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The title compound, tetrakis(tetramethylammonium) bis(lithium tetrahydrate) decavanadate tetrahydrate, (C4H12N)4[Li(H2O)4]2[V10O28].4H2O, was synthesized and found to crystallize in the triclinic system (space group P\overline{1}). The centrosymmetric [V10O28]6- polyanions form layers in the ac plane by hydrogen bonding with tetrahedral [Li(H2O)4]+ cations and water molecules of crystallization. The tetramethylammonium cations fill space between the layers.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, litmadec

hkl

Structure factor file (CIF format)
Contains datablock litmadec

CCDC reference: 128466

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