Synthesis and crystal structure of a new coordination polymer based on lanthanum and 1,4-phenyl­enedi­acetate ligands

Camara, M.; Badiane, I.; Diallo, M.; Daiguebonne, C.; Guillou, O.

doi:10.1107/S2056989019002378

Synthesis and crystal structure of a new coordination polymer based on lanthanum and 1,4-phenylenediacetate ligands

M. Camara, I. Badiane, M. Diallo, C. Daiguebonne and O. Guillou

The crystalline structure of a new three-dimensional coordination polymer based on La^III and 1,4-phenylenediacetate ligands is described.

Keywords: lanthanum ion; coordination polymer; crystal structure.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S2056989019002378/vn2143sup1.cif Contains datablocks global, I
	Structure factor file (CIF format) https://doi.org/10.1107/S2056989019002378/vn2143Isup2.hkl Contains datablock I
	Portable Document Format (PDF) file https://doi.org/10.1107/S2056989019002378/vn2143sup3.pdf Table 2. Valence angles and torsion angles around the ligands

CCDC reference: 1875083

checkCIF report

Key indicators

Single-crystal X-ray study
T = 293 K
Mean (C-C) = 0.006 Å
R factor = 0.030
wR factor = 0.068
Data-to-parameter ratio = 16.2

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT260_ALERT_2_B Large Average Ueq of Residue Including       Ow4      0.154 Check
PLAT417_ALERT_2_B Short Inter D-H..H-D       Hw1A     ..Hw1A     .       1.91 Ang.
                                                 1-x,-y,1-z  =      2_656 Check
PLAT417_ALERT_2_B Short Inter D-H..H-D       Hw2B     ..Hw4A     .       1.90 Ang.
                                                    x,y,1+z  =      1_556 Check

Alert level C
PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density ....       2.72 Report
PLAT230_ALERT_2_C Hirshfeld Test Diff for    O2       --C1       .        5.5 s.u.
PLAT241_ALERT_2_C High   'MainMol' Ueq as Compared to Neighbors of         O4 Check
PLAT242_ALERT_2_C Low    'MainMol' Ueq as Compared to Neighbors of        La1 Check
PLAT260_ALERT_2_C Large Average Ueq of Residue Including       Ow1      0.133 Check
PLAT260_ALERT_2_C Large Average Ueq of Residue Including       Ow3      0.133 Check
PLAT417_ALERT_2_C Short Inter D-H..H-D       Hw1B     ..Hw3B     .       2.11 Ang.
                                                 1-x,-y,1-z  =      2_656 Check
PLAT906_ALERT_3_C Large K Value in the Analysis of Variance ......      2.165 Check
PLAT910_ALERT_3_C Missing # of FCF Reflection(s) Below Theta(Min).         10 Note
PLAT911_ALERT_3_C Missing FCF Refl Between Thmin & STh/L=    0.600          2 Report
PLAT971_ALERT_2_C Check Calcd Resid. Dens.  1.30A   From O4              1.83 eA-3
PLAT971_ALERT_2_C Check Calcd Resid. Dens.  1.33A   From O6              1.75 eA-3
PLAT976_ALERT_2_C Check Calcd Resid. Dens.  0.85A   From Ow3            -0.49 eA-3
PLAT976_ALERT_2_C Check Calcd Resid. Dens.  0.76A   From Ow3            -0.42 eA-3
PLAT978_ALERT_2_C Number C-C Bonds with Positive Residual Density.          0 Info

Alert level G
PLAT004_ALERT_5_G Polymeric Structure Found with Maximum Dimension          3 Info
PLAT005_ALERT_5_G No Embedded Refinement Details Found  in the CIF     Please Do !
PLAT042_ALERT_1_G Calc. and Reported MoietyFormula Strings  Differ     Please Check
PLAT045_ALERT_1_G Calculated and Reported Z Differ by a Factor ...       2.00 Check
PLAT154_ALERT_1_G The s.u.'s on the Cell Angles are Equal ..(Note)      0.001 Degree
PLAT199_ALERT_1_G Reported _cell_measurement_temperature ..... (K)        293 Check
PLAT200_ALERT_1_G Reported   _diffrn_ambient_temperature ..... (K)        293 Check
PLAT232_ALERT_2_G Hirshfeld Test Diff (M-X)  La1      --O1       .        7.1 s.u.
PLAT232_ALERT_2_G Hirshfeld Test Diff (M-X)  La1      --O5_b     .       14.0 s.u.
PLAT232_ALERT_2_G Hirshfeld Test Diff (M-X)  La1      --O3_c     .        8.0 s.u.
PLAT720_ALERT_4_G Number of Unusual/Non-Standard Labels ..........         12 Note
PLAT794_ALERT_5_G Tentative Bond Valency for La1       (III)     .       3.11 Info
PLAT860_ALERT_3_G Number of Least-Squares Restraints .............         18 Note
PLAT912_ALERT_4_G Missing # of FCF Reflections Above STh/L=  0.600          6 Note

   0 ALERT level A = Most likely a serious problem - resolve or explain
   3 ALERT level B = A potentially serious problem, consider carefully
  15 ALERT level C = Check. Ensure it is not caused by an omission or oversight
  14 ALERT level G = General information/check it is not something unexpected

   5 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  18 ALERT type 2 Indicator that the structure model may be wrong or deficient
   4 ALERT type 3 Indicator that the structure quality may be low
   2 ALERT type 4 Improvement, methodology, query or suggestion
   3 ALERT type 5 Informative message, check

Computing details top

Data collection: COLLECT (Bruker, 2004); cell refinement: SCALEPACK (Otwinowski & Minor, 1997); data reduction: DENZO and SCALEPACK (Otwinowski & Minor, 1997); program(s) used to solve structure: SHELXT (Sheldrick, 2015a); program(s) used to refine structure: SHELXL (Sheldrick, 2015b); molecular graphics: DIAMOND (Brandenburg, 2001); software used to prepare material for publication: WinGX (Farrugia, 2012).

Poly[[tetraaquatris(µ-1,4-phenylenediacetato)dilanthanum(III)] octahydrate] top

Crystal data top

[La₂(C₁₀H₈O₄)₃(H₂O)₄]·8H₂O	Z = 1
M_r = 1070.05	F(000) = 534
Triclinic, P1	D_x = 1.768 Mg m⁻³
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 9.1197 (2) Å	Cell parameters from 15558 reflections
b = 11.1231 (2) Å	θ = 2.9–27.5°
c = 11.9434 (2) Å	µ = 2.18 mm⁻¹
α = 107.049 (1)°	T = 293 K
β = 107.729 (1)°	Prism, colorless
γ = 106.622 (1)°	0.08 × 0.06 × 0.05 mm
V = 1005.21 (3) Å³

Data collection top

Nonius KappaCCD diffractometer	3751 reflections with I > 2σ(I)
Radiation source: Enraf Nonius FR590	R_int = 0.045
Horizonally mounted graphite crystal monochromator	θ_max = 27.5°, θ_min = 3.6°
Detector resolution: 9 pixels mm^-1	h = −10→11
CCD rotation images, thick slices scans	k = −14→14
4588 measured reflections	l = −15→15
4588 independent reflections

Refinement top

Refinement on F²	Primary atom site location: dual
Least-squares matrix: full	Secondary atom site location: dual
R[F² > 2σ(F²)] = 0.030	Hydrogen site location: mixed
wR(F²) = 0.068	H atoms treated by a mixture of independent and constrained refinement
S = 1.03	w = 1/[σ²(F_o²) + (0.0308P)²] where P = (F_o² + 2F_c²)/3
4588 reflections	(Δ/σ)_max = 0.001
283 parameters	Δρ_max = 1.76 e Å⁻³
18 restraints	Δρ_min = −0.65 e Å⁻³
0 constraints

Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
La1	0.75090 (2)	0.52031 (2)	0.47969 (2)	0.02048 (7)
O5	0.4472 (3)	0.3677 (2)	0.4069 (2)	0.0332 (6)
O3	1.0575 (3)	0.5881 (3)	0.6253 (2)	0.0323 (6)
O1	0.7627 (3)	0.3041 (3)	0.5311 (2)	0.0336 (6)
O6	0.8146 (3)	0.7579 (3)	0.6435 (3)	0.0362 (6)
O2	0.7422 (3)	0.4674 (3)	0.6736 (2)	0.0351 (6)
O4	0.6840 (3)	0.3616 (3)	0.2490 (2)	0.0415 (7)
O7	0.5690 (4)	0.5882 (4)	0.3233 (3)	0.0486 (8)
H7A	0.468 (3)	0.558 (4)	0.307 (5)	0.058*
H7B	0.591 (5)	0.651 (4)	0.302 (5)	0.058*
O8	0.9316 (4)	0.7051 (3)	0.4326 (4)	0.0503 (8)
H8A	0.947 (6)	0.785 (3)	0.470 (4)	0.060*
H8B	1.026 (4)	0.712 (4)	0.435 (5)	0.060*
C6	0.6834 (4)	0.7426 (3)	0.6621 (3)	0.0260 (7)
C11	0.8165 (4)	0.3436 (3)	0.2659 (3)	0.0261 (7)
C1	0.7640 (4)	0.3589 (4)	0.6405 (4)	0.0315 (8)
C13	0.6579 (5)	0.1147 (4)	0.0739 (4)	0.0340 (9)
C12	0.8247 (5)	0.2382 (4)	0.1565 (4)	0.0390 (9)
H12A	0.857342	0.281262	0.102898	0.058*
H12B	0.910563	0.207990	0.192279	0.058*
C14	0.6017 (5)	0.0190 (4)	0.1196 (4)	0.0427 (10)
H14	0.669560	0.030195	0.201149	0.051*
C8	0.8472 (5)	0.9325 (4)	0.8881 (4)	0.0340 (9)
C10	0.9564 (5)	1.0646 (4)	0.9217 (4)	0.0433 (10)
H10	0.928413	1.109955	0.869797	0.052*
C15	0.5547 (5)	0.0946 (4)	−0.0469 (4)	0.0412 (10)
H15	0.589046	0.157191	−0.080797	0.049*
C7	0.6832 (5)	0.8578 (4)	0.7675 (4)	0.0445 (11)
H7C	0.660724	0.923722	0.734480	0.067*
H7D	0.592152	0.819798	0.789973	0.067*
C9	0.8927 (6)	0.8687 (4)	0.9685 (4)	0.0461 (11)
H9	0.820475	0.779508	0.948162	0.055*
C3	0.8997 (5)	0.3972 (4)	0.8732 (4)	0.0392 (9)
C4	1.0738 (6)	0.4427 (5)	0.9267 (4)	0.0514 (11)
H4	1.125405	0.405378	0.878263	0.062*
C5	0.8281 (6)	0.4561 (5)	0.9477 (4)	0.0501 (11)
H5	0.711419	0.427472	0.913133	0.060*
C2	0.7931 (6)	0.2928 (4)	0.7347 (4)	0.0460 (10)
H2A	0.684726	0.235879	0.727251	0.069*
H2B	0.848359	0.233001	0.711571	0.069*
OW1	0.6313 (10)	0.0072 (5)	0.4440 (6)	0.1327 (17)
HW1A	0.589 (11)	−0.025 (9)	0.491 (8)	0.159*
HW1B	0.639 (13)	−0.072 (6)	0.411 (8)	0.159*
OW2	0.5351 (5)	0.6185 (4)	0.9718 (4)	0.0741 (11)
HW2A	0.476 (7)	0.639 (6)	0.920 (5)	0.111*
HW2B	0.622 (6)	0.678 (5)	1.033 (5)	0.111*
OW3	0.0357 (9)	0.0056 (6)	0.3870 (6)	0.1327 (17)
HW3A	0.059 (10)	0.059 (7)	0.354 (7)	0.159*
HW3B	0.122 (7)	0.023 (10)	0.447 (6)	0.159*
OW4	0.7105 (10)	0.7873 (7)	0.2433 (6)	0.154 (3)
HW4A	0.649 (10)	0.805 (11)	0.192 (8)	0.185*
HW4B	0.810 (5)	0.831 (11)	0.255 (10)	0.185*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
La1	0.01729 (10)	0.02001 (10)	0.01850 (10)	0.00633 (7)	0.00482 (7)	0.00498 (7)
O5	0.0242 (13)	0.0258 (13)	0.0312 (13)	0.0032 (10)	0.0034 (11)	0.0040 (11)
O3	0.0227 (13)	0.0340 (14)	0.0229 (12)	0.0074 (11)	0.0027 (10)	0.0011 (11)
O1	0.0352 (14)	0.0353 (14)	0.0339 (14)	0.0161 (12)	0.0168 (12)	0.0155 (12)
O6	0.0247 (13)	0.0283 (13)	0.0415 (15)	0.0089 (10)	0.0129 (12)	−0.0005 (11)
O2	0.0403 (15)	0.0427 (15)	0.0332 (14)	0.0254 (13)	0.0173 (12)	0.0200 (12)
O4	0.0267 (14)	0.0515 (17)	0.0253 (13)	0.0175 (12)	0.0040 (11)	−0.0052 (12)
O7	0.0425 (17)	0.075 (2)	0.067 (2)	0.0390 (17)	0.0345 (17)	0.0532 (18)
O8	0.0456 (18)	0.0523 (18)	0.088 (2)	0.0315 (16)	0.0434 (18)	0.0469 (19)
C6	0.0228 (17)	0.0219 (17)	0.0260 (17)	0.0100 (14)	0.0051 (14)	0.0052 (14)
C11	0.0187 (16)	0.0250 (17)	0.0236 (16)	0.0060 (13)	0.0062 (14)	0.0018 (14)
C1	0.0184 (17)	0.041 (2)	0.0332 (19)	0.0099 (15)	0.0083 (15)	0.0177 (17)
C13	0.0261 (19)	0.030 (2)	0.0297 (19)	0.0117 (16)	0.0070 (16)	−0.0041 (16)
C12	0.0233 (18)	0.040 (2)	0.0318 (19)	0.0098 (16)	0.0074 (16)	−0.0057 (17)
C14	0.039 (2)	0.044 (2)	0.028 (2)	0.0198 (19)	0.0002 (18)	0.0047 (18)
C8	0.031 (2)	0.0293 (19)	0.0290 (19)	0.0102 (16)	0.0138 (16)	−0.0032 (16)
C10	0.042 (2)	0.033 (2)	0.037 (2)	0.0058 (18)	0.0114 (19)	0.0059 (18)
C15	0.043 (2)	0.037 (2)	0.031 (2)	0.0133 (19)	0.0076 (18)	0.0078 (17)
C7	0.026 (2)	0.040 (2)	0.043 (2)	0.0127 (17)	0.0102 (18)	−0.0078 (19)
C9	0.042 (2)	0.0225 (19)	0.048 (2)	−0.0033 (17)	0.016 (2)	0.0006 (18)
C3	0.043 (2)	0.044 (2)	0.035 (2)	0.0206 (19)	0.0123 (18)	0.0260 (18)
C4	0.051 (3)	0.073 (3)	0.041 (2)	0.037 (2)	0.022 (2)	0.023 (2)
C5	0.032 (2)	0.077 (3)	0.042 (2)	0.024 (2)	0.0112 (19)	0.027 (2)
C2	0.055 (3)	0.040 (2)	0.039 (2)	0.017 (2)	0.012 (2)	0.0233 (19)
OW1	0.192 (4)	0.069 (2)	0.109 (3)	0.009 (3)	0.079 (3)	0.028 (2)
OW2	0.063 (3)	0.086 (3)	0.074 (3)	0.032 (2)	0.020 (2)	0.043 (2)
OW3	0.192 (4)	0.069 (2)	0.109 (3)	0.009 (3)	0.079 (3)	0.028 (2)
OW4	0.158 (6)	0.115 (4)	0.103 (4)	−0.017 (4)	−0.019 (4)	0.084 (4)

Geometric parameters (Å, º) top

La1—O5	2.507 (2)	C12—H12B	0.9700
La1—O5ⁱ	2.905 (3)	C14—H14	0.9300
La1—O3ⁱⁱ	2.781 (2)	C14—C15ⁱⁱⁱ	1.399 (6)
La1—O3	2.545 (2)	C8—C10	1.373 (6)
La1—O1	2.673 (2)	C8—C7	1.509 (5)
La1—O6	2.559 (2)	C8—C9	1.388 (6)
La1—O2	2.569 (2)	C10—H10	0.9300
La1—O4	2.566 (2)	C10—C9^iv	1.382 (6)
La1—O7	2.543 (3)	C15—H15	0.9300
La1—O8	2.562 (3)	C7—H7C	0.9700
La1—C11	3.066 (3)	C7—H7D	0.9700
La1—C1	2.988 (4)	C9—H9	0.9300
O5—C6ⁱ	1.255 (4)	C3—C4	1.385 (6)
O3—C11ⁱⁱ	1.264 (4)	C3—C5	1.381 (6)
O1—C1	1.264 (4)	C3—C2	1.509 (6)
O6—C6	1.256 (4)	C4—H4	0.9300
O2—C1	1.248 (4)	C4—C5^v	1.391 (6)
O4—C11	1.246 (4)	C5—H5	0.9300
O7—H7A	0.824 (19)	C2—H2A	0.9700
O7—H7B	0.806 (18)	C2—H2B	0.9700
O8—H8A	0.815 (19)	OW1—HW1A	0.87 (2)
O8—H8B	0.833 (19)	OW1—HW1B	0.88 (2)
C6—C7	1.512 (5)	OW2—HW2A	0.821 (19)
C11—C12	1.516 (5)	OW2—HW2B	0.81 (2)
C1—C2	1.514 (5)	OW3—HW3A	0.82 (2)
C13—C12	1.507 (5)	OW3—HW3B	0.81 (2)
C13—C14	1.376 (6)	OW4—HW4A	0.81 (2)
C13—C15	1.371 (5)	OW4—HW4B	0.84 (2)
C12—H12A	0.9700

O5—La1—O5ⁱ	61.48 (9)	C11—O4—La1	101.3 (2)
O5—La1—O3	146.45 (9)	La1—O7—H7A	116 (3)
O5—La1—O3ⁱⁱ	118.58 (7)	La1—O7—H7B	133 (3)
O5—La1—O1	75.87 (8)	H7A—O7—H7B	109 (3)
O5—La1—O6	107.86 (8)	La1—O8—H8A	118 (3)
O5—La1—O2	75.29 (8)	La1—O8—H8B	122 (3)
O5—La1—O4	80.33 (8)	H8A—O8—H8B	104 (3)
O5—La1—O7	71.93 (9)	O5ⁱ—C6—La1	68.28 (18)
O5—La1—O8	140.13 (9)	O5ⁱ—C6—O6	120.2 (3)
O5ⁱ—La1—C11	156.28 (8)	O5ⁱ—C6—C7	120.1 (3)
O5—La1—C11	98.48 (8)	O6—C6—La1	52.33 (16)
O5—La1—C1	75.84 (9)	O6—C6—C7	119.7 (3)
O5ⁱ—La1—C1	88.69 (9)	C7—C6—La1	169.6 (2)
O3—La1—O5ⁱ	118.22 (7)	O3ⁱⁱ—C11—La1	65.08 (17)
O3ⁱⁱ—La1—O5ⁱ	179.00 (7)	O3ⁱⁱ—C11—C12	120.3 (3)
O3—La1—O3ⁱⁱ	61.11 (8)	O4—C11—La1	55.16 (17)
O3—La1—O1	73.20 (8)	O4—C11—O3ⁱⁱ	119.9 (3)
O3—La1—O6	80.93 (8)	O4—C11—C12	119.8 (3)
O3—La1—O2	74.87 (8)	C12—C11—La1	171.2 (2)
O3—La1—O4	108.82 (8)	O1—C1—La1	63.39 (19)
O3—La1—O8	73.39 (9)	O1—C1—C2	119.8 (3)
O3ⁱⁱ—La1—C11	24.36 (8)	O2—C1—La1	58.58 (18)
O3—La1—C11	85.47 (8)	O2—C1—O1	121.5 (3)
O3—La1—C1	70.64 (9)	O2—C1—C2	118.7 (3)
O3ⁱⁱ—La1—C1	90.37 (9)	C2—C1—La1	172.4 (3)
O1—La1—O5ⁱ	109.68 (7)	C14—C13—C12	120.5 (4)
O1—La1—O3ⁱⁱ	69.49 (8)	C15—C13—C12	122.1 (4)
O1—La1—C11	74.29 (9)	C15—C13—C14	117.4 (4)
O1—La1—C1	25.01 (9)	C11—C12—H12A	109.2
O6—La1—O5ⁱ	46.41 (7)	C11—C12—H12B	109.2
O6—La1—O3ⁱⁱ	133.56 (8)	C13—C12—C11	112.0 (3)
O6—La1—O1	126.21 (9)	C13—C12—H12A	109.2
O6—La1—O2	78.86 (9)	C13—C12—H12B	109.2
O6—La1—O4	149.49 (10)	H12A—C12—H12B	107.9
O6—La1—O8	71.55 (10)	C13—C14—H14	119.1
O6—La1—C11	149.62 (9)	C13—C14—C15ⁱⁱⁱ	121.8 (4)
O6—La1—C1	101.90 (10)	C15ⁱⁱⁱ—C14—H14	119.1
O2—La1—O5ⁱ	66.57 (8)	C10—C8—C7	121.6 (4)
O2—La1—O3ⁱⁱ	112.44 (8)	C10—C8—C9	117.8 (4)
O2—La1—O1	49.39 (8)	C9—C8—C7	120.6 (4)
O2—La1—C11	123.42 (9)	C8—C10—H10	119.5
O2—La1—C1	24.50 (9)	C8—C10—C9^iv	121.1 (4)
O4—La1—O5ⁱ	132.95 (7)	C9^iv—C10—H10	119.5
O4—La1—O3ⁱⁱ	47.75 (7)	C13—C15—C14ⁱⁱⁱ	120.7 (4)
O4—La1—O1	84.13 (9)	C13—C15—H15	119.6
O4—La1—O2	131.27 (9)	C14ⁱⁱⁱ—C15—H15	119.6
O4—La1—C11	23.49 (8)	C6—C7—H7C	108.9
O4—La1—C1	108.61 (10)	C6—C7—H7D	108.9
O7—La1—O5ⁱ	70.81 (9)	C8—C7—C6	113.4 (3)
O7—La1—O3	141.53 (10)	C8—C7—H7C	108.9
O7—La1—O3ⁱⁱ	110.19 (9)	C8—C7—H7D	108.9
O7—La1—O1	142.43 (10)	H7C—C7—H7D	107.7
O7—La1—O6	82.59 (10)	C8—C9—H9	119.4
O7—La1—O2	134.87 (9)	C10^iv—C9—C8	121.1 (4)
O7—La1—O4	71.95 (10)	C10^iv—C9—H9	119.4
O7—La1—O8	68.46 (10)	C4—C3—C2	120.7 (4)
O7—La1—C11	91.69 (10)	C5—C3—C4	118.0 (4)
O7—La1—C1	147.21 (10)	C5—C3—C2	121.2 (4)
O8—La1—O5ⁱ	108.04 (8)	C3—C4—H4	119.8
O8—La1—O3ⁱⁱ	72.59 (9)	C3—C4—C5^v	120.4 (4)
O8—La1—O1	138.11 (8)	C5^v—C4—H4	119.8
O8—La1—O2	139.28 (10)	C3—C5—C4^v	121.6 (4)
O8—La1—O4	83.41 (11)	C3—C5—H5	119.2
O8—La1—C11	78.57 (10)	C4^v—C5—H5	119.2
O8—La1—C1	144.03 (10)	C1—C2—H2A	109.0
C1—La1—C11	98.95 (10)	C1—C2—H2B	109.0
La1—O5—La1ⁱ	118.52 (9)	C3—C2—C1	112.8 (3)
C6ⁱ—O5—La1ⁱ	88.1 (2)	C3—C2—H2A	109.0
C6ⁱ—O5—La1	153.4 (2)	C3—C2—H2B	109.0
La1—O3—La1ⁱⁱ	118.89 (8)	H2A—C2—H2B	107.8
C11ⁱⁱ—O3—La1	150.5 (2)	HW1A—OW1—HW1B	88 (7)
C11ⁱⁱ—O3—La1ⁱⁱ	90.56 (19)	HW2A—OW2—HW2B	121 (5)
C1—O1—La1	91.6 (2)	HW3A—OW3—HW3B	108 (4)
C6—O6—La1	104.8 (2)	HW4A—OW4—HW4B	107 (4)
C1—O2—La1	96.9 (2)

Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) −x+2, −y+1, −z+1; (iii) −x+1, −y, −z; (iv) −x+2, −y+2, −z+2; (v) −x+2, −y+1, −z+2.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
OW1—HW1A···OW1^vi	0.87 (9)	2.40 (11)	3.067 (13)	133 (9)
OW1—HW1B···OW4^vii	0.89 (9)	2.54 (10)	3.298 (11)	145 (7)
OW2—HW2A···O4ⁱ	0.82 (6)	2.10 (6)	2.895 (5)	164 (6)
OW2—HW2B···OW4^viii	0.82 (6)	2.20 (5)	2.855 (8)	137 (5)
OW3—HW3A···O6ⁱ	0.82 (8)	2.02 (8)	2.780 (8)	154 (7)
OW3—HW3B···OW1^vi	0.81 (7)	2.40 (8)	3.162 (11)	156 (8)
OW4—HW4A···OW2^ix	0.81 (10)	2.49 (9)	2.855 (8)	109 (9)
O7—H7A···O2ⁱ	0.82 (4)	1.95 (4)	2.741 (5)	161 (5)
O7—H7B···OW4	0.81 (5)	2.03 (5)	2.800 (9)	160 (5)
OW4—HW4B···OW3^x	0.84 (9)	2.11 (10)	2.824 (11)	143 (8)
O8—H8A···OW3ⁱ	0.82 (4)	2.38 (4)	3.175 (8)	165 (4)
O8—H8B···O1ⁱⁱ	0.83 (4)	1.92 (4)	2.725 (5)	163 (5)
C7—H7D···O4ⁱ	0.97	2.54	3.442 (6)	154
C12—H12B···O6ⁱⁱ	0.97	2.51	3.406 (6)	154

Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) −x+2, −y+1, −z+1; (vi) −x+1, −y, −z+1; (vii) x, y−1, z; (viii) x, y, z+1; (ix) x, y, z−1; (x) x+1, y+1, z.

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Synthesis and crystal structure of a new coordination polymer based on lanthanum and 1,4-phenyl­enedi­acetate ligands

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Synthesis and crystal structure of a new coordination polymer based on lanthanum and 1,4-phenylenediacetate ligands