
Ag2—Cu2—Ag2^v	73.5 (4)	Ag2^ix—S1—Ag3^ix	30.2 (4)
Ag2—Cu2—Ag2^xii	94.2 (4)	Ag2^ix—S1—Ag3^xi	62.8 (4)
Ag2—Cu2—Ag2^xiii	85.8 (4)	Ag2^ix—S1—Ag3^xii	136.5 (3)
Ag2—Cu2—Ag2^iv	19.1 (6)	Ag2^ix—S1—Ag3^iv	146.2 (2)
Ag2—Cu2—Ag2^xiv	160.9 (6)	Ag2^ix—S1—Ag3^vi	51.7 (4)
Ag2—Cu2—Ag2^vi	78.9 (5)	Ag2^ix—S1—Cu2	73.41 (17)
Ag2—Cu2—Ag2^xv	101.1 (5)	Ag2^xi—S1—Ag2	130.4 (5)
Ag2—Cu2—Ag3	27.3 (4)	Ag2^xi—S1—Ag2^ix	92.1 (5)
Ag2—Cu2—Ag3^viii	152.7 (4)	Ag2^xi—S1—Ag2^xii	21.6 (6)
Ag2—Cu2—Ag3^ix	113.38 (17)	Ag2^xi—S1—Ag2^iv	112.2 (6)
Ag2—Cu2—Ag3^x	66.62 (17)	Ag2^xi—S1—Ag2^vi	112.2 (5)
Ag2—Cu2—Ag3^xi	118.84 (12)	Ag2^xi—S1—Ag3	146.22 (16)
Ag2—Cu2—Ag3^v	61.16 (12)	Ag2^xi—S1—Ag3^ix	62.8 (5)
Ag2—Cu2—Ag3^xii	74.0 (4)	Ag2^xi—S1—Ag3^xi	30.2 (5)
Ag2—Cu2—Ag3^xiii	106.0 (4)	Ag2^xi—S1—Ag3^xii	51.7 (5)
Ag2—Cu2—Ag3^iv	46.3 (4)	Ag2^xi—S1—Ag3^iv	83.8 (5)
Ag2—Cu2—Ag3^xiv	133.7 (4)	Ag2^xi—S1—Ag3^vi	136.5 (3)
Ag2—Cu2—Ag3^vi	56.0 (4)	Ag2^xi—S1—Cu2	73.41 (7)
Ag2—Cu2—Ag3^xv	124.0 (4)	Ag2^xii—S1—Ag2	112.2 (6)
Ag2—Cu2—S1	57.79 (7)	Ag2^xii—S1—Ag2^ix	112.2 (5)
Ag2—Cu2—S1^viii	122.21 (7)	Ag2^xii—S1—Ag2^xi	21.6 (6)
Ag2^viii—Cu2—Ag2	180	Ag2^xii—S1—Ag2^iv	92.1 (6)
Ag2^viii—Cu2—Ag2^ix	85.8 (4)	Ag2^xii—S1—Ag2^vi	130.4 (5)
Ag2^viii—Cu2—Ag2^x	94.2 (4)	Ag2^xii—S1—Ag3	136.5 (3)
Ag2^viii—Cu2—Ag2^xi	73.5 (4)	Ag2^xii—S1—Ag3^ix	83.8 (5)
Ag2^viii—Cu2—Ag2^v	106.5 (4)	Ag2^xii—S1—Ag3^xi	51.7 (5)
Ag2^viii—Cu2—Ag2^xii	85.8 (4)	Ag2^xii—S1—Ag3^xii	30.2 (5)
Ag2^viii—Cu2—Ag2^xiii	94.2 (4)	Ag2^xii—S1—Ag3^iv	62.8 (5)
Ag2^viii—Cu2—Ag2^iv	160.9 (6)	Ag2^xii—S1—Ag3^vi	146.22 (16)
Ag2^viii—Cu2—Ag2^xiv	19.1 (6)	Ag2^xii—S1—Cu2	73.41 (7)
Ag2^viii—Cu2—Ag2^vi	101.1 (5)	Ag2^iv—S1—Ag2	21.6 (6)
Ag2^viii—Cu2—Ag2^xv	78.9 (5)	Ag2^iv—S1—Ag2^ix	130.4 (5)
Ag2^viii—Cu2—Ag3	152.7 (4)	Ag2^iv—S1—Ag2^xi	112.2 (6)
Ag2^viii—Cu2—Ag3^viii	27.3 (4)	Ag2^iv—S1—Ag2^xii	92.1 (6)
Ag2^viii—Cu2—Ag3^ix	66.62 (17)	Ag2^iv—S1—Ag2^vi	112.2 (5)
Ag2^viii—Cu2—Ag3^x	113.38 (17)	Ag2^iv—S1—Ag3	51.7 (5)
Ag2^viii—Cu2—Ag3^xi	61.16 (12)	Ag2^iv—S1—Ag3^ix	146.22 (16)
Ag2^viii—Cu2—Ag3^v	118.84 (12)	Ag2^iv—S1—Ag3^xi	136.5 (3)
Ag2^viii—Cu2—Ag3^xii	106.0 (4)	Ag2^iv—S1—Ag3^xii	62.8 (5)
Ag2^viii—Cu2—Ag3^xiii	74.0 (4)	Ag2^iv—S1—Ag3^iv	30.2 (5)
Ag2^viii—Cu2—Ag3^iv	133.7 (4)	Ag2^iv—S1—Ag3^vi	83.8 (5)
Ag2^viii—Cu2—Ag3^xiv	46.3 (4)	Ag2^iv—S1—Cu2	73.41 (7)
Ag2^viii—Cu2—Ag3^vi	124.0 (4)	Ag2^vi—S1—Ag2	92.1 (5)
Ag2^viii—Cu2—Ag3^xv	56.0 (4)	Ag2^vi—S1—Ag2^ix	21.6 (5)
Ag2^viii—Cu2—S1	122.21 (7)	Ag2^vi—S1—Ag2^xi	112.2 (5)
Ag2^viii—Cu2—S1^viii	57.79 (7)	Ag2^vi—S1—Ag2^xii	130.4 (5)
Ag2^ix—Cu2—Ag2	94.2 (4)	Ag2^vi—S1—Ag2^iv	112.2 (5)
Ag2^ix—Cu2—Ag2^viii	85.8 (4)	Ag2^vi—S1—Ag3	62.8 (4)
Ag2^ix—Cu2—Ag2^x	180	Ag2^vi—S1—Ag3^ix	51.7 (4)
Ag2^ix—Cu2—Ag2^xi	78.9 (5)	Ag2^vi—S1—Ag3^xi	83.8 (4)
Ag2^ix—Cu2—Ag2^v	101.1 (5)	Ag2^vi—S1—Ag3^xii	146.2 (2)
Ag2^ix—Cu2—Ag2^xii	94.2 (5)	Ag2^vi—S1—Ag3^iv	136.5 (3)
Ag2^ix—Cu2—Ag2^xiii	85.8 (5)	Ag2^vi—S1—Ag3^vi	30.2 (4)
Ag2^ix—Cu2—Ag2^iv	106.5 (4)	Ag2^vi—S1—Cu2	73.41 (17)
Ag2^ix—Cu2—Ag2^xiv	73.5 (4)	Ag3—S1—Ag3^ix	112.1 (2)
Ag2^ix—Cu2—Ag2^vi	19.1 (4)	Ag3—S1—Ag3^xi	138.08 (17)
Ag2^ix—Cu2—Ag2^xv	160.9 (4)	Ag3—S1—Ag3^xii	112.1 (2)
Ag2^ix—Cu2—Ag3	74.0 (3)	Ag3—S1—Ag3^iv	81.3 (2)
Ag2^ix—Cu2—Ag3^viii	106.0 (3)	Ag3—S1—Ag3^vi	32.8 (2)
Ag2^ix—Cu2—Ag3^ix	27.3 (3)	Ag3—S1—Cu2	73.31 (8)
Ag2^ix—Cu2—Ag3^x	152.7 (3)	Ag3^ix—S1—Ag3	112.1 (2)
Ag2^ix—Cu2—Ag3^xi	56.0 (3)	Ag3^ix—S1—Ag3^xi	32.8 (2)
Ag2^ix—Cu2—Ag3^v	124.0 (3)	Ag3^ix—S1—Ag3^xii	112.1 (2)
Ag2^ix—Cu2—Ag3^xii	113.4 (3)	Ag3^ix—S1—Ag3^iv	138.08 (18)
Ag2^ix—Cu2—Ag3^xiii	66.6 (3)	Ag3^ix—S1—Ag3^vi	81.3 (2)
Ag2^ix—Cu2—Ag3^iv	118.8 (3)	Ag3^ix—S1—Cu2	73.31 (8)
Ag2^ix—Cu2—Ag3^xiv	61.2 (3)	Ag3^xi—S1—Ag3	138.08 (17)
Ag2^ix—Cu2—Ag3^vi	46.3 (3)	Ag3^xi—S1—Ag3^ix	32.8 (2)
Ag2^ix—Cu2—Ag3^xv	133.7 (3)	Ag3^xi—S1—Ag3^xii	81.3 (2)
Ag2^ix—Cu2—S1	57.8 (3)	Ag3^xi—S1—Ag3^iv	112.1 (2)
Ag2^ix—Cu2—S1^viii	122.2 (3)	Ag3^xi—S1—Ag3^vi	112.1 (2)
Ag2^x—Cu2—Ag2	85.8 (4)	Ag3^xi—S1—Cu2	73.31 (8)
Ag2^x—Cu2—Ag2^viii	94.2 (4)	Ag3^xii—S1—Ag3	112.1 (2)
Ag2^x—Cu2—Ag2^ix	180	Ag3^xii—S1—Ag3^ix	112.1 (2)
Ag2^x—Cu2—Ag2^xi	101.1 (5)	Ag3^xii—S1—Ag3^xi	81.3 (2)
Ag2^x—Cu2—Ag2^v	78.9 (5)	Ag3^xii—S1—Ag3^iv	32.8 (2)
Ag2^x—Cu2—Ag2^xii	85.8 (5)	Ag3^xii—S1—Ag3^vi	138.08 (18)
Ag2^x—Cu2—Ag2^xiii	94.2 (5)	Ag3^xii—S1—Cu2	73.31 (9)
Ag2^x—Cu2—Ag2^iv	73.5 (4)	Ag3^iv—S1—Ag3	81.3 (2)
Ag2^x—Cu2—Ag2^xiv	106.5 (4)	Ag3^iv—S1—Ag3^ix	138.08 (18)
Ag2^x—Cu2—Ag2^vi	160.9 (4)	Ag3^iv—S1—Ag3^xi	112.1 (2)
Ag2^x—Cu2—Ag2^xv	19.1 (4)	Ag3^iv—S1—Ag3^xii	32.8 (2)
Ag2^x—Cu2—Ag3	106.0 (3)	Ag3^iv—S1—Ag3^vi	112.1 (2)
Ag2^x—Cu2—Ag3^viii	74.0 (3)	Ag3^iv—S1—Cu2	73.31 (9)
Ag2^x—Cu2—Ag3^ix	152.7 (3)	Ag3^vi—S1—Ag3	32.8 (2)
Ag2^x—Cu2—Ag3^x	27.3 (3)	Ag3^vi—S1—Ag3^ix	81.3 (2)
Ag2^x—Cu2—Ag3^xi	124.0 (3)	Ag3^vi—S1—Ag3^xi	112.1 (2)
Ag2^x—Cu2—Ag3^v	56.0 (3)	Ag3^vi—S1—Ag3^xii	138.08 (18)
Ag2^x—Cu2—Ag3^xii	66.6 (3)	Ag3^vi—S1—Ag3^iv	112.1 (2)
Ag2^x—Cu2—Ag3^xiii	113.4 (3)	Ag3^vi—S1—Cu2	73.31 (8)
Ag2^x—Cu2—Ag3^iv	61.2 (3)	As—S2—Sb	0
Ag2^x—Cu2—Ag3^xiv	118.8 (3)	As—S2—Ag1^ix	102.29 (5)
Ag2^x—Cu2—Ag3^vi	133.7 (3)	As—S2—Ag1^xvi	102.29 (4)
Ag2^x—Cu2—Ag3^xv	46.3 (3)	As—S2—Cu1^ix	102.29 (4)
Ag2^x—Cu2—S1	122.2 (3)	As—S2—Cu1^xvi	102.29 (3)
Ag2^x—Cu2—S1^viii	57.8 (3)	As—S2—Ag2^xvii	130.4 (2)
Ag2^xi—Cu2—Ag2	106.5 (4)	As—S2—Ag2^vi	130.4 (4)
Ag2^xi—Cu2—Ag2^viii	73.5 (4)	As—S2—Ag3^xvii	105.74 (15)
Ag2^xi—Cu2—Ag2^ix	78.9 (5)	As—S2—Ag3^vi	105.74 (18)
Ag2^xi—Cu2—Ag2^x	101.1 (5)	Sb—S2—Ag1^ix	102.29 (5)
Ag2^xi—Cu2—Ag2^v	180	Sb—S2—Ag1^xvi	102.29 (4)
Ag2^xi—Cu2—Ag2^xii	19.1 (6)	Sb—S2—Cu1^ix	102.29 (4)
Ag2^xi—Cu2—Ag2^xiii	160.9 (6)	Sb—S2—Cu1^xvi	102.29 (3)
Ag2^xi—Cu2—Ag2^iv	94.2 (4)	Sb—S2—Ag2^xvii	130.4 (2)
Ag2^xi—Cu2—Ag2^xiv	85.8 (4)	Sb—S2—Ag2^vi	130.4 (4)
Ag2^xi—Cu2—Ag2^vi	94.2 (4)	Sb—S2—Ag3^xvii	105.74 (15)
Ag2^xi—Cu2—Ag2^xv	85.8 (4)	Sb—S2—Ag3^vi	105.74 (18)
Ag2^xi—Cu2—Ag3	118.84 (12)	Ag1^ix—S2—Ag1^xvi	111.92 (6)
Ag2^xi—Cu2—Ag3^viii	61.16 (12)	Ag1^ix—S2—Cu1^ix	0
Ag2^xi—Cu2—Ag3^ix	56.0 (4)	Ag1^ix—S2—Cu1^xvi	111.92 (5)
Ag2^xi—Cu2—Ag3^x	124.0 (4)	Ag1^ix—S2—Ag2^xvii	125.64 (14)
Ag2^xi—Cu2—Ag3^xi	27.3 (4)	Ag1^ix—S2—Ag2^vi	73.3 (3)
Ag2^xi—Cu2—Ag3^v	152.7 (4)	Ag1^ix—S2—Ag3^xvii	139.26 (12)
Ag2^xi—Cu2—Ag3^xii	46.3 (4)	Ag1^ix—S2—Ag3^vi	90.33 (12)
Ag2^xi—Cu2—Ag3^xiii	133.7 (4)	Ag1^xvi—S2—Ag1^ix	111.92 (6)
Ag2^xi—Cu2—Ag3^iv	74.0 (4)	Ag1^xvi—S2—Cu1^ix	111.92 (5)
Ag2^xi—Cu2—Ag3^xiv	106.0 (4)	Ag1^xvi—S2—Cu1^xvi	0
Ag2^xi—Cu2—Ag3^vi	113.38 (17)	Ag1^xvi—S2—Ag2^xvii	73.3 (3)
Ag2^xi—Cu2—Ag3^xv	66.62 (17)	Ag1^xvi—S2—Ag2^vi	125.6 (5)
Ag2^xi—Cu2—S1	57.79 (7)	Ag1^xvi—S2—Ag3^xvii	90.3 (2)
Ag2^xi—Cu2—S1^viii	122.21 (7)	Ag1^xvi—S2—Ag3^vi	139.26 (19)
Ag2^v—Cu2—Ag2	73.5 (4)	Cu1^ix—S2—Cu1^xvi	111.92 (4)
Ag2^v—Cu2—Ag2^viii	106.5 (4)	Cu1^ix—S2—Ag2^xvii	125.64 (14)
Ag2^v—Cu2—Ag2^ix	101.1 (5)	Cu1^ix—S2—Ag2^vi	73.3 (3)
Ag2^v—Cu2—Ag2^x	78.9 (5)	Cu1^ix—S2—Ag3^xvii	139.26 (12)
Ag2^v—Cu2—Ag2^xi	180	Cu1^ix—S2—Ag3^vi	90.33 (11)
Ag2^v—Cu2—Ag2^xii	160.9 (6)	Cu1^xvi—S2—Cu1^ix	111.92 (4)
Ag2^v—Cu2—Ag2^xiii	19.1 (6)	Cu1^xvi—S2—Ag2^xvii	73.3 (3)
Ag2^v—Cu2—Ag2^iv	85.8 (4)	Cu1^xvi—S2—Ag2^vi	125.6 (5)
Ag2^v—Cu2—Ag2^xiv	94.2 (4)	Cu1^xvi—S2—Ag3^xvii	90.33 (19)
Ag2^v—Cu2—Ag2^vi	85.8 (4)	Cu1^xvi—S2—Ag3^vi	139.26 (18)
Ag2^v—Cu2—Ag2^xv	94.2 (4)	Ag2^xvii—S2—Ag2^vi	63.4 (4)
Ag2^v—Cu2—Ag3	61.16 (12)	Ag2^xvii—S2—Ag3^xvii	28.1 (4)
Ag2^v—Cu2—Ag3^viii	118.84 (12)	Ag2^xvii—S2—Ag3^vi	66.1 (3)
Ag2^v—Cu2—Ag3^ix	124.0 (4)	Ag2^vi—S2—Ag2^xvii	63.4 (4)
Ag2^v—Cu2—Ag3^x	56.0 (4)	Ag2^vi—S2—Ag3^xvii	66.1 (3)
Ag2^v—Cu2—Ag3^xi	152.7 (4)	Ag2^vi—S2—Ag3^vi	28.1 (3)
Ag2^v—Cu2—Ag3^v	27.3 (4)	Ag3^xvii—S2—Ag3^vi	54.0 (2)
Ag2^v—Cu2—Ag3^xii	133.7 (4)	Ag3^vi—S2—Ag3^xvii	54.0 (2)
Ag2^v—Cu2—Ag3^xiii	46.3 (4)	Ag2—S3—Ag2^xviii	94.9 (5)
Ag2^v—Cu2—Ag3^iv	106.0 (4)	Ag2—S3—Ag2ⁱⁱ	77.0 (5)
Ag2^v—Cu2—Ag3^xiv	74.0 (4)	Ag2—S3—Ag2^xix	94.9 (5)
Ag2^v—Cu2—Ag3^vi	66.62 (17)	Ag2—S3—Ag2^iv	22.0 (7)
Ag2^v—Cu2—Ag3^xv	113.38 (17)	Ag2—S3—Ag2^xx	108.8 (4)
Ag2^v—Cu2—S1	122.21 (7)	Ag2—S3—Ag3^vii	105.7 (4)
Ag2^v—Cu2—S1^viii	57.79 (7)	Ag2—S3—Ag3^x	78.0 (2)
Ag2^xii—Cu2—Ag2	94.2 (4)	Ag2—S3—Ag3^v	71.30 (16)
Ag2^xii—Cu2—Ag2^viii	85.8 (4)	Ag2—S3—Ag3^xxi	158.6 (4)
Ag2^xii—Cu2—Ag2^ix	94.2 (5)	Ag2—S3—Ag3^xxii	124.3 (4)
Ag2^xii—Cu2—Ag2^x	85.8 (5)	Ag2—S3—Ag3^xxiii	138.6 (5)
Ag2^xii—Cu2—Ag2^xi	19.1 (6)	Ag2^xviii—S3—Ag2	94.9 (5)
Ag2^xii—Cu2—Ag2^v	160.9 (6)	Ag2^xviii—S3—Ag2ⁱⁱ	108.8 (4)
Ag2^xii—Cu2—Ag2^xiii	180	Ag2^xviii—S3—Ag2^xix	94.9 (4)
Ag2^xii—Cu2—Ag2^iv	78.9 (5)	Ag2^xviii—S3—Ag2^iv	77.0 (5)
Ag2^xii—Cu2—Ag2^xiv	101.1 (5)	Ag2^xviii—S3—Ag2^xx	22.0 (5)
Ag2^xii—Cu2—Ag2^vi	106.5 (4)	Ag2^xviii—S3—Ag3^vii	158.6 (4)
Ag2^xii—Cu2—Ag2^xv	73.5 (4)	Ag2^xviii—S3—Ag3^x	105.7 (4)
Ag2^xii—Cu2—Ag3	113.38 (18)	Ag2^xviii—S3—Ag3^v	138.6 (3)
Ag2^xii—Cu2—Ag3^viii	66.62 (18)	Ag2^xviii—S3—Ag3^xxi	78.0 (4)
Ag2^xii—Cu2—Ag3^ix	74.0 (4)	Ag2^xviii—S3—Ag3^xxii	71.3 (3)
Ag2^xii—Cu2—Ag3^x	106.0 (4)	Ag2^xviii—S3—Ag3^xxiii	124.3 (4)
Ag2^xii—Cu2—Ag3^xi	46.3 (4)	Ag2ⁱⁱ—S3—Ag2	77.0 (5)
Ag2^xii—Cu2—Ag3^v	133.7 (4)	Ag2ⁱⁱ—S3—Ag2^xviii	108.8 (4)
Ag2^xii—Cu2—Ag3^xii	27.3 (4)	Ag2ⁱⁱ—S3—Ag2^xix	22.0 (7)
Ag2^xii—Cu2—Ag3^xiii	152.7 (4)	Ag2ⁱⁱ—S3—Ag2^iv	94.9 (5)
Ag2^xii—Cu2—Ag3^iv	56.0 (4)	Ag2ⁱⁱ—S3—Ag2^xx	94.9 (5)
Ag2^xii—Cu2—Ag3^xiv	124.0 (4)	Ag2ⁱⁱ—S3—Ag3^vii	71.30 (16)
Ag2^xii—Cu2—Ag3^vi	118.84 (13)	Ag2ⁱⁱ—S3—Ag3^x	138.6 (5)
Ag2^xii—Cu2—Ag3^xv	61.16 (13)	Ag2ⁱⁱ—S3—Ag3^v	105.7 (4)
Ag2^xii—Cu2—S1	57.79 (7)	Ag2ⁱⁱ—S3—Ag3^xxi	124.3 (4)
Ag2^xii—Cu2—S1^viii	122.21 (7)	Ag2ⁱⁱ—S3—Ag3^xxii	158.6 (4)
Ag2^xiii—Cu2—Ag2	85.8 (4)	Ag2ⁱⁱ—S3—Ag3^xxiii	78.0 (2)
Ag2^xiii—Cu2—Ag2^viii	94.2 (4)	Ag2^xix—S3—Ag2	94.9 (5)
Ag2^xiii—Cu2—Ag2^ix	85.8 (5)	Ag2^xix—S3—Ag2^xviii	94.9 (4)
Ag2^xiii—Cu2—Ag2^x	94.2 (5)	Ag2^xix—S3—Ag2ⁱⁱ	22.0 (7)
Ag2^xiii—Cu2—Ag2^xi	160.9 (6)	Ag2^xix—S3—Ag2^iv	108.8 (4)
Ag2^xiii—Cu2—Ag2^v	19.1 (6)	Ag2^xix—S3—Ag2^xx	77.0 (5)
Ag2^xiii—Cu2—Ag2^xii	180	Ag2^xix—S3—Ag3^vii	78.0 (2)
Ag2^xiii—Cu2—Ag2^iv	101.1 (5)	Ag2^xix—S3—Ag3^x	158.6 (4)
Ag2^xiii—Cu2—Ag2^xiv	78.9 (5)	Ag2^xix—S3—Ag3^v	124.3 (4)
Ag2^xiii—Cu2—Ag2^vi	73.5 (4)	Ag2^xix—S3—Ag3^xxi	105.7 (4)
Ag2^xiii—Cu2—Ag2^xv	106.5 (4)	Ag2^xix—S3—Ag3^xxii	138.6 (5)
Ag2^xiii—Cu2—Ag3	66.62 (18)	Ag2^xix—S3—Ag3^xxiii	71.30 (16)
Ag2^xiii—Cu2—Ag3^viii	113.38 (18)	Ag2^iv—S3—Ag2	22.0 (7)
Ag2^xiii—Cu2—Ag3^ix	106.0 (4)	Ag2^iv—S3—Ag2^xviii	77.0 (5)
Ag2^xiii—Cu2—Ag3^x	74.0 (4)	Ag2^iv—S3—Ag2ⁱⁱ	94.9 (5)
Ag2^xiii—Cu2—Ag3^xi	133.7 (4)	Ag2^iv—S3—Ag2^xix	108.8 (4)
Ag2^xiii—Cu2—Ag3^v	46.3 (4)	Ag2^iv—S3—Ag2^xx	94.9 (4)
Ag2^xiii—Cu2—Ag3^xii	152.7 (4)	Ag2^iv—S3—Ag3^vii	124.3 (4)
Ag2^xiii—Cu2—Ag3^xiii	27.3 (4)	Ag2^iv—S3—Ag3^x	71.30 (16)
Ag2^xiii—Cu2—Ag3^iv	124.0 (4)	Ag2^iv—S3—Ag3^v	78.0 (2)
Ag2^xiii—Cu2—Ag3^xiv	56.0 (4)	Ag2^iv—S3—Ag3^xxi	138.6 (5)
Ag2^xiii—Cu2—Ag3^vi	61.16 (13)	Ag2^iv—S3—Ag3^xxii	105.7 (4)
Ag2^xiii—Cu2—Ag3^xv	118.84 (13)	Ag2^iv—S3—Ag3^xxiii	158.6 (4)
Ag2^xiii—Cu2—S1	122.21 (7)	Ag2^xx—S3—Ag2	108.8 (4)
Ag2^xiii—Cu2—S1^viii	57.79 (7)	Ag2^xx—S3—Ag2^xviii	22.0 (5)
Ag2^iv—Cu2—Ag2	19.1 (6)	Ag2^xx—S3—Ag2ⁱⁱ	94.9 (5)
Ag2^iv—Cu2—Ag2^viii	160.9 (6)	Ag2^xx—S3—Ag2^xix	77.0 (5)
Ag2^iv—Cu2—Ag2^ix	106.5 (4)	Ag2^xx—S3—Ag2^iv	94.9 (4)
Ag2^iv—Cu2—Ag2^x	73.5 (4)	Ag2^xx—S3—Ag3^vii	138.6 (3)
Ag2^iv—Cu2—Ag2^xi	94.2 (4)	Ag2^xx—S3—Ag3^x	124.3 (4)
Ag2^iv—Cu2—Ag2^v	85.8 (4)	Ag2^xx—S3—Ag3^v	158.6 (4)
Ag2^iv—Cu2—Ag2^xii	78.9 (5)	Ag2^xx—S3—Ag3^xxi	71.3 (3)
Ag2^iv—Cu2—Ag2^xiii	101.1 (5)	Ag2^xx—S3—Ag3^xxii	78.0 (4)
Ag2^iv—Cu2—Ag2^xiv	180	Ag2^xx—S3—Ag3^xxiii	105.7 (4)
Ag2^iv—Cu2—Ag2^vi	94.2 (5)	Ag3^vii—S3—Ag3^x	84.6 (2)
Ag2^iv—Cu2—Ag2^xv	85.8 (5)	Ag3^vii—S3—Ag3^v	56.71 (16)
Ag2^iv—Cu2—Ag3	46.3 (4)	Ag3^vii—S3—Ag3^xxi	84.6 (2)
Ag2^iv—Cu2—Ag3^viii	133.7 (4)	Ag3^vii—S3—Ag3^xxii	100.7 (2)
Ag2^iv—Cu2—Ag3^ix	118.84 (13)	Ag3^vii—S3—Ag3^xxiii	34.3 (3)
Ag2^iv—Cu2—Ag3^x	61.16 (13)	Ag3^x—S3—Ag3^vii	84.6 (2)
Ag2^iv—Cu2—Ag3^xi	113.38 (18)	Ag3^x—S3—Ag3^v	34.3 (3)
Ag2^iv—Cu2—Ag3^v	66.62 (18)	Ag3^x—S3—Ag3^xxi	84.6 (2)
Ag2^iv—Cu2—Ag3^xii	56.0 (4)	Ag3^x—S3—Ag3^xxii	56.7 (2)
Ag2^iv—Cu2—Ag3^xiii	124.0 (4)	Ag3^x—S3—Ag3^xxiii	100.72 (17)
Ag2^iv—Cu2—Ag3^iv	27.3 (4)	Ag3^v—S3—Ag3^vii	56.71 (16)
Ag2^iv—Cu2—Ag3^xiv	152.7 (4)	Ag3^v—S3—Ag3^x	34.3 (3)
Ag2^iv—Cu2—Ag3^vi	74.0 (4)	Ag3^v—S3—Ag3^xxi	100.7 (2)
Ag2^iv—Cu2—Ag3^xv	106.0 (4)	Ag3^v—S3—Ag3^xxii	84.6 (2)
Ag2^iv—Cu2—S1	57.79 (7)	Ag3^v—S3—Ag3^xxiii	84.6 (2)
Ag2^iv—Cu2—S1^viii	122.21 (7)	Ag3^xxi—S3—Ag3^vii	84.6 (2)
Ag2^xiv—Cu2—Ag2	160.9 (6)	Ag3^xxi—S3—Ag3^x	84.6 (2)
Ag2^xiv—Cu2—Ag2^viii	19.1 (6)	Ag3^xxi—S3—Ag3^v	100.7 (2)
Ag2^xiv—Cu2—Ag2^ix	73.5 (4)	Ag3^xxi—S3—Ag3^xxii	34.34 (16)
Ag2^xiv—Cu2—Ag2^x	106.5 (4)	Ag3^xxi—S3—Ag3^xxiii	56.7 (2)
Ag2^xiv—Cu2—Ag2^xi	85.8 (4)	Ag3^xxii—S3—Ag3^vii	100.7 (2)
Ag2^xiv—Cu2—Ag2^v	94.2 (4)	Ag3^xxii—S3—Ag3^x	56.7 (2)
Ag2^xiv—Cu2—Ag2^xii	101.1 (5)	Ag3^xxii—S3—Ag3^v	84.6 (2)
Ag2^xiv—Cu2—Ag2^xiii	78.9 (5)	Ag3^xxii—S3—Ag3^xxi	34.34 (16)
Ag2^xiv—Cu2—Ag2^iv	180	Ag3^xxii—S3—Ag3^xxiii	84.6 (2)
Ag2^xiv—Cu2—Ag2^vi	85.8 (5)	Ag3^xxiii—S3—Ag3^vii	34.3 (3)
Ag2^xiv—Cu2—Ag2^xv	94.2 (5)	Ag3^xxiii—S3—Ag3^x	100.72 (17)
Ag2^xiv—Cu2—Ag3	133.7 (4)	Ag3^xxiii—S3—Ag3^v	84.6 (2)
Ag2^xiv—Cu2—Ag3^viii	46.3 (4)	Ag3^xxiii—S3—Ag3^xxi	56.7 (2)
Ag2^xiv—Cu2—Ag3^ix	61.16 (13)	Ag3^xxiii—S3—Ag3^xxii	84.6 (2)
Ag2^xiv—Cu2—Ag3^x	118.84 (13)	Ag1—S4—Ag1^xxiv	180
Ag2^xiv—Cu2—Ag3^xi	66.62 (18)	Ag1—S4—Ag1^ix	89.92 (5)
Ag2^xiv—Cu2—Ag3^v	113.38 (18)	Ag1—S4—Ag1^xxv	90.08 (5)
Ag2^xiv—Cu2—Ag3^xii	124.0 (4)	Ag1—S4—Ag1^xi	89.92 (3)
Ag2^xiv—Cu2—Ag3^xiii	56.0 (4)	Ag1—S4—Ag1^xxvi	90.08 (3)
Ag2^xiv—Cu2—Ag3^iv	152.7 (4)	Ag1—S4—Cu1	0
Ag2^xiv—Cu2—Ag3^xiv	27.3 (4)	Ag1—S4—Cu1^xxiv	180
Ag2^xiv—Cu2—Ag3^vi	106.0 (4)	Ag1—S4—Cu1^ix	89.92 (4)
Ag2^xiv—Cu2—Ag3^xv	74.0 (4)	Ag1—S4—Cu1^xxv	90.08 (4)
Ag2^xiv—Cu2—S1	122.21 (7)	Ag1—S4—Cu1^xi	89.92 (2)
Ag2^xiv—Cu2—S1^viii	57.79 (7)	Ag1—S4—Cu1^xxvi	90.08 (2)
Ag2^vi—Cu2—Ag2	78.9 (5)	Ag1^xxiv—S4—Ag1	180
Ag2^vi—Cu2—Ag2^viii	101.1 (5)	Ag1^xxiv—S4—Ag1^ix	90.08 (5)
Ag2^vi—Cu2—Ag2^ix	19.1 (4)	Ag1^xxiv—S4—Ag1^xxv	89.92 (5)
Ag2^vi—Cu2—Ag2^x	160.9 (4)	Ag1^xxiv—S4—Ag1^xi	90.08 (3)
Ag2^vi—Cu2—Ag2^xi	94.2 (4)	Ag1^xxiv—S4—Ag1^xxvi	89.92 (3)
Ag2^vi—Cu2—Ag2^v	85.8 (4)	Ag1^xxiv—S4—Cu1	180
Ag2^vi—Cu2—Ag2^xii	106.5 (4)	Ag1^xxiv—S4—Cu1^xxiv	0
Ag2^vi—Cu2—Ag2^xiii	73.5 (4)	Ag1^xxiv—S4—Cu1^ix	90.08 (4)
Ag2^vi—Cu2—Ag2^iv	94.2 (5)	Ag1^xxiv—S4—Cu1^xxv	89.92 (4)
Ag2^vi—Cu2—Ag2^xiv	85.8 (5)	Ag1^xxiv—S4—Cu1^xi	90.08 (2)
Ag2^vi—Cu2—Ag2^xv	180	Ag1^xxiv—S4—Cu1^xxvi	89.92 (2)
Ag2^vi—Cu2—Ag3	56.0 (3)	Ag1^ix—S4—Ag1	89.92 (5)
Ag2^vi—Cu2—Ag3^viii	124.0 (3)	Ag1^ix—S4—Ag1^xxiv	90.08 (5)
Ag2^vi—Cu2—Ag3^ix	46.3 (3)	Ag1^ix—S4—Ag1^xxv	180
Ag2^vi—Cu2—Ag3^x	133.7 (3)	Ag1^ix—S4—Ag1^xi	89.92 (6)
Ag2^vi—Cu2—Ag3^xi	74.0 (3)	Ag1^ix—S4—Ag1^xxvi	90.08 (6)
Ag2^vi—Cu2—Ag3^v	106.0 (3)	Ag1^ix—S4—Cu1	89.92 (2)
Ag2^vi—Cu2—Ag3^xii	118.8 (3)	Ag1^ix—S4—Cu1^xxiv	90.08 (2)
Ag2^vi—Cu2—Ag3^xiii	61.2 (3)	Ag1^ix—S4—Cu1^ix	0
Ag2^vi—Cu2—Ag3^iv	113.4 (3)	Ag1^ix—S4—Cu1^xxv	180
Ag2^vi—Cu2—Ag3^xiv	66.6 (3)	Ag1^ix—S4—Cu1^xi	89.92 (4)
Ag2^vi—Cu2—Ag3^vi	27.3 (3)	Ag1^ix—S4—Cu1^xxvi	90.08 (4)
Ag2^vi—Cu2—Ag3^xv	152.7 (3)	Ag1^xxv—S4—Ag1	90.08 (5)
Ag2^vi—Cu2—S1	57.8 (3)	Ag1^xxv—S4—Ag1^xxiv	89.92 (5)
Ag2^vi—Cu2—S1^viii	122.2 (3)	Ag1^xxv—S4—Ag1^ix	180
Ag2^xv—Cu2—Ag2	101.1 (5)	Ag1^xxv—S4—Ag1^xi	90.08 (6)
Ag2^xv—Cu2—Ag2^viii	78.9 (5)	Ag1^xxv—S4—Ag1^xxvi	89.92 (6)
Ag2^xv—Cu2—Ag2^ix	160.9 (4)	Ag1^xxv—S4—Cu1	90.08 (2)
Ag2^xv—Cu2—Ag2^x	19.1 (4)	Ag1^xxv—S4—Cu1^xxiv	89.92 (2)
Ag2^xv—Cu2—Ag2^xi	85.8 (4)	Ag1^xxv—S4—Cu1^ix	180
Ag2^xv—Cu2—Ag2^v	94.2 (4)	Ag1^xxv—S4—Cu1^xxv	0
Ag2^xv—Cu2—Ag2^xii	73.5 (4)	Ag1^xxv—S4—Cu1^xi	90.08 (4)
Ag2^xv—Cu2—Ag2^xiii	106.5 (4)	Ag1^xxv—S4—Cu1^xxvi	89.92 (4)
Ag2^xv—Cu2—Ag2^iv	85.8 (5)	Ag1^xi—S4—Ag1	89.92 (3)
Ag2^xv—Cu2—Ag2^xiv	94.2 (5)	Ag1^xi—S4—Ag1^xxiv	90.08 (3)
Ag2^xv—Cu2—Ag2^vi	180	Ag1^xi—S4—Ag1^ix	89.92 (6)
Ag2^xv—Cu2—Ag3	124.0 (3)	Ag1^xi—S4—Ag1^xxv	90.08 (6)
Ag2^xv—Cu2—Ag3^viii	56.0 (3)	Ag1^xi—S4—Ag1^xxvi	180
Ag2^xv—Cu2—Ag3^ix	133.7 (3)	Ag1^xi—S4—Cu1	89.92 (2)
Ag2^xv—Cu2—Ag3^x	46.3 (3)	Ag1^xi—S4—Cu1^xxiv	90.08 (2)
Ag2^xv—Cu2—Ag3^xi	106.0 (3)	Ag1^xi—S4—Cu1^ix	89.92 (4)
Ag2^xv—Cu2—Ag3^v	74.0 (3)	Ag1^xi—S4—Cu1^xxv	90.08 (4)
Ag2^xv—Cu2—Ag3^xii	61.2 (3)	Ag1^xi—S4—Cu1^xi	0
Ag2^xv—Cu2—Ag3^xiii	118.8 (3)	Ag1^xi—S4—Cu1^xxvi	180
Ag2^xv—Cu2—Ag3^iv	66.6 (3)	Ag1^xxvi—S4—Ag1	90.08 (3)
Ag2^xv—Cu2—Ag3^xiv	113.4 (3)	Ag1^xxvi—S4—Ag1^xxiv	89.92 (3)
Ag2^xv—Cu2—Ag3^vi	152.7 (3)	Ag1^xxvi—S4—Ag1^ix	90.08 (6)
Ag2^xv—Cu2—Ag3^xv	27.3 (3)	Ag1^xxvi—S4—Ag1^xxv	89.92 (6)
Ag2^xv—Cu2—S1	122.2 (3)	Ag1^xxvi—S4—Ag1^xi	180
Ag2^xv—Cu2—S1^viii	57.8 (3)	Ag1^xxvi—S4—Cu1	90.08 (2)
Ag3—Cu2—Ag3^viii	180	Ag1^xxvi—S4—Cu1^xxiv	89.92 (2)
Ag3—Cu2—Ag3^ix	98.88 (17)	Ag1^xxvi—S4—Cu1^ix	90.08 (4)
Ag3—Cu2—Ag3^x	81.12 (17)	Ag1^xxvi—S4—Cu1^xxv	89.92 (4)
Ag3—Cu2—Ag3^xi	117.57 (12)	Ag1^xxvi—S4—Cu1^xi	180
Ag3—Cu2—Ag3^v	62.43 (12)	Ag1^xxvi—S4—Cu1^xxvi	0
Ag3—Cu2—Ag3^xii	98.88 (16)	Cu1—S4—Cu1^xxiv	180
Ag3—Cu2—Ag3^xiii	81.12 (16)	Cu1—S4—Cu1^ix	89.919
Ag3—Cu2—Ag3^iv	73.3 (2)	Cu1—S4—Cu1^xxv	90.081
Ag3—Cu2—Ag3^xiv	106.7 (2)	Cu1—S4—Cu1^xi	89.919
Ag3—Cu2—Ag3^vi	30.0 (2)	Cu1—S4—Cu1^xxvi	90.081
Ag3—Cu2—Ag3^xv	150.0 (2)	Cu1^xxiv—S4—Cu1	180
Ag3—Cu2—S1	61.31 (7)	Cu1^xxiv—S4—Cu1^ix	90.081
Ag3—Cu2—S1^viii	118.69 (7)	Cu1^xxiv—S4—Cu1^xxv	89.919
Ag3^viii—Cu2—Ag3	180	Cu1^xxiv—S4—Cu1^xi	90.081
Ag3^viii—Cu2—Ag3^ix	81.12 (17)	Cu1^xxiv—S4—Cu1^xxvi	89.919
Ag3^viii—Cu2—Ag3^x	98.88 (17)	Cu1^ix—S4—Cu1	89.919
Ag3^viii—Cu2—Ag3^xi	62.43 (12)	Cu1^ix—S4—Cu1^xxiv	90.081
Ag3^viii—Cu2—Ag3^v	117.57 (12)	Cu1^ix—S4—Cu1^xxv	180
Ag3^viii—Cu2—Ag3^xii	81.12 (16)	Cu1^ix—S4—Cu1^xi	89.919
Ag3^viii—Cu2—Ag3^xiii	98.88 (16)	Cu1^ix—S4—Cu1^xxvi	90.081
Ag3^viii—Cu2—Ag3^iv	106.7 (2)	Cu1^xxv—S4—Cu1	90.081
Ag3^viii—Cu2—Ag3^xiv	73.3 (2)	Cu1^xxv—S4—Cu1^xxiv	89.919
Ag3^viii—Cu2—Ag3^vi	150.0 (2)	Cu1^xxv—S4—Cu1^ix	180
Ag3^viii—Cu2—Ag3^xv	30.0 (2)	Cu1^xxv—S4—Cu1^xi	90.081
Ag3^viii—Cu2—S1	118.69 (7)	Cu1^xxv—S4—Cu1^xxvi	89.919
Ag3^viii—Cu2—S1^viii	61.31 (7)	Cu1^xi—S4—Cu1	89.919
Ag3^ix—Cu2—Ag3	98.88 (17)	Cu1^xi—S4—Cu1^xxiv	90.081
Ag3^ix—Cu2—Ag3^viii	81.12 (17)	Cu1^xi—S4—Cu1^ix	89.919
Ag3^ix—Cu2—Ag3^x	180	Cu1^xi—S4—Cu1^xxv	90.081
Ag3^ix—Cu2—Ag3^xi	30.0 (2)	Cu1^xi—S4—Cu1^xxvi	180
Ag3^ix—Cu2—Ag3^v	150.0 (2)	Cu1^xxvi—S4—Cu1	90.081
Ag3^ix—Cu2—Ag3^xii	98.9 (2)	Cu1^xxvi—S4—Cu1^xxiv	89.919
Ag3^ix—Cu2—Ag3^xiii	81.1 (2)	Cu1^xxvi—S4—Cu1^ix	90.081
Ag3^ix—Cu2—Ag3^iv	117.57 (15)	Cu1^xxvi—S4—Cu1^xxv	89.919
Ag3^ix—Cu2—Ag3^xiv	62.43 (15)	Cu1^xxvi—S4—Cu1^xi	180
Ag3^ix—Cu2—Ag3^vi	73.3 (2)

Symmetry codes: (i) −y+1, x−y+1, z; (ii) −y+1, −x+1, z; (iii) −y+1, −x, z; (iv) x, x−y, z; (v) y, x, −z; (vi) −x+y, y, z; (vii) −x+1, −y+1, −z; (viii) −x, −y, −z; (ix) −y, x−y, z; (x) y, −x+y, −z; (xi) −y, −x, z; (xii) −x+y, −x, z; (xiii) x−y, x, −z; (xiv) −x, −x+y, −z; (xv) x−y, −y, −z; (xvi) −y, −x+1, z; (xvii) −x+y, −x+1, z; (xviii) −y+1, x−y, z; (xix) −x+y+1, −x+1, z; (xx) −x+y+1, y, z; (xxi) x−y+1, x, −z; (xxii) −x+1, −x+y, −z; (xxiii) x−y+1, −y+1, −z; (xxiv) −x, −y, −z+1; (xxv) y, −x+y, −z+1; (xxvi) y, x, −z+1.

(120K) top

Crystal data top

Ag_13.034As_1.179Cu_2.966S₁₁Sb_0.821	F(000) = 955
M_r = 2135.4	D_x = 6.377 Mg m⁻³
Trigonal, P3m1	Mo Kα radiation, λ = 0.71069 Å
Hall symbol: -P 3;-2"	µ = 17.70 mm⁻¹
a = 7.3721 (6) Å	T = 120 K
c = 11.8104 (12) Å	Prism, black
V = 555.88 (9) Å³	0.15 × 0.15 × 0.04 mm
Z = 1

Data collection top

Nonius KappaCCD diffractometer	1167 reflections with I > 2σ(I)
ϕ/ω scans	R_int = 0.048
Absorption correction: gaussian (Jana2000; Petricek, Dusek & Palatinus, 2000)	θ_max = 40.0°, θ_min = 6.5°
T_min = 0.165, T_max = 0.659	h = −12→13
17722 measured reflections	k = −13→13
1341 independent reflections	l = −20→21

Refinement top

Refinement on F²	Weighting scheme based on measured s.u.'s w = 1/[σ²(I) + 0.001936I²]
R[F² > 2σ(F²)] = 0.045	(Δ/σ)_max = 0.001
wR(F²) = 0.133	Δρ_max = 1.57 e Å⁻³
S = 2.19	Δρ_min = −1.86 e Å⁻³
1341 reflections	Extinction correction: B-C type 1 Lorentzian isotropic (Becker & Coppens, 1974)
96 parameters	Extinction coefficient: 0.39 (8)

Crystal data top

Ag_13.034As_1.179Cu_2.966S₁₁Sb_0.821	Z = 1
M_r = 2135.4	Mo Kα radiation
Trigonal, P3m1	µ = 17.70 mm⁻¹
a = 7.3721 (6) Å	T = 120 K
c = 11.8104 (12) Å	0.15 × 0.15 × 0.04 mm
V = 555.88 (9) Å³

Data collection top

Nonius KappaCCD diffractometer	1341 independent reflections
Absorption correction: gaussian (Jana2000; Petricek, Dusek & Palatinus, 2000)	1167 reflections with I > 2σ(I)
T_min = 0.165, T_max = 0.659	R_int = 0.048
17722 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.045	96 parameters
wR(F²) = 0.133	Δρ_max = 1.57 e Å⁻³
S = 2.19	Δρ_min = −1.86 e Å⁻³
1341 reflections

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
As	0.333333	0.666667	0.40833 (5)	0.01518 (14)	0.5896
Sb	0.333333	0.666667	0.408329	0.01518 (14)	0.4104
Ag1	0.29992 (17)	0.14996 (9)	0.38548 (11)	0.0361 (4)	0.6724
Cu1	0.299918	0.149959	0.385482	0.0361 (4)	0.3276
Ag2	0.3567 (4)	0.226 (3)	0.12401 (17)	0.263 (9)	0.324 (5)
Ag3	0.2857 (5)	0.3745 (4)	0.1160 (2)	0.0674 (13)	0.376 (4)
Ag4	0.4538 (11)	−0.092 (2)	0.1137 (5)	0.083 (6)	0.101 (13)
Cu2	0	0	0	0.0191 (3)
S1	0	0	0.18297 (13)	0.0192 (4)
S2	0.01678 (16)	0.50839 (8)	0.31254 (10)	0.0191 (3)
S3	0.666667	0.333333	0.0206 (2)	0.0346 (6)
S4	0.0853 (6)	0	0.5	0.0179 (15)	0.1667

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
As	0.01564 (18)	0.01564 (18)	0.0142 (2)	0.00782 (9)	0	0
Sb	0.01564 (18)	0.01564 (18)	0.0142 (2)	0.00782 (9)	0	0
Ag1	0.0493 (6)	0.0274 (4)	0.0387 (6)	0.0247 (3)	−0.0156 (4)	−0.0078 (2)
Cu1	0.0493 (6)	0.0274 (4)	0.0387 (6)	0.0247 (3)	−0.0156 (4)	−0.0078 (2)
Ag2	0.0224 (7)	0.50 (2)	0.0230 (5)	−0.055 (4)	0.0021 (5)	−0.003 (4)
Ag3	0.106 (2)	0.0315 (14)	0.0310 (11)	0.0092 (12)	−0.0249 (10)	−0.0007 (8)
Ag4	0.105 (8)	0.130 (10)	0.021 (2)	0.065 (5)	−0.0100 (18)	−0.020 (4)
Cu2	0.0243 (4)	0.0243 (4)	0.0086 (4)	0.01216 (18)	0	0
S1	0.0241 (5)	0.0241 (5)	0.0095 (5)	0.0120 (2)	0	0
S2	0.0159 (4)	0.0186 (3)	0.0219 (4)	0.00796 (19)	0.0032 (3)	0.00161 (16)
S3	0.0378 (7)	0.0378 (7)	0.0282 (10)	0.0189 (4)	0	0
S4	0.0138 (14)	0.029 (3)	0.0162 (17)	0.0144 (13)	−0.0018 (7)	−0.0035 (14)

Bond lengths (Å) top

As—Sb	0	Ag2—Ag4	2.78 (3)
As—S2	2.3161 (11)	Ag2—Ag4^xii	2.10 (2)
As—S2ⁱ	2.3161 (12)	Ag2—Cu2	2.731 (4)
As—S2ⁱⁱ	2.3161 (11)	Ag2—S1	2.408 (4)
Sb—S2	2.3161 (11)	Ag2—S2ⁱ	2.865 (13)
Sb—S2ⁱ	2.3161 (12)	Ag2—S3	2.352 (5)
Sb—S2ⁱⁱ	2.3161 (11)	Ag3—Ag3ⁱⁱ	2.504 (3)
Ag1—Cu1	0	Ag3—Ag3^x	2.965 (4)
Ag1—S2ⁱ	2.4469 (13)	Ag3—Ag3^xi	1.452 (6)
Ag1—S2ⁱⁱⁱ	2.4469 (17)	Ag3—Ag4^v	2.33 (2)
Ag1—S4	1.951 (3)	Ag3—Ag4^xii	1.253 (10)
Ag1—S4^iv	2.825 (4)	Ag3—Cu2	2.850 (2)
Ag1—S4^v	2.4272 (18)	Ag3—S1	2.621 (2)
Ag1—S4^vi	2.4272 (16)	Ag3—S2ⁱ	2.677 (3)
Ag1—S4^vii	2.825 (4)	Ag3—S3^xiii	2.570 (3)
Ag1—S4^viii	1.951 (4)	Ag4—Ag4^xiv	2.933 (11)
Cu1—S2ⁱ	2.4469 (11)	Ag4—Ag4^xv	2.664 (15)
Cu1—S2ⁱⁱⁱ	2.4469 (11)	Ag4—Ag4^xvi	2.66 (2)
Cu1—S4	1.951 (3)	Ag4—S2ⁱⁱⁱ	2.398 (7)
Cu1—S4^iv	2.825 (4)	Ag4—S3	2.932 (13)
Cu1—S4^v	2.4272 (12)	Ag4—S3^xiv	2.209 (11)
Cu1—S4^vi	2.4272 (12)	Cu2—S1	2.1610 (16)
Cu1—S4^vii	2.825 (3)	Cu2—S1^xvii	2.1610 (16)
Cu1—S4^viii	1.951 (3)	S4—S4^iv	1.258 (7)
Ag2—Ag2^ix	0.70 (3)	S4—S4^v	1.089 (6)
Ag2—Ag3	1.43 (2)	S4—S4^vi	0.629 (3)
Ag2—Ag3^x	2.861 (4)	S4—S4^vii	1.089 (6)
Ag2—Ag3^ix	2.11 (2)	S4—S4^viii	0.629 (6)
Ag2—Ag3^xi	2.696 (19)

Symmetry codes: (i) −y+1, x−y+1, z; (ii) −y+1, −x+1, z; (iii) −y+1, −x, z; (iv) −x, −y, −z+1; (v) −y, x−y, z; (vi) y, −x+y, −z+1; (vii) −x+y, −x, z; (viii) x−y, x, −z+1; (ix) x, x−y, z; (x) y, x, −z; (xi) −x+y, y, z; (xii) −x+y+1, −x+1, z; (xiii) −x+1, −y+1, −z; (xiv) −x+1, −y, −z; (xv) −y, x−y−1, z; (xvi) −x+y+1, −x, z; (xvii) −x, −y, −z.

(15K) top

Crystal data top

Ag_12.21As_1.194Cu_3.79S₁₁Sb_0.806	F(000) = 941
M_r = 2098.2	D_x = 6.234 Mg m⁻³
Trigonal, P3m1	Mo Kα radiation, λ = 0.71069 Å
Hall symbol: -P 3;-2"	µ = 17.68 mm⁻¹
a = 7.389 (1) Å	T = 15 K
c = 11.816 (2) Å	Prism, black
V = 558.69 (14) Å³	0.18 × 0.16 × 0.15 mm
Z = 1

Data collection top

Oxford Diffraction Xcalibur 2 diffractometer	650 reflections with I > 2σ(I)
ω scans	R_int = 0.051
Absorption correction: gaussian (Jana2000; Petricek, Dusek & Palatinus, 2000)	θ_max = 33.2°, θ_min = 4.7°
T_min = 0.069, T_max = 0.158	h = −11→10
2442 measured reflections	k = −9→10
818 independent reflections	l = −4→18

Refinement top

Refinement on F²	Weighting scheme based on measured s.u.'s w = 1/[σ²(I) + 0.001936I²]
R[F² > 2σ(F²)] = 0.044	(Δ/σ)_max = 0.001
wR(F²) = 0.126	Δρ_max = 1.54 e Å⁻³
S = 1.84	Δρ_min = −1.48 e Å⁻³
818 reflections	Extinction correction: B-C type 1 Lorentzian isotropic (Becker & Coppens, 1974)
77 parameters	Extinction coefficient: 0.01 (2)

Crystal data top

Ag_12.21As_1.194Cu_3.79S₁₁Sb_0.806	Z = 1
M_r = 2098.2	Mo Kα radiation
Trigonal, P3m1	µ = 17.68 mm⁻¹
a = 7.389 (1) Å	T = 15 K
c = 11.816 (2) Å	0.18 × 0.16 × 0.15 mm
V = 558.69 (14) Å³

Data collection top

Oxford Diffraction Xcalibur 2 diffractometer	818 independent reflections
Absorption correction: gaussian (Jana2000; Petricek, Dusek & Palatinus, 2000)	650 reflections with I > 2σ(I)
T_min = 0.069, T_max = 0.158	R_int = 0.051
2442 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.044	77 parameters
wR(F²) = 0.126	Δρ_max = 1.54 e Å⁻³
S = 1.84	Δρ_min = −1.48 e Å⁻³
818 reflections

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
As	0.333333	0.666667	0.40976 (8)	0.0144 (3)	0.596 (17)
Sb	0.333333	0.666667	0.409764	0.0144 (3)	0.404 (17)
Ag1	0.2989 (3)	0.14946 (15)	0.38540 (14)	0.0301 (9)	0.538 (17)
Cu1	0.298921	0.149461	0.385401	0.0301 (9)	0.462 (17)
Ag2	0.3606 (4)	0.2215 (6)	0.1239 (2)	0.0175 (9)*	0.152 (3)
Ag3	0.3341 (6)	0.3675 (12)	0.1109 (3)	0.0346 (11)*	0.225 (7)
Ag4	0.4475 (11)	0.5525 (11)	0.1133 (6)	0.069 (5)	0.1057
Ag5	0.3568 (7)	0.2954 (13)	0.1228 (3)	0.0162 (16)*	0.102 (4)
Ag6	0.251 (2)	0.3821 (5)	0.1211 (4)	0.050 (5)	0.218 (9)
Cu2	0	0	0	0.0195 (6)
S1	0	0	0.1829 (2)	0.0208 (8)
S2	0.0152 (3)	0.50762 (16)	0.31195 (17)	0.0204 (6)
S3	0.666667	0.333333	0.0210 (3)	0.0358 (11)
S4	0.0861 (13)	0	0.5	0.018 (5)	0.1667

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
As	0.0148 (5)	0.0148 (5)	0.0138 (5)	0.0074 (2)	0	0
Sb	0.0148 (5)	0.0148 (5)	0.0138 (5)	0.0074 (2)	0	0
Ag1	0.0418 (13)	0.0237 (11)	0.0310 (12)	0.0209 (6)	−0.0223 (7)	−0.0112 (4)
Cu1	0.0418 (13)	0.0237 (11)	0.0310 (12)	0.0209 (6)	−0.0223 (7)	−0.0112 (4)
Ag4	0.084 (6)	0.084 (6)	0.020 (3)	0.027 (7)	−0.012 (2)	0.012 (2)
Ag6	0.095 (11)	0.0240 (12)	0.0192 (11)	0.0223 (18)	−0.020 (3)	−0.0039 (7)
Cu2	0.0252 (8)	0.0252 (8)	0.0082 (8)	0.0126 (4)	0	0
S1	0.0251 (11)	0.0251 (11)	0.0123 (11)	0.0125 (5)	0	0
S2	0.0175 (9)	0.0199 (7)	0.0230 (9)	0.0087 (5)	0.0022 (7)	0.0011 (3)
S3	0.0409 (15)	0.0409 (15)	0.0254 (16)	0.0205 (8)	0	0
S4	0.015 (4)	0.029 (8)	0.014 (3)	0.014 (4)	0.0000 (14)	0.000 (3)

Bond lengths (Å) top

As—Sb	0	Ag2—Ag6^xviii	2.507 (16)
As—Ag1ⁱ	3.3758 (19)	Ag2—Cu2	2.750 (2)
As—Ag1ⁱⁱ	3.376 (2)	Ag2—S1	2.429 (3)
As—Ag1ⁱⁱⁱ	3.3757 (19)	Ag2—S2^iv	2.880 (4)
As—Cu1ⁱ	3.3758 (7)	Ag2—S2^x	3.263 (5)
As—Cu1ⁱⁱ	3.3757 (7)	Ag2—S3	2.326 (3)
As—Cu1ⁱⁱⁱ	3.3757 (7)	Ag3—Ag3^xix	3.451 (5)
As—S2	2.341 (2)	Ag3—Ag3^v	2.205 (7)
As—S2^iv	2.341 (2)	Ag3—Ag3^xv	2.655 (5)
As—S2^v	2.341 (2)	Ag3—Ag3^ix	2.962 (14)
Sb—Ag1ⁱ	3.3758 (18)	Ag3—Ag3^xviii	2.222 (13)
Sb—Ag1ⁱⁱ	3.376 (2)	Ag3—Ag4	1.194 (10)
Sb—Ag1ⁱⁱⁱ	3.3757 (18)	Ag3—Ag4^xix	3.003 (8)
Sb—Cu1ⁱ	3.3758	Ag3—Ag4^xx	2.655 (16)
Sb—Cu1ⁱⁱ	3.3757	Ag3—Ag5	0.649 (14)
Sb—Cu1ⁱⁱⁱ	3.3757	Ag3—Ag5^v	2.467 (8)
Sb—S2	2.341 (2)	Ag3—Ag5^xv	2.773 (5)
Sb—S2^iv	2.341 (2)	Ag3—Ag5^xxi	3.396 (9)
Sb—S2^v	2.341 (2)	Ag3—Ag5^ix	2.354 (15)
Ag1—Ag1^vi	3.313 (3)	Ag3—Ag5^xviii	2.699 (13)
Ag1—Ag1^vii	3.316 (2)	Ag3—Ag6	0.688 (17)
Ag1—Ag1^viii	3.3131 (17)	Ag3—Ag6^iv	3.218 (15)
Ag1—Ag1ⁱⁱⁱ	3.316 (3)	Ag3—Ag6^xvii	3.361 (12)
Ag1—Cu1	0	Ag3—Ag6^v	2.541 (13)
Ag1—Cu1^vi	3.313 (2)	Ag3—Ag6^xv	2.948 (9)
Ag1—Cu1^vii	3.3156 (15)	Ag3—Ag6^ix	3.422 (19)
Ag1—Cu1^viii	3.3131 (12)	Ag3—Ag6^xviii	1.559 (18)
Ag1—Cu1ⁱⁱⁱ	3.3156 (18)	Ag3—Cu2	2.912 (5)
Ag1—Ag2	3.129 (3)	Ag3—S1	2.736 (6)
Ag1—Ag2^ix	3.129 (3)	Ag3—S2^iv	2.622 (4)
Ag1—Ag5	3.243 (5)	Ag3—S3	2.802 (7)
Ag1—Ag5^ix	3.243 (5)	Ag3—S3^xix	2.707 (8)
Ag1—S1	3.064 (3)	Ag4—Ag4^xix	2.995 (11)
Ag1—S2^iv	2.453 (2)	Ag4—Ag4^iv	2.531 (16)
Ag1—S2^x	2.453 (3)	Ag4—Ag4^xx	2.531 (16)
Ag1—S4	1.946 (5)	Ag4—Ag5	1.672 (12)
Ag1—S4^xi	2.829 (8)	Ag4—Ag5^xix	3.083 (8)
Ag1—S4^vi	2.428 (3)	Ag4—Ag5^iv	3.259 (12)
Ag1—S4^vii	2.428 (3)	Ag4—Ag5^v	1.672 (12)
Ag1—S4^xii	2.829 (7)	Ag4—Ag5^xv	3.083 (8)
Ag1—S4^xiii	1.946 (7)	Ag4—Ag5^xvi	3.346 (14)
Cu1—Cu1^vi	3.3131	Ag4—Ag5^ix	3.346 (14)
Cu1—Cu1^vii	3.3156	Ag4—Ag5^xviii	3.259 (12)
Cu1—Cu1^viii	3.3131	Ag4—Ag6	1.370 (11)
Cu1—Cu1ⁱⁱⁱ	3.3156	Ag4—Ag6^xix	3.435 (13)
Cu1—Ag2	3.129 (2)	Ag4—Ag6^iv	2.027 (15)
Cu1—Ag2^ix	3.129 (3)	Ag4—Ag6^v	1.370 (11)
Cu1—Ag5	3.243 (5)	Ag4—Ag6^xv	3.435 (13)
Cu1—Ag5^ix	3.243 (5)	Ag4—Ag6^xx	3.31 (2)
Cu1—S1	3.064 (2)	Ag4—Ag6^xxii	3.31 (2)
Cu1—S2^iv	2.453 (2)	Ag4—Ag6^xviii	2.027 (15)
Cu1—S2^x	2.453 (2)	Ag4—S2^iv	2.417 (8)
Cu1—S4	1.946 (5)	Ag4—S3	3.009 (10)
Cu1—S4^xi	2.829 (8)	Ag4—S3^xix	2.158 (9)
Cu1—S4^vi	2.428 (3)	Ag5—Ag5^v	2.569 (8)
Cu1—S4^vii	2.428 (3)	Ag5—Ag5^xv	3.006 (7)
Cu1—S4^xii	2.829 (7)	Ag5—Ag5^ix	1.729 (16)
Cu1—S4^xiii	1.946 (7)	Ag5—Ag5^xviii	3.090 (14)
Ag2—Ag2^xiv	3.433 (7)	Ag5—Ag6	1.237 (17)
Ag2—Ag2^v	3.088 (4)	Ag5—Ag6^xvii	3.167 (10)
Ag2—Ag2^xv	3.427 (5)	Ag5—Ag6^v	2.916 (15)
Ag2—Ag2^xvi	3.433 (4)	Ag5—Ag6^xv	2.917 (7)
Ag2—Ag2^ix	0.609 (8)	Ag5—Ag6^ix	2.845 (19)
Ag2—Ag3	1.199 (11)	Ag5—Ag6^xviii	2.062 (18)
Ag2—Ag3^xiv	3.375 (13)	Ag5—Cu2	2.840 (5)
Ag2—Ag3^xvii	3.115 (7)	Ag5—S1	2.543 (5)
Ag2—Ag3^v	2.872 (5)	Ag5—S2^iv	2.624 (6)
Ag2—Ag3^xv	2.890 (5)	Ag5—S3	2.474 (6)
Ag2—Ag3^ix	1.800 (12)	Ag5—S3^xix	3.304 (9)
Ag2—Ag3^xviii	3.105 (13)	Ag6—Ag6^iv	3.245 (12)
Ag2—Ag4	2.200 (10)	Ag6—Ag6^v	2.714 (11)
Ag2—Ag4^xix	3.208 (8)	Ag6—Ag6^xv	3.319 (11)
Ag2—Ag4^xiv	2.792 (14)	Ag6—Ag6^xx	3.24 (2)
Ag2—Ag4^xvii	3.440 (10)	Ag6—Ag6^xviii	0.88 (2)
Ag2—Ag5	0.561 (12)	Ag6—Cu2	2.867 (4)
Ag2—Ag5^xiv	3.297 (13)	Ag6—S1	2.589 (4)
Ag2—Ag5^xvii	3.478 (8)	Ag6—S2	3.254 (11)
Ag2—Ag5^v	2.872 (6)	Ag6—S2^iv	2.735 (9)
Ag2—Ag5^xv	3.196 (6)	Ag6—S3	3.476 (15)
Ag2—Ag5^ix	1.169 (13)	Ag6—S3^xix	2.516 (6)
Ag2—Ag5^xviii	3.424 (13)	Cu2—S1	2.161 (3)
Ag2—Ag6	1.742 (14)	Cu2—S1^xxiii	2.161 (3)
Ag2—Ag6^xvii	2.993 (7)	S4—S4^xi	1.273 (14)
Ag2—Ag6^v	3.378 (14)	S4—S4^vi	1.102 (12)
Ag2—Ag6^xv	2.901 (5)	S4—S4^vii	0.636 (7)
Ag2—Ag6^xii	3.022 (14)	S4—S4^xii	1.102 (12)
Ag2—Ag6^ix	2.312 (16)	S4—S4^xiii	0.636 (12)

Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) y, −x+y+1, −z+1; (iii) y, x, −z+1; (iv) −y+1, x−y+1, z; (v) −y+1, −x+1, z; (vi) −y, x−y, z; (vii) y, −x+y, −z+1; (viii) −y, −x, z; (ix) x, x−y, z; (x) −y+1, −x, z; (xi) −x, −y, −z+1; (xii) −x+y, −x, z; (xiii) x−y, x, −z+1; (xiv) −y+1, x−y, z; (xv) y, x, −z; (xvi) −x+y+1, −x+1, z; (xvii) y, −x+y, −z; (xviii) −x+y, y, z; (xix) −x+1, −y+1, −z; (xx) −x+y, −x+1, z; (xxi) x−y, x, −z; (xxii) x, x−y+1, z; (xxiii) −x, −y, −z.

Experimental details

	(300K)	(120K)	(15K)
Crystal data
Chemical formula	Ag_13.034As_1.179Cu_2.966S₁₁Sb_0.821	Ag_13.034As_1.179Cu_2.966S₁₁Sb_0.821	Ag_12.21As_1.194Cu_3.79S₁₁Sb_0.806
M_r	2135.4	2135.4	2098.2
Crystal system, space group	Trigonal, P3m1	Trigonal, P3m1	Trigonal, P3m1
Temperature (K)	300	120	15
a, c (Å)	7.3876 (4), 11.8882 (7)	7.3721 (6), 11.8104 (12)	7.389 (1), 11.816 (2)
V (Å³)	561.89 (5)	555.88 (9)	558.69 (14)
Z	1	1	1
Radiation type	Mo Kα	Mo Kα	Mo Kα
µ (mm⁻¹)	17.51	17.70	17.68
Crystal size (mm)	0.15 × 0.15 × 0.04	0.15 × 0.15 × 0.04	0.18 × 0.16 × 0.15

Data collection
Diffractometer	Nonius KappaCCD diffractometer	Nonius KappaCCD diffractometer	Oxford Diffraction Xcalibur 2 diffractometer
Absorption correction	Gaussian (Jana2000; Petricek, Dusek & Palatinus, 2000)	Gaussian (Jana2000; Petricek, Dusek & Palatinus, 2000)	Gaussian (Jana2000; Petricek, Dusek & Palatinus, 2000)
T_min, T_max	0.197, 0.727	0.165, 0.659	0.069, 0.158
No. of measured, independent and observed [I > 2σ(I)] reflections	20965, 1352, 1109	17722, 1341, 1167	2442, 818, 650
R_int	0.048	0.048	0.051
(sin θ/λ)_max (Å⁻¹)	0.904	0.904	0.769

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.046, 0.127, 1.89	0.045, 0.133, 2.19	0.044, 0.126, 1.84
No. of reflections	1352	1341	818
No. of parameters	92	96	77
No. of restraints	?	?	?
Δρ_max, Δρ_min (e Å⁻³)	1.41, −1.00	1.57, −1.86	1.54, −1.48

Computer programs: (Jana2000; Petricek and Dusek, 2000).

Selected geometric parameters (Å, º) for (300K) top

As—Sb	0	Ag2—Ag3	1.35 (2)
As—S2	2.3157 (10)	Ag2—Ag3^v	2.881 (5)
As—S2ⁱ	2.3157 (12)	Ag2—Ag3^iv	2.23 (2)
As—S2ⁱⁱ	2.3157 (10)	Ag2—Ag3^vi	2.658 (18)
Sb—S2	2.3157 (10)	Ag2—Cu2	2.750 (4)
Sb—S2ⁱ	2.3157 (12)	Ag2—S1	2.428 (4)
Sb—S2ⁱⁱ	2.3157 (10)	Ag2—S2ⁱ	2.836 (11)
Ag1—Cu1	0	Ag2—S3	2.393 (5)
Ag1—S2ⁱ	2.4459 (14)	Ag3—Ag3ⁱⁱ	2.417 (6)
Ag1—S2ⁱⁱⁱ	2.446 (2)	Ag3—Ag3^vi	1.502 (12)
Ag1—S4	2.3592 (15)	Ag3—Cu2	2.906 (4)
Cu1—S2ⁱ	2.4459 (11)	Ag3—S1	2.661 (4)
Cu1—S2ⁱⁱⁱ	2.4459 (11)	Ag3—S2ⁱ	2.664 (4)
Cu1—S4	2.3592	Ag3—S3^vii	2.545 (6)
Ag2—Ag2ⁱⁱ	2.980 (14)	Cu2—S1	2.1594 (15)
Ag2—Ag2^iv	0.91 (3)	Cu2—S1^viii	2.1594 (15)

Sb—As—S2	0	Ag3^ix—Cu2—Ag3^xv	106.7 (2)
Sb—As—S2ⁱ	0	Ag3^ix—Cu2—S1	61.31 (8)
Sb—As—S2ⁱⁱ	0	Ag3^ix—Cu2—S1^viii	118.69 (8)
S2—As—S2ⁱ	98.57 (4)	Ag3^x—Cu2—Ag3	81.12 (17)
S2—As—S2ⁱⁱ	98.57 (3)	Ag3^x—Cu2—Ag3^viii	98.88 (17)
S2ⁱ—As—S2	98.57 (4)	Ag3^x—Cu2—Ag3^ix	180
S2ⁱ—As—S2ⁱⁱ	98.57 (4)	Ag3^x—Cu2—Ag3^xi	150.0 (2)
S2ⁱⁱ—As—S2	98.57 (3)	Ag3^x—Cu2—Ag3^v	30.0 (2)
S2ⁱⁱ—As—S2ⁱ	98.57 (4)	Ag3^x—Cu2—Ag3^xii	81.1 (2)
As—Sb—S2	0	Ag3^x—Cu2—Ag3^xiii	98.9 (2)
As—Sb—S2ⁱ	0	Ag3^x—Cu2—Ag3^iv	62.43 (15)
As—Sb—S2ⁱⁱ	0	Ag3^x—Cu2—Ag3^xiv	117.57 (15)
S2—Sb—S2ⁱ	98.57 (3)	Ag3^x—Cu2—Ag3^vi	106.7 (2)
S2—Sb—S2ⁱⁱ	98.57 (3)	Ag3^x—Cu2—Ag3^xv	73.3 (2)
S2ⁱ—Sb—S2	98.57 (3)	Ag3^x—Cu2—S1	118.69 (8)
S2ⁱ—Sb—S2ⁱⁱ	98.57 (4)	Ag3^x—Cu2—S1^viii	61.31 (8)
S2ⁱⁱ—Sb—S2	98.57 (3)	Ag3^xi—Cu2—Ag3	117.57 (12)
S2ⁱⁱ—Sb—S2ⁱ	98.57 (4)	Ag3^xi—Cu2—Ag3^viii	62.43 (12)
Cu1—Ag1—S2ⁱ	0	Ag3^xi—Cu2—Ag3^ix	30.0 (2)
Cu1—Ag1—S2ⁱⁱⁱ	0	Ag3^xi—Cu2—Ag3^x	150.0 (2)
Cu1—Ag1—S4	0	Ag3^xi—Cu2—Ag3^v	180
S2ⁱ—Ag1—S2ⁱⁱⁱ	104.86 (6)	Ag3^xi—Cu2—Ag3^xii	73.3 (2)
S2ⁱ—Ag1—S4	127.57 (7)	Ag3^xi—Cu2—Ag3^xiii	106.7 (2)
S2ⁱⁱⁱ—Ag1—S2ⁱ	104.86 (6)	Ag3^xi—Cu2—Ag3^iv	98.88 (16)
S2ⁱⁱⁱ—Ag1—S4	127.57 (4)	Ag3^xi—Cu2—Ag3^xiv	81.12 (16)
Ag1—Cu1—S2ⁱ	0	Ag3^xi—Cu2—Ag3^vi	98.88 (17)
Ag1—Cu1—S2ⁱⁱⁱ	0	Ag3^xi—Cu2—Ag3^xv	81.12 (17)
Ag1—Cu1—S4	0	Ag3^xi—Cu2—S1	61.31 (7)
S2ⁱ—Cu1—S2ⁱⁱⁱ	104.86 (3)	Ag3^xi—Cu2—S1^viii	118.69 (7)
S2ⁱ—Cu1—S4	127.57 (2)	Ag3^v—Cu2—Ag3	62.43 (12)
S2ⁱⁱⁱ—Cu1—S2ⁱ	104.86 (3)	Ag3^v—Cu2—Ag3^viii	117.57 (12)
S2ⁱⁱⁱ—Cu1—S4	127.57 (2)	Ag3^v—Cu2—Ag3^ix	150.0 (2)
Ag2ⁱⁱ—Ag2—Ag2^iv	120.0 (5)	Ag3^v—Cu2—Ag3^x	30.0 (2)
Ag2ⁱⁱ—Ag2—Ag3	77.9 (7)	Ag3^v—Cu2—Ag3^xi	180
Ag2ⁱⁱ—Ag2—Ag3^v	84.4 (2)	Ag3^v—Cu2—Ag3^xii	106.7 (2)
Ag2ⁱⁱ—Ag2—Ag3^iv	130.7 (6)	Ag3^v—Cu2—Ag3^xiii	73.3 (2)
Ag2ⁱⁱ—Ag2—Ag3^vi	100.2 (7)	Ag3^v—Cu2—Ag3^iv	81.12 (16)
Ag2ⁱⁱ—Ag2—Cu2	143.3 (4)	Ag3^v—Cu2—Ag3^xiv	98.88 (16)
Ag2ⁱⁱ—Ag2—S1	155.2 (7)	Ag3^v—Cu2—Ag3^vi	81.12 (17)
Ag2ⁱⁱ—Ag2—S2ⁱ	58.3 (3)	Ag3^v—Cu2—Ag3^xv	98.88 (17)
Ag2ⁱⁱ—Ag2—S3	51.5 (3)	Ag3^v—Cu2—S1	118.69 (7)
Ag2^iv—Ag2—Ag2ⁱⁱ	120.0 (5)	Ag3^v—Cu2—S1^viii	61.31 (7)
Ag2^iv—Ag2—Ag3	161.8 (4)	Ag3^xii—Cu2—Ag3	98.88 (16)
Ag2^iv—Ag2—Ag3^v	95.9 (5)	Ag3^xii—Cu2—Ag3^viii	81.12 (16)
Ag2^iv—Ag2—Ag3^iv	10.8 (3)	Ag3^xii—Cu2—Ag3^ix	98.9 (2)
Ag2^iv—Ag2—Ag3^vi	139.8 (4)	Ag3^xii—Cu2—Ag3^x	81.1 (2)
Ag2^iv—Ag2—Cu2	80.5 (4)	Ag3^xii—Cu2—Ag3^xi	73.3 (2)
Ag2^iv—Ag2—S1	79.2 (5)	Ag3^xii—Cu2—Ag3^v	106.7 (2)
Ag2^iv—Ag2—S2ⁱ	121.5 (4)	Ag3^xii—Cu2—Ag3^xiii	180
Ag2^iv—Ag2—S3	79.0 (5)	Ag3^xii—Cu2—Ag3^iv	29.96 (17)
Ag3—Ag2—Ag3^v	82.3 (4)	Ag3^xii—Cu2—Ag3^xiv	150.04 (17)
Ag3—Ag2—Ag3^iv	151.0 (3)	Ag3^xii—Cu2—Ag3^vi	117.57 (15)
Ag3—Ag2—Ag3^vi	22.3 (2)	Ag3^xii—Cu2—Ag3^xv	62.43 (15)
Ag3—Ag2—Cu2	82.8 (3)	Ag3^xii—Cu2—S1	61.31 (10)
Ag3—Ag2—S1	84.5 (3)	Ag3^xii—Cu2—S1^viii	118.69 (10)
Ag3—Ag2—S2ⁱ	68.8 (5)	Ag3^xiii—Cu2—Ag3	81.12 (16)
Ag3—Ag2—S3	114.1 (7)	Ag3^xiii—Cu2—Ag3^viii	98.88 (16)
Ag3^v—Ag2—Ag3	82.3 (4)	Ag3^xiii—Cu2—Ag3^ix	81.1 (2)
Ag3^v—Ag2—Ag3^iv	94.5 (4)	Ag3^xiii—Cu2—Ag3^x	98.9 (2)
Ag3^v—Ag2—Ag3^vi	86.0 (4)	Ag3^xiii—Cu2—Ag3^xi	106.7 (2)
Ag3^v—Ag2—Cu2	62.09 (10)	Ag3^xiii—Cu2—Ag3^v	73.3 (2)
Ag3^v—Ag2—S1	110.69 (14)	Ag3^xiii—Cu2—Ag3^xii	180
Ag3^v—Ag2—S2ⁱ	136.1 (6)	Ag3^xiii—Cu2—Ag3^iv	150.04 (17)
Ag3^v—Ag2—S3	56.80 (14)	Ag3^xiii—Cu2—Ag3^xiv	29.96 (17)
Ag3^iv—Ag2—Ag3	151.0 (3)	Ag3^xiii—Cu2—Ag3^vi	62.43 (15)
Ag3^iv—Ag2—Ag3^v	94.5 (4)	Ag3^xiii—Cu2—Ag3^xv	117.57 (15)
Ag3^iv—Ag2—Ag3^vi	129.0 (3)	Ag3^xiii—Cu2—S1	118.69 (10)
Ag3^iv—Ag2—Cu2	70.5 (3)	Ag3^xiii—Cu2—S1^viii	61.31 (10)
Ag3^iv—Ag2—S1	69.5 (4)	Ag3^iv—Cu2—Ag3	73.3 (2)
Ag3^iv—Ag2—S2ⁱ	126.5 (4)	Ag3^iv—Cu2—Ag3^viii	106.7 (2)
Ag3^iv—Ag2—S3	87.1 (6)	Ag3^iv—Cu2—Ag3^ix	117.57 (15)
Ag3^vi—Ag2—Ag3	22.3 (2)	Ag3^iv—Cu2—Ag3^x	62.43 (15)
Ag3^vi—Ag2—Ag3^v	86.0 (4)	Ag3^iv—Cu2—Ag3^xi	98.88 (16)
Ag3^vi—Ag2—Ag3^iv	129.0 (3)	Ag3^iv—Cu2—Ag3^v	81.12 (16)
Ag3^vi—Ag2—Cu2	64.98 (19)	Ag3^iv—Cu2—Ag3^xii	29.96 (17)
Ag3^vi—Ag2—S1	62.9 (2)	Ag3^iv—Cu2—Ag3^xiii	150.04 (17)
Ag3^vi—Ag2—S2ⁱ	79.5 (4)	Ag3^iv—Cu2—Ag3^xiv	180
Ag3^vi—Ag2—S3	131.8 (6)	Ag3^iv—Cu2—Ag3^vi	98.9 (2)
Cu2—Ag2—S1	48.81 (9)	Ag3^iv—Cu2—Ag3^xv	81.1 (2)
Cu2—Ag2—S2ⁱ	139.8 (4)	Ag3^iv—Cu2—S1	61.31 (10)
Cu2—Ag2—S3	112.1 (3)	Ag3^iv—Cu2—S1^viii	118.69 (10)
S1—Ag2—S2ⁱ	99.0 (2)	Ag3^xiv—Cu2—Ag3	106.7 (2)
S1—Ag2—S3	153.3 (7)	Ag3^xiv—Cu2—Ag3^viii	73.3 (2)
S2ⁱ—Ag2—S3	105.4 (2)	Ag3^xiv—Cu2—Ag3^ix	62.43 (15)
Ag2—Ag3—Ag2^v	95.3 (4)	Ag3^xiv—Cu2—Ag3^x	117.57 (15)
Ag2—Ag3—Ag2^iv	7.3 (3)	Ag3^xiv—Cu2—Ag3^xi	81.12 (16)
Ag2—Ag3—Ag2^vi	118.0 (6)	Ag3^xiv—Cu2—Ag3^v	98.88 (16)
Ag2—Ag3—Ag3ⁱⁱ	102.1 (5)	Ag3^xiv—Cu2—Ag3^xii	150.04 (17)
Ag2—Ag3—Ag3^vi	137.8 (5)	Ag3^xiv—Cu2—Ag3^xiii	29.96 (17)
Ag2—Ag3—Cu2	69.9 (3)	Ag3^xiv—Cu2—Ag3^iv	180
Ag2—Ag3—S1	65.2 (3)	Ag3^xiv—Cu2—Ag3^vi	81.1 (2)
Ag2—Ag3—S2ⁱ	83.1 (3)	Ag3^xiv—Cu2—Ag3^xv	98.9 (2)
Ag2—Ag3—S3^vii	137.1 (3)	Ag3^xiv—Cu2—S1	118.69 (10)
Ag2^v—Ag3—Ag2	95.3 (4)	Ag3^xiv—Cu2—S1^viii	61.31 (10)
Ag2^v—Ag3—Ag2^iv	93.3 (3)	Ag3^vi—Cu2—Ag3	30.0 (2)
Ag2^v—Ag3—Ag2^vi	84.9 (4)	Ag3^vi—Cu2—Ag3^viii	150.0 (2)
Ag2^v—Ag3—Ag3ⁱⁱ	95.6 (2)	Ag3^vi—Cu2—Ag3^ix	73.3 (2)
Ag2^v—Ag3—Ag3^vi	84.1 (4)	Ag3^vi—Cu2—Ag3^x	106.7 (2)
Ag2^v—Ag3—Cu2	56.75 (12)	Ag3^vi—Cu2—Ag3^xi	98.88 (17)
Ag2^v—Ag3—S1	101.96 (18)	Ag3^vi—Cu2—Ag3^v	81.12 (17)
Ag2^v—Ag3—S2ⁱ	157.4 (3)	Ag3^vi—Cu2—Ag3^xii	117.57 (15)
Ag2^v—Ag3—S3^vii	51.90 (15)	Ag3^vi—Cu2—Ag3^xiii	62.43 (15)
Ag2^iv—Ag3—Ag2	7.3 (3)	Ag3^vi—Cu2—Ag3^iv	98.9 (2)
Ag2^iv—Ag3—Ag2^v	93.3 (3)	Ag3^vi—Cu2—Ag3^xiv	81.1 (2)
Ag2^iv—Ag3—Ag2^vi	110.8 (5)	Ag3^vi—Cu2—Ag3^xv	180
Ag2^iv—Ag3—Ag3ⁱⁱ	109.3 (3)	Ag3^vi—Cu2—S1	61.31 (8)
Ag2^iv—Ag3—Ag3^vi	130.7 (3)	Ag3^vi—Cu2—S1^viii	118.69 (8)
Ag2^iv—Ag3—Cu2	63.15 (16)	Ag3^xv—Cu2—Ag3	150.0 (2)
Ag2^iv—Ag3—S1	58.73 (16)	Ag3^xv—Cu2—Ag3^viii	30.0 (2)
Ag2^iv—Ag3—S2ⁱ	87.6 (2)	Ag3^xv—Cu2—Ag3^ix	106.7 (2)
Ag2^iv—Ag3—S3^vii	139.2 (2)	Ag3^xv—Cu2—Ag3^x	73.3 (2)
Ag2^vi—Ag3—Ag2	118.0 (6)	Ag3^xv—Cu2—Ag3^xi	81.12 (17)
Ag2^vi—Ag3—Ag2^v	84.9 (4)	Ag3^xv—Cu2—Ag3^v	98.88 (17)
Ag2^vi—Ag3—Ag2^iv	110.8 (5)	Ag3^xv—Cu2—Ag3^xii	62.43 (15)
Ag2^vi—Ag3—Ag3ⁱⁱ	139.8 (6)	Ag3^xv—Cu2—Ag3^xiii	117.57 (15)
Ag2^vi—Ag3—Ag3^vi	19.9 (5)	Ag3^xv—Cu2—Ag3^iv	81.1 (2)
Ag2^vi—Ag3—Cu2	59.0 (4)	Ag3^xv—Cu2—Ag3^xiv	98.9 (2)
Ag2^vi—Ag3—S1	54.3 (4)	Ag3^xv—Cu2—Ag3^vi	180
Ag2^vi—Ag3—S2ⁱ	115.78 (19)	Ag3^xv—Cu2—S1	118.69 (8)
Ag2^vi—Ag3—S3^vii	89.0 (4)	Ag3^xv—Cu2—S1^viii	61.31 (8)
Ag3ⁱⁱ—Ag3—Ag3^vi	120.0 (4)	S1—Cu2—S1^viii	180
Ag3ⁱⁱ—Ag3—Cu2	148.8 (2)	S1^viii—Cu2—S1	180
Ag3ⁱⁱ—Ag3—S1	159.0 (3)	Ag2—S1—Ag2^ix	112.2 (5)
Ag3ⁱⁱ—Ag3—S2ⁱ	63.02 (13)	Ag2—S1—Ag2^xi	130.4 (5)
Ag3ⁱⁱ—Ag3—S3^vii	61.65 (18)	Ag2—S1—Ag2^xii	112.2 (6)
Ag3^vi—Ag3—Ag3ⁱⁱ	120.0 (4)	Ag2—S1—Ag2^iv	21.6 (6)
Ag3^vi—Ag3—Cu2	75.0 (2)	Ag2—S1—Ag2^vi	92.1 (5)
Ag3^vi—Ag3—S1	73.6 (3)	Ag2—S1—Ag3	30.2 (5)
Ag3^vi—Ag3—S2ⁱ	112.1 (3)	Ag2—S1—Ag3^ix	136.5 (3)
Ag3^vi—Ag3—S3^vii	72.8 (3)	Ag2—S1—Ag3^xi	146.22 (16)
Cu2—Ag3—S1	45.38 (8)	Ag2—S1—Ag3^xii	83.8 (5)
Cu2—Ag3—S2ⁱ	140.7 (2)	Ag2—S1—Ag3^iv	51.7 (5)
Cu2—Ag3—S3^vii	102.95 (14)	Ag2—S1—Ag3^vi	62.8 (5)
S1—Ag3—S2ⁱ	97.80 (13)	Ag2—S1—Cu2	73.41 (7)
S1—Ag3—S3^vii	139.1 (2)	Ag2^ix—S1—Ag2	112.2 (5)
S2ⁱ—Ag3—S3^vii	116.19 (19)	Ag2^ix—S1—Ag2^xi	92.1 (5)
Ag2—Cu2—Ag2^viii	180	Ag2^ix—S1—Ag2^xii	112.2 (5)
Ag2—Cu2—Ag2^ix	94.2 (4)	Ag2^ix—S1—Ag2^iv	130.4 (5)
Ag2—Cu2—Ag2^x	85.8 (4)	Ag2^ix—S1—Ag2^vi	21.6 (5)
Ag2—Cu2—Ag2^xi	106.5 (4)	Ag2^ix—S1—Ag3	83.8 (4)
Ag2—Cu2—Ag2^v	73.5 (4)	Ag2^ix—S1—Ag3^ix	30.2 (4)
Ag2—Cu2—Ag2^xii	94.2 (4)	Ag2^ix—S1—Ag3^xi	62.8 (4)
Ag2—Cu2—Ag2^xiii	85.8 (4)	Ag2^ix—S1—Ag3^xii	136.5 (3)
Ag2—Cu2—Ag2^iv	19.1 (6)	Ag2^ix—S1—Ag3^iv	146.2 (2)
Ag2—Cu2—Ag2^xiv	160.9 (6)	Ag2^ix—S1—Ag3^vi	51.7 (4)
Ag2—Cu2—Ag2^vi	78.9 (5)	Ag2^ix—S1—Cu2	73.41 (17)
Ag2—Cu2—Ag2^xv	101.1 (5)	Ag2^xi—S1—Ag2	130.4 (5)
Ag2—Cu2—Ag3	27.3 (4)	Ag2^xi—S1—Ag2^ix	92.1 (5)
Ag2—Cu2—Ag3^viii	152.7 (4)	Ag2^xi—S1—Ag2^xii	21.6 (6)
Ag2—Cu2—Ag3^ix	113.38 (17)	Ag2^xi—S1—Ag2^iv	112.2 (6)
Ag2—Cu2—Ag3^x	66.62 (17)	Ag2^xi—S1—Ag2^vi	112.2 (5)
Ag2—Cu2—Ag3^xi	118.84 (12)	Ag2^xi—S1—Ag3	146.22 (16)
Ag2—Cu2—Ag3^v	61.16 (12)	Ag2^xi—S1—Ag3^ix	62.8 (5)
Ag2—Cu2—Ag3^xii	74.0 (4)	Ag2^xi—S1—Ag3^xi	30.2 (5)
Ag2—Cu2—Ag3^xiii	106.0 (4)	Ag2^xi—S1—Ag3^xii	51.7 (5)
Ag2—Cu2—Ag3^iv	46.3 (4)	Ag2^xi—S1—Ag3^iv	83.8 (5)
Ag2—Cu2—Ag3^xiv	133.7 (4)	Ag2^xi—S1—Ag3^vi	136.5 (3)
Ag2—Cu2—Ag3^vi	56.0 (4)	Ag2^xi—S1—Cu2	73.41 (7)
Ag2—Cu2—Ag3^xv	124.0 (4)	Ag2^xii—S1—Ag2	112.2 (6)
Ag2—Cu2—S1	57.79 (7)	Ag2^xii—S1—Ag2^ix	112.2 (5)
Ag2—Cu2—S1^viii	122.21 (7)	Ag2^xii—S1—Ag2^xi	21.6 (6)
Ag2^viii—Cu2—Ag2	180	Ag2^xii—S1—Ag2^iv	92.1 (6)
Ag2^viii—Cu2—Ag2^ix	85.8 (4)	Ag2^xii—S1—Ag2^vi	130.4 (5)
Ag2^viii—Cu2—Ag2^x	94.2 (4)	Ag2^xii—S1—Ag3	136.5 (3)
Ag2^viii—Cu2—Ag2^xi	73.5 (4)	Ag2^xii—S1—Ag3^ix	83.8 (5)
Ag2^viii—Cu2—Ag2^v	106.5 (4)	Ag2^xii—S1—Ag3^xi	51.7 (5)
Ag2^viii—Cu2—Ag2^xii	85.8 (4)	Ag2^xii—S1—Ag3^xii	30.2 (5)
Ag2^viii—Cu2—Ag2^xiii	94.2 (4)	Ag2^xii—S1—Ag3^iv	62.8 (5)
Ag2^viii—Cu2—Ag2^iv	160.9 (6)	Ag2^xii—S1—Ag3^vi	146.22 (16)
Ag2^viii—Cu2—Ag2^xiv	19.1 (6)	Ag2^xii—S1—Cu2	73.41 (7)
Ag2^viii—Cu2—Ag2^vi	101.1 (5)	Ag2^iv—S1—Ag2	21.6 (6)
Ag2^viii—Cu2—Ag2^xv	78.9 (5)	Ag2^iv—S1—Ag2^ix	130.4 (5)
Ag2^viii—Cu2—Ag3	152.7 (4)	Ag2^iv—S1—Ag2^xi	112.2 (6)
Ag2^viii—Cu2—Ag3^viii	27.3 (4)	Ag2^iv—S1—Ag2^xii	92.1 (6)
Ag2^viii—Cu2—Ag3^ix	66.62 (17)	Ag2^iv—S1—Ag2^vi	112.2 (5)
Ag2^viii—Cu2—Ag3^x	113.38 (17)	Ag2^iv—S1—Ag3	51.7 (5)
Ag2^viii—Cu2—Ag3^xi	61.16 (12)	Ag2^iv—S1—Ag3^ix	146.22 (16)
Ag2^viii—Cu2—Ag3^v	118.84 (12)	Ag2^iv—S1—Ag3^xi	136.5 (3)
Ag2^viii—Cu2—Ag3^xii	106.0 (4)	Ag2^iv—S1—Ag3^xii	62.8 (5)
Ag2^viii—Cu2—Ag3^xiii	74.0 (4)	Ag2^iv—S1—Ag3^iv	30.2 (5)
Ag2^viii—Cu2—Ag3^iv	133.7 (4)	Ag2^iv—S1—Ag3^vi	83.8 (5)
Ag2^viii—Cu2—Ag3^xiv	46.3 (4)	Ag2^iv—S1—Cu2	73.41 (7)
Ag2^viii—Cu2—Ag3^vi	124.0 (4)	Ag2^vi—S1—Ag2	92.1 (5)
Ag2^viii—Cu2—Ag3^xv	56.0 (4)	Ag2^vi—S1—Ag2^ix	21.6 (5)
Ag2^viii—Cu2—S1	122.21 (7)	Ag2^vi—S1—Ag2^xi	112.2 (5)
Ag2^viii—Cu2—S1^viii	57.79 (7)	Ag2^vi—S1—Ag2^xii	130.4 (5)
Ag2^ix—Cu2—Ag2	94.2 (4)	Ag2^vi—S1—Ag2^iv	112.2 (5)
Ag2^ix—Cu2—Ag2^viii	85.8 (4)	Ag2^vi—S1—Ag3	62.8 (4)
Ag2^ix—Cu2—Ag2^x	180	Ag2^vi—S1—Ag3^ix	51.7 (4)
Ag2^ix—Cu2—Ag2^xi	78.9 (5)	Ag2^vi—S1—Ag3^xi	83.8 (4)
Ag2^ix—Cu2—Ag2^v	101.1 (5)	Ag2^vi—S1—Ag3^xii	146.2 (2)
Ag2^ix—Cu2—Ag2^xii	94.2 (5)	Ag2^vi—S1—Ag3^iv	136.5 (3)
Ag2^ix—Cu2—Ag2^xiii	85.8 (5)	Ag2^vi—S1—Ag3^vi	30.2 (4)
Ag2^ix—Cu2—Ag2^iv	106.5 (4)	Ag2^vi—S1—Cu2	73.41 (17)
Ag2^ix—Cu2—Ag2^xiv	73.5 (4)	Ag3—S1—Ag3^ix	112.1 (2)
Ag2^ix—Cu2—Ag2^vi	19.1 (4)	Ag3—S1—Ag3^xi	138.08 (17)
Ag2^ix—Cu2—Ag2^xv	160.9 (4)	Ag3—S1—Ag3^xii	112.1 (2)
Ag2^ix—Cu2—Ag3	74.0 (3)	Ag3—S1—Ag3^iv	81.3 (2)
Ag2^ix—Cu2—Ag3^viii	106.0 (3)	Ag3—S1—Ag3^vi	32.8 (2)
Ag2^ix—Cu2—Ag3^ix	27.3 (3)	Ag3—S1—Cu2	73.31 (8)
Ag2^ix—Cu2—Ag3^x	152.7 (3)	Ag3^ix—S1—Ag3	112.1 (2)
Ag2^ix—Cu2—Ag3^xi	56.0 (3)	Ag3^ix—S1—Ag3^xi	32.8 (2)
Ag2^ix—Cu2—Ag3^v	124.0 (3)	Ag3^ix—S1—Ag3^xii	112.1 (2)
Ag2^ix—Cu2—Ag3^xii	113.4 (3)	Ag3^ix—S1—Ag3^iv	138.08 (18)
Ag2^ix—Cu2—Ag3^xiii	66.6 (3)	Ag3^ix—S1—Ag3^vi	81.3 (2)
Ag2^ix—Cu2—Ag3^iv	118.8 (3)	Ag3^ix—S1—Cu2	73.31 (8)
Ag2^ix—Cu2—Ag3^xiv	61.2 (3)	Ag3^xi—S1—Ag3	138.08 (17)
Ag2^ix—Cu2—Ag3^vi	46.3 (3)	Ag3^xi—S1—Ag3^ix	32.8 (2)
Ag2^ix—Cu2—Ag3^xv	133.7 (3)	Ag3^xi—S1—Ag3^xii	81.3 (2)
Ag2^ix—Cu2—S1	57.8 (3)	Ag3^xi—S1—Ag3^iv	112.1 (2)
Ag2^ix—Cu2—S1^viii	122.2 (3)	Ag3^xi—S1—Ag3^vi	112.1 (2)
Ag2^x—Cu2—Ag2	85.8 (4)	Ag3^xi—S1—Cu2	73.31 (8)
Ag2^x—Cu2—Ag2^viii	94.2 (4)	Ag3^xii—S1—Ag3	112.1 (2)
Ag2^x—Cu2—Ag2^ix	180	Ag3^xii—S1—Ag3^ix	112.1 (2)
Ag2^x—Cu2—Ag2^xi	101.1 (5)	Ag3^xii—S1—Ag3^xi	81.3 (2)
Ag2^x—Cu2—Ag2^v	78.9 (5)	Ag3^xii—S1—Ag3^iv	32.8 (2)
Ag2^x—Cu2—Ag2^xii	85.8 (5)	Ag3^xii—S1—Ag3^vi	138.08 (18)
Ag2^x—Cu2—Ag2^xiii	94.2 (5)	Ag3^xii—S1—Cu2	73.31 (9)
Ag2^x—Cu2—Ag2^iv	73.5 (4)	Ag3^iv—S1—Ag3	81.3 (2)
Ag2^x—Cu2—Ag2^xiv	106.5 (4)	Ag3^iv—S1—Ag3^ix	138.08 (18)
Ag2^x—Cu2—Ag2^vi	160.9 (4)	Ag3^iv—S1—Ag3^xi	112.1 (2)
Ag2^x—Cu2—Ag2^xv	19.1 (4)	Ag3^iv—S1—Ag3^xii	32.8 (2)
Ag2^x—Cu2—Ag3	106.0 (3)	Ag3^iv—S1—Ag3^vi	112.1 (2)
Ag2^x—Cu2—Ag3^viii	74.0 (3)	Ag3^iv—S1—Cu2	73.31 (9)
Ag2^x—Cu2—Ag3^ix	152.7 (3)	Ag3^vi—S1—Ag3	32.8 (2)
Ag2^x—Cu2—Ag3^x	27.3 (3)	Ag3^vi—S1—Ag3^ix	81.3 (2)
Ag2^x—Cu2—Ag3^xi	124.0 (3)	Ag3^vi—S1—Ag3^xi	112.1 (2)
Ag2^x—Cu2—Ag3^v	56.0 (3)	Ag3^vi—S1—Ag3^xii	138.08 (18)
Ag2^x—Cu2—Ag3^xii	66.6 (3)	Ag3^vi—S1—Ag3^iv	112.1 (2)
Ag2^x—Cu2—Ag3^xiii	113.4 (3)	Ag3^vi—S1—Cu2	73.31 (8)
Ag2^x—Cu2—Ag3^iv	61.2 (3)	As—S2—Sb	0
Ag2^x—Cu2—Ag3^xiv	118.8 (3)	As—S2—Ag1^ix	102.29 (5)
Ag2^x—Cu2—Ag3^vi	133.7 (3)	As—S2—Ag1^xvi	102.29 (4)
Ag2^x—Cu2—Ag3^xv	46.3 (3)	As—S2—Cu1^ix	102.29 (4)
Ag2^x—Cu2—S1	122.2 (3)	As—S2—Cu1^xvi	102.29 (3)
Ag2^x—Cu2—S1^viii	57.8 (3)	As—S2—Ag2^xvii	130.4 (2)
Ag2^xi—Cu2—Ag2	106.5 (4)	As—S2—Ag2^vi	130.4 (4)
Ag2^xi—Cu2—Ag2^viii	73.5 (4)	As—S2—Ag3^xvii	105.74 (15)
Ag2^xi—Cu2—Ag2^ix	78.9 (5)	As—S2—Ag3^vi	105.74 (18)
Ag2^xi—Cu2—Ag2^x	101.1 (5)	Sb—S2—Ag1^ix	102.29 (5)
Ag2^xi—Cu2—Ag2^v	180	Sb—S2—Ag1^xvi	102.29 (4)
Ag2^xi—Cu2—Ag2^xii	19.1 (6)	Sb—S2—Cu1^ix	102.29 (4)
Ag2^xi—Cu2—Ag2^xiii	160.9 (6)	Sb—S2—Cu1^xvi	102.29 (3)
Ag2^xi—Cu2—Ag2^iv	94.2 (4)	Sb—S2—Ag2^xvii	130.4 (2)
Ag2^xi—Cu2—Ag2^xiv	85.8 (4)	Sb—S2—Ag2^vi	130.4 (4)
Ag2^xi—Cu2—Ag2^vi	94.2 (4)	Sb—S2—Ag3^xvii	105.74 (15)
Ag2^xi—Cu2—Ag2^xv	85.8 (4)	Sb—S2—Ag3^vi	105.74 (18)
Ag2^xi—Cu2—Ag3	118.84 (12)	Ag1^ix—S2—Ag1^xvi	111.92 (6)
Ag2^xi—Cu2—Ag3^viii	61.16 (12)	Ag1^ix—S2—Cu1^ix	0
Ag2^xi—Cu2—Ag3^ix	56.0 (4)	Ag1^ix—S2—Cu1^xvi	111.92 (5)
Ag2^xi—Cu2—Ag3^x	124.0 (4)	Ag1^ix—S2—Ag2^xvii	125.64 (14)
Ag2^xi—Cu2—Ag3^xi	27.3 (4)	Ag1^ix—S2—Ag2^vi	73.3 (3)
Ag2^xi—Cu2—Ag3^v	152.7 (4)	Ag1^ix—S2—Ag3^xvii	139.26 (12)
Ag2^xi—Cu2—Ag3^xii	46.3 (4)	Ag1^ix—S2—Ag3^vi	90.33 (12)
Ag2^xi—Cu2—Ag3^xiii	133.7 (4)	Ag1^xvi—S2—Ag1^ix	111.92 (6)
Ag2^xi—Cu2—Ag3^iv	74.0 (4)	Ag1^xvi—S2—Cu1^ix	111.92 (5)
Ag2^xi—Cu2—Ag3^xiv	106.0 (4)	Ag1^xvi—S2—Cu1^xvi	0
Ag2^xi—Cu2—Ag3^vi	113.38 (17)	Ag1^xvi—S2—Ag2^xvii	73.3 (3)
Ag2^xi—Cu2—Ag3^xv	66.62 (17)	Ag1^xvi—S2—Ag2^vi	125.6 (5)
Ag2^xi—Cu2—S1	57.79 (7)	Ag1^xvi—S2—Ag3^xvii	90.3 (2)
Ag2^xi—Cu2—S1^viii	122.21 (7)	Ag1^xvi—S2—Ag3^vi	139.26 (19)
Ag2^v—Cu2—Ag2	73.5 (4)	Cu1^ix—S2—Cu1^xvi	111.92 (4)
Ag2^v—Cu2—Ag2^viii	106.5 (4)	Cu1^ix—S2—Ag2^xvii	125.64 (14)
Ag2^v—Cu2—Ag2^ix	101.1 (5)	Cu1^ix—S2—Ag2^vi	73.3 (3)
Ag2^v—Cu2—Ag2^x	78.9 (5)	Cu1^ix—S2—Ag3^xvii	139.26 (12)
Ag2^v—Cu2—Ag2^xi	180	Cu1^ix—S2—Ag3^vi	90.33 (11)
Ag2^v—Cu2—Ag2^xii	160.9 (6)	Cu1^xvi—S2—Cu1^ix	111.92 (4)
Ag2^v—Cu2—Ag2^xiii	19.1 (6)	Cu1^xvi—S2—Ag2^xvii	73.3 (3)
Ag2^v—Cu2—Ag2^iv	85.8 (4)	Cu1^xvi—S2—Ag2^vi	125.6 (5)
Ag2^v—Cu2—Ag2^xiv	94.2 (4)	Cu1^xvi—S2—Ag3^xvii	90.33 (19)
Ag2^v—Cu2—Ag2^vi	85.8 (4)	Cu1^xvi—S2—Ag3^vi	139.26 (18)
Ag2^v—Cu2—Ag2^xv	94.2 (4)	Ag2^xvii—S2—Ag2^vi	63.4 (4)
Ag2^v—Cu2—Ag3	61.16 (12)	Ag2^xvii—S2—Ag3^xvii	28.1 (4)
Ag2^v—Cu2—Ag3^viii	118.84 (12)	Ag2^xvii—S2—Ag3^vi	66.1 (3)
Ag2^v—Cu2—Ag3^ix	124.0 (4)	Ag2^vi—S2—Ag2^xvii	63.4 (4)
Ag2^v—Cu2—Ag3^x	56.0 (4)	Ag2^vi—S2—Ag3^xvii	66.1 (3)
Ag2^v—Cu2—Ag3^xi	152.7 (4)	Ag2^vi—S2—Ag3^vi	28.1 (3)
Ag2^v—Cu2—Ag3^v	27.3 (4)	Ag3^xvii—S2—Ag3^vi	54.0 (2)
Ag2^v—Cu2—Ag3^xii	133.7 (4)	Ag3^vi—S2—Ag3^xvii	54.0 (2)
Ag2^v—Cu2—Ag3^xiii	46.3 (4)	Ag2—S3—Ag2^xviii	94.9 (5)
Ag2^v—Cu2—Ag3^iv	106.0 (4)	Ag2—S3—Ag2ⁱⁱ	77.0 (5)
Ag2^v—Cu2—Ag3^xiv	74.0 (4)	Ag2—S3—Ag2^xix	94.9 (5)
Ag2^v—Cu2—Ag3^vi	66.62 (17)	Ag2—S3—Ag2^iv	22.0 (7)
Ag2^v—Cu2—Ag3^xv	113.38 (17)	Ag2—S3—Ag2^xx	108.8 (4)
Ag2^v—Cu2—S1	122.21 (7)	Ag2—S3—Ag3^vii	105.7 (4)
Ag2^v—Cu2—S1^viii	57.79 (7)	Ag2—S3—Ag3^x	78.0 (2)
Ag2^xii—Cu2—Ag2	94.2 (4)	Ag2—S3—Ag3^v	71.30 (16)
Ag2^xii—Cu2—Ag2^viii	85.8 (4)	Ag2—S3—Ag3^xxi	158.6 (4)
Ag2^xii—Cu2—Ag2^ix	94.2 (5)	Ag2—S3—Ag3^xxii	124.3 (4)
Ag2^xii—Cu2—Ag2^x	85.8 (5)	Ag2—S3—Ag3^xxiii	138.6 (5)
Ag2^xii—Cu2—Ag2^xi	19.1 (6)	Ag2^xviii—S3—Ag2	94.9 (5)
Ag2^xii—Cu2—Ag2^v	160.9 (6)	Ag2^xviii—S3—Ag2ⁱⁱ	108.8 (4)
Ag2^xii—Cu2—Ag2^xiii	180	Ag2^xviii—S3—Ag2^xix	94.9 (4)
Ag2^xii—Cu2—Ag2^iv	78.9 (5)	Ag2^xviii—S3—Ag2^iv	77.0 (5)
Ag2^xii—Cu2—Ag2^xiv	101.1 (5)	Ag2^xviii—S3—Ag2^xx	22.0 (5)
Ag2^xii—Cu2—Ag2^vi	106.5 (4)	Ag2^xviii—S3—Ag3^vii	158.6 (4)
Ag2^xii—Cu2—Ag2^xv	73.5 (4)	Ag2^xviii—S3—Ag3^x	105.7 (4)
Ag2^xii—Cu2—Ag3	113.38 (18)	Ag2^xviii—S3—Ag3^v	138.6 (3)
Ag2^xii—Cu2—Ag3^viii	66.62 (18)	Ag2^xviii—S3—Ag3^xxi	78.0 (4)
Ag2^xii—Cu2—Ag3^ix	74.0 (4)	Ag2^xviii—S3—Ag3^xxii	71.3 (3)
Ag2^xii—Cu2—Ag3^x	106.0 (4)	Ag2^xviii—S3—Ag3^xxiii	124.3 (4)
Ag2^xii—Cu2—Ag3^xi	46.3 (4)	Ag2ⁱⁱ—S3—Ag2	77.0 (5)
Ag2^xii—Cu2—Ag3^v	133.7 (4)	Ag2ⁱⁱ—S3—Ag2^xviii	108.8 (4)
Ag2^xii—Cu2—Ag3^xii	27.3 (4)	Ag2ⁱⁱ—S3—Ag2^xix	22.0 (7)
Ag2^xii—Cu2—Ag3^xiii	152.7 (4)	Ag2ⁱⁱ—S3—Ag2^iv	94.9 (5)
Ag2^xii—Cu2—Ag3^iv	56.0 (4)	Ag2ⁱⁱ—S3—Ag2^xx	94.9 (5)
Ag2^xii—Cu2—Ag3^xiv	124.0 (4)	Ag2ⁱⁱ—S3—Ag3^vii	71.30 (16)
Ag2^xii—Cu2—Ag3^vi	118.84 (13)	Ag2ⁱⁱ—S3—Ag3^x	138.6 (5)
Ag2^xii—Cu2—Ag3^xv	61.16 (13)	Ag2ⁱⁱ—S3—Ag3^v	105.7 (4)
Ag2^xii—Cu2—S1	57.79 (7)	Ag2ⁱⁱ—S3—Ag3^xxi	124.3 (4)
Ag2^xii—Cu2—S1^viii	122.21 (7)	Ag2ⁱⁱ—S3—Ag3^xxii	158.6 (4)
Ag2^xiii—Cu2—Ag2	85.8 (4)	Ag2ⁱⁱ—S3—Ag3^xxiii	78.0 (2)
Ag2^xiii—Cu2—Ag2^viii	94.2 (4)	Ag2^xix—S3—Ag2	94.9 (5)
Ag2^xiii—Cu2—Ag2^ix	85.8 (5)	Ag2^xix—S3—Ag2^xviii	94.9 (4)
Ag2^xiii—Cu2—Ag2^x	94.2 (5)	Ag2^xix—S3—Ag2ⁱⁱ	22.0 (7)
Ag2^xiii—Cu2—Ag2^xi	160.9 (6)	Ag2^xix—S3—Ag2^iv	108.8 (4)
Ag2^xiii—Cu2—Ag2^v	19.1 (6)	Ag2^xix—S3—Ag2^xx	77.0 (5)
Ag2^xiii—Cu2—Ag2^xii	180	Ag2^xix—S3—Ag3^vii	78.0 (2)
Ag2^xiii—Cu2—Ag2^iv	101.1 (5)	Ag2^xix—S3—Ag3^x	158.6 (4)
Ag2^xiii—Cu2—Ag2^xiv	78.9 (5)	Ag2^xix—S3—Ag3^v	124.3 (4)
Ag2^xiii—Cu2—Ag2^vi	73.5 (4)	Ag2^xix—S3—Ag3^xxi	105.7 (4)
Ag2^xiii—Cu2—Ag2^xv	106.5 (4)	Ag2^xix—S3—Ag3^xxii	138.6 (5)
Ag2^xiii—Cu2—Ag3	66.62 (18)	Ag2^xix—S3—Ag3^xxiii	71.30 (16)
Ag2^xiii—Cu2—Ag3^viii	113.38 (18)	Ag2^iv—S3—Ag2	22.0 (7)
Ag2^xiii—Cu2—Ag3^ix	106.0 (4)	Ag2^iv—S3—Ag2^xviii	77.0 (5)
Ag2^xiii—Cu2—Ag3^x	74.0 (4)	Ag2^iv—S3—Ag2ⁱⁱ	94.9 (5)
Ag2^xiii—Cu2—Ag3^xi	133.7 (4)	Ag2^iv—S3—Ag2^xix	108.8 (4)
Ag2^xiii—Cu2—Ag3^v	46.3 (4)	Ag2^iv—S3—Ag2^xx	94.9 (4)
Ag2^xiii—Cu2—Ag3^xii	152.7 (4)	Ag2^iv—S3—Ag3^vii	124.3 (4)
Ag2^xiii—Cu2—Ag3^xiii	27.3 (4)	Ag2^iv—S3—Ag3^x	71.30 (16)
Ag2^xiii—Cu2—Ag3^iv	124.0 (4)	Ag2^iv—S3—Ag3^v	78.0 (2)
Ag2^xiii—Cu2—Ag3^xiv	56.0 (4)	Ag2^iv—S3—Ag3^xxi	138.6 (5)
Ag2^xiii—Cu2—Ag3^vi	61.16 (13)	Ag2^iv—S3—Ag3^xxii	105.7 (4)
Ag2^xiii—Cu2—Ag3^xv	118.84 (13)	Ag2^iv—S3—Ag3^xxiii	158.6 (4)
Ag2^xiii—Cu2—S1	122.21 (7)	Ag2^xx—S3—Ag2	108.8 (4)
Ag2^xiii—Cu2—S1^viii	57.79 (7)	Ag2^xx—S3—Ag2^xviii	22.0 (5)
Ag2^iv—Cu2—Ag2	19.1 (6)	Ag2^xx—S3—Ag2ⁱⁱ	94.9 (5)
Ag2^iv—Cu2—Ag2^viii	160.9 (6)	Ag2^xx—S3—Ag2^xix	77.0 (5)
Ag2^iv—Cu2—Ag2^ix	106.5 (4)	Ag2^xx—S3—Ag2^iv	94.9 (4)
Ag2^iv—Cu2—Ag2^x	73.5 (4)	Ag2^xx—S3—Ag3^vii	138.6 (3)
Ag2^iv—Cu2—Ag2^xi	94.2 (4)	Ag2^xx—S3—Ag3^x	124.3 (4)
Ag2^iv—Cu2—Ag2^v	85.8 (4)	Ag2^xx—S3—Ag3^v	158.6 (4)
Ag2^iv—Cu2—Ag2^xii	78.9 (5)	Ag2^xx—S3—Ag3^xxi	71.3 (3)
Ag2^iv—Cu2—Ag2^xiii	101.1 (5)	Ag2^xx—S3—Ag3^xxii	78.0 (4)
Ag2^iv—Cu2—Ag2^xiv	180	Ag2^xx—S3—Ag3^xxiii	105.7 (4)
Ag2^iv—Cu2—Ag2^vi	94.2 (5)	Ag3^vii—S3—Ag3^x	84.6 (2)
Ag2^iv—Cu2—Ag2^xv	85.8 (5)	Ag3^vii—S3—Ag3^v	56.71 (16)
Ag2^iv—Cu2—Ag3	46.3 (4)	Ag3^vii—S3—Ag3^xxi	84.6 (2)
Ag2^iv—Cu2—Ag3^viii	133.7 (4)	Ag3^vii—S3—Ag3^xxii	100.7 (2)
Ag2^iv—Cu2—Ag3^ix	118.84 (13)	Ag3^vii—S3—Ag3^xxiii	34.3 (3)
Ag2^iv—Cu2—Ag3^x	61.16 (13)	Ag3^x—S3—Ag3^vii	84.6 (2)
Ag2^iv—Cu2—Ag3^xi	113.38 (18)	Ag3^x—S3—Ag3^v	34.3 (3)
Ag2^iv—Cu2—Ag3^v	66.62 (18)	Ag3^x—S3—Ag3^xxi	84.6 (2)
Ag2^iv—Cu2—Ag3^xii	56.0 (4)	Ag3^x—S3—Ag3^xxii	56.7 (2)
Ag2^iv—Cu2—Ag3^xiii	124.0 (4)	Ag3^x—S3—Ag3^xxiii	100.72 (17)
Ag2^iv—Cu2—Ag3^iv	27.3 (4)	Ag3^v—S3—Ag3^vii	56.71 (16)
Ag2^iv—Cu2—Ag3^xiv	152.7 (4)	Ag3^v—S3—Ag3^x	34.3 (3)
Ag2^iv—Cu2—Ag3^vi	74.0 (4)	Ag3^v—S3—Ag3^xxi	100.7 (2)
Ag2^iv—Cu2—Ag3^xv	106.0 (4)	Ag3^v—S3—Ag3^xxii	84.6 (2)
Ag2^iv—Cu2—S1	57.79 (7)	Ag3^v—S3—Ag3^xxiii	84.6 (2)
Ag2^iv—Cu2—S1^viii	122.21 (7)	Ag3^xxi—S3—Ag3^vii	84.6 (2)
Ag2^xiv—Cu2—Ag2	160.9 (6)	Ag3^xxi—S3—Ag3^x	84.6 (2)
Ag2^xiv—Cu2—Ag2^viii	19.1 (6)	Ag3^xxi—S3—Ag3^v	100.7 (2)
Ag2^xiv—Cu2—Ag2^ix	73.5 (4)	Ag3^xxi—S3—Ag3^xxii	34.34 (16)
Ag2^xiv—Cu2—Ag2^x	106.5 (4)	Ag3^xxi—S3—Ag3^xxiii	56.7 (2)
Ag2^xiv—Cu2—Ag2^xi	85.8 (4)	Ag3^xxii—S3—Ag3^vii	100.7 (2)
Ag2^xiv—Cu2—Ag2^v	94.2 (4)	Ag3^xxii—S3—Ag3^x	56.7 (2)
Ag2^xiv—Cu2—Ag2^xii	101.1 (5)	Ag3^xxii—S3—Ag3^v	84.6 (2)
Ag2^xiv—Cu2—Ag2^xiii	78.9 (5)	Ag3^xxii—S3—Ag3^xxi	34.34 (16)
Ag2^xiv—Cu2—Ag2^iv	180	Ag3^xxii—S3—Ag3^xxiii	84.6 (2)
Ag2^xiv—Cu2—Ag2^vi	85.8 (5)	Ag3^xxiii—S3—Ag3^vii	34.3 (3)
Ag2^xiv—Cu2—Ag2^xv	94.2 (5)	Ag3^xxiii—S3—Ag3^x	100.72 (17)
Ag2^xiv—Cu2—Ag3	133.7 (4)	Ag3^xxiii—S3—Ag3^v	84.6 (2)
Ag2^xiv—Cu2—Ag3^viii	46.3 (4)	Ag3^xxiii—S3—Ag3^xxi	56.7 (2)
Ag2^xiv—Cu2—Ag3^ix	61.16 (13)	Ag3^xxiii—S3—Ag3^xxii	84.6 (2)
Ag2^xiv—Cu2—Ag3^x	118.84 (13)	Ag1—S4—Ag1^xxiv	180
Ag2^xiv—Cu2—Ag3^xi	66.62 (18)	Ag1—S4—Ag1^ix	89.92 (5)
Ag2^xiv—Cu2—Ag3^v	113.38 (18)	Ag1—S4—Ag1^xxv	90.08 (5)
Ag2^xiv—Cu2—Ag3^xii	124.0 (4)	Ag1—S4—Ag1^xi	89.92 (3)
Ag2^xiv—Cu2—Ag3^xiii	56.0 (4)	Ag1—S4—Ag1^xxvi	90.08 (3)
Ag2^xiv—Cu2—Ag3^iv	152.7 (4)	Ag1—S4—Cu1	0
Ag2^xiv—Cu2—Ag3^xiv	27.3 (4)	Ag1—S4—Cu1^xxiv	180
Ag2^xiv—Cu2—Ag3^vi	106.0 (4)	Ag1—S4—Cu1^ix	89.92 (4)
Ag2^xiv—Cu2—Ag3^xv	74.0 (4)	Ag1—S4—Cu1^xxv	90.08 (4)
Ag2^xiv—Cu2—S1	122.21 (7)	Ag1—S4—Cu1^xi	89.92 (2)
Ag2^xiv—Cu2—S1^viii	57.79 (7)	Ag1—S4—Cu1^xxvi	90.08 (2)
Ag2^vi—Cu2—Ag2	78.9 (5)	Ag1^xxiv—S4—Ag1	180
Ag2^vi—Cu2—Ag2^viii	101.1 (5)	Ag1^xxiv—S4—Ag1^ix	90.08 (5)
Ag2^vi—Cu2—Ag2^ix	19.1 (4)	Ag1^xxiv—S4—Ag1^xxv	89.92 (5)
Ag2^vi—Cu2—Ag2^x	160.9 (4)	Ag1^xxiv—S4—Ag1^xi	90.08 (3)
Ag2^vi—Cu2—Ag2^xi	94.2 (4)	Ag1^xxiv—S4—Ag1^xxvi	89.92 (3)
Ag2^vi—Cu2—Ag2^v	85.8 (4)	Ag1^xxiv—S4—Cu1	180
Ag2^vi—Cu2—Ag2^xii	106.5 (4)	Ag1^xxiv—S4—Cu1^xxiv	0
Ag2^vi—Cu2—Ag2^xiii	73.5 (4)	Ag1^xxiv—S4—Cu1^ix	90.08 (4)
Ag2^vi—Cu2—Ag2^iv	94.2 (5)	Ag1^xxiv—S4—Cu1^xxv	89.92 (4)
Ag2^vi—Cu2—Ag2^xiv	85.8 (5)	Ag1^xxiv—S4—Cu1^xi	90.08 (2)
Ag2^vi—Cu2—Ag2^xv	180	Ag1^xxiv—S4—Cu1^xxvi	89.92 (2)
Ag2^vi—Cu2—Ag3	56.0 (3)	Ag1^ix—S4—Ag1	89.92 (5)
Ag2^vi—Cu2—Ag3^viii	124.0 (3)	Ag1^ix—S4—Ag1^xxiv	90.08 (5)
Ag2^vi—Cu2—Ag3^ix	46.3 (3)	Ag1^ix—S4—Ag1^xxv	180
Ag2^vi—Cu2—Ag3^x	133.7 (3)	Ag1^ix—S4—Ag1^xi	89.92 (6)
Ag2^vi—Cu2—Ag3^xi	74.0 (3)	Ag1^ix—S4—Ag1^xxvi	90.08 (6)
Ag2^vi—Cu2—Ag3^v	106.0 (3)	Ag1^ix—S4—Cu1	89.92 (2)
Ag2^vi—Cu2—Ag3^xii	118.8 (3)	Ag1^ix—S4—Cu1^xxiv	90.08 (2)
Ag2^vi—Cu2—Ag3^xiii	61.2 (3)	Ag1^ix—S4—Cu1^ix	0
Ag2^vi—Cu2—Ag3^iv	113.4 (3)	Ag1^ix—S4—Cu1^xxv	180
Ag2^vi—Cu2—Ag3^xiv	66.6 (3)	Ag1^ix—S4—Cu1^xi	89.92 (4)
Ag2^vi—Cu2—Ag3^vi	27.3 (3)	Ag1^ix—S4—Cu1^xxvi	90.08 (4)
Ag2^vi—Cu2—Ag3^xv	152.7 (3)	Ag1^xxv—S4—Ag1	90.08 (5)
Ag2^vi—Cu2—S1	57.8 (3)	Ag1^xxv—S4—Ag1^xxiv	89.92 (5)
Ag2^vi—Cu2—S1^viii	122.2 (3)	Ag1^xxv—S4—Ag1^ix	180
Ag2^xv—Cu2—Ag2	101.1 (5)	Ag1^xxv—S4—Ag1^xi	90.08 (6)
Ag2^xv—Cu2—Ag2^viii	78.9 (5)	Ag1^xxv—S4—Ag1^xxvi	89.92 (6)
Ag2^xv—Cu2—Ag2^ix	160.9 (4)	Ag1^xxv—S4—Cu1	90.08 (2)
Ag2^xv—Cu2—Ag2^x	19.1 (4)	Ag1^xxv—S4—Cu1^xxiv	89.92 (2)
Ag2^xv—Cu2—Ag2^xi	85.8 (4)	Ag1^xxv—S4—Cu1^ix	180
Ag2^xv—Cu2—Ag2^v	94.2 (4)	Ag1^xxv—S4—Cu1^xxv	0
Ag2^xv—Cu2—Ag2^xii	73.5 (4)	Ag1^xxv—S4—Cu1^xi	90.08 (4)
Ag2^xv—Cu2—Ag2^xiii	106.5 (4)	Ag1^xxv—S4—Cu1^xxvi	89.92 (4)
Ag2^xv—Cu2—Ag2^iv	85.8 (5)	Ag1^xi—S4—Ag1	89.92 (3)
Ag2^xv—Cu2—Ag2^xiv	94.2 (5)	Ag1^xi—S4—Ag1^xxiv	90.08 (3)
Ag2^xv—Cu2—Ag2^vi	180	Ag1^xi—S4—Ag1^ix	89.92 (6)
Ag2^xv—Cu2—Ag3	124.0 (3)	Ag1^xi—S4—Ag1^xxv	90.08 (6)
Ag2^xv—Cu2—Ag3^viii	56.0 (3)	Ag1^xi—S4—Ag1^xxvi	180
Ag2^xv—Cu2—Ag3^ix	133.7 (3)	Ag1^xi—S4—Cu1	89.92 (2)
Ag2^xv—Cu2—Ag3^x	46.3 (3)	Ag1^xi—S4—Cu1^xxiv	90.08 (2)
Ag2^xv—Cu2—Ag3^xi	106.0 (3)	Ag1^xi—S4—Cu1^ix	89.92 (4)
Ag2^xv—Cu2—Ag3^v	74.0 (3)	Ag1^xi—S4—Cu1^xxv	90.08 (4)
Ag2^xv—Cu2—Ag3^xii	61.2 (3)	Ag1^xi—S4—Cu1^xi	0
Ag2^xv—Cu2—Ag3^xiii	118.8 (3)	Ag1^xi—S4—Cu1^xxvi	180
Ag2^xv—Cu2—Ag3^iv	66.6 (3)	Ag1^xxvi—S4—Ag1	90.08 (3)
Ag2^xv—Cu2—Ag3^xiv	113.4 (3)	Ag1^xxvi—S4—Ag1^xxiv	89.92 (3)
Ag2^xv—Cu2—Ag3^vi	152.7 (3)	Ag1^xxvi—S4—Ag1^ix	90.08 (6)
Ag2^xv—Cu2—Ag3^xv	27.3 (3)	Ag1^xxvi—S4—Ag1^xxv	89.92 (6)
Ag2^xv—Cu2—S1	122.2 (3)	Ag1^xxvi—S4—Ag1^xi	180
Ag2^xv—Cu2—S1^viii	57.8 (3)	Ag1^xxvi—S4—Cu1	90.08 (2)
Ag3—Cu2—Ag3^viii	180	Ag1^xxvi—S4—Cu1^xxiv	89.92 (2)
Ag3—Cu2—Ag3^ix	98.88 (17)	Ag1^xxvi—S4—Cu1^ix	90.08 (4)
Ag3—Cu2—Ag3^x	81.12 (17)	Ag1^xxvi—S4—Cu1^xxv	89.92 (4)
Ag3—Cu2—Ag3^xi	117.57 (12)	Ag1^xxvi—S4—Cu1^xi	180
Ag3—Cu2—Ag3^v	62.43 (12)	Ag1^xxvi—S4—Cu1^xxvi	0
Ag3—Cu2—Ag3^xii	98.88 (16)	Cu1—S4—Cu1^xxiv	180
Ag3—Cu2—Ag3^xiii	81.12 (16)	Cu1—S4—Cu1^ix	89.919
Ag3—Cu2—Ag3^iv	73.3 (2)	Cu1—S4—Cu1^xxv	90.081
Ag3—Cu2—Ag3^xiv	106.7 (2)	Cu1—S4—Cu1^xi	89.919
Ag3—Cu2—Ag3^vi	30.0 (2)	Cu1—S4—Cu1^xxvi	90.081
Ag3—Cu2—Ag3^xv	150.0 (2)	Cu1^xxiv—S4—Cu1	180
Ag3—Cu2—S1	61.31 (7)	Cu1^xxiv—S4—Cu1^ix	90.081
Ag3—Cu2—S1^viii	118.69 (7)	Cu1^xxiv—S4—Cu1^xxv	89.919
Ag3^viii—Cu2—Ag3	180	Cu1^xxiv—S4—Cu1^xi	90.081
Ag3^viii—Cu2—Ag3^ix	81.12 (17)	Cu1^xxiv—S4—Cu1^xxvi	89.919
Ag3^viii—Cu2—Ag3^x	98.88 (17)	Cu1^ix—S4—Cu1	89.919
Ag3^viii—Cu2—Ag3^xi	62.43 (12)	Cu1^ix—S4—Cu1^xxiv	90.081
Ag3^viii—Cu2—Ag3^v	117.57 (12)	Cu1^ix—S4—Cu1^xxv	180
Ag3^viii—Cu2—Ag3^xii	81.12 (16)	Cu1^ix—S4—Cu1^xi	89.919
Ag3^viii—Cu2—Ag3^xiii	98.88 (16)	Cu1^ix—S4—Cu1^xxvi	90.081
Ag3^viii—Cu2—Ag3^iv	106.7 (2)	Cu1^xxv—S4—Cu1	90.081
Ag3^viii—Cu2—Ag3^xiv	73.3 (2)	Cu1^xxv—S4—Cu1^xxiv	89.919
Ag3^viii—Cu2—Ag3^vi	150.0 (2)	Cu1^xxv—S4—Cu1^ix	180
Ag3^viii—Cu2—Ag3^xv	30.0 (2)	Cu1^xxv—S4—Cu1^xi	90.081
Ag3^viii—Cu2—S1	118.69 (7)	Cu1^xxv—S4—Cu1^xxvi	89.919
Ag3^viii—Cu2—S1^viii	61.31 (7)	Cu1^xi—S4—Cu1	89.919
Ag3^ix—Cu2—Ag3	98.88 (17)	Cu1^xi—S4—Cu1^xxiv	90.081
Ag3^ix—Cu2—Ag3^viii	81.12 (17)	Cu1^xi—S4—Cu1^ix	89.919
Ag3^ix—Cu2—Ag3^x	180	Cu1^xi—S4—Cu1^xxv	90.081
Ag3^ix—Cu2—Ag3^xi	30.0 (2)	Cu1^xi—S4—Cu1^xxvi	180
Ag3^ix—Cu2—Ag3^v	150.0 (2)	Cu1^xxvi—S4—Cu1	90.081
Ag3^ix—Cu2—Ag3^xii	98.9 (2)	Cu1^xxvi—S4—Cu1^xxiv	89.919
Ag3^ix—Cu2—Ag3^xiii	81.1 (2)	Cu1^xxvi—S4—Cu1^ix	90.081
Ag3^ix—Cu2—Ag3^iv	117.57 (15)	Cu1^xxvi—S4—Cu1^xxv	89.919
Ag3^ix—Cu2—Ag3^xiv	62.43 (15)	Cu1^xxvi—S4—Cu1^xi	180
Ag3^ix—Cu2—Ag3^vi	73.3 (2)

Selected bond lengths (Å) for (120K) top

As—Sb	0	Ag2—Ag4	2.78 (3)
As—S2	2.3161 (11)	Ag2—Ag4^xii	2.10 (2)
As—S2ⁱ	2.3161 (12)	Ag2—Cu2	2.731 (4)
As—S2ⁱⁱ	2.3161 (11)	Ag2—S1	2.408 (4)
Sb—S2	2.3161 (11)	Ag2—S2ⁱ	2.865 (13)
Sb—S2ⁱ	2.3161 (12)	Ag2—S3	2.352 (5)
Sb—S2ⁱⁱ	2.3161 (11)	Ag3—Ag3ⁱⁱ	2.504 (3)
Ag1—Cu1	0	Ag3—Ag3^x	2.965 (4)
Ag1—S2ⁱ	2.4469 (13)	Ag3—Ag3^xi	1.452 (6)
Ag1—S2ⁱⁱⁱ	2.4469 (17)	Ag3—Ag4^v	2.33 (2)
Ag1—S4	1.951 (3)	Ag3—Ag4^xii	1.253 (10)
Ag1—S4^iv	2.825 (4)	Ag3—Cu2	2.850 (2)
Ag1—S4^v	2.4272 (18)	Ag3—S1	2.621 (2)
Ag1—S4^vi	2.4272 (16)	Ag3—S2ⁱ	2.677 (3)
Ag1—S4^vii	2.825 (4)	Ag3—S3^xiii	2.570 (3)
Ag1—S4^viii	1.951 (4)	Ag4—Ag4^xiv	2.933 (11)
Cu1—S2ⁱ	2.4469 (11)	Ag4—Ag4^xv	2.664 (15)
Cu1—S2ⁱⁱⁱ	2.4469 (11)	Ag4—Ag4^xvi	2.66 (2)
Cu1—S4	1.951 (3)	Ag4—S2ⁱⁱⁱ	2.398 (7)
Cu1—S4^iv	2.825 (4)	Ag4—S3	2.932 (13)
Cu1—S4^v	2.4272 (12)	Ag4—S3^xiv	2.209 (11)
Cu1—S4^vi	2.4272 (12)	Cu2—S1	2.1610 (16)
Cu1—S4^vii	2.825 (3)	Cu2—S1^xvii	2.1610 (16)
Cu1—S4^viii	1.951 (3)	S4—S4^iv	1.258 (7)
Ag2—Ag2^ix	0.70 (3)	S4—S4^v	1.089 (6)
Ag2—Ag3	1.43 (2)	S4—S4^vi	0.629 (3)
Ag2—Ag3^x	2.861 (4)	S4—S4^vii	1.089 (6)
Ag2—Ag3^ix	2.11 (2)	S4—S4^viii	0.629 (6)
Ag2—Ag3^xi	2.696 (19)

Selected bond lengths (Å) for (15K) top

As—Sb	0	Ag2—Ag6^xviii	2.507 (16)
As—Ag1ⁱ	3.3758 (19)	Ag2—Cu2	2.750 (2)
As—Ag1ⁱⁱ	3.376 (2)	Ag2—S1	2.429 (3)
As—Ag1ⁱⁱⁱ	3.3757 (19)	Ag2—S2^iv	2.880 (4)
As—Cu1ⁱ	3.3758 (7)	Ag2—S2^x	3.263 (5)
As—Cu1ⁱⁱ	3.3757 (7)	Ag2—S3	2.326 (3)
As—Cu1ⁱⁱⁱ	3.3757 (7)	Ag3—Ag3^xix	3.451 (5)
As—S2	2.341 (2)	Ag3—Ag3^v	2.205 (7)
As—S2^iv	2.341 (2)	Ag3—Ag3^xv	2.655 (5)
As—S2^v	2.341 (2)	Ag3—Ag3^ix	2.962 (14)
Sb—Ag1ⁱ	3.3758 (18)	Ag3—Ag3^xviii	2.222 (13)
Sb—Ag1ⁱⁱ	3.376 (2)	Ag3—Ag4	1.194 (10)
Sb—Ag1ⁱⁱⁱ	3.3757 (18)	Ag3—Ag4^xix	3.003 (8)
Sb—Cu1ⁱ	3.3758	Ag3—Ag4^xx	2.655 (16)
Sb—Cu1ⁱⁱ	3.3757	Ag3—Ag5	0.649 (14)
Sb—Cu1ⁱⁱⁱ	3.3757	Ag3—Ag5^v	2.467 (8)
Sb—S2	2.341 (2)	Ag3—Ag5^xv	2.773 (5)
Sb—S2^iv	2.341 (2)	Ag3—Ag5^xxi	3.396 (9)
Sb—S2^v	2.341 (2)	Ag3—Ag5^ix	2.354 (15)
Ag1—Ag1^vi	3.313 (3)	Ag3—Ag5^xviii	2.699 (13)
Ag1—Ag1^vii	3.316 (2)	Ag3—Ag6	0.688 (17)
Ag1—Ag1^viii	3.3131 (17)	Ag3—Ag6^iv	3.218 (15)
Ag1—Ag1ⁱⁱⁱ	3.316 (3)	Ag3—Ag6^xvii	3.361 (12)
Ag1—Cu1	0	Ag3—Ag6^v	2.541 (13)
Ag1—Cu1^vi	3.313 (2)	Ag3—Ag6^xv	2.948 (9)
Ag1—Cu1^vii	3.3156 (15)	Ag3—Ag6^ix	3.422 (19)
Ag1—Cu1^viii	3.3131 (12)	Ag3—Ag6^xviii	1.559 (18)
Ag1—Cu1ⁱⁱⁱ	3.3156 (18)	Ag3—Cu2	2.912 (5)
Ag1—Ag2	3.129 (3)	Ag3—S1	2.736 (6)
Ag1—Ag2^ix	3.129 (3)	Ag3—S2^iv	2.622 (4)
Ag1—Ag5	3.243 (5)	Ag3—S3	2.802 (7)
Ag1—Ag5^ix	3.243 (5)	Ag3—S3^xix	2.707 (8)
Ag1—S1	3.064 (3)	Ag4—Ag4^xix	2.995 (11)
Ag1—S2^iv	2.453 (2)	Ag4—Ag4^iv	2.531 (16)
Ag1—S2^x	2.453 (3)	Ag4—Ag4^xx	2.531 (16)
Ag1—S4	1.946 (5)	Ag4—Ag5	1.672 (12)
Ag1—S4^xi	2.829 (8)	Ag4—Ag5^xix	3.083 (8)
Ag1—S4^vi	2.428 (3)	Ag4—Ag5^iv	3.259 (12)
Ag1—S4^vii	2.428 (3)	Ag4—Ag5^v	1.672 (12)
Ag1—S4^xii	2.829 (7)	Ag4—Ag5^xv	3.083 (8)
Ag1—S4^xiii	1.946 (7)	Ag4—Ag5^xvi	3.346 (14)
Cu1—Cu1^vi	3.3131	Ag4—Ag5^ix	3.346 (14)
Cu1—Cu1^vii	3.3156	Ag4—Ag5^xviii	3.259 (12)
Cu1—Cu1^viii	3.3131	Ag4—Ag6	1.370 (11)
Cu1—Cu1ⁱⁱⁱ	3.3156	Ag4—Ag6^xix	3.435 (13)
Cu1—Ag2	3.129 (2)	Ag4—Ag6^iv	2.027 (15)
Cu1—Ag2^ix	3.129 (3)	Ag4—Ag6^v	1.370 (11)
Cu1—Ag5	3.243 (5)	Ag4—Ag6^xv	3.435 (13)
Cu1—Ag5^ix	3.243 (5)	Ag4—Ag6^xx	3.31 (2)
Cu1—S1	3.064 (2)	Ag4—Ag6^xxii	3.31 (2)
Cu1—S2^iv	2.453 (2)	Ag4—Ag6^xviii	2.027 (15)
Cu1—S2^x	2.453 (2)	Ag4—S2^iv	2.417 (8)
Cu1—S4	1.946 (5)	Ag4—S3	3.009 (10)
Cu1—S4^xi	2.829 (8)	Ag4—S3^xix	2.158 (9)
Cu1—S4^vi	2.428 (3)	Ag5—Ag5^v	2.569 (8)
Cu1—S4^vii	2.428 (3)	Ag5—Ag5^xv	3.006 (7)
Cu1—S4^xii	2.829 (7)	Ag5—Ag5^ix	1.729 (16)
Cu1—S4^xiii	1.946 (7)	Ag5—Ag5^xviii	3.090 (14)
Ag2—Ag2^xiv	3.433 (7)	Ag5—Ag6	1.237 (17)
Ag2—Ag2^v	3.088 (4)	Ag5—Ag6^xvii	3.167 (10)
Ag2—Ag2^xv	3.427 (5)	Ag5—Ag6^v	2.916 (15)
Ag2—Ag2^xvi	3.433 (4)	Ag5—Ag6^xv	2.917 (7)
Ag2—Ag2^ix	0.609 (8)	Ag5—Ag6^ix	2.845 (19)
Ag2—Ag3	1.199 (11)	Ag5—Ag6^xviii	2.062 (18)
Ag2—Ag3^xiv	3.375 (13)	Ag5—Cu2	2.840 (5)
Ag2—Ag3^xvii	3.115 (7)	Ag5—S1	2.543 (5)
Ag2—Ag3^v	2.872 (5)	Ag5—S2^iv	2.624 (6)
Ag2—Ag3^xv	2.890 (5)	Ag5—S3	2.474 (6)
Ag2—Ag3^ix	1.800 (12)	Ag5—S3^xix	3.304 (9)
Ag2—Ag3^xviii	3.105 (13)	Ag6—Ag6^iv	3.245 (12)
Ag2—Ag4	2.200 (10)	Ag6—Ag6^v	2.714 (11)
Ag2—Ag4^xix	3.208 (8)	Ag6—Ag6^xv	3.319 (11)
Ag2—Ag4^xiv	2.792 (14)	Ag6—Ag6^xx	3.24 (2)
Ag2—Ag4^xvii	3.440 (10)	Ag6—Ag6^xviii	0.88 (2)
Ag2—Ag5	0.561 (12)	Ag6—Cu2	2.867 (4)
Ag2—Ag5^xiv	3.297 (13)	Ag6—S1	2.589 (4)
Ag2—Ag5^xvii	3.478 (8)	Ag6—S2	3.254 (11)
Ag2—Ag5^v	2.872 (6)	Ag6—S2^iv	2.735 (9)
Ag2—Ag5^xv	3.196 (6)	Ag6—S3	3.476 (15)
Ag2—Ag5^ix	1.169 (13)	Ag6—S3^xix	2.516 (6)
Ag2—Ag5^xviii	3.424 (13)	Cu2—S1	2.161 (3)
Ag2—Ag6	1.742 (14)	Cu2—S1^xxiii	2.161 (3)
Ag2—Ag6^xvii	2.993 (7)	S4—S4^xi	1.273 (14)
Ag2—Ag6^v	3.378 (14)	S4—S4^vi	1.102 (12)
Ag2—Ag6^xv	2.901 (5)	S4—S4^vii	0.636 (7)
Ag2—Ag6^xii	3.022 (14)	S4—S4^xii	1.102 (12)
Ag2—Ag6^ix	2.312 (16)	S4—S4^xiii	0.636 (12)

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