[(1,2,5,6-η)-1,5-Cyclo­octa­diene](1-isopropyl-3-methyl­imidazolin-2-yl­idene)(triphenyl­phosphine)iridium(I) tetra­fluorido­borate dichloro­methane solvate

In the title compound, [Ir(C₈H₁₂)(C₇H₁₂N₂)(C₁₈H₁₅P)]BF₄·CH₂Cl₂, the Ir(I) atom has a square-planar conformation with normal bond lengths. One of the phenyl rings, and the solvent dichloro­methane mol­ecule, were refined using separate two part disorder models, each in an approximately 1:1 ratio.

Key indicators

• Single-crystal X-ray study
• T = 100 K
• Mean [sigma](C-C) = 0.005 Å
• Disorder in main residue
• R factor = 0.021
• wR factor = 0.073
• Data-to-parameter ratio = 17.0

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.24 Ratio
PLAT250_ALERT_2_C Large U3/U1 Ratio for Average U(i,j) Tensor ....       2.01
PLAT366_ALERT_2_C Short? C(sp?)-C(sp?) Bond  C26    -   C27    ...       1.39 Ang.
PLAT366_ALERT_2_C Short? C(sp?)-C(sp?) Bond  C30    -   C31    ...       1.38 Ang.
PLAT910_ALERT_3_C Missing # of FCF Reflections Below Th(Min) .....          1
PLAT911_ALERT_3_C Missing # FCF Refl Between THmin & STh/L=  0.600          3
PLAT042_ALERT_1_C Calc. and Reported MoietyFormula Strings  Differ          ?
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors of         C34
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors of           B
PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd.  #          3
              B F4

Alert level G
PLAT301_ALERT_3_G Note: Main Residue  Disorder ...................      14.00 Perc.
PLAT432_ALERT_2_G Short Inter X...Y Contact  F1     ..  C34     ..       2.88 Ang.
PLAT860_ALERT_3_G Note: Number of Least-Squares Restraints .......         84
PLAT302_ALERT_4_G Note: Anion/Solvent Disorder ...................      27.00 Perc.
PLAT779_ALERT_4_G Suspect or Irrelevant (Bond) Angle in CIF ......      13.70 Deg.
              C8   -P    -C8'     1.555   1.555   1.555
PLAT811_ALERT_5_G No ADDSYM Analysis: Too Many Excluded Atoms ....          !

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
  10 ALERT level C = Check and explain
   6 ALERT level G = General alerts; check

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   5 ALERT type 2 Indicator that the structure model may be wrong or deficient
   4 ALERT type 3 Indicator that the structure quality may be low
   5 ALERT type 4 Improvement, methodology, query or suggestion
   1 ALERT type 5 Informative message, check

---

S1. Comment

The title compound, (I), was prepared as part of our ongoing research on Rh and Ir-containing N-heterocyclic carbene complexes (Nichol et al., 2009). The Ir center has an expected square planar conformation and bond distances are unexceptional. One of the phenyl rings, and the solvent dichloromethane molecule, were refined using separate two part disorder models, each in an approximately 1:1 ratio. The structure of the isomorphous Rh analogue has also been reported (Nichol et al., 2010).

Related literature

For structure and dynamics of related N-heterocyclic carbene iridium complexes, see: Chianese et al. (2003); Herrmann et al. (2006); Köcher et al. (1997); Nichol et al. (2009). For the isomorphous Rh analogue, see: Nichol et al. (2010). For catalytic properties of these complexes, see: Albrecht et al. (2002); Frey et al. (2006); Gnanamgari et al. (2007); Voutchkova et al. (2008).

S2. Experimental

The title compound, (I), was synthesized by the reaction of [Ir(cod)(C₇H₁₂N₂)Cl](0.369 mg, 0.80 mmol) and triphenylphosphene (211 mg, 0.80 mmol) in CH₂Cl₂ (8 ml) with silver tetrafluoroborate (157 m, 0.80 mmol) for 1.5 h. The mixture was filtered through Celite to remove silver chloride and the solvent was removed under reduced pressure. Crystals of the resulting solid of the title compound were obtained by slow diffusion of pentane into dichloromethane solution of the compound.

S3. Refinement

One of the phenyl rings, and the solvent dichloromethane molecule, were refined using separate two part disorder models, each in an approximately 1:1 ratio. Bond distance similarity restraints were applied to the dichloromethane molecule, and approximate isotropic restraints were used on the ellipsoids of the disordered C atoms of both the dichloromethane molecule and the phenyl ring. The largest residual peak is approximately 0.76Å from Ir. H atoms were first located in a difference map and then refined using U_isoH = 1.5U_eqC for methyl groups and U_isoH = 1.2U_eqC for all others and constrained C–H distances.

Computing details

Data collection: APEX2 (Bruker, 2007); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT (Bruker, 2007); program(s) used to solve structure: SIR97 (Altomare et al., 1999); program(s) used to refine structure: SHELXTL (Sheldrick, 2008); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997); software used to prepare material for publication: SHELXTL (Sheldrick, 2008) and publCIF (Westrip, 2010).

Figures

Fig. 1. The structure of the Ir complex in (I), with displacement ellipsoids at the 30% probability level and hydrogen atoms omitted.

[(1,2,5,6-η)-1,5-Cyclooctadiene](1-isopropyl-3-methylimidazolin-2- ylidene)(triphenylphosphine)iridium(I) tetrafluoridoborate dichloromethane solvate

Crystal data

[Ir(C8H12)(C7H12N2)(C18H15P)]BF4·CH2Cl2	F(000) = 3408
Mr = 858.57	Dx = 1.674 Mg m^−3
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 9491 reflections
a = 36.3039 (16) Å	θ = 2.4–28.3°
b = 10.4913 (5) Å	µ = 4.17 mm^−1
c = 18.3924 (8) Å	T = 100 K
β = 103.452 (2)°	Prism, red
V = 6813.0 (5) Å^3	0.30 × 0.14 × 0.11 mm
Z = 8

Data collection

Bruker Kappa APEXII DUO CCD diffractometer	7834 independent reflections
Radiation source: fine-focus sealed tube with Miracol optics	6800 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.033
φ and ω scans	θmax = 27.5°, θmin = 2.0°
Absorption correction: numerical (SADABS; Sheldrick, 1996)	h = −47→47
Tmin = 0.370, Tmax = 0.652	k = −13→13
72041 measured reflections	l = −23→23

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.021	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.073	H-atom parameters constrained
S = 1.04	w = 1/[σ^2(Fo^2) + (0.050P)^2 + 5.P] where P = (Fo^2 + 2Fc^2)/3
7834 reflections	(Δ/σ)max = 0.011
460 parameters	Δρmax = 1.31 e Å^−3
84 restraints	Δρmin = −0.94 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ir	0.668273 (3)	0.510395 (9)	0.563854 (6)	0.02420 (5)
Cl1	0.54347 (6)	0.9363 (4)	0.70029 (17)	0.0471 (7)	0.511 (7)
Cl2	0.57718 (16)	1.1103 (5)	0.6136 (5)	0.137 (2)	0.511 (7)
Cl1'	0.54270 (8)	1.0031 (6)	0.71548 (15)	0.0579 (11)	0.489 (7)
Cl2'	0.57231 (13)	1.0807 (4)	0.58942 (14)	0.0553 (9)	0.489 (7)
P	0.60271 (2)	0.52250 (7)	0.53810 (5)	0.02869 (16)
F1	0.63097 (6)	1.1774 (2)	0.28542 (14)	0.0718 (7)
F2	0.68831 (7)	1.2144 (3)	0.26529 (15)	0.0974 (10)
F3	0.68298 (6)	1.1205 (3)	0.37193 (13)	0.0728 (7)
F4	0.66639 (8)	1.0113 (2)	0.2656 (2)	0.0865 (10)
N1	0.67636 (6)	0.7514 (2)	0.47676 (15)	0.0373 (6)
N2	0.67143 (7)	0.5884 (2)	0.40379 (14)	0.0356 (6)
B	0.66725 (11)	1.1321 (5)	0.2973 (3)	0.0557 (11)
C1	0.67157 (7)	0.6230 (3)	0.47509 (17)	0.0318 (6)
C2	0.67518 (8)	0.6943 (3)	0.3618 (2)	0.0455 (8)
H2	0.6756	0.6948	0.3104	0.055*
C3	0.67807 (8)	0.7960 (3)	0.4063 (2)	0.0488 (9)
H3	0.6808	0.8822	0.3926	0.059*
C4	0.67913 (8)	0.8306 (3)	0.5440 (2)	0.0456 (8)
H4	0.6763	0.7737	0.5860	0.055*
C5	0.64780 (9)	0.9295 (3)	0.5322 (3)	0.0681 (13)
H5A	0.6232	0.8869	0.5172	0.102*
H5B	0.6508	0.9890	0.4929	0.102*
H5C	0.6492	0.9765	0.5788	0.102*
C6	0.71784 (8)	0.8956 (3)	0.5664 (2)	0.0525 (9)
H6A	0.7378	0.8324	0.5672	0.079*
H6B	0.7210	0.9335	0.6162	0.079*
H6C	0.7195	0.9625	0.5301	0.079*
C7	0.66684 (10)	0.4574 (3)	0.37577 (19)	0.0403 (7)
H7A	0.6580	0.4034	0.4118	0.060*
H7B	0.6912	0.4254	0.3691	0.060*
H7C	0.6482	0.4556	0.3277	0.060*
C8	0.57817 (16)	0.6605 (5)	0.4981 (5)	0.0241 (16)	0.556 (18)
C9	0.55354 (16)	0.7332 (5)	0.5287 (5)	0.0363 (17)	0.556 (18)
H9	0.5505	0.7149	0.5776	0.044*	0.556 (18)
C10	0.53335 (13)	0.8325 (4)	0.4879 (7)	0.047 (2)	0.556 (18)
H10	0.5165	0.8822	0.5088	0.057*	0.556 (18)
C11	0.53780 (13)	0.8592 (4)	0.4164 (7)	0.041 (2)	0.556 (18)
H11	0.5240	0.9272	0.3885	0.049*	0.556 (18)
C12	0.56243 (15)	0.7866 (6)	0.3857 (5)	0.041 (2)	0.556 (18)
H12	0.5655	0.8049	0.3369	0.049*	0.556 (18)
C13	0.58261 (15)	0.6873 (5)	0.4266 (5)	0.0284 (17)	0.556 (18)
H13	0.5994	0.6376	0.4056	0.034*	0.556 (18)
C8'	0.5794 (2)	0.6616 (5)	0.4725 (5)	0.021 (2)	0.444 (18)
C9'	0.55502 (19)	0.7448 (6)	0.4970 (6)	0.035 (2)	0.444 (18)
H9'	0.5509	0.7363	0.5459	0.042*	0.444 (18)
C10'	0.53665 (19)	0.8404 (6)	0.4499 (7)	0.040 (3)	0.444 (18)
H10'	0.5200	0.8973	0.4666	0.048*	0.444 (18)
C11'	0.5426 (2)	0.8528 (5)	0.3783 (7)	0.042 (3)	0.444 (18)
H11'	0.5301	0.9182	0.3461	0.050*	0.444 (18)
C12'	0.5670 (2)	0.7697 (6)	0.3537 (6)	0.038 (2)	0.444 (18)
H12'	0.5711	0.7781	0.3048	0.046*	0.444 (18)
C13'	0.5854 (2)	0.6741 (6)	0.4008 (5)	0.0260 (19)	0.444 (18)
H13'	0.6020	0.6172	0.3841	0.031*	0.444 (18)
C14	0.58120 (8)	0.5100 (3)	0.6183 (2)	0.0362 (7)
C15	0.59156 (8)	0.5988 (3)	0.6765 (2)	0.0471 (9)
H15	0.6098	0.6628	0.6740	0.057*
C16	0.57541 (8)	0.5937 (4)	0.7375 (2)	0.0510 (9)
H16	0.5820	0.6558	0.7759	0.061*
C17	0.54978 (10)	0.4992 (3)	0.7431 (2)	0.0496 (10)
H17	0.5391	0.4951	0.7856	0.060*
C18	0.53965 (8)	0.4100 (3)	0.68616 (18)	0.0429 (7)
H18	0.5220	0.3446	0.6897	0.052*
C19	0.55513 (7)	0.4160 (3)	0.62424 (17)	0.0351 (6)
H19	0.5478	0.3550	0.5853	0.042*
C20	0.58018 (7)	0.3948 (2)	0.47589 (14)	0.0255 (5)
C21	0.60049 (8)	0.2880 (2)	0.46441 (14)	0.0265 (5)
H21	0.6264	0.2804	0.4895	0.032*
C22	0.58319 (9)	0.1918 (3)	0.41636 (16)	0.0344 (6)
H22	0.5973	0.1191	0.4082	0.041*
C23	0.54526 (10)	0.2028 (3)	0.38053 (17)	0.0412 (7)
H23	0.5333	0.1370	0.3481	0.049*
C24	0.52498 (9)	0.3086 (3)	0.39171 (18)	0.0432 (8)
H24	0.4991	0.3156	0.3665	0.052*
C25	0.54182 (8)	0.4050 (3)	0.43925 (17)	0.0360 (6)
H25	0.5275	0.4775	0.4470	0.043*
C26	0.72262 (7)	0.4198 (3)	0.56404 (17)	0.0310 (6)
H26	0.7287	0.4180	0.5137	0.037*
C27	0.73017 (8)	0.5364 (3)	0.60018 (18)	0.0333 (6)
H27	0.7404	0.6019	0.5707	0.040*
C28	0.74038 (8)	0.5601 (4)	0.68319 (19)	0.0484 (8)
H28A	0.7677	0.5421	0.7026	0.058*
H28B	0.7362	0.6513	0.6925	0.058*
C29	0.71816 (11)	0.4810 (4)	0.7254 (2)	0.0515 (10)
H29A	0.7177	0.5245	0.7729	0.062*
H29B	0.7310	0.3980	0.7379	0.062*
C30	0.67744 (8)	0.4573 (4)	0.68168 (17)	0.0398 (7)
H30	0.6578	0.4914	0.7067	0.048*
C31	0.66613 (8)	0.3492 (3)	0.63912 (15)	0.0335 (6)
H31	0.6399	0.3201	0.6391	0.040*
C32	0.69224 (8)	0.2436 (3)	0.62553 (18)	0.0413 (7)
H32A	0.6999	0.1918	0.6716	0.050*
H32B	0.6781	0.1874	0.5854	0.050*
C33	0.72751 (9)	0.2912 (3)	0.60362 (19)	0.0421 (7)
H33A	0.7353	0.2275	0.5704	0.050*
H33B	0.7482	0.2980	0.6492	0.050*
C34	0.58431 (16)	0.9833 (6)	0.6744 (3)	0.0401 (17)	0.511 (7)
H34A	0.6037	1.0068	0.7198	0.048*	0.511 (7)
H34B	0.5942	0.9105	0.6505	0.048*	0.511 (7)
C34'	0.58224 (16)	1.0511 (6)	0.6851 (3)	0.081 (3)*	0.489 (7)
H34C	0.6019	0.9840	0.6974	0.097*	0.489 (7)
H34D	0.5926	1.1295	0.7122	0.097*	0.489 (7)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ir	0.01353 (7)	0.02279 (7)	0.03367 (8)	0.00024 (3)	0.00019 (5)	−0.00506 (4)
Cl1	0.0276 (8)	0.0522 (16)	0.0600 (13)	−0.0038 (8)	0.0068 (8)	−0.0006 (11)
Cl2	0.082 (3)	0.064 (2)	0.293 (7)	0.033 (2)	0.100 (4)	0.095 (4)
Cl1'	0.0481 (13)	0.087 (3)	0.0383 (11)	−0.0257 (13)	0.0087 (9)	0.0051 (12)
Cl2'	0.0796 (19)	0.0548 (18)	0.0410 (14)	0.0281 (14)	0.0329 (10)	0.0115 (9)
P	0.0143 (3)	0.0221 (3)	0.0463 (4)	−0.0004 (2)	0.0001 (3)	−0.0069 (3)
F1	0.0373 (11)	0.0748 (16)	0.1002 (18)	0.0227 (11)	0.0097 (11)	0.0172 (14)
F2	0.0634 (16)	0.135 (3)	0.0935 (19)	−0.0184 (16)	0.0181 (14)	0.0535 (18)
F3	0.0535 (13)	0.0842 (18)	0.0747 (15)	0.0031 (12)	0.0025 (11)	0.0362 (13)
F4	0.0402 (15)	0.085 (2)	0.124 (3)	0.0264 (11)	−0.0033 (15)	−0.0120 (15)
N1	0.0173 (11)	0.0250 (12)	0.0645 (17)	−0.0015 (9)	−0.0010 (10)	0.0063 (11)
N2	0.0264 (12)	0.0322 (13)	0.0443 (14)	−0.0048 (10)	0.0006 (10)	0.0080 (11)
B	0.0281 (19)	0.069 (3)	0.069 (3)	0.0096 (18)	0.0080 (18)	0.022 (2)
C1	0.0162 (12)	0.0253 (13)	0.0496 (17)	−0.0019 (10)	−0.0013 (11)	0.0031 (12)
C2	0.0313 (16)	0.0437 (18)	0.056 (2)	−0.0060 (13)	−0.0008 (14)	0.0207 (15)
C3	0.0252 (15)	0.0365 (17)	0.079 (2)	−0.0033 (13)	−0.0002 (15)	0.0248 (17)
C4	0.0248 (14)	0.0228 (14)	0.087 (2)	−0.0024 (11)	0.0078 (15)	−0.0061 (15)
C5	0.0224 (15)	0.0287 (17)	0.146 (4)	−0.0007 (13)	0.0055 (19)	−0.014 (2)
C6	0.0221 (15)	0.0325 (16)	0.096 (3)	−0.0015 (12)	−0.0004 (16)	−0.0139 (17)
C7	0.0423 (18)	0.0382 (16)	0.0394 (17)	−0.0084 (15)	0.0073 (13)	0.0021 (14)
C8	0.017 (2)	0.024 (3)	0.029 (4)	−0.0035 (19)	0.000 (2)	0.006 (2)
C9	0.032 (3)	0.028 (3)	0.047 (4)	0.013 (2)	0.006 (3)	0.010 (3)
C10	0.048 (3)	0.033 (3)	0.063 (6)	0.015 (3)	0.017 (3)	0.013 (3)
C11	0.039 (3)	0.032 (3)	0.047 (6)	0.007 (2)	0.000 (3)	0.016 (3)
C12	0.036 (3)	0.039 (4)	0.041 (5)	−0.010 (3)	−0.004 (3)	0.014 (3)
C13	0.022 (3)	0.030 (3)	0.030 (4)	−0.002 (2)	0.001 (3)	0.001 (3)
C8'	0.018 (3)	0.020 (3)	0.024 (5)	−0.001 (2)	0.004 (3)	−0.001 (3)
C9'	0.035 (4)	0.029 (4)	0.035 (5)	0.005 (3)	0.000 (3)	−0.004 (3)
C10'	0.043 (4)	0.033 (4)	0.040 (6)	0.020 (3)	0.003 (4)	0.003 (4)
C11'	0.051 (4)	0.023 (3)	0.042 (6)	0.011 (3)	−0.007 (4)	0.004 (3)
C12'	0.041 (4)	0.031 (4)	0.036 (5)	−0.002 (3)	−0.003 (3)	0.011 (3)
C13'	0.027 (3)	0.024 (3)	0.025 (4)	−0.003 (2)	0.003 (3)	0.005 (3)
C14	0.0134 (13)	0.0382 (16)	0.055 (2)	0.0014 (10)	0.0038 (13)	−0.0189 (13)
C15	0.0152 (13)	0.055 (2)	0.070 (2)	−0.0043 (12)	0.0079 (13)	−0.0321 (17)
C16	0.0195 (14)	0.072 (2)	0.058 (2)	0.0024 (14)	0.0016 (13)	−0.0355 (18)
C17	0.0231 (17)	0.073 (3)	0.051 (2)	0.0063 (13)	0.0047 (15)	−0.0193 (16)
C18	0.0244 (14)	0.0518 (19)	0.0511 (19)	−0.0001 (13)	0.0059 (13)	−0.0088 (15)
C19	0.0183 (12)	0.0370 (15)	0.0476 (17)	0.0010 (11)	0.0024 (11)	−0.0113 (13)
C20	0.0203 (12)	0.0231 (12)	0.0294 (13)	−0.0042 (9)	−0.0015 (10)	0.0005 (10)
C21	0.0267 (13)	0.0236 (12)	0.0275 (13)	−0.0025 (10)	0.0026 (10)	0.0048 (10)
C22	0.0464 (17)	0.0208 (13)	0.0341 (15)	−0.0040 (12)	0.0056 (13)	0.0003 (11)
C23	0.0508 (19)	0.0295 (15)	0.0346 (16)	−0.0129 (13)	−0.0077 (14)	0.0013 (12)
C24	0.0323 (16)	0.0346 (16)	0.0497 (18)	−0.0103 (12)	−0.0171 (13)	0.0066 (13)
C25	0.0242 (14)	0.0280 (14)	0.0486 (17)	−0.0001 (11)	−0.0062 (12)	0.0005 (12)
C26	0.0177 (12)	0.0316 (14)	0.0445 (16)	0.0034 (10)	0.0090 (11)	−0.0012 (12)
C27	0.0112 (12)	0.0369 (15)	0.0479 (18)	0.0001 (11)	−0.0014 (11)	−0.0046 (14)
C28	0.0222 (14)	0.065 (2)	0.0515 (19)	0.0020 (15)	−0.0043 (13)	−0.0185 (17)
C29	0.0306 (18)	0.084 (3)	0.0360 (18)	−0.0043 (16)	−0.0005 (14)	−0.0196 (16)
C30	0.0221 (14)	0.066 (2)	0.0291 (15)	0.0058 (14)	0.0026 (11)	−0.0068 (15)
C31	0.0264 (14)	0.0429 (16)	0.0302 (14)	0.0021 (12)	0.0041 (11)	0.0076 (12)
C32	0.0359 (16)	0.0404 (17)	0.0467 (17)	0.0094 (13)	0.0074 (13)	0.0117 (14)
C33	0.0360 (16)	0.0327 (16)	0.058 (2)	0.0082 (13)	0.0126 (14)	0.0022 (14)
C34	0.034 (3)	0.026 (3)	0.066 (4)	0.004 (2)	0.022 (3)	−0.002 (3)

Geometric parameters (Å, º)

Ir—P	2.3196 (7)	C10'—H10'	0.950
Ir—C1	2.041 (3)	C10'—C11'	1.390
Ir—C26	2.189 (3)	C11'—H11'	0.950
Ir—C27	2.207 (3)	C11'—C12'	1.390
Ir—C30	2.187 (3)	C12'—H12'	0.950
Ir—C31	2.198 (3)	C12'—C13'	1.390
Cl1—C34	1.731 (5)	C13'—H13'	0.950
Cl2—C34	1.719 (6)	C14—C15	1.404 (4)
Cl1'—C34'	1.732 (5)	C14—C19	1.389 (4)
Cl2'—C34'	1.740 (5)	C15—H15	0.950
P—C8	1.769 (4)	C15—C16	1.382 (5)
P—C8'	1.957 (6)	C16—H16	0.950
P—C14	1.827 (4)	C16—C17	1.380 (5)
P—C20	1.827 (3)	C17—H17	0.950
F1—B	1.369 (4)	C17—C18	1.389 (5)
F2—B	1.373 (5)	C18—H18	0.950
F3—B	1.364 (5)	C18—C19	1.384 (4)
F4—B	1.393 (6)	C19—H19	0.950
N1—C1	1.358 (3)	C20—C21	1.384 (4)
N1—C3	1.392 (4)	C20—C25	1.403 (4)
N1—C4	1.474 (4)	C21—H21	0.950
N2—C1	1.360 (4)	C21—C22	1.391 (4)
N2—C2	1.377 (4)	C22—H22	0.950
N2—C7	1.464 (4)	C22—C23	1.386 (4)
C2—H2	0.950	C23—H23	0.950
C2—C3	1.334 (5)	C23—C24	1.373 (5)
C3—H3	0.950	C24—H24	0.950
C4—H4	1.000	C24—C25	1.383 (4)
C4—C5	1.517 (4)	C25—H25	0.950
C4—C6	1.529 (4)	C26—H26	1.000
C5—H5A	0.980	C26—C27	1.388 (4)
C5—H5B	0.980	C26—C33	1.524 (4)
C5—H5C	0.980	C27—H27	1.000
C6—H6A	0.980	C27—C28	1.506 (5)
C6—H6B	0.980	C28—H28A	0.990
C6—H6C	0.980	C28—H28B	0.990
C7—H7A	0.980	C28—C29	1.494 (6)
C7—H7B	0.980	C29—H29A	0.990
C7—H7C	0.980	C29—H29B	0.990
C8—C9	1.390	C29—C30	1.530 (5)
C8—C13	1.390	C30—H30	1.000
C9—H9	0.950	C30—C31	1.384 (4)
C9—C10	1.390	C31—H31	1.000
C10—H10	0.950	C31—C32	1.516 (4)
C10—C11	1.390	C32—H32A	0.990
C11—H11	0.950	C32—H32B	0.990
C11—C12	1.390	C32—C33	1.514 (4)
C12—H12	0.950	C33—H33A	0.990
C12—C13	1.390	C33—H33B	0.990
C13—H13	0.950	C34—H34A	0.990
C8'—C9'	1.390	C34—H34B	0.990
C8'—C13'	1.390	C34'—H34C	0.990
C9'—H9'	0.950	C34'—H34D	0.990
C9'—C10'	1.390
P—Ir—C1	93.05 (7)	C11'—C12'—C13'	120.0
P—Ir—C26	154.91 (8)	H12'—C12'—C13'	120.0
P—Ir—C27	168.25 (9)	C8'—C13'—C12'	120.0
P—Ir—C30	97.40 (8)	C8'—C13'—H13'	120.0
P—Ir—C31	89.18 (8)	C12'—C13'—H13'	120.0
C1—Ir—C26	91.82 (11)	P—C14—C15	118.7 (2)
C1—Ir—C27	85.73 (11)	P—C14—C19	122.8 (2)
C1—Ir—C30	156.42 (12)	C15—C14—C19	118.5 (3)
C1—Ir—C31	165.05 (11)	C14—C15—H15	119.9
C26—Ir—C27	36.81 (11)	C14—C15—C16	120.3 (3)
C26—Ir—C30	87.62 (11)	H15—C15—C16	119.9
C26—Ir—C31	80.16 (11)	C15—C16—H16	119.7
C27—Ir—C30	79.75 (12)	C15—C16—C17	120.6 (3)
C27—Ir—C31	95.00 (12)	H16—C16—C17	119.7
C30—Ir—C31	36.81 (12)	C16—C17—H17	120.3
Ir—P—C8	121.6 (2)	C16—C17—C18	119.5 (4)
Ir—P—C8'	116.3 (3)	H17—C17—C18	120.3
Ir—P—C14	116.25 (11)	C17—C18—H18	119.9
Ir—P—C20	112.12 (9)	C17—C18—C19	120.2 (3)
C8—P—C8'	13.7 (2)	H18—C18—C19	119.9
C8—P—C14	97.2 (3)	C14—C19—C18	120.8 (3)
C8—P—C20	103.3 (3)	C14—C19—H19	119.6
C8'—P—C14	110.3 (3)	C18—C19—H19	119.6
C8'—P—C20	95.4 (3)	P—C20—C21	120.81 (19)
C14—P—C20	103.87 (13)	P—C20—C25	119.7 (2)
C1—N1—C3	110.2 (3)	C21—C20—C25	119.5 (2)
C1—N1—C4	124.2 (3)	C20—C21—H21	119.8
C3—N1—C4	125.6 (3)	C20—C21—C22	120.4 (2)
C1—N2—C2	110.3 (3)	H21—C21—C22	119.8
C1—N2—C7	124.4 (2)	C21—C22—H22	120.2
C2—N2—C7	125.3 (3)	C21—C22—C23	119.6 (3)
F1—B—F2	108.9 (3)	H22—C22—C23	120.2
F1—B—F3	110.7 (4)	C22—C23—H23	119.9
F1—B—F4	108.8 (4)	C22—C23—C24	120.3 (3)
F2—B—F3	110.1 (4)	H23—C23—C24	119.9
F2—B—F4	110.7 (4)	C23—C24—H24	119.6
F3—B—F4	107.7 (4)	C23—C24—C25	120.8 (3)
Ir—C1—N1	125.9 (2)	H24—C24—C25	119.6
Ir—C1—N2	129.0 (2)	C20—C25—C24	119.4 (3)
N1—C1—N2	105.0 (3)	C20—C25—H25	120.3
N2—C2—H2	126.1	C24—C25—H25	120.3
N2—C2—C3	107.8 (3)	Ir—C26—H26	113.5
H2—C2—C3	126.1	Ir—C26—C27	72.31 (15)
N1—C3—C2	106.7 (3)	Ir—C26—C33	112.95 (18)
N1—C3—H3	126.6	H26—C26—C27	113.5
C2—C3—H3	126.6	H26—C26—C33	113.5
N1—C4—H4	108.1	C27—C26—C33	124.3 (3)
N1—C4—C5	111.3 (3)	Ir—C27—C26	70.88 (15)
N1—C4—C6	110.8 (3)	Ir—C27—H27	113.7
H4—C4—C5	108.1	Ir—C27—C28	108.7 (2)
H4—C4—C6	108.1	C26—C27—H27	113.7
C5—C4—C6	110.2 (3)	C26—C27—C28	127.3 (3)
C4—C5—H5A	109.5	H27—C27—C28	113.7
C4—C5—H5B	109.5	C27—C28—H28A	108.9
C4—C5—H5C	109.5	C27—C28—H28B	108.9
H5A—C5—H5B	109.5	C27—C28—C29	113.6 (3)
H5A—C5—H5C	109.5	H28A—C28—H28B	107.7
H5B—C5—H5C	109.5	H28A—C28—C29	108.9
C4—C6—H6A	109.5	H28B—C28—C29	108.9
C4—C6—H6B	109.5	C28—C29—H29A	109.0
C4—C6—H6C	109.5	C28—C29—H29B	109.0
H6A—C6—H6B	109.5	C28—C29—C30	112.9 (3)
H6A—C6—H6C	109.5	H29A—C29—H29B	107.8
H6B—C6—H6C	109.5	H29A—C29—C30	109.0
N2—C7—H7A	109.5	H29B—C29—C30	109.0
N2—C7—H7B	109.5	Ir—C30—C29	112.7 (2)
N2—C7—H7C	109.5	Ir—C30—H30	113.8
H7A—C7—H7B	109.5	Ir—C30—C31	72.04 (17)
H7A—C7—H7C	109.5	C29—C30—H30	113.8
H7B—C7—H7C	109.5	C29—C30—C31	123.6 (3)
P—C8—C9	126.1 (3)	H30—C30—C31	113.8
P—C8—C13	113.6 (3)	Ir—C31—C30	71.15 (19)
C9—C8—C13	120.0	Ir—C31—H31	114.1
C8—C9—H9	120.0	Ir—C31—C32	110.07 (18)
C8—C9—C10	120.0	C30—C31—H31	114.1
H9—C9—C10	120.0	C30—C31—C32	125.2 (3)
C9—C10—H10	120.0	H31—C31—C32	114.1
C9—C10—C11	120.0	C31—C32—H32A	108.8
H10—C10—C11	120.0	C31—C32—H32B	108.8
C10—C11—H11	120.0	C31—C32—C33	113.8 (3)
C10—C11—C12	120.0	H32A—C32—H32B	107.7
H11—C11—C12	120.0	H32A—C32—C33	108.8
C11—C12—H12	120.0	H32B—C32—C33	108.8
C11—C12—C13	120.0	C26—C33—C32	114.0 (2)
H12—C12—C13	120.0	C26—C33—H33A	108.7
C8—C13—C12	120.0	C26—C33—H33B	108.7
C8—C13—H13	120.0	C32—C33—H33A	108.7
C12—C13—H13	120.0	C32—C33—H33B	108.7
P—C8'—C9'	119.0 (3)	H33A—C33—H33B	107.6
P—C8'—C13'	120.9 (3)	Cl1—C34—Cl2	113.0 (4)
C9'—C8'—C13'	120.0	Cl1—C34—H34A	109.0
C8'—C9'—H9'	120.0	Cl1—C34—H34B	109.0
C8'—C9'—C10'	120.0	Cl2—C34—H34A	109.0
H9'—C9'—C10'	120.0	Cl2—C34—H34B	109.0
C9'—C10'—H10'	120.0	H34A—C34—H34B	107.8
C9'—C10'—C11'	120.0	Cl1'—C34'—Cl2'	112.7 (4)
H10'—C10'—C11'	120.0	Cl1'—C34'—H34C	109.1
C10'—C11'—H11'	120.0	Cl1'—C34'—H34D	109.1
C10'—C11'—C12'	120.0	Cl2'—C34'—H34C	109.1
H11'—C11'—C12'	120.0	Cl2'—C34'—H34D	109.1
C11'—C12'—H12'	120.0	H34C—C34'—H34D	107.8
C1—Ir—P—C8	−32.6 (3)	C8—P—C14—C19	108.2 (3)
C1—Ir—P—C8'	−18.0 (3)	C8'—P—C14—C15	−76.7 (4)
C1—Ir—P—C14	−150.47 (13)	C8'—P—C14—C19	103.6 (4)
C1—Ir—P—C20	90.25 (12)	C20—P—C14—C15	−177.9 (3)
C26—Ir—P—C8	−133.5 (4)	C20—P—C14—C19	2.4 (3)
C26—Ir—P—C8'	−118.9 (3)	P—C14—C15—C16	178.9 (3)
C26—Ir—P—C14	108.6 (2)	C19—C14—C15—C16	−1.4 (5)
C26—Ir—P—C20	−10.6 (2)	C14—C15—C16—C17	1.9 (5)
C27—Ir—P—C8	51.2 (6)	C15—C16—C17—C18	−1.2 (5)
C27—Ir—P—C8'	65.7 (5)	C16—C17—C18—C19	−0.1 (5)
C27—Ir—P—C14	−66.7 (5)	C17—C18—C19—C14	0.6 (5)
C27—Ir—P—C20	174.0 (4)	P—C14—C19—C18	179.8 (2)
C30—Ir—P—C8	126.3 (3)	C15—C14—C19—C18	0.1 (5)
C30—Ir—P—C8'	140.8 (3)	Ir—P—C20—C21	16.3 (2)
C30—Ir—P—C14	8.35 (14)	Ir—P—C20—C25	−163.7 (2)
C30—Ir—P—C20	−110.93 (14)	C8—P—C20—C21	148.9 (3)
C31—Ir—P—C8	162.2 (3)	C8—P—C20—C25	−31.1 (4)
C31—Ir—P—C8'	176.7 (3)	C8'—P—C20—C21	137.6 (3)
C31—Ir—P—C14	44.32 (13)	C8'—P—C20—C25	−42.4 (4)
C31—Ir—P—C20	−74.96 (12)	C14—P—C20—C21	−110.0 (2)
C3—N1—C1—Ir	178.82 (19)	C14—P—C20—C25	70.0 (3)
C3—N1—C1—N2	1.7 (3)	P—C20—C21—C22	−179.4 (2)
C4—N1—C1—Ir	−1.4 (4)	C25—C20—C21—C22	0.6 (4)
C4—N1—C1—N2	−178.5 (2)	C20—C21—C22—C23	−0.7 (4)
C2—N2—C1—Ir	−178.4 (2)	C21—C22—C23—C24	0.7 (5)
C2—N2—C1—N1	−1.4 (3)	C22—C23—C24—C25	−0.6 (5)
C7—N2—C1—Ir	3.2 (4)	C23—C24—C25—C20	0.6 (5)
C7—N2—C1—N1	−179.8 (2)	P—C20—C25—C24	179.5 (2)
P—Ir—C1—N1	92.8 (2)	C21—C20—C25—C24	−0.5 (4)
P—Ir—C1—N2	−90.8 (2)	P—Ir—C26—C27	−178.43 (16)
C26—Ir—C1—N1	−111.9 (2)	P—Ir—C26—C33	−58.0 (3)
C26—Ir—C1—N2	64.6 (2)	C1—Ir—C26—C27	80.4 (2)
C27—Ir—C1—N1	−75.5 (2)	C1—Ir—C26—C33	−159.1 (2)
C27—Ir—C1—N2	100.9 (2)	C27—Ir—C26—C33	120.5 (3)
C30—Ir—C1—N1	−23.6 (4)	C30—Ir—C26—C27	−76.0 (2)
C30—Ir—C1—N2	152.8 (3)	C30—Ir—C26—C33	44.4 (2)
C31—Ir—C1—N1	−168.9 (3)	C31—Ir—C26—C27	−112.3 (2)
C31—Ir—C1—N2	7.5 (5)	C31—Ir—C26—C33	8.2 (2)
C1—N2—C2—C3	0.6 (3)	Ir—C26—C27—C28	99.3 (3)
C7—N2—C2—C3	178.9 (3)	C33—C26—C27—Ir	−106.1 (3)
N2—C2—C3—N1	0.4 (3)	C33—C26—C27—C28	−6.8 (4)
C1—N1—C3—C2	−1.4 (3)	P—Ir—C27—C26	176.7 (3)
C4—N1—C3—C2	178.9 (3)	P—Ir—C27—C28	52.7 (6)
C1—N1—C4—C5	−119.8 (3)	C1—Ir—C27—C26	−98.8 (2)
C1—N1—C4—C6	117.1 (3)	C1—Ir—C27—C28	137.2 (3)
C3—N1—C4—C5	59.9 (4)	C26—Ir—C27—C28	−124.0 (3)
C3—N1—C4—C6	−63.1 (4)	C30—Ir—C27—C26	99.9 (2)
Ir—P—C8—C9	−122.0 (3)	C30—Ir—C27—C28	−24.1 (2)
Ir—P—C8—C13	63.8 (4)	C31—Ir—C27—C26	66.2 (2)
C8'—P—C8—C9	167 (2)	C31—Ir—C27—C28	−57.8 (2)
C8'—P—C8—C13	−7.4 (17)	Ir—C27—C28—C29	39.1 (4)
C14—P—C8—C9	4.9 (4)	C26—C27—C28—C29	−40.7 (4)
C14—P—C8—C13	−169.3 (3)	C27—C28—C29—C30	−34.5 (4)
C20—P—C8—C9	111.1 (3)	C28—C29—C30—Ir	12.4 (4)
C20—P—C8—C13	−63.1 (3)	C28—C29—C30—C31	95.2 (4)
P—C8—C9—C10	−173.9 (5)	P—Ir—C30—C29	−161.7 (2)
C13—C8—C9—C10	0.0	P—Ir—C30—C31	78.60 (17)
C8—C9—C10—C11	0.0	C1—Ir—C30—C29	−46.1 (4)
C9—C10—C11—C12	0.0	C1—Ir—C30—C31	−165.8 (2)
C10—C11—C12—C13	0.0	C26—Ir—C30—C29	43.0 (3)
C11—C12—C13—C8	0.0	C26—Ir—C30—C31	−76.72 (18)
P—C8—C13—C12	174.6 (4)	C27—Ir—C30—C29	6.8 (3)
C9—C8—C13—C12	0.0	C27—Ir—C30—C31	−112.94 (19)
Ir—P—C8'—C9'	−125.3 (3)	C31—Ir—C30—C29	119.7 (3)
Ir—P—C8'—C13'	58.0 (4)	Ir—C30—C31—C32	101.7 (3)
C8—P—C8'—C9'	−9.4 (16)	C29—C30—C31—Ir	−105.7 (3)
C8—P—C8'—C13'	174 (2)	C29—C30—C31—C32	−4.0 (5)
C14—P—C8'—C9'	9.8 (5)	P—Ir—C31—C30	−103.54 (17)
C14—P—C8'—C13'	−166.9 (3)	P—Ir—C31—C32	134.9 (2)
C20—P—C8'—C9'	116.8 (4)	C1—Ir—C31—C30	157.7 (3)
C20—P—C8'—C13'	−60.0 (4)	C1—Ir—C31—C32	36.1 (5)
P—C8'—C9'—C10'	−176.8 (5)	C26—Ir—C31—C30	99.28 (18)
C13'—C8'—C9'—C10'	0.0	C26—Ir—C31—C32	−22.3 (2)
C8'—C9'—C10'—C11'	0.0	C27—Ir—C31—C30	65.46 (18)
C9'—C10'—C11'—C12'	0.0	C27—Ir—C31—C32	−56.1 (2)
C10'—C11'—C12'—C13'	0.0	C30—Ir—C31—C32	−121.6 (3)
C11'—C12'—C13'—C8'	0.0	Ir—C31—C32—C33	33.6 (3)
P—C8'—C13'—C12'	176.7 (5)	C30—C31—C32—C33	−47.0 (4)
C9'—C8'—C13'—C12'	0.0	C31—C32—C33—C26	−27.6 (4)
Ir—P—C14—C15	58.5 (3)	Ir—C26—C33—C32	7.8 (3)
Ir—P—C14—C19	−121.2 (2)	C27—C26—C33—C32	91.4 (3)
C8—P—C14—C15	−72.2 (4)