(Piperidine-1-carbodithioato-S,S')bis(triphenylphosphine-P)gold(I)

In the title compound, [Au(C₆H₁₀NS₂)(C₁₈H₁₅P)₂], the Au atom is in a distorted tetrahedral environment, with the two P atoms of the tri­phenyl­phosphine ligands and the S atoms of the bidentate piperidine­carbodi­thio­ate ligand occupying the vertices. The piperidine ring adopts a chair conformation.

Computing details

Data collection: SMART (Siemens, 1996); cell refinement: SAINT (Siemens, 1996); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 1997); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL and PLATON (Spek, 1990).

(Piperidine-1-carbodithioato-S,S')bis(triphenylphosphine-P)gold(I)

Crystal data

[Au(C6H10NS2)(C18H15P)2]	F(000) = 880
Mr = 881.78	Dx = 1.551 Mg m^−3
Triclinic, P1	Melting point: 424 K K
a = 10.1318 (2) Å	Mo Kα radiation, λ = 0.71073 Å
b = 13.2019 (2) Å	Cell parameters from 3234 reflections
c = 14.9565 (5) Å	θ = 2.9–28.4°
α = 77.207 (1)°	µ = 4.12 mm^−1
β = 80.992 (2)°	T = 293 K
γ = 76.834 (2)°	Slab, colourless
V = 1887.71 (8) Å^3	0.46 × 0.20 × 0.12 mm
Z = 2

Data collection

Siemens SMART CCD area detector diffractometer	6550 independent reflections
Radiation source: fine-focus sealed tube	4263 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.069
Detector resolution: 8.33 pixels mm^-1	θmax = 25°, θmin = 2.9°
ω scans	h = −12→11
Absorption correction: empirical (using intensity measurements) (SADABS; Sheldrick, 1996)	k = −15→15
Tmin = 0.253, Tmax = 0.638	l = −17→12
10680 measured reflections

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.054	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.124	H-atom parameters constrained
S = 0.89	w = 1/[σ^2(Fo^2) + (0.049P)^2] where P = (Fo^2 + 2Fc^2)/3
6550 reflections	(Δ/σ)max < 0.001
433 parameters	Δρmax = 1.65 e Å^−3
0 restraints	Δρmin = −2.38 e Å^−3

Special details

Experimental. The data collection covered over a hemisphere of reciprocal space by a combination of three sets of exposures; each set had a different φ angle (0, 88 and 180°) for the crystal and each exposure of 10 s covered 0.3° in ω. The crystal-to-detector distance was 4 cm and the detector swing angle was -35°. Crystal decay was monitored by repeating fifty initial frames at the end of data collection and analysing the intensity of duplicate reflections, and was found to be negligible.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Au1	−0.13760 (4)	0.22377 (3)	0.27471 (3)	0.03261 (15)
S1	−0.1394 (2)	0.3194 (2)	0.08367 (19)	0.0449 (7)
S2	0.0852 (2)	0.2814 (2)	0.19883 (18)	0.0425 (7)
P1	−0.2721 (2)	0.34304 (17)	0.36300 (17)	0.0267 (6)
P2	−0.1550 (2)	0.05213 (18)	0.26538 (18)	0.0307 (6)
N1	0.1073 (8)	0.3634 (6)	0.0195 (6)	0.043 (2)
C1	−0.2216 (9)	0.4648 (7)	0.3662 (7)	0.033 (2)
C2	−0.0846 (9)	0.4663 (8)	0.3713 (7)	0.043 (3)
H2A	−0.0180	0.4059	0.3655	0.052*
C3	−0.0469 (11)	0.5552 (8)	0.3847 (8)	0.052 (3)
H3A	0.0439	0.5533	0.3901	0.063*
C4	−0.1414 (11)	0.6461 (8)	0.3900 (7)	0.045 (3)
H4A	−0.1157	0.7055	0.4001	0.054*
C5	−0.2759 (10)	0.6492 (7)	0.3803 (7)	0.043 (3)
H5A	−0.3395	0.7123	0.3807	0.052*
C6	−0.3169 (10)	0.5603 (7)	0.3701 (7)	0.039 (3)
H6A	−0.4084	0.5633	0.3657	0.047*
C7	−0.3012 (9)	0.2864 (7)	0.4846 (6)	0.030 (2)
C8	−0.3052 (10)	0.3389 (8)	0.5542 (7)	0.048 (3)
H8A	−0.2964	0.4094	0.5388	0.057*
C9	−0.3219 (11)	0.2922 (10)	0.6471 (8)	0.059 (3)
H9A	−0.3203	0.3291	0.6931	0.071*
C10	−0.3409 (11)	0.1885 (9)	0.6683 (8)	0.056 (3)
H10A	−0.3539	0.1556	0.7298	0.067*
C11	−0.3409 (10)	0.1330 (8)	0.6005 (8)	0.048 (3)
H11A	−0.3561	0.0640	0.6158	0.058*
C12	−0.3180 (9)	0.1813 (7)	0.5098 (8)	0.042 (3)
H12A	−0.3136	0.1429	0.4638	0.051*
C13	−0.4412 (9)	0.3875 (7)	0.3239 (7)	0.035 (2)
C14	−0.4507 (10)	0.4274 (8)	0.2306 (8)	0.046 (3)
H14A	−0.3711	0.4306	0.1905	0.055*
C15	−0.5750 (12)	0.4625 (8)	0.1957 (9)	0.060 (3)
H15A	−0.5796	0.4940	0.1339	0.072*
C16	−0.6944 (11)	0.4500 (8)	0.2551 (9)	0.054 (3)
H16A	−0.7785	0.4682	0.2320	0.065*
C17	−0.6861 (10)	0.4104 (9)	0.3483 (9)	0.057 (3)
H17A	−0.7657	0.4044	0.3877	0.069*
C18	−0.5616 (9)	0.3793 (7)	0.3840 (8)	0.045 (3)
H18A	−0.5577	0.3535	0.4469	0.053*
C19	−0.0199 (9)	−0.0234 (7)	0.1940 (7)	0.031 (2)
C20	0.0134 (10)	−0.1334 (8)	0.2122 (8)	0.048 (3)
H20A	−0.0313	−0.1720	0.2628	0.058*
C21	0.1131 (12)	−0.1849 (10)	0.1547 (10)	0.065 (4)
H21A	0.1357	−0.2586	0.1659	0.078*
C22	0.1790 (11)	−0.1263 (11)	0.0806 (10)	0.065 (4)
H22A	0.2454	−0.1611	0.0413	0.078*
C23	0.1485 (12)	−0.0179 (10)	0.0636 (9)	0.071 (4)
H23A	0.1929	0.0213	0.0131	0.085*
C24	0.0523 (11)	0.0308 (9)	0.1221 (8)	0.054 (3)
H24A	0.0345	0.1045	0.1128	0.065*
C25	−0.3127 (9)	0.0574 (7)	0.2182 (6)	0.033 (2)
C26	−0.3312 (10)	−0.0203 (8)	0.1768 (7)	0.045 (3)
H26A	−0.2588	−0.0764	0.1688	0.054*
C27	−0.4557 (11)	−0.0179 (9)	0.1462 (8)	0.057 (3)
H27A	−0.4655	−0.0701	0.1164	0.068*
C28	−0.5632 (10)	0.0636 (9)	0.1611 (8)	0.052 (3)
H28A	−0.6468	0.0660	0.1416	0.062*
C29	−0.5490 (11)	0.1445 (10)	0.2060 (9)	0.063 (4)
H29A	−0.6222	0.1990	0.2169	0.075*
C30	−0.4245 (10)	0.1394 (8)	0.2325 (8)	0.052 (3)
H30A	−0.4132	0.1922	0.2610	0.062*
C31	−0.1719 (9)	−0.0361 (7)	0.3770 (7)	0.034 (2)
C32	−0.0584 (10)	−0.0730 (7)	0.4290 (7)	0.041 (3)
H32A	0.0257	−0.0569	0.4030	0.049*
C33	−0.0699 (12)	−0.1305 (8)	0.5149 (8)	0.052 (3)
H33A	0.0068	−0.1539	0.5467	0.063*
C34	−0.1912 (13)	−0.1558 (8)	0.5571 (8)	0.059 (3)
H34A	−0.1972	−0.1953	0.6168	0.071*
C35	−0.3054 (11)	−0.1214 (8)	0.5092 (8)	0.051 (3)
H35A	−0.3887	−0.1375	0.5374	0.062*
C36	−0.2957 (9)	−0.0626 (7)	0.4187 (7)	0.037 (2)
H36A	−0.3720	−0.0414	0.3865	0.044*
C37	0.0262 (9)	0.3252 (7)	0.0946 (7)	0.038 (2)
C38	0.2484 (10)	0.3673 (9)	0.0253 (8)	0.056 (3)
H38A	0.2677	0.3452	0.0890	0.067*
H38B	0.2620	0.4395	0.0038	0.067*
C39	0.3462 (12)	0.2946 (10)	−0.0335 (8)	0.068 (4)
H39A	0.4383	0.3050	−0.0350	0.081*
H39B	0.3441	0.2213	−0.0050	0.081*
C40	0.3105 (12)	0.3150 (9)	−0.1311 (8)	0.064 (3)
H40A	0.3648	0.2597	−0.1623	0.077*
H40B	0.3319	0.3823	−0.1643	0.077*
C41	0.1591 (12)	0.3174 (9)	−0.1318 (8)	0.059 (3)
H41A	0.1365	0.3393	−0.1948	0.071*
H41B	0.1415	0.2465	−0.1086	0.071*
C42	0.0698 (11)	0.3913 (9)	−0.0745 (7)	0.057 (3)
H42A	0.0794	0.4635	−0.1013	0.069*
H42B	−0.0248	0.3871	−0.0735	0.069*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Au1	0.0324 (2)	0.0319 (2)	0.0336 (2)	−0.00318 (14)	−0.00047 (16)	−0.01220 (17)
S1	0.0414 (14)	0.0526 (16)	0.0403 (17)	−0.0077 (12)	−0.0101 (13)	−0.0061 (14)
S2	0.0349 (13)	0.0634 (17)	0.0300 (15)	−0.0151 (12)	−0.0032 (12)	−0.0057 (14)
P1	0.0278 (12)	0.0258 (12)	0.0280 (15)	−0.0019 (10)	−0.0006 (11)	−0.0135 (11)
P2	0.0285 (12)	0.0290 (13)	0.0362 (16)	−0.0033 (10)	−0.0013 (12)	−0.0138 (12)
N1	0.052 (5)	0.053 (5)	0.030 (5)	−0.020 (4)	0.002 (5)	−0.010 (4)
C1	0.036 (5)	0.041 (6)	0.026 (6)	−0.015 (4)	−0.001 (5)	−0.011 (5)
C2	0.038 (6)	0.047 (6)	0.051 (7)	−0.005 (5)	−0.009 (5)	−0.023 (6)
C3	0.046 (6)	0.047 (7)	0.073 (9)	−0.018 (5)	−0.010 (6)	−0.022 (6)
C4	0.067 (7)	0.033 (6)	0.046 (7)	−0.025 (5)	−0.002 (6)	−0.019 (5)
C5	0.057 (7)	0.027 (5)	0.046 (7)	−0.009 (5)	0.003 (6)	−0.013 (5)
C6	0.038 (5)	0.038 (6)	0.038 (7)	0.002 (5)	0.002 (5)	−0.017 (5)
C7	0.036 (5)	0.028 (5)	0.027 (6)	−0.003 (4)	−0.008 (5)	−0.009 (5)
C8	0.060 (7)	0.038 (6)	0.042 (7)	−0.005 (5)	0.001 (6)	−0.011 (6)
C9	0.075 (8)	0.065 (8)	0.038 (8)	−0.007 (7)	−0.013 (7)	−0.013 (7)
C10	0.060 (7)	0.060 (8)	0.035 (7)	−0.011 (6)	0.003 (6)	0.009 (6)
C11	0.061 (7)	0.028 (5)	0.055 (8)	−0.015 (5)	0.012 (6)	−0.012 (6)
C12	0.051 (6)	0.034 (6)	0.043 (7)	−0.010 (5)	0.002 (6)	−0.013 (5)
C13	0.032 (5)	0.030 (5)	0.040 (7)	−0.004 (4)	0.000 (5)	−0.008 (5)
C14	0.043 (6)	0.049 (6)	0.043 (7)	0.000 (5)	−0.002 (6)	−0.014 (6)
C15	0.074 (8)	0.048 (7)	0.059 (9)	0.014 (6)	−0.033 (8)	−0.022 (6)
C16	0.040 (6)	0.051 (7)	0.072 (10)	0.009 (5)	−0.021 (7)	−0.023 (7)
C17	0.030 (6)	0.067 (8)	0.077 (10)	−0.010 (5)	0.006 (6)	−0.026 (7)
C18	0.046 (6)	0.043 (6)	0.046 (7)	−0.007 (5)	−0.009 (6)	−0.011 (5)
C19	0.030 (5)	0.045 (6)	0.027 (6)	−0.018 (4)	0.000 (5)	−0.018 (5)
C20	0.058 (7)	0.037 (6)	0.046 (7)	0.005 (5)	−0.001 (6)	−0.018 (6)
C21	0.064 (8)	0.057 (8)	0.072 (10)	0.011 (6)	−0.008 (8)	−0.035 (7)
C22	0.039 (6)	0.088 (10)	0.081 (10)	0.006 (7)	−0.001 (7)	−0.065 (9)
C23	0.068 (8)	0.078 (9)	0.055 (9)	−0.012 (7)	0.035 (7)	−0.023 (7)
C24	0.059 (7)	0.050 (7)	0.045 (7)	−0.007 (6)	0.022 (6)	−0.018 (6)
C25	0.039 (5)	0.033 (5)	0.021 (5)	−0.007 (4)	0.003 (5)	0.000 (5)
C26	0.049 (6)	0.040 (6)	0.054 (8)	−0.001 (5)	−0.018 (6)	−0.026 (6)
C27	0.058 (7)	0.069 (8)	0.060 (9)	−0.023 (6)	−0.017 (7)	−0.027 (7)
C28	0.040 (6)	0.059 (7)	0.062 (8)	−0.004 (5)	−0.022 (6)	−0.019 (7)
C29	0.048 (7)	0.064 (8)	0.078 (10)	0.005 (6)	−0.027 (7)	−0.020 (7)
C30	0.052 (7)	0.050 (7)	0.059 (8)	−0.002 (5)	−0.025 (6)	−0.019 (6)
C31	0.042 (5)	0.022 (5)	0.040 (6)	0.000 (4)	−0.009 (5)	−0.017 (5)
C32	0.042 (6)	0.040 (6)	0.043 (7)	−0.007 (5)	−0.006 (5)	−0.012 (5)
C33	0.064 (7)	0.052 (7)	0.048 (8)	−0.015 (6)	−0.025 (7)	−0.007 (6)
C34	0.087 (9)	0.045 (7)	0.045 (8)	−0.011 (6)	−0.036 (8)	0.011 (6)
C35	0.061 (7)	0.040 (6)	0.053 (8)	−0.022 (6)	0.013 (6)	−0.011 (6)
C36	0.037 (5)	0.029 (5)	0.044 (7)	−0.012 (4)	−0.007 (5)	0.001 (5)
C37	0.034 (5)	0.042 (6)	0.038 (7)	0.001 (5)	−0.001 (5)	−0.018 (5)
C38	0.047 (6)	0.081 (8)	0.047 (8)	−0.032 (6)	0.003 (6)	−0.011 (7)
C39	0.062 (7)	0.083 (9)	0.048 (8)	−0.012 (7)	0.010 (7)	−0.006 (7)
C40	0.081 (9)	0.059 (8)	0.043 (8)	−0.004 (7)	0.011 (7)	−0.012 (6)
C41	0.091 (9)	0.058 (7)	0.031 (7)	−0.014 (7)	−0.007 (7)	−0.015 (6)
C42	0.067 (7)	0.064 (8)	0.031 (7)	−0.002 (6)	−0.003 (6)	−0.003 (6)

Geometric parameters (Å, º)

Au1—P1	2.336 (2)	C19—C24	1.363 (13)
Au1—P2	2.348 (2)	C19—C20	1.388 (13)
Au1—S2	2.561 (2)	C20—C21	1.377 (14)
Au1—S1	2.858 (3)	C20—H20A	0.9300
S1—C37	1.731 (9)	C21—C22	1.378 (16)
S2—C37	1.690 (10)	C21—H21A	0.9300
P1—C1	1.807 (9)	C22—C23	1.368 (16)
P1—C7	1.812 (10)	C22—H22A	0.9300
P1—C13	1.824 (9)	C23—C24	1.351 (14)
P2—C31	1.820 (10)	C23—H23A	0.9300
P2—C25	1.827 (10)	C24—H24A	0.9300
P2—C19	1.844 (9)	C25—C26	1.370 (13)
N1—C37	1.357 (12)	C25—C30	1.402 (13)
N1—C38	1.459 (12)	C26—C27	1.400 (14)
N1—C42	1.460 (13)	C26—H26A	0.9300
C1—C2	1.407 (12)	C27—C28	1.375 (14)
C1—C6	1.409 (12)	C27—H27A	0.9300
C2—C3	1.377 (13)	C28—C29	1.425 (15)
C2—H2A	0.9300	C28—H28A	0.9300
C3—C4	1.363 (13)	C29—C30	1.363 (14)
C3—H3A	0.9300	C29—H29A	0.9300
C4—C5	1.383 (14)	C30—H30A	0.9300
C4—H4A	0.9300	C31—C36	1.394 (12)
C5—C6	1.377 (13)	C31—C32	1.423 (13)
C5—H5A	0.9300	C32—C33	1.343 (14)
C6—H6A	0.9300	C32—H32A	0.9300
C7—C8	1.364 (13)	C33—C34	1.367 (15)
C7—C12	1.398 (12)	C33—H33A	0.9300
C8—C9	1.390 (15)	C34—C35	1.390 (15)
C8—H8A	0.9300	C34—H34A	0.9300
C9—C10	1.387 (15)	C35—C36	1.406 (14)
C9—H9A	0.9300	C35—H35A	0.9300
C10—C11	1.377 (15)	C36—H36A	0.9300
C10—H10A	0.9300	C38—C39	1.531 (15)
C11—C12	1.373 (14)	C38—H38A	0.9700
C11—H11A	0.9300	C38—H38B	0.9700
C12—H12A	0.9300	C39—C40	1.510 (16)
C13—C14	1.389 (14)	C39—H39A	0.9700
C13—C18	1.408 (13)	C39—H39B	0.9700
C14—C15	1.380 (14)	C40—C41	1.528 (15)
C14—H14A	0.9300	C40—H40A	0.9700
C15—C16	1.402 (15)	C40—H40B	0.9700
C15—H15A	0.9300	C41—C42	1.493 (14)
C16—C17	1.385 (16)	C41—H41A	0.9700
C16—H16A	0.9300	C41—H41B	0.9700
C17—C18	1.387 (14)	C42—H42A	0.9700
C17—H17A	0.9300	C42—H42B	0.9700
C18—H18A	0.9300
P1—Au1—P2	130.86 (8)	C19—C20—H20A	120.2
P1—Au1—S2	112.26 (9)	C20—C21—C22	119.3 (11)
P2—Au1—S2	115.94 (9)	C20—C21—H21A	120.3
P1—Au1—S1	109.05 (8)	C22—C21—H21A	120.3
P2—Au1—S1	98.80 (9)	C23—C22—C21	121.3 (11)
S2—Au1—S1	65.77 (8)	C23—C22—H22A	119.4
C37—S1—Au1	82.2 (4)	C21—C22—H22A	119.4
C37—S2—Au1	92.6 (3)	C24—C23—C22	118.2 (12)
C1—P1—C7	102.0 (4)	C24—C23—H23A	120.9
C1—P1—C13	103.7 (4)	C22—C23—H23A	120.9
C7—P1—C13	105.3 (4)	C23—C24—C19	122.8 (11)
C1—P1—Au1	120.8 (3)	C23—C24—H24A	118.6
C7—P1—Au1	113.9 (3)	C19—C24—H24A	118.6
C13—P1—Au1	109.6 (3)	C26—C25—C30	118.1 (9)
C31—P2—C25	103.1 (4)	C26—C25—P2	122.9 (7)
C31—P2—C19	105.3 (4)	C30—C25—P2	118.7 (8)
C25—P2—C19	104.9 (4)	C25—C26—C27	122.0 (10)
C31—P2—Au1	113.9 (3)	C25—C26—H26A	119.0
C25—P2—Au1	109.7 (3)	C27—C26—H26A	119.0
C19—P2—Au1	118.5 (3)	C28—C27—C26	118.4 (10)
C37—N1—C38	121.5 (9)	C28—C27—H27A	120.8
C37—N1—C42	124.2 (9)	C26—C27—H27A	120.8
C38—N1—C42	113.8 (9)	C27—C28—C29	121.2 (9)
C2—C1—C6	116.9 (9)	C27—C28—H28A	119.4
C2—C1—P1	120.7 (7)	C29—C28—H28A	119.4
C6—C1—P1	122.3 (7)	C30—C29—C28	117.8 (10)
C3—C2—C1	121.4 (9)	C30—C29—H29A	121.1
C3—C2—H2A	119.3	C28—C29—H29A	121.1
C1—C2—H2A	119.3	C29—C30—C25	122.4 (11)
C4—C3—C2	120.6 (9)	C29—C30—H30A	118.8
C4—C3—H3A	119.7	C25—C30—H30A	118.8
C2—C3—H3A	119.7	C36—C31—C32	117.2 (9)
C3—C4—C5	119.5 (9)	C36—C31—P2	122.8 (7)
C3—C4—H4A	120.2	C32—C31—P2	119.7 (7)
C5—C4—H4A	120.2	C33—C32—C31	121.5 (10)
C6—C5—C4	120.9 (9)	C33—C32—H32A	119.3
C6—C5—H5A	119.5	C31—C32—H32A	119.3
C4—C5—H5A	119.5	C32—C33—C34	121.9 (10)
C5—C6—C1	120.6 (9)	C32—C33—H33A	119.1
C5—C6—H6A	119.7	C34—C33—H33A	119.1
C1—C6—H6A	119.7	C33—C34—C35	118.9 (10)
C8—C7—C12	117.1 (9)	C33—C34—H34A	120.5
C8—C7—P1	124.4 (7)	C35—C34—H34A	120.5
C12—C7—P1	118.5 (8)	C34—C35—C36	120.4 (10)
C7—C8—C9	123.3 (10)	C34—C35—H35A	119.8
C7—C8—H8A	118.3	C36—C35—H35A	119.8
C9—C8—H8A	118.3	C31—C36—C35	120.0 (9)
C10—C9—C8	117.2 (11)	C31—C36—H36A	120.0
C10—C9—H9A	121.4	C35—C36—H36A	120.0
C8—C9—H9A	121.4	N1—C37—S2	120.9 (7)
C11—C10—C9	121.6 (11)	N1—C37—S1	119.8 (8)
C11—C10—H10A	119.2	S2—C37—S1	119.4 (6)
C9—C10—H10A	119.2	N1—C38—C39	110.4 (10)
C12—C11—C10	118.8 (10)	N1—C38—H38A	109.6
C12—C11—H11A	120.6	C39—C38—H38A	109.6
C10—C11—H11A	120.6	N1—C38—H38B	109.6
C11—C12—C7	121.9 (10)	C39—C38—H38B	109.6
C11—C12—H12A	119.0	H38A—C38—H38B	108.1
C7—C12—H12A	119.0	C40—C39—C38	112.6 (10)
C14—C13—C18	119.0 (8)	C40—C39—H39A	109.1
C14—C13—P1	118.4 (7)	C38—C39—H39A	109.1
C18—C13—P1	122.5 (8)	C40—C39—H39B	109.1
C15—C14—C13	121.8 (10)	C38—C39—H39B	109.1
C15—C14—H14A	119.1	H39A—C39—H39B	107.8
C13—C14—H14A	119.1	C39—C40—C41	110.9 (10)
C14—C15—C16	119.0 (11)	C39—C40—H40A	109.5
C14—C15—H15A	120.5	C41—C40—H40A	109.5
C16—C15—H15A	120.5	C39—C40—H40B	109.5
C17—C16—C15	119.5 (10)	C41—C40—H40B	109.5
C17—C16—H16A	120.3	H40A—C40—H40B	108.1
C15—C16—H16A	120.3	C42—C41—C40	112.2 (10)
C16—C17—C18	121.5 (10)	C42—C41—H41A	109.2
C16—C17—H17A	119.3	C40—C41—H41A	109.2
C18—C17—H17A	119.3	C42—C41—H41B	109.2
C17—C18—C13	119.1 (10)	C40—C41—H41B	109.2
C17—C18—H18A	120.5	H41A—C41—H41B	107.9
C13—C18—H18A	120.5	N1—C42—C41	110.1 (9)
C24—C19—C20	118.7 (9)	N1—C42—H42A	109.6
C24—C19—P2	118.8 (8)	C41—C42—H42A	109.6
C20—C19—P2	122.5 (8)	N1—C42—H42B	109.6
C21—C20—C19	119.5 (11)	C41—C42—H42B	109.6
C21—C20—H20A	120.2	H42A—C42—H42B	108.2
P1—Au1—S1—C37	107.8 (3)	C15—C16—C17—C18	−2.1 (17)
P2—Au1—S1—C37	−113.2 (3)	C16—C17—C18—C13	−0.6 (16)
S2—Au1—S1—C37	1.3 (3)	C14—C13—C18—C17	0.6 (15)
P1—Au1—S2—C37	−103.0 (3)	P1—C13—C18—C17	−177.0 (8)
P2—Au1—S2—C37	86.8 (3)	C31—P2—C19—C24	−155.0 (8)
S1—Au1—S2—C37	−1.4 (3)	C25—P2—C19—C24	96.5 (9)
P2—Au1—P1—C1	172.4 (4)	Au1—P2—C19—C24	−26.3 (9)
S2—Au1—P1—C1	4.1 (4)	C31—P2—C19—C20	23.4 (9)
S1—Au1—P1—C1	−66.7 (4)	C25—P2—C19—C20	−85.1 (9)
P2—Au1—P1—C7	50.5 (3)	Au1—P2—C19—C20	152.1 (7)
S2—Au1—P1—C7	−117.8 (3)	C24—C19—C20—C21	−3.3 (15)
S1—Au1—P1—C7	171.3 (3)	P2—C19—C20—C21	178.4 (8)
P2—Au1—P1—C13	−67.2 (3)	C19—C20—C21—C22	0.6 (17)
S2—Au1—P1—C13	124.5 (3)	C20—C21—C22—C23	0.8 (19)
S1—Au1—P1—C13	53.7 (3)	C21—C22—C23—C24	0 (2)
P1—Au1—P2—C31	−50.3 (3)	C22—C23—C24—C19	−3.4 (19)
S2—Au1—P2—C31	117.6 (3)	C20—C19—C24—C23	4.8 (17)
S1—Au1—P2—C31	−175.1 (3)	P2—C19—C24—C23	−176.8 (10)
P1—Au1—P2—C25	64.7 (3)	C31—P2—C25—C26	−80.4 (9)
S2—Au1—P2—C25	−127.4 (3)	C19—P2—C25—C26	29.6 (9)
S1—Au1—P2—C25	−60.1 (3)	Au1—P2—C25—C26	157.9 (8)
P1—Au1—P2—C19	−175.0 (3)	C31—P2—C25—C30	93.5 (8)
S2—Au1—P2—C19	−7.0 (4)	C19—P2—C25—C30	−156.5 (8)
S1—Au1—P2—C19	60.2 (4)	Au1—P2—C25—C30	−28.2 (9)
C7—P1—C1—C2	86.4 (9)	C30—C25—C26—C27	2.2 (16)
C13—P1—C1—C2	−164.3 (8)	P2—C25—C26—C27	176.0 (8)
Au1—P1—C1—C2	−41.1 (10)	C25—C26—C27—C28	−2.1 (17)
C7—P1—C1—C6	−89.2 (9)	C26—C27—C28—C29	0.5 (18)
C13—P1—C1—C6	20.0 (9)	C27—C28—C29—C30	1.0 (18)
Au1—P1—C1—C6	143.3 (7)	C28—C29—C30—C25	−1.0 (18)
C6—C1—C2—C3	3.6 (15)	C26—C25—C30—C29	−0.6 (16)
P1—C1—C2—C3	−172.3 (8)	P2—C25—C30—C29	−174.7 (9)
C1—C2—C3—C4	−2.4 (17)	C25—P2—C31—C36	−15.5 (9)
C2—C3—C4—C5	−1.1 (17)	C19—P2—C31—C36	−125.2 (8)
C3—C4—C5—C6	3.4 (17)	Au1—P2—C31—C36	103.3 (8)
C4—C5—C6—C1	−2.1 (16)	C25—P2—C31—C32	170.4 (8)
C2—C1—C6—C5	−1.3 (15)	C19—P2—C31—C32	60.7 (8)
P1—C1—C6—C5	174.5 (8)	Au1—P2—C31—C32	−70.8 (8)
C1—P1—C7—C8	10.2 (9)	C36—C31—C32—C33	−0.3 (14)
C13—P1—C7—C8	−97.8 (9)	P2—C31—C32—C33	174.1 (8)
Au1—P1—C7—C8	142.1 (7)	C31—C32—C33—C34	−0.6 (17)
C1—P1—C7—C12	−168.4 (7)	C32—C33—C34—C35	0.5 (18)
C13—P1—C7—C12	83.6 (8)	C33—C34—C35—C36	0.6 (17)
Au1—P1—C7—C12	−36.5 (8)	C32—C31—C36—C35	1.4 (14)
C12—C7—C8—C9	1.5 (15)	P2—C31—C36—C35	−172.9 (7)
P1—C7—C8—C9	−177.1 (8)	C34—C35—C36—C31	−1.6 (15)
C7—C8—C9—C10	−2.8 (16)	C38—N1—C37—S2	0.6 (13)
C8—C9—C10—C11	1.1 (17)	C42—N1—C37—S2	172.7 (8)
C9—C10—C11—C12	1.7 (17)	C38—N1—C37—S1	−178.5 (8)
C10—C11—C12—C7	−3.1 (16)	C42—N1—C37—S1	−6.5 (13)
C8—C7—C12—C11	1.5 (14)	Au1—S2—C37—N1	−176.9 (8)
P1—C7—C12—C11	−179.8 (8)	Au1—S2—C37—S1	2.3 (6)
C1—P1—C13—C14	78.2 (9)	Au1—S1—C37—N1	177.1 (8)
C7—P1—C13—C14	−175.0 (8)	Au1—S1—C37—S2	−2.1 (5)
Au1—P1—C13—C14	−52.1 (8)	C37—N1—C38—C39	115.9 (11)
C1—P1—C13—C18	−104.1 (8)	C42—N1—C38—C39	−56.9 (12)
C7—P1—C13—C18	2.7 (9)	N1—C38—C39—C40	51.7 (13)
Au1—P1—C13—C18	125.6 (7)	C38—C39—C40—C41	−49.5 (14)
C18—C13—C14—C15	2.2 (15)	C39—C40—C41—C42	51.8 (13)
P1—C13—C14—C15	180.0 (8)	C37—N1—C42—C41	−113.3 (11)
C13—C14—C15—C16	−5.0 (16)	C38—N1—C42—C41	59.3 (13)
C14—C15—C16—C17	4.9 (16)	C40—C41—C42—N1	−55.6 (13)

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
C4—H4A···Cg1^i	0.93	2.91	3.743	150
C24—H24A···Cg2	0.93	2.60	3.468	155
C41—H41A···Cg3^ii	0.97	2.78	3.668	152

Symmetry codes: (i) x, y+1, z; (ii) −x, −y+1, −z.