Crystal structure of poly[[di-μ3-acetato-tetra­aqua­bis­(μ2-cyclo­hexane-1,4-di­carboxyl­ato)dilanth­an­um(III)] dihydrate]

Drisya, R.; Mol, U.S.S.; Chandran, P.R.S.; Sithambaresan, M.; Sudarsankumar, M.R.

doi:10.1107/S2056989017016103

Crystal structure of poly[[di-μ₃-acetato-tetraaquabis(μ₂-cyclohexane-1,4-dicarboxylato)dilanthanum(III)] dihydrate]

R. Drisya, U. S. S. Mol, P. R. S. Chandran, M. Sithambaresan and M. R. Sudarsankumar

The title compound is a binuclear lanthanum(III) complex having each metal ion in decacoordination with oxygen atoms from 1,4-chdc²⁻ ligands, acetate groups and coordinated water molecules to form a distorted bicapped square antiprismatic geometry. The strong intermolecular O–H

O and weak C–H

O interactions lead to the construction of a three-dimensional supramolecular architecture.

Keywords: crystal structure; cyclohexane-1,4-dicarboxylic acid; lanthanum(III) complex.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S2056989017016103/vn2132sup1.cif Contains datablock I
	Structure factor file (CIF format) https://doi.org/10.1107/S2056989017016103/vn2132Isup2.hkl Contains datablock I

CCDC reference: 1546730

checkCIF report

Key indicators

Single-crystal X-ray study
T = 293 K
Mean (C-C) = 0.016 Å
R factor = 0.041
wR factor = 0.146
Data-to-parameter ratio = 13.8

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT342_ALERT_3_C Low Bond Precision on  C-C Bonds ...............    0.01589 Ang.

Alert level G
PLAT002_ALERT_2_G Number of Distance or Angle Restraints on AtSite          9 Note
PLAT004_ALERT_5_G Polymeric Structure Found with Maximum Dimension          2 Info
PLAT042_ALERT_1_G Calc. and Reported MoietyFormula Strings  Differ     Please Check
PLAT045_ALERT_1_G Calculated and Reported Z Differ by a Factor ...       2.00 Check
PLAT083_ALERT_2_G SHELXL Second Parameter in WGHT  Unusually Large       6.15 Why ?
PLAT154_ALERT_1_G The s.u.'s on the Cell Angles are Equal ..(Note)      0.005 Degree
PLAT171_ALERT_4_G The CIF-Embedded .res File Contains EADP Records          3 Report
PLAT172_ALERT_4_G The CIF-Embedded .res File Contains DFIX Records          6 Report
PLAT180_ALERT_4_G Check Cell Rounding: # of Values Ending with 0 =          3 Note
PLAT199_ALERT_1_G Reported _cell_measurement_temperature ..... (K)        293 Check
PLAT200_ALERT_1_G Reported   _diffrn_ambient_temperature ..... (K)        293 Check
PLAT764_ALERT_4_G Overcomplete CIF Bond List Detected (Rep/Expd) .       1.36 Ratio
PLAT790_ALERT_4_G Centre of Gravity not Within Unit Cell: Resd.  #          2 Note
              H2 O
PLAT860_ALERT_3_G Number of Least-Squares Restraints .............          9 Note
PLAT870_ALERT_4_G ALERTS Related to Twinning Effects Suppressed ..          ! Info
PLAT910_ALERT_3_G Missing # of FCF Reflection(s) Below Theta(Min).          1 Note

   0 ALERT level A = Most likely a serious problem - resolve or explain
   0 ALERT level B = A potentially serious problem, consider carefully
   1 ALERT level C = Check. Ensure it is not caused by an omission or oversight
  16 ALERT level G = General information/check it is not something unexpected

   5 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   2 ALERT type 2 Indicator that the structure model may be wrong or deficient
   3 ALERT type 3 Indicator that the structure quality may be low
   6 ALERT type 4 Improvement, methodology, query or suggestion
   1 ALERT type 5 Informative message, check

Computing details top

Data collection: APEX2 (Bruker, 2004); cell refinement: APEX2 and SAINT (Bruker, 2004); data reduction: SAINT and XPREP (Bruker, 2004); program(s) used to solve structure: SIR92 (Sheldrick, 2015); program(s) used to refine structure: SHELXL2014 (Sheldrick, 2015); molecular graphics: DIAMOND (Brandenburg, 2010); software used to prepare material for publication: SHELXL2014 (Sheldrick, 2015) and publCIF (Westrip, 2010)'.

Poly[[di-µ₃-acetato-tetraaquabis(µ₂-cyclohexane-1,4-dicarboxylato)dilanthanum(III)] dihydrate] top

Crystal data top

[La₂(C₂H₃O₂)₂(C₈H₁₀O₄)₂(H₂O)₄]·2H₂O	Z = 1
M_r = 844.32	F(000) = 416
Triclinic, P1	D_x = 1.960 Mg m⁻³
a = 6.9341 (8) Å	Mo Kα radiation, λ = 0.71073 Å
b = 8.9597 (13) Å	Cell parameters from 7100 reflections
c = 12.3030 (16) Å	θ = 2.8–30.9°
α = 110.217 (5)°	µ = 3.02 mm⁻¹
β = 91.060 (5)°	T = 293 K
γ = 93.280 (5)°	Block, colourless
V = 715.49 (16) Å³	0.20 × 0.15 × 0.15 mm

Data collection top

Bruker Kappa APEXII CCD diffractometer	2815 independent reflections
Radiation source: Sealed tube	2447 reflections with I > 2σ(I)
ω and φ scan	θ_max = 26.0°, θ_min = 2.4°
Absorption correction: multi-scan (SADABS; Bruker, 2004)	h = −8→8
T_min = 0.60, T_max = 0.74	k = −11→10
2818 measured reflections	l = 0→15

Refinement top

Refinement on F²	9 restraints
Least-squares matrix: full	Hydrogen site location: mixed
R[F² > 2σ(F²)] = 0.041	H atoms treated by a mixture of independent and constrained refinement
wR(F²) = 0.146	w = 1/[σ²(F_o²) + (0.0821P)² + 6.1459P] where P = (F_o² + 2F_c²)/3
S = 1.07	(Δ/σ)_max = 0.005
2818 reflections	Δρ_max = 2.17 e Å⁻³
204 parameters	Δρ_min = −2.46 e Å⁻³

Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refined as a two-component twin.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
C1	0.2377 (17)	0.7936 (10)	0.7752 (7)	0.0203 (18)
C2	0.2486 (18)	0.7706 (11)	0.8920 (8)	0.030 (2)
H2	0.2447	0.8760	0.9522	0.036*
C3	0.0724 (17)	0.6681 (16)	0.9058 (11)	0.033 (3)
H3A	0.0698	0.6715	0.9855	0.040*
H3B	−0.0448	0.7116	0.8889	0.040*
C4	0.0778 (17)	0.4962 (14)	0.8253 (10)	0.030 (3)
H4A	0.0694	0.4919	0.7455	0.036*
H4B	−0.0331	0.4339	0.8379	0.036*
C5	0.2631 (16)	0.4239 (11)	0.8460 (7)	0.024 (2)
H5	0.2633	0.4196	0.9245	0.028*
C6	0.4375 (16)	0.5264 (15)	0.8372 (11)	0.030 (3)
H6A	0.4468	0.5213	0.7574	0.036*
H6B	0.5526	0.4836	0.8576	0.036*
C7	0.4325 (17)	0.6994 (14)	0.9147 (10)	0.028 (2)
H7A	0.5438	0.7602	0.9010	0.034*
H7B	0.4403	0.7067	0.9952	0.034*
C8	0.2736 (16)	0.2574 (10)	0.7614 (8)	0.0229 (19)
C9	0.7522 (14)	1.0347 (9)	0.6555 (7)	0.0141 (16)
C10	0.7542 (18)	1.0729 (13)	0.7831 (8)	0.030 (2)
H10A	0.7030	1.1749	0.8194	0.046*
H10B	0.8846	1.0758	0.8118	0.046*
H10C	0.6763	0.9926	0.8006	0.046*
O1	0.3916 (11)	0.7991 (10)	0.7225 (7)	0.0280 (18)
O2	0.0804 (11)	0.8116 (10)	0.7334 (7)	0.0272 (18)
O3	−0.0144 (11)	0.6946 (10)	0.4871 (7)	0.0310 (18)
O4	0.3865 (13)	0.6914 (10)	0.4470 (8)	0.039 (2)
O5	0.5999 (10)	0.9978 (10)	0.5957 (6)	0.0219 (16)
O6	0.9100 (10)	1.0455 (9)	0.6066 (6)	0.0220 (16)
O7	0.2827 (11)	0.2366 (7)	0.6530 (5)	0.0223 (14)
O8	0.2635 (12)	0.1397 (7)	0.7932 (5)	0.0283 (15)
O9	−0.2682 (13)	0.6345 (9)	0.6499 (7)	0.0384 (18)
La1	0.23952 (8)	0.92768 (5)	0.58722 (4)	0.01486 (18)
H4C	0.474 (15)	0.704 (14)	0.398 (8)	0.05 (3)*
H4D	0.326 (16)	0.597 (8)	0.406 (8)	0.05 (3)*
H3C	−0.088 (14)	0.668 (17)	0.538 (9)	0.06 (3)*
H3D	−0.105 (12)	0.705 (17)	0.437 (9)	0.06 (3)*
H9A	−0.207 (15)	0.687 (15)	0.719 (6)	0.06 (3)*
H9B	−0.388 (9)	0.669 (17)	0.663 (10)	0.06 (3)*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
C1	0.026 (5)	0.012 (4)	0.025 (4)	−0.004 (4)	0.006 (5)	0.008 (3)
C2	0.047 (7)	0.023 (5)	0.019 (4)	0.003 (5)	−0.002 (5)	0.008 (4)
C3	0.029 (7)	0.041 (7)	0.034 (7)	0.011 (5)	0.007 (5)	0.017 (6)
C4	0.031 (7)	0.027 (6)	0.030 (6)	0.004 (5)	0.003 (4)	0.005 (5)
C5	0.030 (6)	0.026 (5)	0.016 (4)	−0.005 (4)	−0.002 (4)	0.011 (4)
C6	0.022 (6)	0.037 (7)	0.033 (6)	0.004 (5)	−0.005 (4)	0.014 (5)
C7	0.041 (8)	0.025 (6)	0.017 (5)	0.001 (5)	−0.004 (4)	0.007 (4)
C8	0.017 (5)	0.024 (5)	0.029 (5)	0.002 (4)	−0.001 (4)	0.012 (4)
C9	0.010 (4)	0.012 (3)	0.018 (4)	0.003 (4)	−0.002 (4)	0.001 (3)
C10	0.026 (6)	0.042 (6)	0.020 (4)	−0.006 (5)	0.003 (5)	0.007 (4)
O1	0.016 (4)	0.039 (5)	0.039 (5)	0.005 (3)	0.005 (3)	0.025 (4)
O2	0.026 (5)	0.031 (5)	0.028 (4)	0.004 (3)	−0.005 (3)	0.015 (4)
O3	0.026 (5)	0.035 (5)	0.034 (5)	−0.005 (3)	−0.002 (3)	0.017 (4)
O4	0.033 (5)	0.022 (4)	0.051 (5)	−0.009 (3)	0.023 (4)	−0.001 (4)
O5	0.012 (4)	0.037 (4)	0.020 (4)	−0.001 (3)	0.002 (3)	0.014 (3)
O6	0.011 (4)	0.032 (4)	0.025 (4)	−0.001 (3)	0.002 (3)	0.011 (3)
O7	0.025 (4)	0.024 (3)	0.018 (3)	0.001 (3)	0.006 (3)	0.007 (2)
O8	0.042 (4)	0.021 (3)	0.024 (3)	−0.001 (4)	−0.004 (3)	0.011 (3)
O9	0.023 (5)	0.033 (4)	0.057 (5)	0.004 (4)	0.004 (4)	0.013 (4)
La1	0.0121 (3)	0.0169 (3)	0.0169 (3)	0.0017 (2)	0.0015 (2)	0.00745 (18)

Geometric parameters (Å, º) top

C1—O2	1.240 (13)	C9—La1ⁱⁱ	3.119 (8)
C1—O1	1.266 (13)	C10—H10A	0.9600
C1—C2	1.522 (12)	C10—H10B	0.9600
C1—La1	2.952 (8)	C10—H10C	0.9600
C2—C7	1.521 (17)	O1—La1	2.570 (7)
C2—C3	1.533 (17)	O2—La1	2.601 (8)
C2—H2	0.9800	O3—La1	2.588 (8)
C3—C4	1.519 (18)	O3—H3C	0.90 (2)
C3—H3A	0.9700	O3—H3D	0.90 (2)
C3—H3B	0.9700	O4—La1	2.506 (8)
C4—C5	1.527 (16)	O4—H4C	0.90 (2)
C4—H4A	0.9700	O4—H4D	0.89 (2)
C4—H4B	0.9700	O5—La1	2.533 (7)
C5—C8	1.502 (12)	O5—La1ⁱⁱ	2.792 (7)
C5—C6	1.505 (15)	O6—La1ⁱⁱⁱ	2.552 (7)
C5—H5	0.9800	O6—La1ⁱⁱ	2.674 (7)
C6—C7	1.516 (17)	O7—La1ⁱ	2.598 (6)
C6—H6A	0.9700	O8—La1ⁱ	2.585 (6)
C6—H6B	0.9700	O9—H9A	0.90 (2)
C7—H7A	0.9700	O9—H9B	0.90 (2)
C7—H7B	0.9700	La1—O6^iv	2.552 (7)
C8—O8	1.244 (11)	La1—O8^v	2.585 (6)
C8—O7	1.284 (11)	La1—O7^v	2.598 (6)
C8—La1ⁱ	2.983 (9)	La1—O6ⁱⁱ	2.674 (7)
C9—O5	1.237 (11)	La1—O5ⁱⁱ	2.792 (7)
C9—O6	1.273 (11)	La1—C8^v	2.983 (9)
C9—C10	1.487 (11)

O2—C1—O1	120.1 (8)	C9—O6—La1ⁱⁱ	98.1 (5)
O2—C1—C2	120.4 (9)	La1ⁱⁱⁱ—O6—La1ⁱⁱ	115.2 (3)
O1—C1—C2	119.5 (10)	C8—O7—La1ⁱ	94.3 (5)
O2—C1—La1	61.6 (5)	C8—O8—La1ⁱ	96.0 (5)
O1—C1—La1	60.2 (5)	H9A—O9—H9B	101 (3)
C2—C1—La1	164.8 (6)	O4—La1—O5	73.2 (3)
C1—C2—C7	114.2 (9)	O4—La1—O6^iv	135.8 (3)
C1—C2—C3	110.9 (9)	O5—La1—O6^iv	143.4 (2)
C7—C2—C3	109.4 (8)	O4—La1—O1	77.7 (3)
C1—C2—H2	107.4	O5—La1—O1	73.8 (2)
C7—C2—H2	107.4	O6^iv—La1—O1	126.4 (2)
C3—C2—H2	107.4	O4—La1—O8^v	146.0 (3)
C4—C3—C2	111.4 (9)	O5—La1—O8^v	82.5 (3)
C4—C3—H3A	109.4	O6^iv—La1—O8^v	76.9 (2)
C2—C3—H3A	109.4	O1—La1—O8^v	72.8 (2)
C4—C3—H3B	109.4	O4—La1—O3	67.5 (3)
C2—C3—H3B	109.4	O5—La1—O3	140.7 (3)
H3A—C3—H3B	108.0	O6^iv—La1—O3	73.0 (3)
C3—C4—C5	111.4 (10)	O1—La1—O3	96.1 (3)
C3—C4—H4A	109.4	O8^v—La1—O3	131.7 (3)
C5—C4—H4A	109.4	O4—La1—O7^v	138.0 (2)
C3—C4—H4B	109.4	O5—La1—O7^v	73.7 (2)
C5—C4—H4B	109.4	O6^iv—La1—O7^v	69.9 (2)
H4A—C4—H4B	108.0	O1—La1—O7^v	116.4 (2)
C8—C5—C6	110.0 (9)	O8^v—La1—O7^v	49.88 (18)
C8—C5—C4	111.2 (9)	O3—La1—O7^v	140.6 (2)
C6—C5—C4	110.4 (8)	O4—La1—O2	103.1 (3)
C8—C5—H5	108.4	O5—La1—O2	121.8 (2)
C6—C5—H5	108.4	O6^iv—La1—O2	78.8 (2)
C4—C5—H5	108.4	O1—La1—O2	49.7 (2)
C5—C6—C7	113.4 (9)	O8^v—La1—O2	69.9 (2)
C5—C6—H6A	108.9	O3—La1—O2	67.7 (3)
C7—C6—H6A	108.9	O7^v—La1—O2	116.2 (2)
C5—C6—H6B	108.9	O4—La1—O6ⁱⁱ	83.0 (3)
C7—C6—H6B	108.9	O5—La1—O6ⁱⁱ	107.7 (2)
H6A—C6—H6B	107.7	O6^iv—La1—O6ⁱⁱ	64.8 (3)
C6—C7—C2	111.4 (9)	O1—La1—O6ⁱⁱ	159.3 (3)
C6—C7—H7A	109.3	O8^v—La1—O6ⁱⁱ	127.8 (2)
C2—C7—H7A	109.3	O3—La1—O6ⁱⁱ	69.3 (2)
C6—C7—H7B	109.3	O7^v—La1—O6ⁱⁱ	83.2 (2)
C2—C7—H7B	109.3	O2—La1—O6ⁱⁱ	129.9 (2)
H7A—C7—H7B	108.0	O4—La1—O5ⁱⁱ	68.8 (3)
O8—C8—O7	119.6 (8)	O5—La1—O5ⁱⁱ	61.3 (3)
O8—C8—C5	121.6 (8)	O6^iv—La1—O5ⁱⁱ	103.7 (2)
O7—C8—C5	118.7 (7)	O1—La1—O5ⁱⁱ	129.6 (2)
O8—C8—La1ⁱ	59.5 (5)	O8^v—La1—O5ⁱⁱ	119.3 (2)
O7—C8—La1ⁱ	60.3 (4)	O3—La1—O5ⁱⁱ	104.2 (2)
C5—C8—La1ⁱ	172.5 (8)	O7^v—La1—O5ⁱⁱ	72.9 (2)
O5—C9—O6	118.9 (7)	O2—La1—O5ⁱⁱ	170.7 (2)
O5—C9—C10	121.7 (9)	O6ⁱⁱ—La1—O5ⁱⁱ	46.51 (19)
O6—C9—C10	119.4 (9)	O4—La1—C1	93.6 (3)
O5—C9—La1ⁱⁱ	63.3 (4)	O5—La1—C1	97.2 (3)
O6—C9—La1ⁱⁱ	58.1 (4)	O6^iv—La1—C1	101.4 (3)
C10—C9—La1ⁱⁱ	161.8 (6)	O1—La1—C1	25.3 (3)
C9—C10—H10A	109.5	O8^v—La1—C1	65.9 (2)
C9—C10—H10B	109.5	O3—La1—C1	84.1 (3)
H10A—C10—H10B	109.5	O7^v—La1—C1	115.7 (2)
C9—C10—H10C	109.5	O2—La1—C1	24.8 (3)
H10A—C10—H10C	109.5	O6ⁱⁱ—La1—C1	152.5 (3)
H10B—C10—H10C	109.5	O5ⁱⁱ—La1—C1	154.8 (3)
C1—O1—La1	94.4 (6)	O4—La1—C8^v	151.3 (3)
C1—O2—La1	93.6 (6)	O5—La1—C8^v	78.0 (3)
La1—O3—H3C	113 (9)	O6^iv—La1—C8^v	70.6 (3)
La1—O3—H3D	120 (9)	O1—La1—C8^v	94.8 (3)
H3C—O3—H3D	101 (3)	O8^v—La1—C8^v	24.5 (2)
La1—O4—H4C	121 (8)	O3—La1—C8^v	141.2 (3)
La1—O4—H4D	127 (8)	O7^v—La1—C8^v	25.4 (2)
H4C—O4—H4D	102 (3)	O2—La1—C8^v	92.3 (3)
C9—O5—La1	147.1 (6)	O6ⁱⁱ—La1—C8^v	105.7 (2)
C9—O5—La1ⁱⁱ	93.4 (5)	O5ⁱⁱ—La1—C8^v	97.0 (2)
La1—O5—La1ⁱⁱ	118.7 (3)	C1—La1—C8^v	90.4 (2)
C9—O6—La1ⁱⁱⁱ	138.0 (6)

O2—C1—C2—C7	161.8 (9)	C4—C5—C8—O7	63.7 (13)
O1—C1—C2—C7	−20.4 (13)	O2—C1—O1—La1	15.4 (9)
La1—C1—C2—C7	−105 (3)	C2—C1—O1—La1	−162.5 (7)
O2—C1—C2—C3	37.7 (12)	O1—C1—O2—La1	−15.2 (9)
O1—C1—C2—C3	−144.5 (9)	C2—C1—O2—La1	162.6 (7)
La1—C1—C2—C3	131 (3)	O6—C9—O5—La1	174.3 (8)
C1—C2—C3—C4	69.6 (12)	C10—C9—O5—La1	−8.2 (16)
C7—C2—C3—C4	−57.2 (11)	La1ⁱⁱ—C9—O5—La1	−168.1 (12)
C2—C3—C4—C5	57.2 (12)	O6—C9—O5—La1ⁱⁱ	−17.7 (8)
C3—C4—C5—C8	−176.5 (9)	C10—C9—O5—La1ⁱⁱ	159.9 (7)
C3—C4—C5—C6	−54.1 (12)	O5—C9—O6—La1ⁱⁱⁱ	−124.4 (8)
C8—C5—C6—C7	176.5 (9)	C10—C9—O6—La1ⁱⁱⁱ	58.0 (12)
C4—C5—C6—C7	53.4 (11)	La1ⁱⁱ—C9—O6—La1ⁱⁱⁱ	−143.1 (9)
C5—C6—C7—C2	−55.0 (12)	O5—C9—O6—La1ⁱⁱ	18.6 (9)
C1—C2—C7—C6	−69.6 (12)	C10—C9—O6—La1ⁱⁱ	−158.9 (7)
C3—C2—C7—C6	55.3 (11)	O8—C8—O7—La1ⁱ	4.7 (11)
C6—C5—C8—O8	124.8 (11)	C5—C8—O7—La1ⁱ	−171.5 (9)
C4—C5—C8—O8	−112.5 (12)	O7—C8—O8—La1ⁱ	−4.8 (11)
C6—C5—C8—O7	−59.0 (13)	C5—C8—O8—La1ⁱ	171.4 (9)

Symmetry codes: (i) x, y−1, z; (ii) −x+1, −y+2, −z+1; (iii) x+1, y, z; (iv) x−1, y, z; (v) x, y+1, z.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
C10—H10C···O1	0.96	2.49	3.295 (14)	141
O4—H4C···O7^vi	0.90 (2)	1.92 (5)	2.771 (10)	158 (12)
O4—H4D···O9^vii	0.89 (2)	1.96 (6)	2.812 (11)	158 (12)
O3—H3C···O9	0.90 (2)	1.97 (3)	2.858 (12)	172 (13)
O3—H3D···O7^vii	0.90 (2)	1.86 (3)	2.750 (11)	170 (14)
O9—H9A···O2	0.90 (2)	2.20 (11)	2.786 (12)	122 (11)
O9—H9B···O1^iv	0.90 (2)	1.97 (5)	2.846 (11)	164 (13)

Symmetry codes: (iv) x−1, y, z; (vi) −x+1, −y+1, −z+1; (vii) −x, −y+1, −z+1.

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Crystal structure of poly[[di-μ3-acetato-tetra­aqua­bis­(μ2-cyclo­hexane-1,4-di­carboxyl­ato)dilanth­an­um(III)] dihydrate]

Supporting information

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Crystal structure of poly[[di-μ₃-acetato-tetraaquabis(μ₂-cyclohexane-1,4-dicarboxylato)dilanthanum(III)] dihydrate]