5-[(Benzo[d][1,3]dioxol-5-yl)meth­yl]-3-[4-(pyridin-2-yl)phen­yl]-4,5-di­hydro­isoxazole

El-Khatatneh, N.; Vinayaka, A.C.; Chandra; Sadashiva, M.P.; Jeyaseelan, S.; Mahendra, M.

doi:10.1107/S2414314617002784

5-[(Benzo[d][1,3]dioxol-5-yl)methyl]-3-[4-(pyridin-2-yl)phenyl]-4,5-dihydroisoxazole

N. El-Khatatneh, A. C. Vinayaka, Chandra, M. P. Sadashiva, S. Jeyaseelan and M. Mahendra

In the molecule of the title compound C₂₂H₁₈N₂O₃, the benzodioxole and dihydroisoxazole rings are bridged via a methylene (CH₂) group. The linkage is disordered over two positions with a occupancy factors of 0.887 (5) and 0.113 (5). The dihydroisoxazole and pyridine rings exhibit syn-clinal and anti-periplanar conformations with respect to the benzodioxole and benzene ring groups, as quantified by the torsion angle values of 70.7 (3) and 157.00 (17)°. Aside from van der Waals contacts, there are no significant intermolecular interactions.

Keywords: crystal structure; isoxazole derivatives; hydrogen bonds.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S2414314617002784/pk4012sup1.cif Contains datablocks I, global
	Structure factor file (CIF format) https://doi.org/10.1107/S2414314617002784/pk4012Isup2.hkl Contains datablock I

CCDC reference: 1533548

checkCIF report

Key indicators

Single-crystal X-ray study
T = 293 K
Mean (C-C) = 0.003 Å
Disorder in main residue
R factor = 0.044
wR factor = 0.127
Data-to-parameter ratio = 12.3

checkCIF/PLATON results

No syntax errors found



Alert level A
DIFF019_ALERT_1_A  _diffrn_standards_number is missing
            Number of standards used in measurement.

Author Response: Not sure why this is suddenly a problem - SHELXL2016/6 does not even write these things anymore. (This comment is from the co-editor.)

DIFF020_ALERT_1_A  _diffrn_standards_interval_count and
            _diffrn_standards_interval_time are missing. Number of measurements
            between standards or time (min) between standards.

Author Response: Not sure why this is suddenly a problem - SHELXL2016/6 does not even write these things anymore. (This comment is from the co-editor.)

DIFF022_ALERT_1_A  _diffrn_standards_decay_% is missing
            Percentage decrease in standards intensity.

Author Response: Not sure why this is suddenly a problem - SHELXL2016/6 does not even write these things anymore. (This comment is from the co-editor.)


Alert level C
PLAT241_ALERT_2_C High   'MainMol' Ueq as Compared to Neighbors of         O2 Check
PLAT241_ALERT_2_C High   'MainMol' Ueq as Compared to Neighbors of        C26 Check
PLAT242_ALERT_2_C Low    'MainMol' Ueq as Compared to Neighbors of        C22 Check
PLAT397_ALERT_2_C Deviating  C-O-C  Angle from 120 Deg for  O2          104.8 Degree
PLAT397_ALERT_2_C Deviating  C-O-C  Angle from 120 Deg for  O5          105.1 Degree
PLAT761_ALERT_1_C CIF Contains no X-H Bonds ......................     Please Check
PLAT762_ALERT_1_C CIF Contains no X-Y-H or H-Y-H Angles ..........     Please Check
PLAT911_ALERT_3_C Missing # FCF Refl Between THmin & STh/L=  0.600         13 Report
PLAT913_ALERT_3_C Missing # of Very Strong Reflections in FCF ....          6 Note

Alert level G
PLAT003_ALERT_2_G Number of Uiso or Uij Restrained non-H Atoms ...          4 Report
PLAT171_ALERT_4_G The CIF-Embedded .res File Contains EADP Records          3 Report
PLAT178_ALERT_4_G The CIF-Embedded .res File Contains SIMU Records          2 Report
PLAT187_ALERT_4_G The CIF-Embedded .res File Contains RIGU Records          2 Report
PLAT199_ALERT_1_G Reported _cell_measurement_temperature ..... (K)        293 Check
PLAT200_ALERT_1_G Reported   _diffrn_ambient_temperature ..... (K)        293 Check
PLAT301_ALERT_3_G Main Residue  Disorder ..............(Resd  1)..         19 % Note
PLAT395_ALERT_2_G Deviating  X-O-Y   Angle from 120 Deg for >O12         108.2 Degre
PLAT395_ALERT_2_G Deviating  X-O-Y   Angle from 120 Deg for <O12'        108.3 Degre
PLAT793_ALERT_4_G The Model has Chirality at C11     (Centro SPGR)          R Verify
PLAT860_ALERT_3_G Number of Least-Squares Restraints .............         60 Note
PLAT910_ALERT_3_G Missing # of FCF Reflection(s) Below Theta(Min)           1 Note
PLAT978_ALERT_2_G Number C-C Bonds with Positive Residual Density.          6 Note

   3 ALERT level A = Most likely a serious problem - resolve or explain
   0 ALERT level B = A potentially serious problem, consider carefully
   9 ALERT level C = Check. Ensure it is not caused by an omission or oversight
  13 ALERT level G = General information/check it is not something unexpected

   7 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   9 ALERT type 2 Indicator that the structure model may be wrong or deficient
   5 ALERT type 3 Indicator that the structure quality may be low
   4 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check


checkCIF publication errors

Alert level A
PUBL024_ALERT_1_A The number of authors is greater than 5.
              Please specify the role of each of the co-authors
              for your paper.

   1 ALERT level A = Data missing that is essential or data in wrong format
   0 ALERT level G = General alerts. Data that may be required is missing

Computing details top

Data collection: APEX2 (Bruker, 2009); cell refinement: SAINT (Bruker, 2009); data reduction: SAINT (Bruker, 2009); program(s) used to solve structure: SHELXS (Sheldrick, 2008); program(s) used to refine structure: SHELXL2016/6 (Sheldrick, 2015); molecular graphics: PLATON (Spek, 2009) and Mercury (Macrae et al., 2008); software used to prepare material for publication: SHELXL2016/6 (Sheldrick, 2015) and PLATON (Spek, 2009).

5-[(Benzo[d][1,3]dioxol-5-yl)methyl]-3-[4-(pyridin-2-yl)phenyl]-4,5-dihydroisoxazole top

Crystal data top

C₂₂H₁₈N₂O₃	F(000) = 752
M_r = 358.38	D_x = 1.340 Mg m⁻³
Monoclinic, P2₁/c	Mo Kα radiation, λ = 0.71073 Å
a = 17.548 (5) Å	Cell parameters from 3242 reflections
b = 8.719 (3) Å	θ = 2.5–25.4°
c = 12.237 (4) Å	µ = 0.09 mm⁻¹
β = 108.380 (9)°	T = 293 K
V = 1776.8 (9) Å³	Block, colourless
Z = 4	0.30 × 0.25 × 0.20 mm

Data collection top

Bruker MicroStar microfocus rotating anode diffractometer	R_int = 0.067
φ and ω scans	θ_max = 25.4°, θ_min = 2.5°
12236 measured reflections	h = −21→19
3242 independent reflections	k = −10→10
2353 reflections with I > 2σ(I)	l = −14→14

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.044	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.127	H-atom parameters constrained
S = 1.05	w = 1/[σ²(F_o²) + (0.0725P)²] where P = (F_o² + 2F_c²)/3
3242 reflections	(Δ/σ)_max < 0.001
263 parameters	Δρ_max = 0.15 e Å⁻³
60 restraints	Δρ_min = −0.16 e Å⁻³

Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
C1	0.47963 (13)	0.9248 (3)	0.34808 (19)	0.0910 (7)
H1A	0.476464	1.030174	0.321532	0.109*
H1B	0.532351	0.908313	0.403500	0.109*
O2	0.41886 (8)	0.89620 (18)	0.40031 (11)	0.0904 (5)
C3	0.36100 (10)	0.8108 (2)	0.31934 (14)	0.0573 (5)
C4	0.39006 (10)	0.7669 (2)	0.23254 (15)	0.0590 (5)
O5	0.46718 (7)	0.82244 (18)	0.25346 (12)	0.0840 (5)
C6	0.28619 (10)	0.7700 (2)	0.32070 (14)	0.0599 (5)
H6	0.267161	0.801304	0.379978	0.072*
C8	0.26959 (11)	0.6370 (2)	0.14350 (15)	0.0639 (5)
H8	0.237722	0.577815	0.083071	0.077*
C9	0.34576 (11)	0.6787 (2)	0.14300 (15)	0.0705 (6)
H9	0.365640	0.647985	0.084423	0.085*
C7	0.23922 (10)	0.67991 (18)	0.23030 (14)	0.0516 (4)	0.887 (5)
C10	0.15409 (14)	0.6325 (3)	0.2197 (2)	0.0547 (6)	0.887 (5)
H10A	0.117542	0.692128	0.158454	0.066*	0.887 (5)
H10B	0.147334	0.525643	0.196520	0.066*	0.887 (5)
C11	0.12945 (13)	0.6508 (2)	0.3270 (2)	0.0424 (6)	0.887 (5)
H11	0.170276	0.604578	0.392771	0.051*	0.887 (5)
O12	0.12162 (6)	0.81353 (11)	0.34924 (10)	0.0531 (3)	0.887 (5)
C15	0.04667 (9)	0.58461 (17)	0.31803 (14)	0.0499 (4)	0.887 (5)
H15A	0.013153	0.573540	0.238529	0.060*	0.887 (5)
H15B	0.051054	0.486500	0.356906	0.060*	0.887 (5)
C7'	0.23922 (10)	0.67991 (18)	0.23030 (14)	0.0516 (4)	0.113 (5)
C10'	0.1723 (11)	0.582 (2)	0.276 (2)	0.054 (3)	0.113 (5)
H10C	0.157134	0.487997	0.232027	0.065*	0.113 (5)
H10D	0.196003	0.554748	0.356613	0.065*	0.113 (5)
C11'	0.1014 (11)	0.6773 (18)	0.2615 (18)	0.047 (3)	0.113 (5)
H11'	0.074237	0.708414	0.181713	0.057*	0.113 (5)
O12'	0.12162 (6)	0.81353 (11)	0.34924 (10)	0.0531 (3)	0.113 (5)
C15'	0.04667 (9)	0.58461 (17)	0.31803 (14)	0.0499 (4)	0.113 (5)
H15C	0.003058	0.534073	0.260051	0.060*	0.113 (5)
H15D	0.077513	0.508525	0.371765	0.060*	0.113 (5)
N13	0.05736 (8)	0.83097 (14)	0.39460 (12)	0.0506 (4)
C14	0.01581 (9)	0.70717 (15)	0.37897 (12)	0.0398 (4)
C16	−0.05616 (8)	0.69760 (15)	0.41597 (12)	0.0393 (4)
C17	−0.07063 (9)	0.80733 (16)	0.49036 (13)	0.0455 (4)
H17	−0.033776	0.886052	0.517743	0.055*
C18	−0.13835 (9)	0.80089 (16)	0.52372 (13)	0.0473 (4)
H18	−0.146039	0.874131	0.574493	0.057*
C19	−0.19610 (9)	0.68566 (16)	0.48246 (12)	0.0426 (4)
C20	−0.18195 (9)	0.57667 (17)	0.40750 (12)	0.0465 (4)
H20	−0.219542	0.499587	0.378580	0.056*
C21	−0.11317 (9)	0.58109 (16)	0.37545 (12)	0.0447 (4)
H21	−0.104622	0.506083	0.326543	0.054*
C22	−0.26850 (10)	0.67674 (18)	0.52005 (14)	0.0498 (4)
C23	−0.27040 (12)	0.7388 (2)	0.62257 (17)	0.0738 (6)
H23	−0.225885	0.791438	0.669142	0.089*
C24	−0.33721 (13)	0.7237 (3)	0.6566 (2)	0.0890 (7)
H24	−0.338453	0.765019	0.726104	0.107*
C25	−0.40116 (14)	0.6478 (3)	0.5874 (2)	0.0954 (8)
H25	−0.447397	0.635161	0.608123	0.114*
C26	−0.39649 (14)	0.5894 (3)	0.4855 (2)	0.1125 (10)
H26	−0.440903	0.537175	0.438327	0.135*
N27	−0.33213 (10)	0.6029 (2)	0.44961 (15)	0.0849 (6)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
C1	0.0725 (13)	0.1224 (19)	0.0919 (15)	−0.0282 (13)	0.0456 (12)	−0.0187 (14)
O2	0.0684 (8)	0.1366 (13)	0.0756 (9)	−0.0439 (9)	0.0362 (7)	−0.0360 (9)
C3	0.0549 (10)	0.0713 (12)	0.0488 (10)	−0.0075 (9)	0.0207 (8)	−0.0040 (8)
C4	0.0497 (10)	0.0810 (12)	0.0518 (10)	0.0025 (9)	0.0240 (8)	0.0077 (9)
O5	0.0583 (8)	0.1301 (13)	0.0742 (9)	−0.0154 (8)	0.0360 (7)	−0.0085 (9)
C6	0.0603 (11)	0.0757 (12)	0.0526 (10)	−0.0100 (9)	0.0306 (8)	−0.0120 (9)
C8	0.0614 (11)	0.0793 (13)	0.0529 (10)	−0.0003 (9)	0.0208 (8)	−0.0142 (9)
C9	0.0661 (12)	0.1025 (16)	0.0512 (11)	0.0064 (11)	0.0302 (9)	−0.0079 (10)
C7	0.0536 (10)	0.0527 (10)	0.0513 (9)	−0.0013 (8)	0.0205 (8)	−0.0056 (8)
C10	0.0606 (14)	0.0617 (15)	0.0455 (14)	−0.0097 (11)	0.0218 (11)	−0.0101 (11)
C11	0.0484 (12)	0.0368 (9)	0.0434 (14)	−0.0023 (8)	0.0162 (10)	0.0014 (8)
O12	0.0586 (7)	0.0405 (6)	0.0691 (8)	−0.0076 (5)	0.0328 (6)	−0.0050 (5)
C15	0.0565 (10)	0.0413 (9)	0.0570 (10)	−0.0056 (7)	0.0253 (8)	−0.0051 (7)
C7'	0.0536 (10)	0.0527 (10)	0.0513 (9)	−0.0013 (8)	0.0205 (8)	−0.0056 (8)
C10'	0.059 (6)	0.050 (7)	0.053 (8)	−0.010 (5)	0.016 (6)	0.000 (6)
C11'	0.056 (6)	0.043 (6)	0.039 (7)	−0.016 (5)	0.011 (6)	−0.001 (5)
O12'	0.0586 (7)	0.0405 (6)	0.0691 (8)	−0.0076 (5)	0.0328 (6)	−0.0050 (5)
C15'	0.0565 (10)	0.0413 (9)	0.0570 (10)	−0.0056 (7)	0.0253 (8)	−0.0051 (7)
N13	0.0569 (8)	0.0387 (7)	0.0624 (9)	−0.0057 (6)	0.0277 (7)	−0.0041 (6)
C14	0.0465 (8)	0.0329 (8)	0.0381 (8)	0.0003 (7)	0.0104 (6)	0.0028 (6)
C16	0.0448 (9)	0.0329 (8)	0.0390 (8)	0.0012 (6)	0.0115 (6)	0.0028 (6)
C17	0.0516 (9)	0.0338 (8)	0.0511 (9)	−0.0049 (7)	0.0162 (7)	−0.0038 (7)
C18	0.0572 (10)	0.0365 (8)	0.0505 (9)	0.0013 (7)	0.0203 (8)	−0.0060 (7)
C19	0.0454 (9)	0.0402 (8)	0.0412 (8)	0.0008 (7)	0.0121 (7)	0.0031 (6)
C20	0.0506 (9)	0.0427 (9)	0.0454 (8)	−0.0109 (7)	0.0142 (7)	−0.0064 (7)
C21	0.0546 (9)	0.0372 (8)	0.0435 (8)	−0.0044 (7)	0.0173 (7)	−0.0079 (7)
C22	0.0502 (9)	0.0494 (9)	0.0510 (9)	−0.0015 (8)	0.0177 (8)	−0.0018 (7)
C23	0.0637 (12)	0.0994 (15)	0.0632 (12)	−0.0121 (10)	0.0270 (9)	−0.0261 (11)
C24	0.0831 (15)	0.1189 (19)	0.0782 (14)	−0.0061 (14)	0.0442 (12)	−0.0245 (13)
C25	0.0810 (15)	0.1163 (19)	0.1119 (19)	−0.0210 (14)	0.0634 (15)	−0.0224 (15)
C26	0.0797 (15)	0.151 (2)	0.128 (2)	−0.0545 (15)	0.0627 (15)	−0.0619 (18)
N27	0.0682 (11)	0.1091 (14)	0.0893 (12)	−0.0340 (10)	0.0419 (9)	−0.0387 (11)

Geometric parameters (Å, º) top

C1—O5	1.423 (2)	C11'—O12'	1.565 (15)
C1—O2	1.427 (2)	C11'—C15'	1.573 (15)
O2—C3	1.390 (2)	O12'—N13	1.4134 (15)
C3—C6	1.365 (2)	C15'—C14	1.499 (2)
C3—C4	1.370 (2)	N13—C14	1.2827 (18)
C4—C9	1.364 (3)	C14—C16	1.4723 (19)
C4—O5	1.383 (2)	C16—C17	1.398 (2)
C6—C7'	1.395 (2)	C16—C21	1.402 (2)
C6—C7	1.395 (2)	C17—C18	1.374 (2)
C8—C7'	1.382 (2)	C18—C19	1.403 (2)
C8—C7	1.382 (2)	C19—C20	1.396 (2)
C8—C9	1.387 (2)	C19—C22	1.483 (2)
C7—C10	1.516 (2)	C20—C21	1.382 (2)
C10—C11	1.514 (4)	C22—N27	1.341 (2)
C11—O12	1.459 (2)	C22—C23	1.376 (2)
C11—C15	1.535 (2)	C23—C24	1.369 (3)
O12—N13	1.4134 (15)	C24—C25	1.348 (3)
C15—C14	1.499 (2)	C25—C26	1.372 (3)
C7'—C10'	1.686 (18)	C26—N27	1.340 (2)
C10'—C11'	1.46 (3)

O5—C1—O2	108.04 (15)	O12'—C11'—C15'	97.2 (9)
C3—O2—C1	104.80 (13)	N13—O12'—C11'	108.3 (6)
C6—C3—C4	122.10 (17)	C14—C15'—C11'	102.6 (6)
C6—C3—O2	128.30 (15)	C14—N13—O12	109.71 (11)
C4—C3—O2	109.59 (15)	C14—N13—O12'	109.71 (11)
C9—C4—C3	121.55 (16)	N13—C14—C16	120.28 (12)
C9—C4—O5	128.53 (16)	N13—C14—C15'	113.37 (13)
C3—C4—O5	109.91 (17)	C16—C14—C15'	126.32 (12)
C4—O5—C1	105.10 (14)	N13—C14—C15	113.37 (13)
C3—C6—C7'	117.84 (15)	C16—C14—C15	126.32 (12)
C3—C6—C7	117.84 (15)	C17—C16—C21	118.06 (13)
C7'—C8—C9	122.56 (17)	C17—C16—C14	120.73 (12)
C7—C8—C9	122.56 (17)	C21—C16—C14	121.19 (13)
C4—C9—C8	116.77 (16)	C18—C17—C16	121.14 (13)
C8—C7—C6	119.18 (15)	C17—C18—C19	121.10 (14)
C8—C7—C10	117.97 (16)	C20—C19—C18	117.77 (14)
C6—C7—C10	122.78 (15)	C20—C19—C22	121.00 (13)
C11—C10—C7	116.1 (2)	C18—C19—C22	121.20 (13)
O12—C11—C10	109.52 (19)	C21—C20—C19	121.29 (13)
O12—C11—C15	103.67 (13)	C20—C21—C16	120.62 (13)
C10—C11—C15	114.90 (19)	N27—C22—C23	121.34 (16)
N13—O12—C11	108.16 (10)	N27—C22—C19	116.55 (14)
C14—C15—C11	100.29 (13)	C23—C22—C19	122.10 (15)
C8—C7'—C6	119.18 (15)	C24—C23—C22	120.60 (18)
C8—C7'—C10'	126.6 (6)	C25—C24—C23	118.6 (2)
C6—C7'—C10'	108.8 (7)	C24—C25—C26	118.5 (2)
C11'—C10'—C7'	109.0 (16)	N27—C26—C25	124.3 (2)
C10'—C11'—O12'	110.4 (16)	C26—N27—C22	116.64 (17)
C10'—C11'—C15'	105.5 (16)

O5—C1—O2—C3	−15.6 (2)	C10'—C11'—C15'—C14	139.5 (13)
C1—O2—C3—C6	−171.1 (2)	O12'—C11'—C15'—C14	25.9 (11)
C1—O2—C3—C4	9.9 (2)	C11—O12—N13—C14	−13.84 (18)
C6—C3—C4—C9	−0.6 (3)	C11'—O12'—N13—C14	19.5 (9)
O2—C3—C4—C9	178.55 (18)	O12—N13—C14—C16	−178.32 (11)
C6—C3—C4—O5	−179.39 (16)	O12'—N13—C14—C16	−178.32 (11)
O2—C3—C4—O5	−0.3 (2)	O12'—N13—C14—C15'	−0.43 (17)
C9—C4—O5—C1	171.8 (2)	O12—N13—C14—C15	−0.43 (17)
C3—C4—O5—C1	−9.4 (2)	C11'—C15'—C14—N13	−18.2 (9)
O2—C1—O5—C4	15.5 (2)	C11'—C15'—C14—C16	159.6 (8)
C4—C3—C6—C7'	0.5 (3)	C11—C15—C14—N13	13.34 (18)
O2—C3—C6—C7'	−178.47 (18)	C11—C15—C14—C16	−168.92 (15)
C4—C3—C6—C7	0.5 (3)	N13—C14—C16—C17	−14.3 (2)
O2—C3—C6—C7	−178.47 (18)	C15'—C14—C16—C17	168.09 (14)
C3—C4—C9—C8	0.7 (3)	C15—C14—C16—C17	168.09 (14)
O5—C4—C9—C8	179.26 (18)	N13—C14—C16—C21	163.95 (14)
C7'—C8—C9—C4	−0.7 (3)	C15'—C14—C16—C21	−13.6 (2)
C7—C8—C9—C4	−0.7 (3)	C15—C14—C16—C21	−13.6 (2)
C9—C8—C7—C6	0.7 (3)	C21—C16—C17—C18	0.5 (2)
C9—C8—C7—C10	177.9 (2)	C14—C16—C17—C18	178.82 (12)
C3—C6—C7—C8	−0.5 (3)	C16—C17—C18—C19	−1.3 (2)
C3—C6—C7—C10	−177.6 (2)	C17—C18—C19—C20	0.8 (2)
C8—C7—C10—C11	167.2 (2)	C17—C18—C19—C22	178.84 (13)
C6—C7—C10—C11	−15.8 (3)	C18—C19—C20—C21	0.4 (2)
C7—C10—C11—O12	70.7 (3)	C22—C19—C20—C21	−177.61 (13)
C7—C10—C11—C15	−173.16 (15)	C19—C20—C21—C16	−1.2 (2)
C10—C11—O12—N13	144.47 (18)	C17—C16—C21—C20	0.7 (2)
C15—C11—O12—N13	21.4 (2)	C14—C16—C21—C20	−177.59 (13)
O12—C11—C15—C14	−19.99 (19)	C20—C19—C22—N27	−25.0 (2)
C10—C11—C15—C14	−139.5 (2)	C18—C19—C22—N27	157.00 (17)
C9—C8—C7'—C6	0.7 (3)	C20—C19—C22—C23	154.08 (17)
C9—C8—C7'—C10'	−150.2 (10)	C18—C19—C22—C23	−23.9 (2)
C3—C6—C7'—C8	−0.5 (3)	N27—C22—C23—C24	1.4 (3)
C3—C6—C7'—C10'	155.2 (8)	C19—C22—C23—C24	−177.63 (18)
C8—C7'—C10'—C11'	−120.6 (13)	C22—C23—C24—C25	−0.4 (4)
C6—C7'—C10'—C11'	86.1 (16)	C23—C24—C25—C26	−0.3 (4)
C7'—C10'—C11'—O12'	−70 (2)	C24—C25—C26—N27	0.0 (4)
C7'—C10'—C11'—C15'	−174.2 (9)	C25—C26—N27—C22	1.0 (4)
C10'—C11'—O12'—N13	−137.7 (14)	C23—C22—N27—C26	−1.6 (3)
C15'—C11'—O12'—N13	−28.1 (12)	C19—C22—N27—C26	177.46 (18)

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5-[(Benzo[d][1,3]dioxol-5-yl)meth­yl]-3-[4-(pyridin-2-yl)phen­yl]-4,5-di­hydro­isoxazole

Supporting information

Key indicators

checkCIF/PLATON results

5-[(Benzo[d][1,3]dioxol-5-yl)methyl]-3-[4-(pyridin-2-yl)phenyl]-4,5-dihydroisoxazole