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The title complex, [CoCl2(C24H16N6)].2C3H7NO, has been prepared from cobalt chloride and 6,6'-dibenzimidazolyl-2,2'-bipyridine (DBBP). The metal center is coordinated in a distorted tetrahedral configuration to two Cl- ions and to two N donor atoms of the DBBP ligand which acts bidentately. The Co-N distances are 2.033 (4) Å and the Co-Cl distances are 2.2300 (18) Å. The coordination angles lie between 102.61 (13) and 118.13 (18)°. The complex has C2 symmetry.

Supporting information

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Crystallographic Information File (CIF)
Contains datablocks text, ta1062a

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Supplementary material

CCDC reference: 129043

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