Di-μ3-chlorido-tetra-μ2-chlorido-di­chloridotetra­kis­(N,N-di­ethyl­ethane-1,2-di­amine-κ2N,N′)tetra­cadmium(II)

Al-Sudani, A.-R.H.; Abdulridha, M.Q.; Kariuki, B.M.

doi:10.1107/S2414314619016183

Di-μ₃-chlorido-tetra-μ₂-chlorido-dichloridotetrakis(N,N-diethylethane-1,2-diamine-κ²N,N′)tetracadmium(II)

A.-R. H. Al-Sudani, M. Q. Abdulridha and B. M. Kariuki

In the title compound, [Cd₄Cl₈(C₆H₁₆N₂)₄], the Cd²⁺ cations and Cl⁻ anions form M₄Cl₈ clusters with six of the Cl⁻ ions bridging Cd²⁺ cations and two being pendant. Each Cd²⁺ cation has distorted octahedral coordination completed by four Cl⁻ ions and two N atoms of the asymmetrical bidentate amino ligand. The cluster consists of pairs of face-sharing hexahedra linked by a shared edge.

Keywords: crystal structure; metal cluster; N-H

Cl contact; cadmium.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S2414314619016183/vm4043sup1.cif Contains datablock I
	Structure factor file (CIF format) https://doi.org/10.1107/S2414314619016183/vm4043Isup2.hkl Contains datablock I

CCDC reference: 1969371

checkCIF report

Key indicators

Single-crystal X-ray study
T = 293 K
Mean (C-C) = 0.011 Å
Disorder in main residue
R factor = 0.050
wR factor = 0.131
Data-to-parameter ratio = 20.7

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT342_ALERT_3_C Low Bond Precision on  C-C Bonds ...............      0.011 Ang.
PLAT420_ALERT_2_C D-H Without Acceptor       N4       --H4C      .     Please Check
PLAT911_ALERT_3_C Missing FCF Refl Between Thmin & STh/L=    0.600          6 Report
PLAT975_ALERT_2_C Check Calcd Resid. Dens.  0.93A   From N2              0.82 eA-3
PLAT975_ALERT_2_C Check Calcd Resid. Dens.  0.93A   From N2              0.64 eA-3
PLAT977_ALERT_2_C Check Negative Difference Density on H4B              -0.37 eA-3
PLAT977_ALERT_2_C Check Negative Difference Density on H11B             -0.34 eA-3
PLAT977_ALERT_2_C Check Negative Difference Density on H11C             -0.44 eA-3

Alert level G
PLAT002_ALERT_2_G Number of Distance or Angle Restraints on AtSite         21 Note
PLAT003_ALERT_2_G Number of Uiso or Uij Restrained non-H Atoms ...         21 Report
PLAT007_ALERT_5_G Number of Unrefined Donor-H Atoms ..............          4 Report
PLAT042_ALERT_1_G Calc. and Reported MoietyFormula Strings  Differ     Please Check
PLAT045_ALERT_1_G Calculated and Reported Z Differ by a Factor ...       0.50 Check
PLAT083_ALERT_2_G SHELXL Second Parameter in WGHT  Unusually Large       6.22 Why ?
PLAT171_ALERT_4_G The CIF-Embedded .res File Contains EADP Records          2 Report
PLAT175_ALERT_4_G The CIF-Embedded .res File Contains SAME Records          2 Report
PLAT178_ALERT_4_G The CIF-Embedded .res File Contains SIMU Records          1 Report
PLAT186_ALERT_4_G The CIF-Embedded .res File Contains ISOR Records          1 Report
PLAT199_ALERT_1_G Reported _cell_measurement_temperature ..... (K)        293 Check
PLAT200_ALERT_1_G Reported   _diffrn_ambient_temperature ..... (K)        293 Check
PLAT301_ALERT_3_G Main Residue  Disorder ..............(Resd  1  )        32% Note
PLAT794_ALERT_5_G Tentative Bond Valency for Cd1       (II)      .       1.91 Info
PLAT811_ALERT_5_G No ADDSYM Analysis: Too Many Excluded Atoms ....          ! Info
PLAT860_ALERT_3_G Number of Least-Squares Restraints .............        390 Note
PLAT910_ALERT_3_G Missing # of FCF Reflection(s) Below Theta(Min).          1 Note
PLAT912_ALERT_4_G Missing # of FCF Reflections Above STh/L=  0.600       1092 Note
PLAT978_ALERT_2_G Number C-C Bonds with Positive Residual Density.          1 Info

   0 ALERT level A = Most likely a serious problem - resolve or explain
   0 ALERT level B = A potentially serious problem, consider carefully
   8 ALERT level C = Check. Ensure it is not caused by an omission or oversight
  19 ALERT level G = General information/check it is not something unexpected

   4 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  10 ALERT type 2 Indicator that the structure model may be wrong or deficient
   5 ALERT type 3 Indicator that the structure quality may be low
   5 ALERT type 4 Improvement, methodology, query or suggestion
   3 ALERT type 5 Informative message, check

Computing details top

Data collection: CrysAlis PRO (Rigaku OD, 2018); cell refinement: CrysAlis PRO (Rigaku OD, 2018); data reduction: CrysAlis PRO (Rigaku OD, 2018); program(s) used to solve structure: SHELXS (Sheldrick, 2008); program(s) used to refine structure: SHELXL (Sheldrick, 2015); molecular graphics: ORTEP-3 for Windows (Farrugia, 2012); software used to prepare material for publication: ORTEP-3 for Windows (Farrugia, 2012).

Di-µ₃-chlorido-tetra-µ₂-chlorido-dichloridotetrakis(N,N-diethylethane-1,2-diamine-κ²N,N')tetracadmium(II) top

Crystal data top

[Cd₂Cl₄(C₆H₁₆N₂)₂]	Z = 2
M_r = 599.01	F(000) = 592
Triclinic, P1	D_x = 1.842 Mg m⁻³
a = 9.3622 (10) Å	Mo Kα radiation, λ = 0.71073 Å
b = 9.4023 (10) Å	Cell parameters from 3382 reflections
c = 12.4248 (9) Å	θ = 4.3–29.0°
α = 87.667 (7)°	µ = 2.46 mm⁻¹
β = 86.171 (7)°	T = 293 K
γ = 81.993 (9)°	Plate, colourless
V = 1080.08 (18) Å³	0.26 × 0.17 × 0.06 mm

Data collection top

Rigaku Oxford Diffraction SuperNova, Dual, Cu at home/near, Atlas diffractometer	3897 reflections with I > 2σ(I)
ω scans	R_int = 0.042
Absorption correction: multi-scan (CrysAlisPro; Rigaku OD, 2018)	θ_max = 29.9°, θ_min = 2.2°
T_min = 0.498, T_max = 1.000	h = −12→12
15671 measured reflections	k = −13→11
5120 independent reflections	l = −16→17

Refinement top

Refinement on F²	390 restraints
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F² > 2σ(F²)] = 0.050	H-atom parameters constrained
wR(F²) = 0.131	w = 1/[σ²(F_o²) + (0.0348P)² + 6.2177P] where P = (F_o² + 2F_c²)/3
S = 1.07	(Δ/σ)_max = 0.001
5120 reflections	Δρ_max = 1.01 e Å⁻³
247 parameters	Δρ_min = −1.42 e Å⁻³

Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Non-hydrogen atoms were refined with anisotropic displacement parameters. All hydrogen atoms were placed in calculated positions and refined using a riding model. Methyl C—H bonds were fixed at 0.96 Å, with displacement parameters 1.5 times U_eq(C). C—H distances for methylene groups were set to 0.97 Å and their U_iso(H) set to 1.2 times the U_eq(C). N—H distances for methylene groups were set to 0.89 Å and their U_iso(H) set to 1.2 times the U_eq(N).

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
C1	0.3866 (10)	0.7344 (10)	0.3329 (9)	0.082 (3)
H1A	0.465814	0.696964	0.284423	0.123*
H1B	0.407495	0.704330	0.405591	0.123*
H1C	0.372739	0.837455	0.326914	0.123*
C2	0.2507 (8)	0.6784 (7)	0.3041 (7)	0.0558 (19)
H2A	0.173933	0.708569	0.358127	0.067*
H2B	0.221937	0.722091	0.235435	0.067*
C3	0.2355 (13)	0.4747 (12)	0.4994 (6)	0.089 (3)
H3A	0.142236	0.444258	0.496016	0.133*
H3B	0.223962	0.575986	0.511236	0.133*
H3C	0.284821	0.423647	0.557614	0.133*
C4	0.3231 (8)	0.4433 (8)	0.3941 (5)	0.0545 (18)
H4A	0.419740	0.466318	0.401386	0.065*
H4B	0.331569	0.340956	0.382622	0.065*
C5	0.1245 (7)	0.4757 (8)	0.2735 (5)	0.0514 (17)
H5A	0.132528	0.371930	0.281572	0.062*
H5B	0.051170	0.516084	0.326825	0.062*
C6	0.0763 (8)	0.5190 (9)	0.1657 (6)	0.060 (2)
H6A	0.063721	0.622981	0.158022	0.073*
H6B	−0.016600	0.487290	0.157711	0.073*
N1	0.2651 (5)	0.5211 (5)	0.2966 (4)	0.0394 (12)
C7	0.714 (4)	−0.077 (3)	0.4663 (12)	0.073 (6)	0.553 (13)
H7A	0.635299	−0.063720	0.520053	0.110*	0.553 (13)
H7B	0.730646	−0.176329	0.446588	0.110*	0.553 (13)
H7C	0.799720	−0.052313	0.494931	0.110*	0.553 (13)
C8	0.6775 (13)	0.0172 (16)	0.3676 (9)	0.048 (3)	0.553 (13)
H8A	0.588856	−0.007556	0.341762	0.057*	0.553 (13)
H8B	0.657684	0.116019	0.389934	0.057*	0.553 (13)
C9	0.926 (2)	0.1786 (15)	0.3716 (14)	0.072 (5)	0.553 (13)
H9A	1.021730	0.188722	0.390221	0.108*	0.553 (13)
H9B	0.889663	0.258784	0.326183	0.108*	0.553 (13)
H9C	0.863855	0.175657	0.436148	0.108*	0.553 (13)
C10	0.9295 (11)	0.0413 (15)	0.3123 (12)	0.060 (4)	0.553 (13)
H10A	0.969293	−0.038212	0.358338	0.072*	0.553 (13)
H10B	0.995039	0.044716	0.248637	0.072*	0.553 (13)
C11	0.8223 (14)	−0.1326 (11)	0.2264 (10)	0.056 (3)	0.553 (13)
H11A	0.922980	−0.142333	0.200069	0.067*	0.553 (13)
H11B	0.813489	−0.206590	0.282200	0.067*	0.553 (13)
C12	0.7378 (10)	−0.1610 (8)	0.1385 (7)	0.064 (2)	0.553 (13)
H12A	0.785831	−0.246872	0.103918	0.076*	0.553 (13)
H12B	0.644811	−0.182497	0.169054	0.076*	0.553 (13)
N3	0.7854 (6)	0.0103 (6)	0.2774 (4)	0.0485 (13)	0.553 (13)
C7A	0.717 (5)	−0.036 (4)	0.4747 (16)	0.086 (10)	0.447 (13)
H7D	0.660368	0.008251	0.534889	0.129*	0.447 (13)
H7E	0.682484	−0.124036	0.459786	0.129*	0.447 (13)
H7F	0.816379	−0.055382	0.491673	0.129*	0.447 (13)
C8A	0.703 (2)	0.0650 (18)	0.3765 (11)	0.054 (4)	0.447 (13)
H8C	0.601901	0.086166	0.361723	0.065*	0.447 (13)
H8D	0.735526	0.154681	0.393546	0.065*	0.447 (13)
C9A	1.006 (2)	0.109 (2)	0.320 (2)	0.086 (6)	0.447 (13)
H9D	1.108561	0.084451	0.324111	0.129*	0.447 (13)
H9E	0.987038	0.186474	0.267480	0.129*	0.447 (13)
H9F	0.963054	0.138641	0.388936	0.129*	0.447 (13)
C10A	0.9423 (11)	−0.0202 (18)	0.2858 (17)	0.066 (4)	0.447 (13)
H10C	0.987562	−0.050771	0.216465	0.079*	0.447 (13)
H10D	0.963571	−0.098619	0.337960	0.079*	0.447 (13)
C11A	0.7214 (17)	−0.1211 (14)	0.2495 (9)	0.049 (3)	0.447 (13)
H11C	0.764720	−0.201795	0.292893	0.059*	0.447 (13)
H11D	0.618980	−0.105711	0.270666	0.059*	0.447 (13)
C12A	0.7378 (10)	−0.1610 (8)	0.1385 (7)	0.064 (2)	0.447 (13)
H12C	0.673030	−0.231003	0.129259	0.076*	0.447 (13)
H12D	0.835534	−0.209166	0.125144	0.076*	0.447 (13)
N3A	0.7854 (6)	0.0103 (6)	0.2774 (4)	0.0485 (13)	0.447 (13)
N2	0.1805 (6)	0.4578 (6)	0.0801 (4)	0.0433 (13)
H2C	0.174767	0.515162	0.021306	0.052*
H2D	0.159441	0.372377	0.063023	0.052*
N4	0.7120 (7)	−0.0498 (6)	0.0565 (5)	0.0477 (14)
H4C	0.627621	−0.054594	0.028690	0.057*
H4D	0.781024	−0.062664	0.003613	0.057*
Cl1	0.41595 (19)	0.15941 (18)	0.19230 (15)	0.0480 (4)
Cl2	0.44096 (18)	0.68635 (17)	0.04175 (13)	0.0431 (4)
Cl3	0.66065 (18)	0.41883 (19)	0.21743 (14)	0.0473 (4)
Cl4	0.9546 (2)	0.2105 (2)	0.04702 (19)	0.0635 (5)
Cd1	0.40910 (5)	0.43345 (5)	0.13790 (4)	0.03912 (14)
Cd2	0.70911 (5)	0.17078 (5)	0.12779 (4)	0.04159 (15)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
C1	0.085 (7)	0.066 (6)	0.097 (7)	−0.025 (5)	0.027 (6)	−0.028 (5)
C2	0.059 (5)	0.041 (4)	0.064 (4)	−0.002 (3)	0.017 (4)	−0.010 (3)
C3	0.109 (8)	0.107 (8)	0.044 (5)	−0.001 (6)	0.013 (5)	0.000 (5)
C4	0.056 (4)	0.064 (5)	0.042 (4)	−0.005 (4)	0.001 (3)	−0.002 (3)
C5	0.040 (4)	0.064 (4)	0.049 (4)	−0.008 (3)	0.013 (3)	−0.005 (3)
C6	0.040 (4)	0.068 (5)	0.068 (5)	0.007 (3)	0.001 (4)	0.001 (4)
N1	0.037 (3)	0.043 (3)	0.038 (3)	−0.007 (2)	0.004 (2)	−0.002 (2)
C7	0.102 (12)	0.076 (13)	0.043 (9)	−0.022 (11)	−0.010 (9)	0.023 (8)
C8	0.051 (6)	0.051 (7)	0.044 (6)	−0.018 (5)	−0.003 (5)	0.005 (5)
C9	0.076 (11)	0.056 (9)	0.091 (12)	−0.023 (8)	−0.033 (9)	−0.003 (8)
C10	0.057 (7)	0.059 (8)	0.055 (7)	0.024 (6)	−0.002 (6)	0.016 (6)
C11	0.065 (6)	0.039 (5)	0.058 (6)	0.007 (5)	−0.004 (5)	−0.001 (5)
C12	0.076 (5)	0.047 (4)	0.070 (4)	−0.014 (4)	−0.012 (4)	0.000 (3)
N3	0.063 (3)	0.039 (3)	0.042 (3)	0.001 (2)	−0.006 (3)	−0.001 (2)
C7A	0.109 (16)	0.080 (18)	0.061 (13)	0.007 (15)	0.009 (12)	0.006 (11)
C8A	0.065 (8)	0.049 (8)	0.049 (7)	−0.011 (7)	−0.007 (7)	0.005 (6)
C9A	0.082 (14)	0.087 (14)	0.093 (14)	−0.018 (11)	−0.018 (12)	−0.005 (12)
C10A	0.059 (7)	0.058 (8)	0.069 (8)	0.019 (7)	0.002 (7)	0.014 (7)
C11A	0.055 (6)	0.039 (6)	0.051 (6)	−0.008 (5)	0.006 (6)	−0.001 (5)
C12A	0.076 (5)	0.047 (4)	0.070 (4)	−0.014 (4)	−0.012 (4)	0.000 (3)
N3A	0.063 (3)	0.039 (3)	0.042 (3)	0.001 (2)	−0.006 (3)	−0.001 (2)
N2	0.044 (3)	0.043 (3)	0.044 (3)	−0.008 (2)	−0.001 (2)	−0.001 (2)
N4	0.054 (4)	0.045 (3)	0.042 (3)	0.001 (3)	−0.004 (3)	−0.005 (2)
Cl1	0.0453 (9)	0.0411 (8)	0.0549 (10)	−0.0014 (7)	0.0034 (8)	0.0047 (7)
Cl2	0.0476 (9)	0.0430 (8)	0.0370 (8)	−0.0030 (7)	0.0026 (7)	0.0002 (6)
Cl3	0.0386 (9)	0.0483 (9)	0.0544 (10)	0.0014 (7)	−0.0098 (7)	−0.0096 (7)
Cl4	0.0472 (10)	0.0562 (11)	0.0829 (14)	−0.0023 (8)	0.0150 (10)	0.0002 (10)
Cd1	0.0324 (3)	0.0429 (3)	0.0388 (3)	0.00378 (19)	0.00272 (19)	−0.00057 (19)
Cd2	0.0398 (3)	0.0354 (3)	0.0466 (3)	0.00223 (19)	0.0016 (2)	0.0013 (2)

Geometric parameters (Å, º) top

C1—C2	1.512 (10)	C12—H12A	0.9700
C1—H1A	0.9600	C12—H12B	0.9700
C1—H1B	0.9600	N3—Cd2	2.427 (5)
C1—H1C	0.9600	C7A—C8A	1.516 (11)
C2—N1	1.473 (7)	C7A—H7D	0.9600
C2—H2A	0.9700	C7A—H7E	0.9600
C2—H2B	0.9700	C7A—H7F	0.9600
C3—C4	1.514 (9)	C8A—N3A	1.479 (9)
C3—H3A	0.9600	C8A—H8C	0.9700
C3—H3B	0.9600	C8A—H8D	0.9700
C3—H3C	0.9600	C9A—C10A	1.514 (12)
C4—N1	1.484 (8)	C9A—H9D	0.9600
C4—H4A	0.9700	C9A—H9E	0.9600
C4—H4B	0.9700	C9A—H9F	0.9600
C5—C6	1.465 (9)	C10A—N3A	1.467 (10)
C5—N1	1.488 (7)	C10A—H10C	0.9700
C5—H5A	0.9700	C10A—H10D	0.9700
C5—H5B	0.9700	C11A—C12A	1.436 (10)
C6—N2	1.473 (9)	C11A—N3A	1.508 (9)
C6—H6A	0.9700	C11A—H11C	0.9700
C6—H6B	0.9700	C11A—H11D	0.9700
N1—Cd1	2.419 (5)	C12A—N4	1.437 (9)
C7—C8	1.516 (11)	C12A—H12C	0.9700
C7—H7A	0.9600	C12A—H12D	0.9700
C7—H7B	0.9600	N3A—Cd2	2.427 (5)
C7—H7C	0.9600	N2—Cd1	2.282 (6)
C8—N3	1.455 (9)	N2—H2C	0.8900
C8—H8A	0.9700	N2—H2D	0.8900
C8—H8B	0.9700	N4—Cd2	2.285 (6)
C9—C10	1.507 (12)	N4—H4C	0.8900
C9—H9A	0.9600	N4—H4D	0.8900
C9—H9B	0.9600	Cl1—Cd1	2.6302 (17)
C9—H9C	0.9600	Cl1—Cd2	2.8227 (18)
C10—N3	1.514 (10)	Cl2—Cd1	2.6625 (17)
C10—H10A	0.9700	Cl2—Cd1ⁱ	2.7509 (16)
C10—H10B	0.9700	Cl2—Cd2ⁱ	2.8027 (17)
C11—C12	1.445 (10)	Cl3—Cd2	2.5952 (18)
C11—N3	1.495 (9)	Cl3—Cd1	2.5983 (18)
C11—H11A	0.9700	Cl4—Cd2	2.5158 (19)
C11—H11B	0.9700	Cd1—Cd2	3.4713 (8)
C12—N4	1.437 (9)

C2—C1—H1A	109.5	C10A—C9A—H9D	109.5
C2—C1—H1B	109.5	C10A—C9A—H9E	109.5
H1A—C1—H1B	109.5	H9D—C9A—H9E	109.5
C2—C1—H1C	109.5	C10A—C9A—H9F	109.5
H1A—C1—H1C	109.5	H9D—C9A—H9F	109.5
H1B—C1—H1C	109.5	H9E—C9A—H9F	109.5
N1—C2—C1	114.4 (6)	N3A—C10A—C9A	112.3 (11)
N1—C2—H2A	108.7	N3A—C10A—H10C	109.1
C1—C2—H2A	108.7	C9A—C10A—H10C	109.1
N1—C2—H2B	108.7	N3A—C10A—H10D	109.1
C1—C2—H2B	108.7	C9A—C10A—H10D	109.1
H2A—C2—H2B	107.6	H10C—C10A—H10D	107.9
C4—C3—H3A	109.5	C12A—C11A—N3A	116.9 (8)
C4—C3—H3B	109.5	C12A—C11A—H11C	108.1
H3A—C3—H3B	109.5	N3A—C11A—H11C	108.1
C4—C3—H3C	109.5	C12A—C11A—H11D	108.1
H3A—C3—H3C	109.5	N3A—C11A—H11D	108.1
H3B—C3—H3C	109.5	H11C—C11A—H11D	107.3
N1—C4—C3	116.0 (6)	C11A—C12A—N4	118.4 (8)
N1—C4—H4A	108.3	C11A—C12A—H12C	107.7
C3—C4—H4A	108.3	N4—C12A—H12C	107.7
N1—C4—H4B	108.3	C11A—C12A—H12D	107.7
C3—C4—H4B	108.3	N4—C12A—H12D	107.7
H4A—C4—H4B	107.4	H12C—C12A—H12D	107.1
C6—C5—N1	114.4 (6)	C10A—N3A—C8A	114.8 (10)
C6—C5—H5A	108.7	C10A—N3A—C11A	112.0 (9)
N1—C5—H5A	108.7	C8A—N3A—C11A	106.0 (8)
C6—C5—H5B	108.7	C10A—N3A—Cd2	114.9 (9)
N1—C5—H5B	108.7	C8A—N3A—Cd2	107.9 (8)
H5A—C5—H5B	107.6	C11A—N3A—Cd2	99.9 (6)
C5—C6—N2	111.8 (6)	C6—N2—Cd1	109.8 (4)
C5—C6—H6A	109.3	C6—N2—H2C	109.7
N2—C6—H6A	109.3	Cd1—N2—H2C	109.7
C5—C6—H6B	109.3	C6—N2—H2D	109.7
N2—C6—H6B	109.3	Cd1—N2—H2D	109.7
H6A—C6—H6B	107.9	H2C—N2—H2D	108.2
C2—N1—C4	113.0 (5)	C12A—N4—Cd2	110.2 (4)
C2—N1—C5	110.5 (5)	C12—N4—Cd2	110.2 (4)
C4—N1—C5	110.6 (5)	C12—N4—H4C	109.6
C2—N1—Cd1	112.9 (4)	Cd2—N4—H4C	109.6
C4—N1—Cd1	109.5 (4)	C12—N4—H4D	109.6
C5—N1—Cd1	99.5 (4)	Cd2—N4—H4D	109.6
C8—C7—H7A	109.5	H4C—N4—H4D	108.1
C8—C7—H7B	109.5	Cd1—Cl1—Cd2	78.99 (5)
H7A—C7—H7B	109.5	Cd1—Cl2—Cd1ⁱ	93.97 (5)
C8—C7—H7C	109.5	Cd1—Cl2—Cd2ⁱ	128.87 (7)
H7A—C7—H7C	109.5	Cd1ⁱ—Cl2—Cd2ⁱ	77.36 (4)
H7B—C7—H7C	109.5	Cd2—Cl3—Cd1	83.89 (5)
N3—C8—C7	117.1 (11)	N2—Cd1—N1	78.02 (18)
N3—C8—H8A	108.0	N2—Cd1—Cl3	175.17 (15)
C7—C8—H8A	108.0	N1—Cd1—Cl3	97.32 (13)
N3—C8—H8B	108.0	N2—Cd1—Cl1	94.40 (15)
C7—C8—H8B	108.0	N1—Cd1—Cl1	95.61 (12)
H8A—C8—H8B	107.3	Cl3—Cd1—Cl1	87.24 (6)
C10—C9—H9A	109.5	N2—Cd1—Cl2	88.67 (14)
C10—C9—H9B	109.5	N1—Cd1—Cl2	98.15 (12)
H9A—C9—H9B	109.5	Cl3—Cd1—Cl2	90.80 (6)
C10—C9—H9C	109.5	Cl1—Cd1—Cl2	166.24 (5)
H9A—C9—H9C	109.5	N2—Cd1—Cl2ⁱ	99.30 (14)
H9B—C9—H9C	109.5	N1—Cd1—Cl2ⁱ	174.93 (12)
C9—C10—N3	115.6 (9)	Cl3—Cd1—Cl2ⁱ	85.45 (5)
C9—C10—H10A	108.4	Cl1—Cd1—Cl2ⁱ	80.24 (5)
N3—C10—H10A	108.4	Cl2—Cd1—Cl2ⁱ	86.03 (5)
C9—C10—H10B	108.4	N2—Cd1—Cd2	136.10 (14)
N3—C10—H10B	108.4	N1—Cd1—Cd2	127.43 (12)
H10A—C10—H10B	107.4	Cl3—Cd1—Cd2	48.02 (4)
C12—C11—N3	117.2 (7)	Cl1—Cd1—Cd2	52.96 (4)
C12—C11—H11A	108.0	Cl2—Cd1—Cd2	116.86 (4)
N3—C11—H11A	108.0	Cl2ⁱ—Cd1—Cd2	51.98 (4)
C12—C11—H11B	108.0	N4—Cd2—N3	78.04 (19)
N3—C11—H11B	108.0	N4—Cd2—N3A	78.04 (19)
H11A—C11—H11B	107.2	N4—Cd2—Cl4	95.52 (17)
N4—C12—C11	117.4 (8)	N3—Cd2—Cl4	98.54 (15)
N4—C12—H12A	108.0	N3A—Cd2—Cl4	98.54 (15)
C11—C12—H12A	108.0	N4—Cd2—Cl3	170.42 (17)
N4—C12—H12B	108.0	N3—Cd2—Cl3	102.29 (13)
C11—C12—H12B	108.0	N3A—Cd2—Cl3	102.29 (13)
H12A—C12—H12B	107.2	Cl4—Cd2—Cl3	93.90 (6)
C8—N3—C11	115.9 (8)	N4—Cd2—Cl2ⁱ	93.02 (15)
C8—N3—C10	111.3 (8)	N3—Cd2—Cl2ⁱ	164.69 (14)
C11—N3—C10	103.2 (7)	Cl4—Cd2—Cl2ⁱ	94.66 (6)
C8—N3—Cd2	112.4 (7)	Cl3—Cd2—Cl2ⁱ	84.45 (5)
C11—N3—Cd2	103.4 (5)	N4—Cd2—Cl1	87.06 (16)
C10—N3—Cd2	110.0 (6)	N3—Cd2—Cl1	90.86 (14)
C8A—C7A—H7D	109.5	N3A—Cd2—Cl1	90.86 (14)
C8A—C7A—H7E	109.5	Cl4—Cd2—Cl1	170.58 (6)
H7D—C7A—H7E	109.5	Cl3—Cd2—Cl1	83.36 (5)
C8A—C7A—H7F	109.5	Cl2ⁱ—Cd2—Cl1	76.14 (5)
H7D—C7A—H7F	109.5	N4—Cd2—Cd1	123.88 (16)
H7E—C7A—H7F	109.5	N3—Cd2—Cd1	124.95 (13)
N3A—C8A—C7A	115.2 (11)	N3A—Cd2—Cd1	124.95 (13)
N3A—C8A—H8C	108.5	Cl4—Cd2—Cd1	124.18 (5)
C7A—C8A—H8C	108.5	Cl3—Cd2—Cd1	48.10 (4)
N3A—C8A—H8D	108.5	Cl2ⁱ—Cd2—Cd1	50.65 (3)
C7A—C8A—H8D	108.5	Cl1—Cd2—Cd1	48.05 (4)
H8C—C8A—H8D	107.5

Symmetry code: (i) −x+1, −y+1, −z.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
N2—H2C···Cl4ⁱ	0.89	2.82	3.548 (6)	141
N2—H2D···Cl4ⁱⁱ	0.89	2.63	3.407 (6)	146
N4—H4D···Cl4ⁱⁱⁱ	0.89	2.71	3.463 (6)	143

Symmetry codes: (i) −x+1, −y+1, −z; (ii) x−1, y, z; (iii) −x+2, −y, −z.

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Di-μ3-chlorido-tetra-μ2-chlorido-di­chloridotetra­kis­(N,N-di­ethyl­ethane-1,2-di­amine-κ2N,N′)tetra­cadmium(II)

Supporting information

Key indicators

checkCIF/PLATON results

Di-μ₃-chlorido-tetra-μ₂-chlorido-dichloridotetrakis(N,N-diethylethane-1,2-diamine-κ²N,N′)tetracadmium(II)