Bis[μ3-2-(pyridin-3-yl)acetato-κ3O:O:O′]bis­[μ2-2-(pyridin-3-yl)acetato-κ2O:O′]bis­[chlorido­(1,10-phenanthroline-κ2N,N′)dysprosium(III)]

Lin, Y.; Yu, J.-P.

doi:10.1107/S2414314622002310

Bis[μ₃-2-(pyridin-3-yl)acetato-κ³O:O:O′]bis[μ₂-2-(pyridin-3-yl)acetato-κ²O:O′]bis[chlorido(1,10-phenanthroline-κ²N,N′)dysprosium(III)]

The title Dy^III complex, [Dy₂(C₇H₆NO₂)₄Cl₂(C₁₂H₈N₂)₂] or [Dy₂(μ₃-PAA)₄(Cl)₂(phen)₂] (PAA = 3-pyridylacetate, phen = 1,10-phenanthroline), obtained by reaction of Dy(ClO₄)₃, 3-pyridylacetic acid ligands and 1,10-phenanthroline, exhibits a dinuclear structure. Adjacent binuclear dimers are further connected via face-to-face π–π stacking interactions resulting in supramolecular chains along the c-axis direction.

Keywords: crystal structure.

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Supporting information

Crystallographic Information File (CIF) https://doi.org/10.1107/S2414314622002310/vm4049sup1.cif
Contains datablocks I, New_Global_Publ_Block

CCDC reference: 2155088

checkCIF report

Key indicators

Single-crystal X-ray study
T = 296 K
Mean (C-C) = 0.004 Å
R factor = 0.021
wR factor = 0.056
Data-to-parameter ratio = 13.8

checkCIF/PLATON results

No syntax errors found



Datablock: I


Alert level C
PLAT125_ALERT_4_C No '_symmetry_space_group_name_Hall' Given .....     Please Do !
PLAT220_ALERT_2_C NonSolvent   Resd 1  C   Ueq(max)/Ueq(min) Range        3.8 Ratio
PLAT220_ALERT_2_C NonSolvent   Resd 1  N   Ueq(max)/Ueq(min) Range        3.7 Ratio
PLAT230_ALERT_2_C Hirshfeld Test Diff for    O2       --C7       .        5.2 s.u.
PLAT241_ALERT_2_C High   'MainMol' Ueq as Compared to Neighbors of         N1 Check
PLAT241_ALERT_2_C High   'MainMol' Ueq as Compared to Neighbors of         C3 Check
PLAT241_ALERT_2_C High   'MainMol' Ueq as Compared to Neighbors of        C13 Check
PLAT242_ALERT_2_C Low    'MainMol' Ueq as Compared to Neighbors of         C5 Check
PLAT242_ALERT_2_C Low    'MainMol' Ueq as Compared to Neighbors of        C12 Check

Alert level G
PLAT003_ALERT_2_G Number of Uiso or Uij Restrained non-H Atoms ...          2 Report
PLAT005_ALERT_5_G No Embedded Refinement Details Found  in the CIF     Please Do !
PLAT143_ALERT_4_G s.u. on c - Axis Small or Missing ..............    0.00010 Ang.
PLAT232_ALERT_2_G Hirshfeld Test Diff (M-X)  Dy1      --Cl1      .        7.8 s.u.
PLAT232_ALERT_2_G Hirshfeld Test Diff (M-X)  Dy1      --O2       .        7.0 s.u.
PLAT232_ALERT_2_G Hirshfeld Test Diff (M-X)  Dy1      --N4       .        6.0 s.u.
PLAT860_ALERT_3_G Number of Least-Squares Restraints .............          1 Note
PLAT899_ALERT_4_G SHELXL97  is Deprecated and Succeeded by SHELXL/       2018 Note

   0 ALERT level A = Most likely a serious problem - resolve or explain
   0 ALERT level B = A potentially serious problem, consider carefully
   9 ALERT level C = Check. Ensure it is not caused by an omission or oversight
   8 ALERT level G = General information/check it is not something unexpected

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  12 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   3 ALERT type 4 Improvement, methodology, query or suggestion
   1 ALERT type 5 Informative message, check

Computing details top

Data collection: SMART (Bruker, 2008); cell refinement: SAINT (Bruker, 2008); data reduction: SAINT (Bruker, 2008); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXTL (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

\ Bis[µ₃-2-(pyridin-3-yl)acetato-κ³O:O:O']\ bis[µ-2-(pyridin-3-yl)acetato-κ²O:O']bis[chlorido(1,10-\ phenanthroline-κ²N,N')dysprosium(III)], top

Crystal data top

[Dy₂(C₇H₆NO₂)₄Cl₂(C₁₂H₈N₂)₂]	F(000) = 1276
M_r = 1300.82	D_x = 1.773 Mg m⁻³
Monoclinic, P2₁/c	Mo Kα radiation, λ = 0.71073 Å
a = 8.8922 (1) Å	Cell parameters from 7687 reflections
b = 21.5425 (3) Å	θ = 2.5–27.3°
c = 12.9887 (1) Å	µ = 3.22 mm⁻¹
β = 101.755 (1)°	T = 296 K
V = 2435.94 (5) Å³	Block, yellow
Z = 2	0.22 × 0.20 × 0.19 mm

Data collection top

Bruker SAINT CCD area detector diffractometer	4487 independent reflections
Radiation source: fine-focus sealed tube	3954 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.024
phi and ω scans	θ_max = 25.5°, θ_min = 1.9°
Absorption correction: multi-scan (SADABS; Bruker, 2008)	h = −10→10
T_min = 0.626, T_max = 0.746	k = −26→23
16420 measured reflections	l = −15→15

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.021	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.056	H-atom parameters constrained
S = 1.00	w = 1/[σ²(F_o²) + (0.035P)²] where P = (F_o² + 2F_c²)/3
4487 reflections	(Δ/σ)_max = 0.002
325 parameters	Δρ_max = 0.59 e Å⁻³
1 restraint	Δρ_min = −0.34 e Å⁻³

Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

H atoms were placed in calculated positions with C—H = 0.93 Å in phenyl and pyridine rings while C–H = 0.97 Å in CH₂ groups and refined in riding mode with U_iso(H) = 1.2U_eq(C).

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Dy1	0.387207 (12)	0.510416 (5)	0.855827 (7)	0.03127 (3)
Cl1	0.13833 (7)	0.58009 (3)	0.81071 (5)	0.05938 (19)
O3	0.57734 (18)	0.58550 (8)	0.90135 (12)	0.0487 (5)
N3	0.4153 (2)	0.55350 (10)	0.67882 (13)	0.0420 (5)
O1	0.57990 (18)	0.44419 (8)	0.80320 (11)	0.0472 (4)
N4	0.2364 (2)	0.45183 (9)	0.69718 (13)	0.0383 (5)
C7	0.6642 (3)	0.43988 (11)	0.89307 (17)	0.0365 (6)
C14	0.6799 (3)	0.60069 (12)	0.97945 (18)	0.0455 (6)
C18	0.3415 (3)	0.54877 (14)	0.48832 (18)	0.0544 (7)
C26	0.3341 (3)	0.52662 (12)	0.58975 (17)	0.0416 (6)
C25	0.2402 (3)	0.47369 (12)	0.59934 (17)	0.0420 (6)
C21	0.1571 (3)	0.44537 (15)	0.50734 (18)	0.0545 (8)
C6	0.8200 (3)	0.41057 (12)	0.90869 (18)	0.0441 (6)
H6A	0.8755	0.4280	0.8585	0.053*
H6B	0.8770	0.4202	0.9788	0.053*
C24	0.1525 (3)	0.40185 (12)	0.7037 (2)	0.0498 (7)
H24A	0.1480	0.3871	0.7702	0.060*
C5	0.8108 (3)	0.34153 (13)	0.8952 (2)	0.0476 (7)
C19	0.2538 (4)	0.51931 (16)	0.3983 (2)	0.0687 (10)
H19A	0.2583	0.5344	0.3319	0.082*
C22	0.0729 (3)	0.39253 (16)	0.5185 (2)	0.0696 (9)
H22A	0.0181	0.3724	0.4592	0.084*
C12	0.7310 (3)	0.69858 (12)	0.8813 (2)	0.0494 (7)
C8	0.7993 (3)	0.70351 (14)	0.7954 (2)	0.0662 (9)
H8A	0.8829	0.6781	0.7929	0.079*
C11	0.6079 (3)	0.73727 (15)	0.8813 (2)	0.0690 (9)
H11A	0.5574	0.7359	0.9374	0.083*
C23	0.0701 (3)	0.36993 (15)	0.6167 (2)	0.0657 (9)
H23A	0.0149	0.3343	0.6252	0.079*
N2	0.7518 (3)	0.74312 (14)	0.7148 (2)	0.0894 (9)
C17	0.4394 (4)	0.59840 (15)	0.4816 (2)	0.0658 (8)
H17A	0.4493	0.6133	0.4161	0.079*
C13	0.7883 (3)	0.65317 (14)	0.9671 (2)	0.0682 (9)
H13A	0.8129	0.6757	1.0331	0.082*
H13B	0.8831	0.6352	0.9547	0.082*
O2	0.61601 (17)	0.46036 (8)	0.97223 (11)	0.0421 (4)
O4	0.70410 (19)	0.57482 (8)	1.06850 (12)	0.0509 (5)
C15	0.5041 (3)	0.60095 (13)	0.6677 (2)	0.0565 (8)
H15A	0.5597	0.6197	0.7281	0.068*
C20	0.1653 (4)	0.47066 (18)	0.4064 (2)	0.0720 (10)
H20A	0.1078	0.4527	0.3458	0.086*
C16	0.5196 (4)	0.62483 (14)	0.5697 (2)	0.0690 (9)
H16A	0.5842	0.6583	0.5659	0.083*
C1	0.7804 (4)	0.30426 (16)	0.9734 (3)	0.0882 (12)
H1A	0.7679	0.3235	1.0352	0.106*
C10	0.5589 (4)	0.77733 (16)	0.8009 (3)	0.0875 (12)
H10A	0.4759	0.8035	0.8011	0.105*
C4	0.8326 (4)	0.31262 (18)	0.8051 (3)	0.0958 (12)
H4A	0.8526	0.3356	0.7487	0.115*
N1	0.7671 (5)	0.24248 (16)	0.9688 (3)	0.1415 (16)
C3	0.8239 (5)	0.2480 (2)	0.8001 (4)	0.1398 (18)
H3A	0.8416	0.2267	0.7413	0.168*
C9	0.6330 (5)	0.77806 (17)	0.7218 (3)	0.0939 (13)
H9A	0.5980	0.8055	0.6668	0.113*
C2	0.7889 (5)	0.2167 (2)	0.8833 (5)	0.140 (2)
H2A	0.7800	0.1738	0.8781	0.168*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Dy1	0.03380 (6)	0.03284 (7)	0.02427 (6)	0.00167 (4)	−0.00091 (4)	0.00130 (4)
Cl1	0.0556 (4)	0.0664 (4)	0.0473 (3)	0.0255 (3)	−0.0104 (3)	−0.0088 (3)
O3	0.0544 (10)	0.0502 (11)	0.0343 (8)	−0.0156 (8)	−0.0077 (7)	0.0103 (8)
N3	0.0500 (11)	0.0439 (12)	0.0303 (9)	0.0042 (10)	0.0043 (8)	0.0054 (8)
O1	0.0509 (9)	0.0605 (11)	0.0286 (8)	0.0160 (9)	0.0047 (7)	−0.0012 (7)
N4	0.0372 (10)	0.0439 (12)	0.0312 (9)	0.0055 (9)	0.0009 (8)	−0.0030 (8)
C7	0.0383 (12)	0.0338 (13)	0.0362 (12)	0.0016 (10)	0.0051 (10)	0.0017 (10)
C14	0.0493 (14)	0.0429 (15)	0.0403 (13)	−0.0087 (12)	−0.0003 (11)	0.0052 (11)
C18	0.0604 (16)	0.0681 (19)	0.0349 (13)	0.0217 (14)	0.0098 (11)	0.0097 (12)
C26	0.0482 (14)	0.0459 (15)	0.0290 (11)	0.0127 (12)	0.0041 (10)	0.0035 (10)
C25	0.0397 (13)	0.0538 (15)	0.0303 (12)	0.0140 (12)	0.0020 (10)	−0.0057 (11)
C21	0.0440 (14)	0.080 (2)	0.0353 (13)	0.0073 (14)	−0.0017 (11)	−0.0138 (13)
C6	0.0365 (12)	0.0509 (16)	0.0445 (13)	0.0049 (11)	0.0071 (10)	−0.0035 (11)
C24	0.0494 (14)	0.0535 (17)	0.0448 (14)	−0.0060 (13)	0.0053 (11)	−0.0079 (12)
C5	0.0319 (12)	0.0499 (16)	0.0566 (15)	0.0096 (11)	−0.0013 (11)	−0.0084 (12)
C19	0.078 (2)	0.095 (3)	0.0318 (14)	0.0236 (18)	0.0077 (14)	0.0053 (14)
C22	0.0583 (17)	0.097 (2)	0.0471 (15)	−0.0097 (18)	−0.0034 (13)	−0.0313 (16)
C12	0.0444 (13)	0.0429 (15)	0.0568 (15)	−0.0134 (10)	0.0005 (12)	0.0090 (12)
C8	0.0567 (17)	0.0577 (19)	0.086 (2)	−0.0059 (15)	0.0176 (16)	0.0155 (16)
C11	0.0628 (16)	0.067 (2)	0.078 (2)	−0.0037 (13)	0.0156 (16)	−0.0113 (17)
C23	0.0564 (16)	0.072 (2)	0.0648 (17)	−0.0175 (15)	0.0045 (14)	−0.0239 (15)
N2	0.101 (2)	0.090 (2)	0.0763 (17)	−0.0263 (18)	0.0171 (16)	0.0270 (16)
C17	0.0842 (19)	0.076 (2)	0.0398 (14)	0.0175 (18)	0.0187 (13)	0.0244 (14)
C13	0.0551 (16)	0.072 (2)	0.0658 (18)	−0.0288 (15)	−0.0150 (14)	0.0267 (15)
O2	0.0440 (9)	0.0520 (10)	0.0284 (8)	0.0135 (8)	0.0028 (7)	−0.0033 (7)
O4	0.0602 (11)	0.0502 (11)	0.0347 (8)	−0.0181 (9)	−0.0083 (8)	0.0070 (8)
C15	0.0703 (18)	0.0530 (17)	0.0455 (14)	−0.0066 (15)	0.0101 (13)	0.0103 (12)
C20	0.072 (2)	0.111 (3)	0.0272 (13)	0.016 (2)	−0.0040 (13)	−0.0135 (16)
C16	0.094 (2)	0.0609 (19)	0.0574 (17)	−0.0034 (17)	0.0266 (15)	0.0194 (14)
C1	0.128 (3)	0.057 (2)	0.065 (2)	−0.012 (2)	−0.016 (2)	0.0032 (17)
C10	0.069 (2)	0.051 (2)	0.129 (3)	0.0161 (17)	−0.011 (2)	0.004 (2)
C4	0.077 (2)	0.103 (3)	0.116 (3)	−0.003 (2)	0.041 (2)	−0.048 (2)
N1	0.183 (3)	0.057 (2)	0.146 (3)	−0.026 (2)	−0.057 (3)	0.026 (2)
C3	0.079 (2)	0.124 (3)	0.222 (4)	−0.001 (3)	0.044 (3)	−0.118 (3)
C9	0.103 (3)	0.060 (2)	0.100 (3)	−0.015 (2)	−0.025 (2)	0.026 (2)
C2	0.082 (3)	0.062 (3)	0.240 (6)	0.028 (2)	−0.052 (3)	−0.042 (3)

Geometric parameters (Å, º) top

Dy1—O4ⁱ	2.3069 (17)	C19—C20	1.327 (5)
Dy1—O3	2.3275 (16)	C19—H19A	0.9300
Dy1—O2ⁱ	2.3261 (14)	C22—C23	1.371 (4)
Dy1—O1	2.4323 (16)	C22—H22A	0.9300
Dy1—O2	2.5170 (15)	C12—C11	1.376 (4)
Dy1—N3	2.5386 (18)	C12—C8	1.378 (4)
Dy1—N4	2.5516 (17)	C12—C13	1.493 (4)
Dy1—Cl1	2.6392 (6)	C8—N2	1.350 (4)
Dy1—C7	2.850 (2)	C8—H8A	0.9300
Dy1—Dy1ⁱ	3.8976 (2)	C11—C10	1.356 (4)
O3—C14	1.261 (3)	C11—H11A	0.9300
N3—C15	1.317 (3)	C23—H23A	0.9300
N3—C26	1.362 (3)	N2—C9	1.315 (5)
O1—C7	1.256 (2)	C17—C16	1.346 (4)
N4—C24	1.323 (3)	C17—H17A	0.9300
N4—C25	1.362 (3)	C13—H13A	0.9700
C7—O2	1.271 (3)	C13—H13B	0.9700
C7—C6	1.498 (3)	O2—Dy1ⁱ	2.3261 (14)
C14—O4	1.262 (3)	O4—Dy1ⁱ	2.3069 (17)
C14—C13	1.515 (4)	C15—C16	1.405 (4)
C18—C19	1.417 (4)	C15—H15A	0.9300
C18—C26	1.415 (3)	C20—H20A	0.9300
C18—C17	1.393 (4)	C16—H16A	0.9300
C26—C25	1.434 (4)	C1—N1	1.336 (5)
C25—C21	1.409 (3)	C1—H1A	0.9300
C21—C22	1.386 (4)	C10—C9	1.329 (5)
C21—C20	1.435 (4)	C10—H10A	0.9300
C6—C5	1.498 (4)	C4—C3	1.395 (6)
C6—H6A	0.9700	C4—H4A	0.9300
C6—H6B	0.9700	N1—C2	1.291 (7)
C24—C23	1.396 (4)	C3—C2	1.362 (7)
C24—H24A	0.9300	C3—H3A	0.9300
C5—C1	1.364 (4)	C9—H9A	0.9300
C5—C4	1.374 (4)	C2—H2A	0.9300

O4ⁱ—Dy1—O3	138.19 (5)	C25—C21—C20	119.7 (3)
O4ⁱ—Dy1—O2ⁱ	74.46 (6)	C5—C6—C7	112.05 (19)
O3—Dy1—O2ⁱ	73.64 (6)	C5—C6—H6A	109.2
O4ⁱ—Dy1—O1	88.97 (6)	C7—C6—H6A	109.2
O3—Dy1—O1	87.84 (6)	C5—C6—H6B	109.2
O2ⁱ—Dy1—O1	125.15 (5)	C7—C6—H6B	109.2
O4ⁱ—Dy1—O2	73.42 (6)	H6A—C6—H6B	107.9
O3—Dy1—O2	71.86 (6)	N4—C24—C23	124.0 (3)
O2ⁱ—Dy1—O2	72.89 (6)	N4—C24—H24A	118.0
O1—Dy1—O2	52.27 (5)	C23—C24—H24A	118.0
O4ⁱ—Dy1—N3	141.73 (6)	C1—C5—C4	116.8 (3)
O3—Dy1—N3	77.03 (6)	C1—C5—C6	120.8 (3)
O2ⁱ—Dy1—N3	142.50 (7)	C4—C5—C6	122.4 (3)
O1—Dy1—N3	75.81 (6)	C20—C19—C18	121.6 (3)
O2—Dy1—N3	118.94 (6)	C20—C19—H19A	119.2
O4ⁱ—Dy1—N4	77.16 (6)	C18—C19—H19A	119.2
O3—Dy1—N4	141.62 (6)	C21—C22—C23	120.1 (3)
O2ⁱ—Dy1—N4	143.32 (6)	C21—C22—H22A	120.0
O1—Dy1—N4	76.54 (5)	C23—C22—H22A	120.0
O2—Dy1—N4	120.04 (6)	C11—C12—C8	115.8 (3)
N3—Dy1—N4	65.29 (6)	C11—C12—C13	123.2 (3)
O4ⁱ—Dy1—Cl1	101.26 (5)	C8—C12—C13	121.0 (3)
O3—Dy1—Cl1	101.19 (5)	N2—C8—C12	123.8 (3)
O2ⁱ—Dy1—Cl1	83.42 (4)	N2—C8—H8A	118.1
O1—Dy1—Cl1	151.41 (4)	C12—C8—H8A	118.1
O2—Dy1—Cl1	156.30 (4)	C12—C11—C10	121.0 (3)
N3—Dy1—Cl1	79.86 (5)	C12—C11—H11A	119.5
N4—Dy1—Cl1	79.81 (4)	C10—C11—H11A	119.5
O4ⁱ—Dy1—C7	82.55 (6)	C24—C23—C22	118.2 (3)
O3—Dy1—C7	76.68 (6)	C24—C23—H23A	120.9
O2ⁱ—Dy1—C7	99.24 (6)	C22—C23—H23A	120.9
O1—Dy1—C7	25.99 (5)	C9—N2—C8	115.9 (3)
O2—Dy1—C7	26.47 (5)	C16—C17—C18	120.1 (3)
N3—Dy1—C7	96.17 (6)	C16—C17—H17A	120.0
N4—Dy1—C7	99.62 (6)	C18—C17—H17A	120.0
Cl1—Dy1—C7	175.87 (5)	C12—C13—C14	116.1 (2)
O4ⁱ—Dy1—Dy1ⁱ	69.87 (4)	C12—C13—H13A	108.3
O3—Dy1—Dy1ⁱ	68.34 (4)	C14—C13—H13A	108.3
O2ⁱ—Dy1—Dy1ⁱ	38.11 (4)	C12—C13—H13B	108.3
O1—Dy1—Dy1ⁱ	87.04 (3)	C14—C13—H13B	108.3
O2—Dy1—Dy1ⁱ	34.78 (3)	H13A—C13—H13B	107.4
N3—Dy1—Dy1ⁱ	141.81 (4)	C7—O2—Dy1ⁱ	160.55 (14)
N4—Dy1—Dy1ⁱ	143.32 (4)	C7—O2—Dy1	91.55 (12)
Cl1—Dy1—Dy1ⁱ	121.533 (15)	Dy1ⁱ—O2—Dy1	107.11 (6)
C7—Dy1—Dy1ⁱ	61.17 (4)	C14—O4—Dy1ⁱ	137.13 (15)
C14—O3—Dy1	138.89 (15)	N3—C15—C16	123.7 (3)
C15—N3—C26	117.5 (2)	N3—C15—H15A	118.1
C15—N3—Dy1	123.72 (16)	C16—C15—H15A	118.1
C26—N3—Dy1	118.73 (16)	C19—C20—C21	120.9 (3)
C7—O1—Dy1	95.93 (14)	C19—C20—H20A	119.6
C24—N4—C25	117.5 (2)	C21—C20—H20A	119.6
C24—N4—Dy1	124.18 (15)	C17—C16—C15	118.9 (3)
C25—N4—Dy1	118.28 (15)	C17—C16—H16A	120.6
O1—C7—O2	119.4 (2)	C15—C16—H16A	120.6
O1—C7—C6	121.2 (2)	N1—C1—C5	125.6 (4)
O2—C7—C6	119.44 (19)	N1—C1—H1A	117.2
O1—C7—Dy1	58.08 (12)	C5—C1—H1A	117.2
O2—C7—Dy1	61.98 (11)	C9—C10—C11	118.1 (3)
C6—C7—Dy1	172.26 (17)	C9—C10—H10A	120.9
O4—C14—O3	125.6 (2)	C11—C10—H10A	120.9
O4—C14—C13	115.7 (2)	C5—C4—C3	118.4 (4)
O3—C14—C13	118.7 (2)	C5—C4—H4A	120.8
C19—C18—C26	119.7 (3)	C3—C4—H4A	120.8
C19—C18—C17	122.6 (3)	C2—N1—C1	116.0 (4)
C26—C18—C17	117.7 (2)	C2—C3—C4	118.4 (4)
N3—C26—C18	122.0 (2)	C2—C3—H3A	120.8
N3—C26—C25	118.8 (2)	C4—C3—H3A	120.8
C18—C26—C25	119.2 (2)	N2—C9—C10	125.3 (3)
N4—C25—C21	122.2 (2)	N2—C9—H9A	117.4
N4—C25—C26	118.8 (2)	C10—C9—H9A	117.4
C21—C25—C26	119.0 (2)	N1—C2—C3	124.7 (4)
C22—C21—C25	117.9 (2)	N1—C2—H2A	117.6
C22—C21—C20	122.4 (3)	C3—C2—H2A	117.6

Symmetry code: (i) −x+1, −y+1, −z+2.

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Bis[μ3-2-(pyridin-3-yl)acetato-κ3O:O:O′]bis­[μ2-2-(pyridin-3-yl)acetato-κ2O:O′]bis­[chlorido­(1,10-phenanthroline-κ2N,N′)dysprosium(III)]

Supporting information

Key indicators

checkCIF/PLATON results

Bis[μ₃-2-(pyridin-3-yl)acetato-κ³O:O:O′]bis[μ₂-2-(pyridin-3-yl)acetato-κ²O:O′]bis[chlorido(1,10-phenanthroline-κ²N,N′)dysprosium(III)]