Bis­[bis­(di­phenyl­phosphino­methyl)­phenyl­phosphine]­di­chloro­tetra­gold(I) bis­[chloro­tris­(penta­fluoro­phenyl)­aurate(III)]

The cation of the title compound, [Au₄(PPh₂CH₂PPhCH₂PPh₂)₂Cl₂][Au(C₆F₅)₃Cl]₂ or [Au₄Cl₂(C₃₂H₂₉P₃)₂][AuCl(C₆F₅)₃]₂, displays a rhomboidal geometry for the Au atoms, with short Au...Au distances of 3.104 (2) and 3.185 (1) Å; the linear coordination at the Au^I atoms is distorted: P-Au-P 164.7 (2)° and P-Au-Cl 170.67 (11)°. The anion shows the expected square-planar geometry at Au^III, with the Au atom 0.022 (5) Å out of the plane of the four donor atoms.

Computing details

Data collection: DIF4 (Stoe & Cie, 1988); cell refinement: DIF4; data reduction: REDU4 (Stoe & Cie, 1988); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); software used to prepare material for publication: SHELXL97.

(I)

Crystal data

[Au4(C32H29P3)2Cl2][AuCl(C6F5)3]2	Z = 1
Mr = 3338.88	F(000) = 1560
Triclinic, P1	Dx = 2.207 Mg m^−3
a = 12.193 (6) Å	Mo Kα radiation, λ = 0.71073 Å
b = 14.439 (8) Å	Cell parameters from 52 reflections
c = 16.531 (9) Å	θ = 9–11.5°
α = 65.93 (2)°	µ = 9.03 mm^−1
β = 86.36 (3)°	T = 173 K
γ = 71.46 (3)°	Prism, colourless
V = 2512 (2) Å^3	0.34 × 0.30 × 0.23 mm

Data collection

Siemens–Stoe AED-2 diffractometer	6194 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	Rint = 0.060
Graphite monochromator	θmax = 25.0°, θmin = 3.1°
ω/θ scans	h = −14→4
Absorption correction: ψ scan (XEMP; Siemens, 1990)	k = −17→17
Tmin = 0.039, Tmax = 0.125	l = −19→19
12573 measured reflections	3 standard reflections every 60 min
8863 independent reflections	intensity decay: 4.5%

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.049	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.104	H-atom parameters constrained
S = 0.98	w = 1/[σ^2(Fo^2) + (0.0493P)^2] where P = (Fo^2 + 2Fc^2)/3
8863 reflections	(Δ/σ)max = 0.001
658 parameters	Δρmax = 2.44 e Å^−3
40 restraints	Δρmin = −1.92 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Au1	0.01597 (4)	0.53497 (4)	0.13997 (2)	0.02311 (12)
Au2	−0.15015 (4)	0.51505 (4)	0.01107 (3)	0.02507 (12)
Au3	0.25340 (4)	0.86948 (4)	0.39366 (3)	0.02417 (12)
P1	−0.1287 (2)	0.6986 (2)	0.09338 (16)	0.0206 (6)
P2	−0.2138 (2)	0.6919 (3)	−0.07028 (17)	0.0234 (7)
P3	0.1508 (3)	0.3723 (2)	0.22389 (17)	0.0246 (7)
Cl1	0.0671 (2)	0.9926 (3)	0.35046 (19)	0.0356 (7)
Cl2	−0.1161 (3)	0.3360 (3)	0.09273 (19)	0.0395 (8)
F1	0.1882 (7)	0.8070 (7)	0.5991 (4)	0.055 (2)
F2	0.2133 (7)	0.8831 (8)	0.7164 (4)	0.069 (3)
F3	0.3106 (7)	1.0410 (8)	0.6708 (5)	0.073 (3)
F4	0.3902 (8)	1.1159 (7)	0.5074 (5)	0.065 (3)
F5	0.3665 (7)	1.0388 (6)	0.3888 (4)	0.047 (2)
F6	0.3599 (6)	0.6419 (7)	0.5545 (4)	0.060 (2)
F7	0.5756 (6)	0.5058 (7)	0.5979 (5)	0.061 (2)
F8	0.7497 (6)	0.5548 (7)	0.4952 (5)	0.067 (3)
F9	0.7041 (6)	0.7395 (8)	0.3494 (5)	0.064 (2)
F10	0.4867 (6)	0.8785 (6)	0.3044 (4)	0.0449 (19)
F11	0.2678 (6)	0.9713 (6)	0.1821 (4)	0.0451 (19)
F12	0.2481 (7)	0.9038 (7)	0.0575 (4)	0.056 (2)
F13	0.1957 (7)	0.7217 (7)	0.0997 (5)	0.060 (2)
F14	0.1714 (7)	0.6010 (7)	0.2725 (6)	0.059 (2)
F15	0.2001 (6)	0.6635 (6)	0.3997 (4)	0.0450 (19)
C1	−0.1589 (10)	0.7694 (9)	−0.0269 (6)	0.025 (3)
H1A	−0.0872	0.7799	−0.0551	0.030*
H1B	−0.2174	0.8408	−0.0417	0.030*
C2	−0.1677 (9)	0.7309 (9)	−0.1835 (6)	0.022 (2)
H2A	−0.2258	0.7981	−0.2234	0.026*
H2B	−0.0929	0.7446	−0.1847	0.026*
C11	−0.2638 (9)	0.6876 (8)	0.1409 (6)	0.021 (2)
C12	−0.3612 (9)	0.7786 (10)	0.1180 (7)	0.034 (3)
H12	−0.3580	0.8456	0.0750	0.041*
C13	−0.4637 (10)	0.7705 (13)	0.1588 (8)	0.050 (4)
H13	−0.5306	0.8322	0.1431	0.060*
C14	−0.4682 (11)	0.6735 (10)	0.2216 (7)	0.046 (4)
H14	−0.5380	0.6689	0.2496	0.055*
C15	−0.3719 (11)	0.5829 (11)	0.2441 (7)	0.041 (3)
H15	−0.3757	0.5162	0.2875	0.049*
C16	−0.2689 (10)	0.5891 (11)	0.2032 (7)	0.040 (3)
H16	−0.2031	0.5266	0.2176	0.048*
C21	−0.1004 (8)	0.7912 (9)	0.1302 (6)	0.027 (3)
C22	−0.0871 (9)	0.8858 (10)	0.0724 (7)	0.036 (3)
H22	−0.0880	0.9033	0.0104	0.043*
C23	−0.0721 (10)	0.9573 (11)	0.1053 (9)	0.047 (4)
H23	−0.0636	1.0236	0.0653	0.056*
C24	−0.0696 (10)	0.9314 (12)	0.1948 (8)	0.052 (4)
H24	−0.0578	0.9791	0.2169	0.063*
C25	−0.0840 (13)	0.8377 (14)	0.2518 (9)	0.066 (5)
H25	−0.0845	0.8211	0.3137	0.080*
C26	−0.0979 (10)	0.7655 (12)	0.2204 (7)	0.043 (4)
H26	−0.1057	0.6991	0.2609	0.052*
C31	−0.3705 (10)	0.7486 (8)	−0.0815 (6)	0.026 (3)
C32	−0.4241 (10)	0.8563 (10)	−0.1314 (6)	0.036 (3)
H32	−0.3785	0.9015	−0.1600	0.043*
C33	−0.5441 (10)	0.8991 (11)	−0.1400 (7)	0.046 (4)
H33	−0.5809	0.9735	−0.1739	0.055*
C34	−0.6087 (11)	0.8336 (10)	−0.0995 (8)	0.051 (4)
H34	−0.6909	0.8629	−0.1061	0.061*
C35	−0.5575 (11)	0.7257 (12)	−0.0492 (8)	0.048 (4)
H35	−0.6040	0.6812	−0.0217	0.057*
C36	−0.4365 (10)	0.6823 (11)	−0.0390 (8)	0.041 (3)
H36	−0.4000	0.6084	−0.0034	0.049*
C51	0.1060 (10)	0.3188 (8)	0.3349 (6)	0.029 (3)
C52	0.0826 (14)	0.3824 (12)	0.3817 (8)	0.091 (7)
H52	0.0949	0.4500	0.3576	0.110*
C53	0.0407 (17)	0.3451 (15)	0.4650 (9)	0.113 (9)
H53	0.0256	0.3875	0.4984	0.136*
C54	0.0209 (15)	0.2505 (11)	0.4994 (8)	0.066 (5)
H54	−0.0105	0.2283	0.5556	0.079*
C55	0.0451 (10)	0.1859 (11)	0.4549 (7)	0.040 (3)
H55	0.0345	0.1176	0.4806	0.048*
C56	0.0853 (9)	0.2218 (9)	0.3720 (6)	0.027 (3)
H56	0.0993	0.1787	0.3393	0.032*
C61	0.2948 (9)	0.3764 (8)	0.2336 (7)	0.030 (3)
C62	0.3756 (10)	0.2916 (10)	0.2976 (9)	0.057 (4)
H62	0.3540	0.2332	0.3395	0.068*
C63	0.4873 (13)	0.2922 (14)	0.3004 (12)	0.089 (7)
H63	0.5421	0.2337	0.3451	0.107*
C64	0.5225 (14)	0.3734 (13)	0.2416 (11)	0.085 (7)
H64	0.6010	0.3712	0.2435	0.102*
C65	0.4420 (12)	0.4579 (13)	0.1797 (10)	0.057 (4)
H65	0.4643	0.5167	0.1392	0.069*
C66	0.3286 (10)	0.4605 (11)	0.1745 (7)	0.042 (4)
H66	0.2739	0.5200	0.1302	0.050*
C71	0.2737 (9)	0.9219 (11)	0.4894 (7)	0.032 (3)
C72	0.2375 (11)	0.8837 (11)	0.5743 (7)	0.038 (3)
C73	0.2475 (10)	0.9231 (12)	0.6356 (7)	0.044 (4)
C74	0.3006 (11)	0.9998 (13)	0.6116 (9)	0.049 (4)
C75	0.3394 (11)	1.0391 (13)	0.5306 (9)	0.050 (4)
C76	0.3276 (11)	0.9982 (10)	0.4704 (7)	0.033 (3)
C81	0.4158 (9)	0.7653 (9)	0.4284 (7)	0.024 (3)
C82	0.4456 (10)	0.6677 (11)	0.5010 (7)	0.035 (3)
C83	0.5545 (11)	0.5988 (11)	0.5267 (8)	0.042 (3)
C84	0.6413 (11)	0.6226 (12)	0.4737 (9)	0.045 (4)
C85	0.6165 (11)	0.7156 (12)	0.4003 (8)	0.042 (3)
C86	0.5059 (11)	0.7872 (10)	0.3789 (7)	0.030 (3)
C91	0.2382 (9)	0.8167 (10)	0.2974 (7)	0.028 (3)
C92	0.2448 (9)	0.8774 (10)	0.2082 (7)	0.027 (3)
C93	0.2347 (10)	0.8433 (11)	0.1422 (7)	0.034 (3)
C94	0.2117 (10)	0.7511 (11)	0.1650 (8)	0.036 (3)
C95	0.1985 (10)	0.6904 (11)	0.2509 (9)	0.038 (3)
C96	0.2139 (10)	0.7255 (10)	0.3149 (8)	0.030 (3)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Au1	0.0228 (2)	0.0221 (3)	0.0202 (2)	−0.0030 (2)	−0.00062 (17)	−0.00736 (19)
Au2	0.0297 (3)	0.0230 (3)	0.0211 (2)	−0.0098 (2)	0.00228 (18)	−0.00672 (19)
Au3	0.0255 (2)	0.0218 (3)	0.0251 (2)	−0.0055 (2)	−0.00009 (18)	−0.0109 (2)
P1	0.0208 (15)	0.0228 (18)	0.0178 (12)	−0.0065 (13)	0.0032 (11)	−0.0085 (12)
P2	0.0246 (15)	0.0256 (19)	0.0205 (13)	−0.0084 (14)	0.0023 (12)	−0.0097 (13)
P3	0.0303 (17)	0.0194 (18)	0.0212 (13)	−0.0035 (14)	−0.0044 (12)	−0.0080 (13)
Cl1	0.0286 (16)	0.035 (2)	0.0449 (16)	0.0017 (14)	−0.0045 (13)	−0.0255 (15)
Cl2	0.0371 (17)	0.0253 (19)	0.0451 (16)	−0.0115 (15)	0.0031 (14)	−0.0028 (14)
F1	0.054 (5)	0.071 (7)	0.041 (4)	−0.028 (5)	0.007 (4)	−0.019 (4)
F2	0.059 (5)	0.110 (9)	0.034 (4)	−0.012 (5)	0.007 (4)	−0.037 (5)
F3	0.076 (6)	0.085 (7)	0.068 (5)	0.010 (5)	−0.022 (5)	−0.065 (5)
F4	0.079 (6)	0.060 (7)	0.077 (5)	−0.026 (5)	−0.013 (5)	−0.042 (5)
F5	0.066 (5)	0.041 (5)	0.042 (4)	−0.023 (4)	0.007 (4)	−0.021 (4)
F6	0.041 (5)	0.059 (6)	0.043 (4)	−0.012 (4)	0.012 (4)	0.009 (4)
F7	0.049 (5)	0.041 (6)	0.052 (4)	0.000 (4)	−0.001 (4)	0.010 (4)
F8	0.026 (4)	0.051 (6)	0.090 (6)	0.013 (4)	−0.002 (4)	−0.014 (5)
F9	0.034 (4)	0.072 (7)	0.075 (5)	−0.016 (5)	0.017 (4)	−0.023 (5)
F10	0.043 (4)	0.041 (5)	0.045 (4)	−0.014 (4)	0.012 (3)	−0.013 (4)
F11	0.064 (5)	0.030 (5)	0.035 (4)	−0.023 (4)	−0.005 (3)	0.001 (3)
F12	0.066 (5)	0.055 (6)	0.028 (3)	−0.001 (5)	−0.004 (4)	−0.013 (4)
F13	0.051 (5)	0.079 (7)	0.068 (5)	−0.003 (5)	−0.009 (4)	−0.061 (5)
F14	0.069 (6)	0.034 (5)	0.103 (6)	−0.026 (5)	0.022 (5)	−0.051 (5)
F15	0.059 (5)	0.032 (5)	0.045 (4)	−0.021 (4)	0.029 (4)	−0.016 (4)
C1	0.033 (6)	0.027 (7)	0.012 (5)	−0.009 (6)	0.002 (4)	−0.006 (5)
C2	0.028 (6)	0.025 (7)	0.015 (5)	−0.012 (5)	0.006 (4)	−0.009 (5)
C11	0.024 (6)	0.021 (7)	0.020 (5)	−0.010 (5)	0.006 (4)	−0.009 (5)
C12	0.025 (6)	0.038 (9)	0.032 (6)	−0.005 (6)	0.000 (5)	−0.011 (6)
C13	0.031 (8)	0.075 (13)	0.055 (8)	−0.011 (8)	0.011 (6)	−0.043 (9)
C14	0.034 (8)	0.072 (12)	0.046 (7)	−0.024 (8)	0.023 (6)	−0.036 (8)
C15	0.048 (8)	0.041 (9)	0.040 (7)	−0.028 (8)	0.017 (6)	−0.014 (7)
C16	0.045 (8)	0.038 (9)	0.039 (7)	−0.019 (7)	0.014 (6)	−0.014 (6)
C21	0.016 (6)	0.037 (8)	0.034 (6)	−0.013 (6)	0.002 (5)	−0.019 (6)
C22	0.047 (8)	0.036 (9)	0.037 (6)	−0.017 (7)	−0.002 (6)	−0.022 (6)
C23	0.039 (8)	0.033 (9)	0.070 (9)	−0.006 (7)	−0.012 (7)	−0.025 (8)
C24	0.026 (7)	0.077 (13)	0.077 (10)	−0.003 (8)	0.005 (7)	−0.064 (10)
C25	0.065 (11)	0.109 (17)	0.049 (8)	−0.026 (11)	−0.001 (8)	−0.055 (11)
C26	0.034 (7)	0.075 (12)	0.030 (6)	−0.025 (8)	0.012 (5)	−0.025 (7)
C31	0.028 (6)	0.024 (7)	0.028 (5)	−0.009 (6)	0.006 (5)	−0.013 (5)
C32	0.038 (7)	0.031 (8)	0.029 (6)	−0.009 (6)	0.009 (5)	−0.004 (6)
C33	0.029 (7)	0.039 (10)	0.044 (7)	0.012 (7)	−0.011 (6)	−0.008 (7)
C34	0.024 (7)	0.071 (13)	0.049 (8)	0.006 (8)	−0.005 (6)	−0.031 (8)
C35	0.043 (8)	0.053 (11)	0.047 (7)	−0.021 (8)	0.008 (7)	−0.017 (8)
C36	0.037 (8)	0.038 (9)	0.043 (7)	−0.013 (7)	0.008 (6)	−0.013 (6)
C51	0.039 (7)	0.029 (8)	0.017 (5)	−0.010 (6)	−0.004 (5)	−0.009 (5)
C52	0.21 (2)	0.055 (12)	0.033 (7)	−0.066 (14)	0.046 (10)	−0.029 (8)
C53	0.23 (3)	0.088 (18)	0.054 (10)	−0.069 (18)	0.050 (13)	−0.054 (11)
C54	0.110 (14)	0.041 (11)	0.030 (7)	−0.019 (10)	0.024 (8)	−0.007 (7)
C55	0.035 (7)	0.034 (9)	0.035 (6)	−0.004 (7)	0.004 (6)	−0.006 (6)
C56	0.031 (6)	0.016 (7)	0.032 (6)	−0.009 (6)	0.008 (5)	−0.008 (5)
C61	0.025 (6)	0.030 (8)	0.045 (7)	−0.016 (6)	0.001 (5)	−0.021 (6)
C62	0.045 (9)	0.020 (8)	0.091 (10)	−0.002 (7)	−0.044 (8)	−0.008 (8)
C63	0.063 (12)	0.041 (12)	0.147 (18)	0.020 (10)	−0.068 (12)	−0.040 (13)
C64	0.030 (9)	0.086 (17)	0.159 (19)	0.008 (10)	−0.019 (11)	−0.084 (16)
C65	0.055 (10)	0.067 (13)	0.088 (11)	−0.043 (10)	0.025 (9)	−0.053 (10)
C66	0.043 (8)	0.052 (10)	0.037 (7)	−0.016 (7)	−0.008 (6)	−0.023 (7)
C71	0.020 (6)	0.042 (9)	0.032 (6)	0.004 (6)	−0.010 (5)	−0.022 (6)
C72	0.037 (8)	0.035 (9)	0.031 (6)	0.003 (7)	−0.007 (6)	−0.014 (6)
C73	0.022 (7)	0.062 (11)	0.030 (6)	0.009 (7)	−0.008 (5)	−0.018 (7)
C74	0.036 (8)	0.078 (12)	0.048 (8)	−0.006 (8)	−0.008 (6)	−0.049 (9)
C75	0.036 (8)	0.057 (11)	0.058 (9)	−0.004 (8)	−0.010 (7)	−0.032 (8)
C76	0.041 (7)	0.021 (7)	0.037 (6)	−0.003 (6)	−0.005 (6)	−0.016 (6)
C81	0.025 (6)	0.014 (7)	0.034 (6)	−0.006 (5)	0.003 (5)	−0.011 (5)
C82	0.033 (7)	0.038 (9)	0.034 (6)	−0.022 (7)	0.002 (6)	−0.008 (6)
C83	0.043 (8)	0.023 (8)	0.039 (7)	−0.004 (7)	−0.007 (6)	0.003 (6)
C84	0.031 (8)	0.050 (10)	0.051 (8)	−0.006 (7)	−0.004 (6)	−0.022 (8)
C85	0.035 (8)	0.051 (10)	0.047 (7)	−0.017 (7)	0.017 (6)	−0.024 (7)
C86	0.042 (8)	0.019 (7)	0.029 (6)	−0.011 (6)	−0.002 (5)	−0.008 (5)
C91	0.023 (6)	0.028 (8)	0.028 (6)	−0.007 (6)	0.000 (5)	−0.009 (5)
C92	0.018 (6)	0.022 (7)	0.037 (6)	−0.004 (5)	0.005 (5)	−0.010 (6)
C93	0.034 (7)	0.033 (8)	0.034 (6)	0.000 (6)	−0.002 (5)	−0.020 (6)
C94	0.033 (7)	0.042 (9)	0.046 (7)	−0.007 (7)	0.003 (6)	−0.035 (7)
C95	0.019 (6)	0.040 (9)	0.067 (8)	−0.009 (6)	0.011 (6)	−0.036 (8)
C96	0.026 (7)	0.018 (7)	0.048 (7)	−0.009 (6)	0.012 (5)	−0.018 (6)

Geometric parameters (Å, º)

Au1—P3	2.307 (3)	C24—C25	1.356 (15)
Au1—P1	2.307 (3)	C24—H24	0.9500
Au1—Au2^i	3.1037 (15)	C25—C26	1.397 (15)
Au1—Au2	3.1850 (14)	C25—H25	0.9500
Au2—P2	2.237 (3)	C26—H26	0.9500
Au2—Cl2	2.285 (3)	C31—C32	1.379 (13)
Au2—Au1^i	3.1037 (15)	C31—C36	1.389 (13)
Au3—C81	2.014 (11)	C32—C33	1.387 (14)
Au3—C91	2.065 (10)	C32—H32	0.9500
Au3—C71	2.071 (10)	C33—C34	1.362 (14)
Au3—Cl1	2.330 (3)	C33—H33	0.9500
P1—C11	1.805 (10)	C34—C35	1.378 (14)
P1—C21	1.806 (11)	C34—H34	0.9500
P1—C1	1.825 (9)	C35—C36	1.398 (14)
P2—C31	1.812 (11)	C35—H35	0.9500
P2—C2	1.828 (9)	C36—H36	0.9500
P2—C1	1.845 (10)	C51—C52	1.381 (13)
P3—C61	1.795 (11)	C51—C56	1.381 (12)
P3—C51	1.803 (10)	C52—C53	1.387 (15)
P3—C2^i	1.818 (10)	C52—H52	0.9500
F1—C72	1.334 (15)	C53—C54	1.345 (16)
F2—C73	1.321 (14)	C53—H53	0.9500
F3—C74	1.365 (13)	C54—C55	1.362 (14)
F4—C75	1.349 (16)	C54—H54	0.9500
F5—C76	1.356 (13)	C55—C56	1.372 (13)
F6—C82	1.369 (13)	C55—H55	0.9500
F7—C83	1.337 (14)	C56—H56	0.9500
F8—C84	1.336 (15)	C61—C66	1.378 (13)
F9—C85	1.360 (14)	C61—C62	1.378 (13)
F10—C86	1.350 (13)	C62—C63	1.368 (16)
F11—C92	1.360 (13)	C62—H62	0.9500
F12—C93	1.346 (13)	C63—C64	1.357 (17)
F13—C94	1.355 (12)	C63—H63	0.9500
F14—C95	1.336 (14)	C64—C65	1.359 (16)
F15—C96	1.355 (13)	C64—H64	0.9500
C1—H1A	0.9900	C65—C66	1.379 (15)
C1—H1B	0.9900	C65—H65	0.9500
C2—P3^i	1.818 (10)	C66—H66	0.9500
C2—H2A	0.9900	C71—C76	1.376 (17)
C2—H2B	0.9900	C71—C72	1.382 (16)
C11—C16	1.393 (13)	C72—C73	1.376 (17)
C11—C12	1.393 (12)	C73—C74	1.37 (2)
C12—C13	1.397 (13)	C74—C75	1.345 (19)
C12—H12	0.9500	C75—C76	1.382 (16)
C13—C14	1.378 (14)	C81—C86	1.368 (15)
C13—H13	0.9500	C81—C82	1.382 (16)
C14—C15	1.383 (14)	C82—C83	1.349 (17)
C14—H14	0.9500	C83—C84	1.369 (18)
C15—C16	1.400 (13)	C84—C85	1.351 (19)
C15—H15	0.9500	C85—C86	1.374 (17)
C16—H16	0.9500	C91—C96	1.354 (16)
C21—C22	1.364 (13)	C91—C92	1.388 (14)
C21—C26	1.382 (11)	C92—C93	1.393 (15)
C22—C23	1.409 (14)	C93—C94	1.345 (17)
C22—H22	0.9500	C94—C95	1.362 (17)
C23—C24	1.370 (14)	C95—F14	1.336 (14)
C23—H23	0.9500	C95—C96	1.392 (15)
P3—Au1—P1	164.40 (9)	C34—C35—H35	120.3
P3—Au1—Au2^i	80.43 (8)	C36—C35—H35	120.3
P1—Au1—Au2^i	114.89 (7)	C31—C36—C35	119.1 (12)
P3—Au1—Au2	112.15 (8)	C31—C36—H36	120.4
P1—Au1—Au2	77.84 (8)	C35—C36—H36	120.4
Au2^i—Au1—Au2	68.96 (4)	C52—C51—C56	118.9 (11)
P2—Au2—Cl2	170.67 (11)	C52—C51—P3	117.8 (8)
P2—Au2—Au1^i	93.89 (8)	C56—C51—P3	123.0 (7)
Cl2—Au2—Au1^i	89.63 (9)	C51—C52—C53	118.4 (13)
P2—Au2—Au1	92.77 (8)	C51—C52—H52	120.8
Cl2—Au2—Au1	94.03 (9)	C53—C52—H52	120.8
Au1^i—Au2—Au1	111.04 (4)	C54—C53—C52	121.4 (13)
C81—Au3—C91	89.1 (4)	C54—C53—H53	119.3
C81—Au3—C71	89.6 (4)	C52—C53—H53	119.3
C91—Au3—C71	178.3 (4)	C53—C54—C55	121.0 (13)
C81—Au3—Cl1	178.6 (3)	C53—C54—H54	119.5
C91—Au3—Cl1	90.6 (3)	C55—C54—H54	119.5
C71—Au3—Cl1	90.8 (3)	C54—C55—C56	118.4 (12)
C11—P1—C21	102.0 (4)	C54—C55—H55	120.8
C11—P1—C1	107.5 (5)	C56—C55—H55	120.8
C21—P1—C1	105.9 (5)	C55—C56—C51	121.7 (10)
C11—P1—Au1	112.2 (3)	C55—C56—H56	119.1
C21—P1—Au1	113.7 (3)	C51—C56—H56	119.1
C1—P1—Au1	114.6 (4)	C66—C61—C62	118.8 (11)
C31—P2—C2	106.0 (5)	C66—C61—P3	121.0 (8)
C31—P2—C1	106.3 (5)	C62—C61—P3	120.0 (9)
C2—P2—C1	103.0 (5)	C63—C62—C61	119.5 (13)
C31—P2—Au2	113.2 (3)	C63—C62—H62	120.3
C2—P2—Au2	113.3 (4)	C61—C62—H62	120.3
C1—P2—Au2	114.1 (3)	C64—C63—C62	122.4 (14)
C61—P3—C51	107.3 (5)	C64—C63—H63	118.8
C61—P3—C2^i	105.1 (5)	C62—C63—H63	118.8
C51—P3—C2^i	104.8 (5)	C63—C64—C65	117.9 (15)
C61—P3—Au1	114.9 (4)	C63—C64—H64	121.0
C51—P3—Au1	109.9 (4)	C65—C64—H64	121.0
C2^i—P3—Au1	114.2 (3)	C64—C65—C66	121.5 (14)
F14—F14—C95	0 (10)	C64—C65—H65	119.2
P1—C1—P2	110.0 (6)	C66—C65—H65	119.2
P1—C1—H1A	109.7	C65—C66—C61	119.8 (12)
P2—C1—H1A	109.7	C65—C66—H66	120.1
P1—C1—H1B	109.7	C61—C66—H66	120.1
P2—C1—H1B	109.7	C76—C71—C72	116.2 (10)
H1A—C1—H1B	108.2	C76—C71—Au3	119.9 (8)
P3^i—C2—P2	111.8 (6)	C72—C71—Au3	123.9 (10)
P3^i—C2—H2A	109.3	F1—C72—C73	117.1 (11)
P2—C2—H2A	109.3	F1—C72—C71	120.0 (11)
P3^i—C2—H2B	109.3	C73—C72—C71	122.9 (13)
P2—C2—H2B	109.3	F2—C73—C74	121.5 (12)
H2A—C2—H2B	107.9	F2—C73—C72	120.8 (14)
C16—C11—C12	120.3 (11)	C74—C73—C72	117.5 (12)
C16—C11—P1	119.9 (8)	C75—C74—F3	118.7 (14)
C12—C11—P1	119.8 (8)	C75—C74—C73	122.5 (12)
C11—C12—C13	119.4 (11)	F3—C74—C73	118.8 (12)
C11—C12—H12	120.3	C74—C75—F4	121.8 (12)
C13—C12—H12	120.3	C74—C75—C76	118.5 (14)
C14—C13—C12	120.4 (12)	F4—C75—C76	119.7 (13)
C14—C13—H13	119.8	F5—C76—C71	119.6 (9)
C12—C13—H13	119.8	F5—C76—C75	118.0 (12)
C13—C14—C15	120.4 (12)	C71—C76—C75	122.3 (12)
C13—C14—H14	119.8	C86—C81—C82	114.8 (11)
C15—C14—H14	119.8	C86—C81—Au3	121.0 (9)
C14—C15—C16	120.1 (12)	C82—C81—Au3	124.2 (8)
C14—C15—H15	120.0	C83—C82—F6	117.2 (11)
C16—C15—H15	120.0	C83—C82—C81	124.8 (11)
C11—C16—C15	119.4 (12)	F6—C82—C81	117.8 (11)
C11—C16—H16	120.3	F7—C83—C82	120.9 (12)
C15—C16—H16	120.3	F7—C83—C84	120.7 (12)
C22—C21—C26	120.0 (11)	C82—C83—C84	118.2 (12)
C22—C21—P1	122.4 (7)	F8—C84—C85	120.6 (12)
C26—C21—P1	117.4 (9)	F8—C84—C83	120.0 (13)
C21—C22—C23	119.5 (10)	C85—C84—C83	119.4 (13)
C21—C22—H22	120.2	C84—C85—F9	118.8 (12)
C23—C22—H22	120.2	C84—C85—C86	121.0 (12)
C24—C23—C22	120.2 (12)	F9—C85—C86	120.2 (12)
C24—C23—H23	119.9	F10—C86—C81	120.2 (11)
C22—C23—H23	119.9	F10—C86—C85	118.1 (11)
C25—C24—C23	120.0 (13)	C81—C86—C85	121.6 (11)
C25—C24—H24	120.0	C96—C91—C92	115.1 (10)
C23—C24—H24	120.0	C96—C91—Au3	123.4 (8)
C24—C25—C26	120.5 (12)	C92—C91—Au3	121.4 (9)
C24—C25—H25	119.7	F11—C92—C91	120.6 (10)
C26—C25—H25	119.7	F11—C92—C93	117.0 (10)
C21—C26—C25	119.7 (12)	C91—C92—C93	122.3 (12)
C21—C26—H26	120.2	C94—C93—F12	122.0 (10)
C25—C26—H26	120.2	C94—C93—C92	119.0 (11)
C32—C31—C36	120.2 (12)	F12—C93—C92	119.0 (12)
C32—C31—P2	120.6 (8)	C93—C94—F13	118.5 (11)
C36—C31—P2	119.2 (8)	C93—C94—C95	121.5 (11)
C31—C32—C33	120.4 (11)	F13—C94—C95	119.9 (12)
C31—C32—H32	119.8	F14—C95—F14	0.0 (11)
C33—C32—H32	119.8	F14—C95—C94	121.1 (11)
C34—C33—C32	119.4 (12)	F14—C95—C94	121.1 (11)
C34—C33—H33	120.3	F14—C95—C96	121.5 (12)
C32—C33—H33	120.3	F14—C95—C96	121.5 (12)
C33—C34—C35	121.5 (13)	C94—C95—C96	117.4 (12)
C33—C34—H34	119.2	C91—C96—F15	119.5 (10)
C35—C34—H34	119.2	C91—C96—C95	124.5 (11)
C34—C35—C36	119.5 (12)	F15—C96—C95	116.0 (11)

Symmetry code: (i) −x, −y+1, −z.

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
C32—H32···F11^ii	0.95	2.51	3.412 (14)	159
C52—H52···F14	0.95	2.50	3.417 (17)	163

Symmetry code: (ii) −x, −y+2, −z.