Bis(μ-cobaltoceniumseleno­late-1:2κ²Se:Se)bis[bis­(cobaltoceniumseleno­late-κSe)mercury(II)] tetra­kis­(hexa­fluorido­phosphate) aceto­nitrile disolvate

The title compound, [Co₆Hg₂(C₅H₅)₆(C₅H₄Se)₆](PF₆)₄·2CH₃CN or [Hg₂(CcSe)₆][PF₆]₄·2CH₃CN (Cc = C₁₀H₉Co), was obtained as bright-orange needle-shaped crystals. It is a salt containing a tetra­cationic dimercury species with six cobaltoceniumseleno­late ligands, four hexa­fluorido­phosphate counter-ions and two aceto­nitrile solvent mol­ecules. The cation (point group ) has a bi­tetra­hedral {Hg₂Se₆} core with two bridging Se atoms and four terminal Se atoms.

Key indicators

• Single-crystal X-ray study
• T = 183 K
• Mean [sigma](C-C) = 0.005 Å
• Disorder in solvent or counterion
• R factor = 0.017
• wR factor = 0.042
• Data-to-parameter ratio = 13.6

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT232_ALERT_2_B Hirshfeld Test Diff (M-X)  Hg1      --Se2      .       28.4 s.u.
PLAT232_ALERT_2_B Hirshfeld Test Diff (M-X)  Hg1      --Se2_a    .       30.3 s.u.

Alert level C
PLAT241_ALERT_2_C High   'MainMol' Ueq as Compared to Neighbors of         C4 Check
PLAT241_ALERT_2_C High   'MainMol' Ueq as Compared to Neighbors of        C24 Check
PLAT241_ALERT_2_C High   'MainMol' Ueq as Compared to Neighbors of        C25 Check
PLAT242_ALERT_2_C Low    'MainMol' Ueq as Compared to Neighbors of        Co1 Check
PLAT242_ALERT_2_C Low    'MainMol' Ueq as Compared to Neighbors of        Co2 Check
PLAT242_ALERT_2_C Low    'MainMol' Ueq as Compared to Neighbors of        Co3 Check
PLAT250_ALERT_2_C Large U3/U1 Ratio for Average U(i,j) Tensor ....        2.1 Note
PLAT250_ALERT_2_C Large U3/U1 Ratio for Average U(i,j) Tensor ....        2.2 Note
PLAT260_ALERT_2_C Large Average Ueq of Residue Including        P2      0.110 Check

Alert level G
PLAT042_ALERT_1_G Calc. and Reported Moiety Formula Strings Differ     Please Check
PLAT231_ALERT_4_G Hirshfeld Test (Solvent)   P2       --F9       .        5.5 s.u.
PLAT232_ALERT_2_G Hirshfeld Test Diff (M-X)  Hg1      --Se1      .        8.5 s.u.
PLAT244_ALERT_4_G Low    'Solvent' Ueq as Compared to Neighbors of         P2 Check
PLAT244_ALERT_4_G Low    'Solvent' Ueq as Compared to Neighbors of         P1 Check
PLAT300_ALERT_4_G Atom Site Occupancy of F7         Constrained at       0.67 Check
PLAT300_ALERT_4_G Atom Site Occupancy of F8         Constrained at       0.67 Check
PLAT300_ALERT_4_G Atom Site Occupancy of F9         Constrained at       0.67 Check
PLAT300_ALERT_4_G Atom Site Occupancy of F10        Constrained at       0.67 Check
PLAT300_ALERT_4_G Atom Site Occupancy of F7A        Constrained at       0.33 Check
PLAT300_ALERT_4_G Atom Site Occupancy of F8A        Constrained at       0.33 Check
PLAT300_ALERT_4_G Atom Site Occupancy of F9A        Constrained at       0.33 Check
PLAT300_ALERT_4_G Atom Site Occupancy of F10A       Constrained at       0.33 Check
PLAT300_ALERT_4_G Atom Site Occupancy of N1A        Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of C31A       Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of C32A       Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H32D       Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H32E       Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H32F       Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of N1         Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of C31        Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of C32        Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H32A       Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H32B       Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H32C       Constrained at        0.5 Check
PLAT302_ALERT_4_G Anion/Solvent/Minor-Residue Disorder (Resd  2  )        57% Note
PLAT302_ALERT_4_G Anion/Solvent/Minor-Residue Disorder (Resd  4  )       100% Note
PLAT302_ALERT_4_G Anion/Solvent/Minor-Residue Disorder (Resd  5  )       100% Note
PLAT432_ALERT_2_G Short Inter X...Y Contact  C1       ..C23              3.06 Ang.
                                                   x,-1+y,z  =      1_545 Check
PLAT790_ALERT_4_G Centre of Gravity not Within Unit Cell: Resd.  #          5 Note
              C2 H3 N
PLAT794_ALERT_5_G Tentative Bond Valency for Co1       (III)     .       3.44 Info
PLAT794_ALERT_5_G Tentative Bond Valency for Co2       (III)     .       3.40 Info
PLAT794_ALERT_5_G Tentative Bond Valency for Co3       (III)     .       3.46 Info
PLAT910_ALERT_3_G Missing # of FCF Reflection(s) Below Theta(Min).          4 Note
PLAT913_ALERT_3_G Missing # of Very Strong Reflections in FCF ....          1 Note
PLAT933_ALERT_2_G Number of OMIT Records in Embedded .res File ...          1 Note
PLAT978_ALERT_2_G Number C-C Bonds with Positive Residual Density.          3 Info

   0 ALERT level A = Most likely a serious problem - resolve or explain
   2 ALERT level B = A potentially serious problem, consider carefully
   9 ALERT level C = Check. Ensure it is not caused by an omission or oversight
  37 ALERT level G = General information/check it is not something unexpected

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  15 ALERT type 2 Indicator that the structure model may be wrong or deficient
   2 ALERT type 3 Indicator that the structure quality may be low
  27 ALERT type 4 Improvement, methodology, query or suggestion
   3 ALERT type 5 Informative message, check

---

Computing details

Data collection: APEX2 (Bruker, 2014); cell refinement: SAINT (Bruker, 2014); data reduction: SAINT (Bruker, 2014); program(s) used to solve structure: SHELXT (Sheldrick, 2015a); program(s) used to refine structure: SHELXL (Sheldrick, 2015b); molecular graphics: OLEX2 (Dolomanov et al., 2009); software used to prepare material for publication: publCIF (Westrip, 2010).

Bis(µ-cobaltoceniumselenolate-1:2κ²Se:Se)bis[bis(cobaltoceniumselenolate-κSe)mercury(II)] tetrakis(hexafluoridophosphate) acetonitrile disolvate

Crystal data

[Co6Hg2(C5H5)6(C5H4Se)6](PF6)4·2C2H3N	Z = 1
Mr = 2665.54	F(000) = 1260
Triclinic, P1	Dx = 2.306 Mg m^−3
a = 10.2933 (8) Å	Mo Kα radiation, λ = 0.71073 Å
b = 14.3271 (12) Å	Cell parameters from 9672 reflections
c = 15.1087 (12) Å	θ = 2.3–26.4°
α = 109.744 (3)°	µ = 8.28 mm^−1
β = 109.764 (2)°	T = 183 K
γ = 95.306 (3)°	Prism, orange
V = 1919.1 (3) Å^3	0.18 × 0.09 × 0.04 mm

Data collection

Bruker D8 QUEST PHOTON 100 diffractometer	7546 independent reflections
Radiation source: Incoatec Microfocus	7005 reflections with I > 2σ(I)
Multi layered optics monochromator	Rint = 0.038
Detector resolution: 10.4 pixels mm^-1	θmax = 26.0°, θmin = 2.2°
φ and ω scans	h = −12→12
Absorption correction: multi-scan (SADABS; Krause et al., 2015)	k = −17→17
Tmin = 0.574, Tmax = 0.837	l = −18→18
69321 measured reflections

Refinement

Refinement on F^2	Hydrogen site location: inferred from neighbouring sites
Least-squares matrix: full	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.017	w = 1/[σ^2(Fo^2) + (0.0197P)^2 + 1.8079P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.042	(Δ/σ)max = 0.003
S = 1.04	Δρmax = 0.77 e Å^−3
7546 reflections	Δρmin = −0.80 e Å^−3
553 parameters	Extinction correction: SHELXL2014/7 (Sheldrick, 2015b), Fc^*=kFc[1+0.001xFc^2λ^3/sin(2θ)]^-1/4
0 restraints	Extinction coefficient: 0.00230 (10)
Primary atom site location: structure-invariant direct methods

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. C-bound hydrogen atoms were placed in calculated positions and constrained to ride on their parent atoms with U_iso(H) = 1.2U_eq(C) and a C—H distance of 0.95 Å for aromatic H atoms. Positinal disorder of same flourine atoms at P2 in ratio 2:1 for F7-F10 : F7a-F10a and for solvent acetonitrile C32-C31-N1 : C32a-C31a-N1a in ratio 1:1, respectively.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Hg1	0.31028 (2)	0.47867 (2)	0.51180 (2)	0.02781 (4)
Se1	0.32480 (3)	0.45328 (2)	0.67355 (2)	0.02603 (6)
Se2	0.40933 (3)	0.35008 (2)	0.39551 (2)	0.02572 (6)
Se3	0.13272 (3)	0.56435 (2)	0.42414 (2)	0.02556 (6)
Co1	0.51168 (3)	0.26149 (2)	0.69145 (3)	0.02302 (8)
Co2	0.21259 (4)	0.23319 (2)	0.12527 (3)	0.02438 (8)
Co3	0.18455 (3)	0.79863 (2)	0.63293 (3)	0.02143 (7)
C1	0.4091 (3)	0.1559 (2)	0.7209 (3)	0.0462 (8)
H1	0.4018	0.1660	0.7843	0.055*
C2	0.5175 (3)	0.1204 (2)	0.6918 (3)	0.0416 (7)
H2	0.5954	0.1018	0.7320	0.050*
C3	0.4906 (4)	0.1174 (2)	0.5936 (3)	0.0482 (8)
H3	0.5471	0.0967	0.5554	0.058*
C4	0.3634 (4)	0.1508 (2)	0.5614 (3)	0.0580 (11)
H4	0.3197	0.1566	0.4977	0.070*
C5	0.3142 (3)	0.1739 (2)	0.6405 (3)	0.0519 (10)
H5	0.2308	0.1976	0.6395	0.062*
C6	0.5531 (3)	0.3958 (2)	0.8092 (2)	0.0312 (6)
H6	0.5136	0.4081	0.8594	0.037*
C7	0.6793 (3)	0.3613 (2)	0.8153 (2)	0.0337 (6)
H7	0.7394	0.3473	0.8703	0.040*
C8	0.6998 (3)	0.3516 (2)	0.7255 (2)	0.0312 (6)
H8	0.7763	0.3297	0.7093	0.037*
C9	0.5863 (3)	0.38023 (19)	0.6631 (2)	0.0267 (5)
H9	0.5737	0.3801	0.5978	0.032*
C10	0.4948 (3)	0.40899 (17)	0.71494 (19)	0.0233 (5)
C11	0.1956 (3)	0.0996 (2)	0.1453 (2)	0.0393 (7)
H11	0.2363	0.0915	0.2080	0.047*
C12	0.2595 (3)	0.0951 (2)	0.0760 (2)	0.0402 (7)
H12	0.3511	0.0831	0.0835	0.048*
C13	0.1648 (4)	0.1113 (2)	−0.0067 (2)	0.0411 (7)
H13	0.1816	0.1126	−0.0644	0.049*
C14	0.0411 (3)	0.1252 (2)	0.0110 (2)	0.0438 (8)
H14	−0.0407	0.1371	−0.0328	0.053*
C15	0.0598 (3)	0.1183 (2)	0.1054 (3)	0.0437 (8)
H15	−0.0069	0.1250	0.1365	0.052*
C16	0.3985 (3)	0.34072 (19)	0.1954 (2)	0.0338 (6)
H16	0.4904	0.3277	0.2072	0.041*
C17	0.3071 (4)	0.3502 (2)	0.1062 (2)	0.0482 (9)
H17	0.3276	0.3454	0.0483	0.058*
C18	0.1804 (4)	0.3679 (2)	0.1184 (2)	0.0474 (9)
H18	0.1010	0.3775	0.0702	0.057*
C19	0.1920 (3)	0.36898 (19)	0.2153 (2)	0.0323 (6)
H19	0.1211	0.3780	0.2425	0.039*
C20	0.3288 (3)	0.35406 (17)	0.26440 (19)	0.0241 (5)
C21	0.3979 (3)	0.8491 (2)	0.6884 (3)	0.0446 (8)
H21	0.4663	0.8112	0.7061	0.053*
C22	0.3452 (3)	0.9115 (2)	0.7541 (2)	0.0368 (7)
H22	0.3713	0.9237	0.8243	0.044*
C23	0.2474 (3)	0.9533 (2)	0.6989 (3)	0.0456 (8)
H23	0.1953	0.9988	0.7249	0.055*
C24	0.2399 (4)	0.9162 (3)	0.5986 (3)	0.0642 (12)
H24	0.1818	0.9318	0.5442	0.077*
C25	0.3341 (4)	0.8515 (3)	0.5931 (3)	0.0603 (12)
H25	0.3509	0.8156	0.5339	0.072*
C26	0.1367 (3)	0.65878 (18)	0.6361 (2)	0.0279 (6)
H26	0.2027	0.6255	0.6669	0.033*
C27	0.0690 (3)	0.7278 (2)	0.6860 (2)	0.0373 (7)
H27	0.0805	0.7476	0.7554	0.045*
C28	−0.0186 (3)	0.7617 (2)	0.6146 (3)	0.0439 (8)
H28	−0.0767	0.8081	0.6275	0.053*
C29	−0.0046 (3)	0.7144 (2)	0.5202 (2)	0.0350 (6)
H29	−0.0500	0.7252	0.4594	0.042*
C30	0.0896 (3)	0.64768 (18)	0.5321 (2)	0.0242 (5)
P1	0.94494 (10)	0.11818 (8)	0.70615 (7)	0.0506 (2)
F1	0.9016 (3)	0.1795 (2)	0.79546 (19)	0.0935 (9)
F2	0.9873 (3)	0.0561 (2)	0.61544 (18)	0.0837 (8)
F3	0.7858 (3)	0.0741 (3)	0.6318 (2)	0.1244 (14)
F4	1.1077 (3)	0.1638 (2)	0.7786 (2)	0.0832 (7)
F5	0.9538 (3)	0.0274 (2)	0.7437 (2)	0.0931 (9)
F6	0.9436 (4)	0.2112 (3)	0.6708 (3)	0.1183 (12)
P2	0.65318 (11)	0.20499 (8)	1.02043 (7)	0.0507 (2)
F11	0.5820 (5)	0.2828 (3)	0.9804 (3)	0.1310 (14)
F12	0.7338 (3)	0.13036 (18)	1.06292 (17)	0.0688 (6)
N1	0.6305 (9)	0.5411 (7)	1.0496 (6)	0.077 (2)	0.5
C31	0.7429 (13)	0.5419 (11)	1.0966 (8)	0.058 (3)	0.5
C32	0.8832 (15)	0.5370 (17)	1.1525 (14)	0.077 (4)	0.5
H32A	0.8795	0.4739	1.1644	0.115*	0.5
H32B	0.9248	0.5957	1.2183	0.115*	0.5
H32C	0.9415	0.5381	1.1131	0.115*	0.5
N1A	0.9757 (6)	0.5167 (5)	1.0373 (5)	0.0523 (14)	0.5
C31A	0.9058 (7)	0.5274 (6)	1.0817 (5)	0.0459 (15)	0.5
C32A	0.8167 (17)	0.5410 (13)	1.1386 (14)	0.087 (6)	0.5
H32D	0.7207	0.4990	1.0938	0.130*	0.5
H32E	0.8132	0.6129	1.1648	0.130*	0.5
H32F	0.8556	0.5204	1.1961	0.130*	0.5
F7	0.6905 (9)	0.1622 (8)	0.9240 (5)	0.118 (3)	0.67
F8	0.6295 (11)	0.2495 (9)	1.1213 (8)	0.082 (3)	0.67
F9	0.5086 (7)	0.1332 (5)	0.9654 (5)	0.0956 (18)	0.67
F10	0.8129 (6)	0.2804 (5)	1.0832 (6)	0.105 (2)	0.67
F7A	0.7705 (17)	0.2628 (12)	1.0115 (16)	0.121 (5)	0.33
F8A	0.5165 (16)	0.1357 (19)	1.0199 (17)	0.168 (9)	0.33
F9A	0.609 (2)	0.1161 (9)	0.9079 (10)	0.121 (7)	0.33
F10A	0.668 (3)	0.281 (2)	1.1255 (19)	0.154 (13)	0.33

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Hg1	0.03160 (6)	0.02915 (6)	0.02704 (6)	0.01267 (4)	0.01398 (4)	0.01231 (4)
Se1	0.02882 (13)	0.02585 (13)	0.02935 (14)	0.00876 (10)	0.01531 (11)	0.01336 (11)
Se2	0.02821 (13)	0.02356 (13)	0.02013 (13)	0.00917 (10)	0.00767 (10)	0.00348 (10)
Se3	0.02908 (13)	0.02367 (12)	0.02107 (13)	0.00690 (10)	0.00785 (10)	0.00730 (10)
Co1	0.02233 (16)	0.01826 (16)	0.02694 (18)	0.00221 (12)	0.00697 (14)	0.01050 (14)
Co2	0.02932 (18)	0.01654 (16)	0.01857 (17)	0.00271 (13)	0.00503 (14)	0.00182 (13)
Co3	0.02007 (16)	0.01581 (15)	0.02571 (18)	0.00371 (12)	0.00727 (14)	0.00689 (13)
C1	0.0466 (18)	0.0297 (15)	0.071 (2)	−0.0005 (13)	0.0282 (17)	0.0274 (16)
C2	0.0366 (16)	0.0237 (14)	0.064 (2)	0.0061 (12)	0.0136 (15)	0.0233 (14)
C3	0.057 (2)	0.0213 (14)	0.054 (2)	0.0030 (13)	0.0219 (17)	0.0022 (14)
C4	0.059 (2)	0.0277 (16)	0.047 (2)	−0.0104 (15)	−0.0151 (18)	0.0080 (15)
C5	0.0243 (15)	0.0290 (16)	0.090 (3)	−0.0009 (12)	0.0104 (17)	0.0234 (17)
C6	0.0413 (15)	0.0252 (13)	0.0229 (13)	0.0037 (11)	0.0104 (12)	0.0079 (11)
C7	0.0294 (14)	0.0290 (14)	0.0305 (15)	−0.0014 (11)	−0.0020 (12)	0.0132 (12)
C8	0.0223 (13)	0.0301 (14)	0.0419 (16)	0.0020 (10)	0.0085 (12)	0.0202 (13)
C9	0.0259 (13)	0.0285 (13)	0.0318 (14)	0.0039 (10)	0.0129 (11)	0.0180 (11)
C10	0.0254 (12)	0.0158 (11)	0.0250 (13)	0.0003 (9)	0.0073 (10)	0.0072 (10)
C11	0.0577 (19)	0.0170 (13)	0.0280 (15)	−0.0002 (12)	0.0064 (14)	0.0039 (11)
C12	0.0337 (15)	0.0198 (13)	0.0475 (19)	0.0063 (11)	0.0087 (14)	−0.0024 (12)
C13	0.0564 (19)	0.0258 (14)	0.0254 (15)	0.0006 (13)	0.0142 (14)	−0.0041 (12)
C14	0.0368 (16)	0.0258 (14)	0.0384 (18)	0.0021 (12)	−0.0049 (14)	−0.0017 (13)
C15	0.0432 (17)	0.0223 (14)	0.052 (2)	−0.0044 (12)	0.0247 (15)	−0.0040 (13)
C16	0.0404 (16)	0.0215 (13)	0.0314 (15)	−0.0066 (11)	0.0171 (13)	0.0015 (11)
C17	0.083 (3)	0.0272 (15)	0.0290 (16)	−0.0053 (15)	0.0226 (17)	0.0083 (13)
C18	0.075 (2)	0.0218 (14)	0.0302 (16)	0.0126 (15)	0.0033 (16)	0.0100 (12)
C19	0.0404 (15)	0.0177 (12)	0.0280 (14)	0.0108 (11)	0.0058 (12)	0.0030 (11)
C20	0.0290 (13)	0.0130 (11)	0.0209 (12)	−0.0007 (9)	0.0072 (10)	−0.0001 (9)
C21	0.0231 (14)	0.0267 (15)	0.073 (2)	0.0011 (11)	0.0160 (15)	0.0105 (15)
C22	0.0359 (15)	0.0291 (14)	0.0299 (15)	−0.0080 (12)	0.0041 (12)	0.0064 (12)
C23	0.0366 (16)	0.0152 (13)	0.072 (2)	0.0037 (11)	0.0158 (16)	0.0076 (14)
C24	0.070 (2)	0.042 (2)	0.054 (2)	−0.0220 (18)	−0.0121 (19)	0.0341 (18)
C25	0.079 (3)	0.0366 (18)	0.053 (2)	−0.0262 (18)	0.045 (2)	−0.0056 (16)
C26	0.0362 (14)	0.0185 (12)	0.0326 (15)	0.0019 (10)	0.0189 (12)	0.0101 (11)
C27	0.0395 (16)	0.0289 (14)	0.0458 (18)	−0.0005 (12)	0.0294 (14)	0.0069 (13)
C28	0.0216 (14)	0.0340 (15)	0.061 (2)	0.0054 (11)	0.0183 (14)	−0.0007 (15)
C29	0.0176 (12)	0.0309 (14)	0.0404 (17)	0.0037 (10)	0.0027 (12)	0.0043 (12)
C30	0.0208 (12)	0.0166 (11)	0.0290 (14)	−0.0013 (9)	0.0090 (10)	0.0041 (10)
P1	0.0506 (5)	0.0761 (6)	0.0418 (5)	0.0398 (5)	0.0252 (4)	0.0293 (5)
F1	0.101 (2)	0.136 (2)	0.0600 (15)	0.0695 (18)	0.0506 (15)	0.0277 (16)
F2	0.0968 (18)	0.132 (2)	0.0508 (13)	0.0788 (17)	0.0438 (13)	0.0416 (15)
F3	0.0510 (15)	0.205 (4)	0.076 (2)	0.0419 (19)	0.0156 (14)	0.014 (2)
F4	0.0610 (15)	0.108 (2)	0.0796 (18)	0.0221 (14)	0.0262 (13)	0.0368 (16)
F5	0.134 (2)	0.0842 (18)	0.092 (2)	0.0295 (17)	0.0632 (19)	0.0511 (16)
F6	0.192 (4)	0.111 (2)	0.102 (2)	0.091 (3)	0.067 (2)	0.075 (2)
P2	0.0680 (6)	0.0642 (6)	0.0458 (5)	0.0353 (5)	0.0347 (5)	0.0346 (5)
F11	0.204 (4)	0.137 (3)	0.114 (3)	0.113 (3)	0.071 (3)	0.095 (2)
F12	0.0914 (17)	0.0751 (15)	0.0558 (13)	0.0503 (13)	0.0336 (13)	0.0318 (12)
N1	0.095 (6)	0.114 (6)	0.053 (4)	0.060 (5)	0.044 (4)	0.046 (4)
C31	0.075 (8)	0.086 (6)	0.041 (6)	0.045 (6)	0.037 (5)	0.036 (5)
C32	0.066 (9)	0.117 (9)	0.063 (7)	0.042 (9)	0.035 (8)	0.040 (6)
N1A	0.046 (3)	0.070 (4)	0.050 (4)	0.020 (3)	0.020 (3)	0.031 (3)
C31A	0.051 (4)	0.053 (4)	0.035 (4)	0.012 (3)	0.017 (3)	0.019 (3)
C32A	0.103 (18)	0.103 (9)	0.089 (16)	0.036 (15)	0.077 (16)	0.036 (11)
F7	0.150 (7)	0.212 (10)	0.061 (4)	0.111 (6)	0.079 (5)	0.079 (6)
F8	0.104 (4)	0.122 (7)	0.058 (4)	0.084 (4)	0.056 (4)	0.039 (5)
F9	0.069 (3)	0.107 (4)	0.076 (4)	−0.009 (3)	0.009 (3)	0.022 (3)
F10	0.081 (3)	0.114 (4)	0.122 (5)	−0.002 (3)	0.019 (4)	0.077 (4)
F7A	0.134 (12)	0.122 (11)	0.199 (17)	0.046 (9)	0.120 (13)	0.114 (14)
F8A	0.070 (8)	0.29 (2)	0.22 (2)	0.032 (10)	0.076 (13)	0.17 (2)
F9A	0.211 (19)	0.061 (6)	0.050 (6)	0.051 (8)	0.008 (10)	0.012 (5)
F10A	0.25 (3)	0.133 (17)	0.041 (8)	0.141 (19)	0.021 (12)	0.007 (8)

Geometric parameters (Å, º)

Hg1—Se3	2.5451 (3)	C12—H12	0.9500
Hg1—Se1	2.5476 (3)	C13—C14	1.404 (5)
Hg1—Se2	2.6254 (3)	C13—H13	0.9500
Hg1—Se2^i	3.1537 (4)	C14—C15	1.413 (5)
Se1—C10	1.894 (3)	C14—H14	0.9500
Se2—C20	1.895 (3)	C15—H15	0.9500
Se2—Hg1^i	3.1537 (4)	C16—C17	1.417 (5)
Se3—C30	1.886 (3)	C16—C20	1.427 (4)
Co1—C6	2.018 (3)	C16—H16	0.9500
Co1—C1	2.019 (3)	C17—C18	1.411 (5)
Co1—C7	2.019 (3)	C17—H17	0.9500
Co1—C8	2.024 (3)	C18—C19	1.423 (4)
Co1—C5	2.029 (3)	C18—H18	0.9500
Co1—C2	2.030 (3)	C19—C20	1.426 (4)
Co1—C4	2.030 (3)	C19—H19	0.9500
Co1—C3	2.033 (3)	C21—C25	1.380 (5)
Co1—C9	2.035 (2)	C21—C22	1.390 (4)
Co1—C10	2.056 (2)	C21—H21	0.9500
Co2—C17	2.013 (3)	C22—C23	1.395 (4)
Co2—C18	2.019 (3)	C22—H22	0.9500
Co2—C13	2.023 (3)	C23—C24	1.398 (6)
Co2—C14	2.030 (3)	C23—H23	0.9500
Co2—C12	2.031 (3)	C24—C25	1.405 (6)
Co2—C16	2.034 (3)	C24—H24	0.9500
Co2—C15	2.035 (3)	C25—H25	0.9500
Co2—C11	2.037 (3)	C26—C27	1.418 (4)
Co2—C19	2.041 (3)	C26—C30	1.425 (4)
Co2—C20	2.075 (2)	C26—H26	0.9500
Co3—C25	2.006 (3)	C27—C28	1.411 (5)
Co3—C28	2.008 (3)	C27—H27	0.9500
Co3—C24	2.010 (3)	C28—C29	1.422 (4)
Co3—C27	2.015 (3)	C28—H28	0.9500
Co3—C29	2.021 (3)	C29—C30	1.435 (4)
Co3—C21	2.025 (3)	C29—H29	0.9500
Co3—C23	2.032 (3)	P1—F3	1.559 (3)
Co3—C26	2.039 (2)	P1—F1	1.571 (2)
Co3—C22	2.039 (3)	P1—F4	1.583 (3)
Co3—C30	2.081 (2)	P1—F5	1.584 (3)
C1—C5	1.397 (5)	P1—F2	1.585 (2)
C1—C2	1.408 (5)	P1—F6	1.595 (3)
C1—H1	0.9500	P2—F7A	1.471 (11)
C2—C3	1.399 (5)	P2—F9	1.505 (6)
C2—H2	0.9500	P2—F10A	1.54 (2)
C3—C4	1.423 (5)	P2—F8	1.553 (8)
C3—H3	0.9500	P2—F11	1.566 (3)
C4—C5	1.402 (6)	P2—F7	1.570 (5)
C4—H4	0.9500	P2—F12	1.585 (2)
C5—H5	0.9500	P2—F9A	1.621 (12)
C6—C7	1.418 (4)	P2—F8A	1.642 (14)
C6—C10	1.432 (4)	P2—F10	1.642 (6)
C6—H6	0.9500	N1—C31	1.131 (12)
C7—C8	1.406 (4)	C31—C32	1.427 (16)
C7—H7	0.9500	C32—H32A	0.9800
C8—C9	1.425 (4)	C32—H32B	0.9800
C8—H8	0.9500	C32—H32C	0.9800
C9—C10	1.422 (4)	N1A—C31A	1.126 (9)
C9—H9	0.9500	N1A—N1A^ii	1.345 (12)
C11—C12	1.400 (5)	C31A—C32A	1.440 (15)
C11—C15	1.413 (5)	C32A—H32D	0.9800
C11—H11	0.9500	C32A—H32E	0.9800
C12—C13	1.407 (5)	C32A—H32F	0.9800
Se3—Hg1—Se1	124.083 (9)	Co1—C8—H8	126.4
Se3—Hg1—Se2	116.198 (10)	C10—C9—C8	108.5 (2)
Se1—Hg1—Se2	115.319 (10)	C10—C9—Co1	70.43 (14)
Se3—Hg1—Se2^i	99.723 (10)	C8—C9—Co1	69.04 (14)
Se1—Hg1—Se2^i	99.201 (9)	C10—C9—H9	125.8
Se2—Hg1—Se2^i	91.509 (10)	C8—C9—H9	125.8
C10—Se1—Hg1	104.54 (8)	Co1—C9—H9	126.4
C20—Se2—Hg1	106.04 (7)	C9—C10—C6	106.6 (2)
C20—Se2—Hg1^i	98.79 (7)	C9—C10—Se1	129.78 (19)
Hg1—Se2—Hg1^i	88.491 (10)	C6—C10—Se1	123.6 (2)
C30—Se3—Hg1	102.46 (8)	C9—C10—Co1	68.88 (14)
C6—Co1—C1	106.10 (13)	C6—C10—Co1	68.01 (14)
C6—Co1—C7	41.12 (12)	Se1—C10—Co1	126.55 (12)
C1—Co1—C7	113.44 (14)	C12—C11—C15	107.9 (3)
C6—Co1—C8	68.77 (12)	C12—C11—Co2	69.63 (17)
C1—Co1—C8	146.55 (13)	C15—C11—Co2	69.62 (17)
C7—Co1—C8	40.69 (12)	C12—C11—H11	126.0
C6—Co1—C5	113.78 (14)	C15—C11—H11	126.0
C1—Co1—C5	40.39 (14)	Co2—C11—H11	126.3
C7—Co1—C5	145.45 (15)	C11—C12—C13	108.3 (3)
C8—Co1—C5	172.73 (14)	C11—C12—Co2	70.10 (16)
C6—Co1—C2	129.59 (13)	C13—C12—Co2	69.38 (16)
C1—Co1—C2	40.71 (13)	C11—C12—H12	125.8
C7—Co1—C2	107.44 (12)	C13—C12—H12	125.8
C8—Co1—C2	115.98 (12)	Co2—C12—H12	126.3
C5—Co1—C2	68.15 (12)	C14—C13—C12	108.0 (3)
C6—Co1—C4	146.87 (15)	C14—C13—Co2	69.98 (16)
C1—Co1—C4	68.11 (16)	C12—C13—Co2	70.02 (16)
C7—Co1—C4	171.93 (15)	C14—C13—H13	126.0
C8—Co1—C4	134.13 (16)	C12—C13—H13	126.0
C5—Co1—C4	40.42 (16)	Co2—C13—H13	125.6
C2—Co1—C4	68.22 (14)	C13—C14—C15	108.0 (3)
C6—Co1—C3	169.18 (13)	C13—C14—Co2	69.47 (16)
C1—Co1—C3	68.23 (15)	C15—C14—Co2	69.88 (16)
C7—Co1—C3	131.41 (13)	C13—C14—H14	126.0
C8—Co1—C3	110.49 (13)	C15—C14—H14	126.0
C5—Co1—C3	68.37 (14)	Co2—C14—H14	126.2
C2—Co1—C3	40.27 (14)	C14—C15—C11	107.7 (3)
C4—Co1—C3	40.99 (15)	C14—C15—Co2	69.44 (17)
C6—Co1—C9	68.73 (11)	C11—C15—Co2	69.78 (16)
C1—Co1—C9	169.81 (12)	C14—C15—H15	126.1
C7—Co1—C9	68.91 (11)	C11—C15—H15	126.1
C8—Co1—C9	41.10 (10)	Co2—C15—H15	126.2
C5—Co1—C9	132.51 (13)	C17—C16—C20	108.3 (3)
C2—Co1—C9	149.25 (12)	C17—C16—Co2	68.69 (17)
C4—Co1—C9	111.05 (14)	C20—C16—Co2	71.22 (14)
C3—Co1—C9	118.31 (13)	C17—C16—H16	125.9
C6—Co1—C10	41.14 (10)	C20—C16—H16	125.9
C1—Co1—C10	129.79 (12)	Co2—C16—H16	125.8
C7—Co1—C10	69.29 (10)	C18—C17—C16	108.2 (3)
C8—Co1—C10	68.99 (10)	C18—C17—Co2	69.77 (18)
C5—Co1—C10	108.10 (11)	C16—C17—Co2	70.33 (16)
C2—Co1—C10	168.83 (12)	C18—C17—H17	125.9
C4—Co1—C10	116.29 (12)	C16—C17—H17	125.9
C3—Co1—C10	149.47 (13)	Co2—C17—H17	125.6
C9—Co1—C10	40.70 (10)	C17—C18—C19	108.2 (3)
C17—Co2—C18	40.97 (15)	C17—C18—Co2	69.26 (17)
C17—Co2—C13	104.66 (13)	C19—C18—Co2	70.27 (16)
C18—Co2—C13	118.79 (13)	C17—C18—H18	125.9
C17—Co2—C14	122.20 (14)	C19—C18—H18	125.9
C18—Co2—C14	106.12 (13)	Co2—C18—H18	126.1
C13—Co2—C14	40.55 (13)	C18—C19—C20	108.0 (3)
C17—Co2—C12	119.40 (14)	C18—C19—Co2	68.68 (16)
C18—Co2—C12	154.38 (14)	C20—C19—Co2	71.02 (14)
C13—Co2—C12	40.60 (13)	C18—C19—H19	126.0
C14—Co2—C12	68.12 (12)	C20—C19—H19	126.0
C17—Co2—C16	40.98 (13)	Co2—C19—H19	125.9
C18—Co2—C16	68.82 (14)	C19—C20—C16	107.3 (2)
C13—Co2—C16	122.91 (12)	C19—C20—Se2	128.4 (2)
C14—Co2—C16	159.32 (13)	C16—C20—Se2	124.3 (2)
C12—Co2—C16	107.28 (12)	C19—C20—Co2	68.43 (14)
C17—Co2—C15	160.25 (15)	C16—C20—Co2	68.17 (14)
C18—Co2—C15	124.82 (15)	Se2—C20—Co2	128.02 (12)
C13—Co2—C15	68.31 (13)	C25—C21—C22	108.4 (3)
C14—Co2—C15	40.68 (14)	C25—C21—Co3	69.25 (19)
C12—Co2—C15	68.04 (12)	C22—C21—Co3	70.55 (16)
C16—Co2—C15	158.24 (14)	C25—C21—H21	125.8
C17—Co2—C11	155.77 (15)	C22—C21—H21	125.8
C18—Co2—C11	162.92 (15)	Co3—C21—H21	126.0
C13—Co2—C11	68.18 (13)	C21—C22—C23	108.1 (3)
C14—Co2—C11	68.27 (13)	C21—C22—Co3	69.44 (17)
C12—Co2—C11	40.27 (13)	C23—C22—Co3	69.68 (16)
C16—Co2—C11	122.15 (13)	C21—C22—H22	125.9
C15—Co2—C11	40.60 (13)	C23—C22—H22	125.9
C17—Co2—C19	69.01 (13)	Co3—C22—H22	126.5
C18—Co2—C19	41.04 (12)	C22—C23—C24	107.8 (3)
C13—Co2—C19	155.45 (12)	C22—C23—Co3	70.25 (16)
C14—Co2—C19	121.50 (12)	C24—C23—Co3	68.93 (18)
C12—Co2—C19	163.16 (12)	C22—C23—H23	126.1
C16—Co2—C19	68.67 (12)	C24—C23—H23	126.1
C15—Co2—C19	109.28 (12)	Co3—C23—H23	126.3
C11—Co2—C19	126.94 (12)	C23—C24—C25	107.6 (3)
C17—Co2—C20	68.61 (11)	C23—C24—Co3	70.62 (18)
C18—Co2—C20	68.51 (11)	C25—C24—Co3	69.38 (18)
C13—Co2—C20	161.03 (12)	C23—C24—H24	126.2
C14—Co2—C20	158.00 (12)	C25—C24—H24	126.2
C12—Co2—C20	125.96 (11)	Co3—C24—H24	125.4
C16—Co2—C20	40.62 (10)	C21—C25—C24	108.1 (3)
C15—Co2—C20	123.73 (12)	C21—C25—Co3	70.72 (18)
C11—Co2—C20	110.28 (11)	C24—C25—Co3	69.7 (2)
C19—Co2—C20	40.55 (10)	C21—C25—H25	125.9
C25—Co3—C28	151.76 (18)	C24—C25—H25	125.9
C25—Co3—C24	40.96 (17)	Co3—C25—H25	125.3
C28—Co3—C24	117.02 (17)	C27—C26—C30	108.8 (3)
C25—Co3—C27	166.20 (17)	C27—C26—Co3	68.63 (15)
C28—Co3—C27	41.05 (14)	C30—C26—Co3	71.34 (14)
C24—Co3—C27	151.55 (17)	C27—C26—H26	125.6
C25—Co3—C29	117.88 (15)	C30—C26—H26	125.6
C28—Co3—C29	41.32 (13)	Co3—C26—H26	126.0
C24—Co3—C29	106.39 (14)	C28—C27—C26	108.1 (3)
C27—Co3—C29	69.23 (13)	C28—C27—Co3	69.21 (17)
C25—Co3—C21	40.03 (16)	C26—C27—Co3	70.43 (15)
C28—Co3—C21	165.87 (15)	C28—C27—H27	125.9
C24—Co3—C21	67.94 (15)	C26—C27—H27	125.9
C27—Co3—C21	128.78 (15)	Co3—C27—H27	126.0
C29—Co3—C21	152.40 (13)	C27—C28—C29	108.1 (3)
C25—Co3—C23	68.09 (14)	C27—C28—Co3	69.74 (16)
C28—Co3—C23	106.95 (12)	C29—C28—Co3	69.80 (16)
C24—Co3—C23	40.45 (16)	C27—C28—H28	126.0
C27—Co3—C23	118.42 (13)	C29—C28—H28	126.0
C29—Co3—C23	126.63 (12)	Co3—C28—H28	126.1
C21—Co3—C23	67.55 (12)	C28—C29—C30	108.4 (3)
C25—Co3—C26	128.18 (14)	C28—C29—Co3	68.88 (16)
C28—Co3—C26	68.92 (12)	C30—C29—Co3	71.79 (14)
C24—Co3—C26	165.64 (16)	C28—C29—H29	125.8
C27—Co3—C26	40.94 (11)	C30—C29—H29	125.8
C29—Co3—C26	68.77 (12)	Co3—C29—H29	125.1
C21—Co3—C26	109.67 (12)	C26—C30—C29	106.6 (2)
C23—Co3—C26	153.11 (14)	C26—C30—Se3	130.28 (19)
C25—Co3—C22	67.48 (14)	C29—C30—Se3	123.1 (2)
C28—Co3—C22	127.60 (13)	C26—C30—Co3	68.20 (14)
C24—Co3—C22	67.71 (13)	C29—C30—Co3	67.29 (14)
C27—Co3—C22	108.91 (13)	Se3—C30—Co3	129.52 (12)
C29—Co3—C22	164.94 (12)	F3—P1—F1	90.82 (16)
C21—Co3—C22	40.01 (13)	F3—P1—F4	177.97 (19)
C23—Co3—C22	40.07 (13)	F1—P1—F4	90.61 (16)
C26—Co3—C22	120.28 (12)	F3—P1—F5	94.2 (2)
C25—Co3—C30	108.22 (12)	F1—P1—F5	90.20 (16)
C28—Co3—C30	68.96 (11)	F4—P1—F5	87.26 (16)
C24—Co3—C30	127.29 (14)	F3—P1—F2	88.73 (16)
C27—Co3—C30	68.69 (11)	F1—P1—F2	179.55 (15)
C29—Co3—C30	40.91 (10)	F4—P1—F2	89.84 (15)
C21—Co3—C30	119.73 (11)	F5—P1—F2	89.87 (15)
C23—Co3—C30	164.93 (13)	F3—P1—F6	88.3 (2)
C26—Co3—C30	40.46 (10)	F1—P1—F6	90.27 (17)
C22—Co3—C30	153.56 (11)	F4—P1—F6	90.23 (19)
C5—C1—C2	108.3 (3)	F5—P1—F6	177.5 (2)
C5—C1—Co1	70.19 (18)	F2—P1—F6	89.67 (16)
C2—C1—Co1	70.06 (16)	F7A—P2—F10A	97.8 (13)
C5—C1—H1	125.9	F9—P2—F8	92.2 (5)
C2—C1—H1	125.9	F7A—P2—F11	77.8 (6)
Co1—C1—H1	125.5	F9—P2—F11	87.0 (3)
C3—C2—C1	108.2 (3)	F10A—P2—F11	84.2 (10)
C3—C2—Co1	70.01 (17)	F8—P2—F11	91.9 (4)
C1—C2—Co1	69.24 (16)	F9—P2—F7	92.0 (4)
C3—C2—H2	125.9	F8—P2—F7	175.3 (5)
C1—C2—H2	125.9	F11—P2—F7	90.6 (3)
Co1—C2—H2	126.4	F7A—P2—F12	99.1 (6)
C2—C3—C4	107.6 (3)	F9—P2—F12	96.2 (3)
C2—C3—Co1	69.72 (17)	F10A—P2—F12	95.3 (10)
C4—C3—Co1	69.39 (18)	F8—P2—F12	88.6 (4)
C2—C3—H3	126.2	F11—P2—F12	176.7 (2)
C4—C3—H3	126.2	F7—P2—F12	88.7 (3)
Co1—C3—H3	126.3	F7A—P2—F9A	92.5 (9)
C5—C4—C3	107.8 (3)	F10A—P2—F9A	169.3 (13)
C5—C4—Co1	69.73 (19)	F11—P2—F9A	95.3 (5)
C3—C4—Co1	69.62 (18)	F12—P2—F9A	85.9 (5)
C5—C4—H4	126.1	F7A—P2—F8A	175.2 (11)
C3—C4—H4	126.1	F10A—P2—F8A	86.6 (13)
Co1—C4—H4	126.1	F11—P2—F8A	100.8 (7)
C1—C5—C4	108.2 (3)	F12—P2—F8A	82.4 (7)
C1—C5—Co1	69.43 (17)	F9A—P2—F8A	83.0 (10)
C4—C5—Co1	69.85 (18)	F9—P2—F10	177.7 (3)
C1—C5—H5	125.9	F8—P2—F10	87.0 (5)
C4—C5—H5	125.9	F11—P2—F10	95.2 (3)
Co1—C5—H5	126.4	F7—P2—F10	88.7 (4)
C7—C6—C10	108.8 (2)	F12—P2—F10	81.5 (2)
C7—C6—Co1	69.48 (16)	N1—C31—C32	176.8 (19)
C10—C6—Co1	70.84 (14)	C31—C32—H32A	109.5
C7—C6—H6	125.6	C31—C32—H32B	109.5
C10—C6—H6	125.6	H32A—C32—H32B	109.5
Co1—C6—H6	125.6	C31—C32—H32C	109.5
C8—C7—C6	107.9 (2)	H32A—C32—H32C	109.5
C8—C7—Co1	69.85 (15)	H32B—C32—H32C	109.5
C6—C7—Co1	69.40 (15)	C31A—N1A—N1A^ii	163.0 (9)
C8—C7—H7	126.0	N1A—C31A—C32A	179.9 (11)
C6—C7—H7	126.0	C31A—C32A—H32D	109.5
Co1—C7—H7	126.3	C31A—C32A—H32E	109.5
C7—C8—C9	108.3 (2)	H32D—C32A—H32E	109.5
C7—C8—Co1	69.46 (15)	C31A—C32A—H32F	109.5
C9—C8—Co1	69.87 (14)	H32D—C32A—H32F	109.5
C7—C8—H8	125.9	H32E—C32A—H32F	109.5
C9—C8—H8	125.9
C5—C1—C2—C3	0.6 (3)	C16—C17—C18—Co2	−60.1 (2)
Co1—C1—C2—C3	−59.4 (2)	C17—C18—C19—C20	1.4 (3)
C5—C1—C2—Co1	60.0 (2)	Co2—C18—C19—C20	60.42 (18)
C1—C2—C3—C4	−0.4 (3)	C17—C18—C19—Co2	−59.1 (2)
Co1—C2—C3—C4	−59.3 (2)	C18—C19—C20—C16	−1.8 (3)
C1—C2—C3—Co1	58.9 (2)	Co2—C19—C20—C16	57.16 (17)
C2—C3—C4—C5	0.0 (3)	C18—C19—C20—Se2	178.91 (19)
Co1—C3—C4—C5	−59.5 (2)	Co2—C19—C20—Se2	−122.13 (19)
C2—C3—C4—Co1	59.5 (2)	C18—C19—C20—Co2	−58.96 (18)
C2—C1—C5—C4	−0.6 (3)	C17—C16—C20—C19	1.6 (3)
Co1—C1—C5—C4	59.3 (2)	Co2—C16—C20—C19	−57.32 (17)
C2—C1—C5—Co1	−59.9 (2)	C17—C16—C20—Se2	−179.09 (18)
C3—C4—C5—C1	0.4 (3)	Co2—C16—C20—Se2	122.00 (17)
Co1—C4—C5—C1	−59.0 (2)	C17—C16—C20—Co2	58.90 (18)
C3—C4—C5—Co1	59.5 (2)	Hg1—Se2—C20—C19	−33.8 (2)
C10—C6—C7—C8	−0.7 (3)	Hg1^i—Se2—C20—C19	−124.7 (2)
Co1—C6—C7—C8	59.45 (19)	Hg1—Se2—C20—C16	147.06 (19)
C10—C6—C7—Co1	−60.18 (18)	Hg1^i—Se2—C20—C16	56.1 (2)
C6—C7—C8—C9	0.1 (3)	Hg1—Se2—C20—Co2	−125.16 (14)
Co1—C7—C8—C9	59.30 (18)	Hg1^i—Se2—C20—Co2	143.88 (14)
C6—C7—C8—Co1	−59.17 (18)	C25—C21—C22—C23	0.0 (3)
C7—C8—C9—C10	0.5 (3)	Co3—C21—C22—C23	−59.1 (2)
Co1—C8—C9—C10	59.57 (17)	C25—C21—C22—Co3	59.1 (2)
C7—C8—C9—Co1	−59.04 (18)	C21—C22—C23—C24	0.0 (3)
C8—C9—C10—C6	−1.0 (3)	Co3—C22—C23—C24	−58.9 (2)
Co1—C9—C10—C6	57.75 (17)	C21—C22—C23—Co3	59.0 (2)
C8—C9—C10—Se1	−179.32 (18)	C22—C23—C24—C25	−0.1 (3)
Co1—C9—C10—Se1	−120.6 (2)	Co3—C23—C24—C25	−59.8 (2)
C8—C9—C10—Co1	−58.71 (17)	C22—C23—C24—Co3	59.8 (2)
C7—C6—C10—C9	1.0 (3)	C22—C21—C25—C24	0.0 (3)
Co1—C6—C10—C9	−58.30 (17)	Co3—C21—C25—C24	59.9 (2)
C7—C6—C10—Se1	179.53 (17)	C22—C21—C25—Co3	−59.9 (2)
Co1—C6—C10—Se1	120.19 (17)	C23—C24—C25—C21	0.1 (4)
C7—C6—C10—Co1	59.34 (18)	Co3—C24—C25—C21	−60.5 (2)
Hg1—Se1—C10—C9	−8.8 (2)	C23—C24—C25—Co3	60.6 (2)
Hg1—Se1—C10—C6	173.14 (19)	C30—C26—C27—C28	−1.1 (3)
Hg1—Se1—C10—Co1	−100.68 (14)	Co3—C26—C27—C28	59.16 (19)
C15—C11—C12—C13	0.3 (3)	C30—C26—C27—Co3	−60.26 (17)
Co2—C11—C12—C13	−59.0 (2)	C26—C27—C28—C29	−0.4 (3)
C15—C11—C12—Co2	59.29 (19)	Co3—C27—C28—C29	59.5 (2)
C11—C12—C13—C14	−0.4 (3)	C26—C27—C28—Co3	−59.92 (18)
Co2—C12—C13—C14	−59.9 (2)	C27—C28—C29—C30	1.8 (3)
C11—C12—C13—Co2	59.48 (19)	Co3—C28—C29—C30	61.25 (18)
C12—C13—C14—C15	0.4 (3)	C27—C28—C29—Co3	−59.45 (19)
Co2—C13—C14—C15	−59.5 (2)	C27—C26—C30—C29	2.2 (3)
C12—C13—C14—Co2	59.93 (19)	Co3—C26—C30—C29	−56.42 (17)
C13—C14—C15—C11	−0.3 (3)	C27—C26—C30—Se3	−177.39 (18)
Co2—C14—C15—C11	−59.51 (19)	Co3—C26—C30—Se3	124.0 (2)
C13—C14—C15—Co2	59.3 (2)	C27—C26—C30—Co3	58.60 (17)
C12—C11—C15—C14	0.0 (3)	C28—C29—C30—C26	−2.4 (3)
Co2—C11—C15—C14	59.3 (2)	Co3—C29—C30—C26	56.98 (17)
C12—C11—C15—Co2	−59.30 (19)	C28—C29—C30—Se3	177.18 (18)
C20—C16—C17—C18	−0.8 (3)	Co3—C29—C30—Se3	−123.41 (17)
Co2—C16—C17—C18	59.7 (2)	C28—C29—C30—Co3	−59.42 (19)
C20—C16—C17—Co2	−60.48 (18)	Hg1—Se3—C30—C26	−2.6 (2)
C16—C17—C18—C19	−0.4 (3)	Hg1—Se3—C30—C29	177.93 (19)
Co2—C17—C18—C19	59.7 (2)	Hg1—Se3—C30—Co3	91.34 (16)

Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) −x+2, −y+1, −z+2.