Tetra-μ-acetato-κ8O:O′-bis­[(3-chloro­pyridine-κN)ruthenium(II,III)](Ru—Ru) hexa­fluorido­phosphate 1,2-di­chloro­ethane monosolvate

Aquino, A.J.; Gerrior, D.; Cameron, T.S.; Robertson, K.N.; Aquino, M.A.S.

doi:10.1107/S2414314622002498

Tetra-μ-acetato-κ⁸O:O′-bis[(3-chloropyridine-κN)ruthenium(II,III)](Ru—Ru) hexafluoridophosphate 1,2-dichloroethane monosolvate

A. J. Aquino, D. Gerrior, T. S. Cameron, K. N. Robertson and M. A. S. Aquino

The title compound, [Ru₂(μ-O₂CCH₃)₄(C₅H₄ClN)₂]PF₆·C₂H₄Cl₂, was obtained via a rapid substitution reaction of 3-chloropyridine for water in [Ru₂(μ-O₂CCH₃)₄(H₂O)₂]PF₆ in 2-propanol and subsequent crystallization from a dichloroethane solution. The cationic diruthenium(II,III) tetraacetate core lies on a crystallographic inversion center with Ru—Ru and Ru—N bond lengths of 2.2738 (3) and 2.2920 (17) Å, respectively. The Ru—Ru—N bond angle is close to linear at 176.48 (4)°, and a significant π-stacking interaction of 3.5649 (16) Å is seen between overlapping pyridine rings of adjacent cations.

Keywords: crystal structure; coordination compound; mixed-valency; diruthenium tetracarboxylate.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S2414314622002498/wm4161sup1.cif Contains datablock I
	Structure factor file (CIF format) https://doi.org/10.1107/S2414314622002498/wm4161Isup2.hkl Contains datablock I

CCDC reference: 2156199

checkCIF report

Key indicators

Single-crystal X-ray study
T = 293 K
Mean (C-C) = 0.004 Å
Disorder in solvent or counterion
R factor = 0.024
wR factor = 0.069
Data-to-parameter ratio = 16.3

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT242_ALERT_2_C Low    'MainMol' Ueq as Compared to Neighbors of         C2 Check
PLAT260_ALERT_2_C Large Average Ueq of Residue Including      Cl2A      0.209 Check
PLAT260_ALERT_2_C Large Average Ueq of Residue Including      Cl2B      0.195 Check
PLAT910_ALERT_3_C Missing # of FCF Reflection(s) Below Theta(Min).          6 Note
PLAT911_ALERT_3_C Missing FCF Refl Between Thmin & STh/L=    0.600        213 Report

Alert level G
PLAT002_ALERT_2_G Number of Distance or Angle Restraints on AtSite          8 Note
PLAT003_ALERT_2_G Number of Uiso or Uij Restrained non-H Atoms ...          8 Report
PLAT152_ALERT_1_G The Supplied and Calc. Volume s.u. Differ by ...          4 Units
PLAT172_ALERT_4_G The CIF-Embedded .res File Contains DFIX Records          2 Report
PLAT175_ALERT_4_G The CIF-Embedded .res File Contains SAME Records          1 Report
PLAT178_ALERT_4_G The CIF-Embedded .res File Contains SIMU Records          2 Report
PLAT186_ALERT_4_G The CIF-Embedded .res File Contains ISOR Records          1 Report
PLAT187_ALERT_4_G The CIF-Embedded .res File Contains RIGU Records          2 Report
PLAT199_ALERT_1_G Reported _cell_measurement_temperature ..... (K)        293 Check
PLAT200_ALERT_1_G Reported   _diffrn_ambient_temperature ..... (K)        293 Check
PLAT244_ALERT_4_G Low    'Solvent' Ueq as Compared to Neighbors of         P1 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H7A        Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H7B        Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H7C        Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H7D        Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H7E        Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H7F        Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H9A        Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H9B        Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H9C        Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H9D        Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H9E        Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H9F        Constrained at        0.5 Check
PLAT300_ALERT_4_G Atom Site Occupancy of Cl2A       Constrained at       0.25 Check
PLAT300_ALERT_4_G Atom Site Occupancy of Cl3A       Constrained at       0.25 Check
PLAT300_ALERT_4_G Atom Site Occupancy of C11A       Constrained at       0.25 Check
PLAT300_ALERT_4_G Atom Site Occupancy of C12A       Constrained at       0.25 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H11A       Constrained at       0.25 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H11B       Constrained at       0.25 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H12A       Constrained at       0.25 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H12B       Constrained at       0.25 Check
PLAT300_ALERT_4_G Atom Site Occupancy of Cl2B       Constrained at       0.25 Check
PLAT300_ALERT_4_G Atom Site Occupancy of Cl3B       Constrained at       0.25 Check
PLAT300_ALERT_4_G Atom Site Occupancy of C11B       Constrained at       0.25 Check
PLAT300_ALERT_4_G Atom Site Occupancy of C12B       Constrained at       0.25 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H11C       Constrained at       0.25 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H11D       Constrained at       0.25 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H12C       Constrained at       0.25 Check
PLAT300_ALERT_4_G Atom Site Occupancy of H12D       Constrained at       0.25 Check
PLAT302_ALERT_4_G Anion/Solvent/Minor-Residue Disorder (Resd  3  )       100% Note
PLAT302_ALERT_4_G Anion/Solvent/Minor-Residue Disorder (Resd  4  )       100% Note
PLAT367_ALERT_2_G Long?  C(sp?)-C(sp?) Bond  C6       - C7       .       1.50 Ang.
PLAT789_ALERT_4_G Atoms with Negative _atom_site_disorder_group  #         16 Check
PLAT860_ALERT_3_G Number of Least-Squares Restraints .............         99 Note
PLAT882_ALERT_1_G No Datum for _diffrn_reflns_av_unetI/netI ......     Please Do !
PLAT912_ALERT_4_G Missing # of FCF Reflections Above STh/L=  0.600        264 Note
PLAT913_ALERT_3_G Missing # of Very Strong Reflections in FCF ....          2 Note
PLAT933_ALERT_2_G Number of HKL-OMIT Records in Embedded .res File          2 Note
PLAT940_ALERT_3_G Fsqd Refinement With I > n * Sigma(I) Only .....     Please Check
PLAT961_ALERT_5_G Dataset Contains no Negative Intensities .......     Please Check
PLAT978_ALERT_2_G Number C-C Bonds with Positive Residual Density.          3 Info

   0 ALERT level A = Most likely a serious problem - resolve or explain
   0 ALERT level B = A potentially serious problem, consider carefully
   5 ALERT level C = Check. Ensure it is not caused by an omission or oversight
  51 ALERT level G = General information/check it is not something unexpected

   4 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   8 ALERT type 2 Indicator that the structure model may be wrong or deficient
   5 ALERT type 3 Indicator that the structure quality may be low
  38 ALERT type 4 Improvement, methodology, query or suggestion
   1 ALERT type 5 Informative message, check

Computing details top

Data collection: CrystalStructure (Rigaku, 2007); cell refinement: CrystalStructure (Rigaku, 2007); data reduction: CrystalStructure (Rigaku, 2007); program(s) used to solve structure: SIR2004 (Burla et al., 2005); program(s) used to refine structure: SHELXL (Sheldrick, 2015); molecular graphics: Merdury (Macrae et al., 2020); software used to prepare material for publication: publCIF (Westrip, 2010).

Tetra-µ-acetato-κ⁸O:O'-bis[(3-chloropyridine-κN)ruthenium(II,III)](Ru—Ru) hexafluoridophosphate 1,2-dichloroethane monosolvate top

Crystal data top

[Ru₂(C₂H₃O₂)₄(C₅H₄ClN)₂]PF₆	Z = 1
M_r = 909.32	F(000) = 447
Triclinic, P1	D_x = 1.793 Mg m⁻³
a = 8.2737 (1) Å	Mo Kα radiation, λ = 0.71075 Å
b = 10.5784 (3) Å	Cell parameters from 8636 reflections
c = 11.5534 (1) Å	θ = 2.7–58.1°
α = 100.764 (7)°	µ = 1.34 mm⁻¹
β = 108.980 (8)°	T = 293 K
γ = 110.525 (7)°	Needle plate, light brown
V = 842.27 (6) Å³	0.43 × 0.20 × 0.07 mm

Data collection top

Rigaku R-AXIS RAPID diffractometer	4084 reflections with I > 2σ(I)
Detector resolution: 10.00 pixels mm^-1	R_int = 0.084
ω scans	θ_max = 29.2°
Absorption correction: multi-scan (ABSCOR; Higashi, 1995).	h = −11→11
T_min = 0.702, T_max = 0.921	k = −14→14
23200 measured reflections	l = −15→15
4084 independent reflections

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: iterative
R[F² > 2σ(F²)] = 0.024	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.069	H-atom parameters constrained
S = 1.10	w = 1/[σ²(F_o²) + (0.0183P)²] where P = (F_o² + 2F_c²)/3
4084 reflections	(Δ/σ)_max = 0.002
250 parameters	Δρ_max = 0.49 e Å⁻³
99 restraints	Δρ_min = −0.51 e Å⁻³

Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Ru1	0.53229 (2)	0.11769 (2)	0.03458 (2)	0.03317 (6)
Cl1	0.94986 (12)	0.69082 (8)	0.05336 (11)	0.0947 (3)
P1	1.000000	0.000000	0.500000	0.0569 (2)
F1	0.9249 (3)	0.0893 (2)	0.57695 (18)	0.0917 (6)
F2	0.8293 (3)	−0.1428 (2)	0.4802 (2)	0.0949 (6)
F3	0.8683 (2)	0.0034 (2)	0.36556 (16)	0.0862 (5)
O1	0.5024 (2)	0.09675 (16)	0.19771 (13)	0.0425 (3)
O2	0.5603 (2)	0.13381 (16)	−0.13033 (14)	0.0416 (3)
O3	0.81269 (19)	0.16819 (15)	0.12454 (14)	0.0415 (3)
O4	0.25099 (19)	0.06299 (16)	−0.05668 (14)	0.0410 (3)
N1	0.6166 (2)	0.35849 (18)	0.10681 (18)	0.0427 (4)
C1	0.7380 (3)	0.4444 (2)	0.0712 (3)	0.0544 (5)
H1	0.787140	0.404761	0.020620	0.065*
C2	0.7934 (3)	0.5901 (2)	0.1069 (2)	0.0541 (5)
C3	0.7242 (4)	0.6514 (2)	0.1813 (3)	0.0615 (6)
H3	0.759615	0.749444	0.205596	0.074*
C4	0.6005 (4)	0.5631 (3)	0.2192 (3)	0.0692 (7)
H4	0.550116	0.600878	0.269981	0.083*
C5	0.5508 (4)	0.4172 (3)	0.1814 (2)	0.0564 (5)
H5	0.468896	0.358717	0.209052	0.068*
C6	0.4646 (3)	−0.0242 (2)	0.21398 (18)	0.0417 (4)
C7	0.4480 (4)	−0.0360 (3)	0.3375 (2)	0.0600 (6)
H7A	0.470433	0.055322	0.390462	0.090*	0.5
H7B	0.322347	−0.106306	0.316927	0.090*	0.5
H7C	0.540552	−0.064512	0.384004	0.090*	0.5
H7D	0.418455	−0.132319	0.337133	0.090*	0.5
H7E	0.566541	0.029309	0.410669	0.090*	0.5
H7F	0.348336	−0.012486	0.343592	0.090*	0.5
C8	0.1350 (3)	−0.0685 (2)	−0.11919 (18)	0.0402 (4)
C9	−0.0728 (3)	−0.1078 (3)	−0.1872 (2)	0.0562 (5)
H9A	−0.143002	−0.209827	−0.230077	0.084*	0.5
H9B	−0.116969	−0.078012	−0.124702	0.084*	0.5
H9C	−0.091531	−0.060687	−0.250386	0.084*	0.5
H9D	−0.091332	−0.022523	−0.173366	0.084*	0.5
H9E	−0.117366	−0.154338	−0.278742	0.084*	0.5
H9F	−0.142804	−0.171664	−0.153057	0.084*	0.5
Cl2A	0.218 (3)	0.548 (2)	0.3742 (19)	0.233 (6)	0.25
C11A	0.138 (5)	0.586 (4)	0.499 (3)	0.162 (8)	0.25
H11A	0.241338	0.623432	0.584600	0.194*	0.25
H11B	0.086968	0.655324	0.488739	0.194*	0.25
C12A	−0.014 (7)	0.444 (3)	0.477 (5)	0.154 (7)	0.25
H12A	0.038817	0.383465	0.511063	0.184*	0.25
H12B	−0.101345	0.394270	0.385840	0.184*	0.25
Cl3A	−0.126 (4)	0.506 (3)	0.571 (2)	0.290 (10)	0.25
Cl2B	0.202 (3)	0.5888 (19)	0.454 (3)	0.212 (6)	0.25
C11B	0.035 (6)	0.589 (4)	0.525 (5)	0.155 (7)	0.25
H11C	0.102125	0.668383	0.607326	0.186*	0.25
H11D	−0.064456	0.605649	0.467743	0.186*	0.25
C12B	−0.053 (4)	0.455 (4)	0.549 (4)	0.160 (7)	0.25
H12C	0.025345	0.456765	0.633197	0.192*	0.25
H12D	−0.075663	0.372165	0.481778	0.192*	0.25
Cl3B	−0.275 (3)	0.452 (3)	0.544 (2)	0.254 (9)	0.25

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ru1	0.03692 (9)	0.03044 (9)	0.03524 (9)	0.01429 (7)	0.01879 (7)	0.01260 (7)
Cl1	0.0931 (5)	0.0526 (4)	0.1638 (9)	0.0269 (4)	0.0820 (6)	0.0510 (5)
P1	0.0473 (4)	0.0698 (5)	0.0440 (4)	0.0201 (4)	0.0198 (3)	0.0101 (4)
F1	0.0812 (12)	0.1152 (16)	0.0748 (11)	0.0509 (11)	0.0357 (9)	0.0047 (10)
F2	0.0731 (11)	0.0886 (13)	0.0909 (14)	0.0053 (10)	0.0353 (10)	0.0225 (11)
F3	0.0722 (10)	0.1275 (16)	0.0568 (9)	0.0446 (11)	0.0237 (8)	0.0329 (10)
O1	0.0500 (8)	0.0477 (8)	0.0356 (7)	0.0228 (6)	0.0237 (6)	0.0144 (6)
O2	0.0478 (7)	0.0434 (7)	0.0423 (7)	0.0192 (6)	0.0257 (6)	0.0234 (6)
O3	0.0348 (6)	0.0399 (7)	0.0453 (7)	0.0123 (5)	0.0165 (6)	0.0142 (6)
O4	0.0402 (7)	0.0439 (7)	0.0471 (8)	0.0224 (6)	0.0220 (6)	0.0190 (6)
N1	0.0444 (9)	0.0320 (8)	0.0489 (9)	0.0155 (7)	0.0197 (7)	0.0111 (7)
C1	0.0560 (12)	0.0392 (10)	0.0764 (15)	0.0215 (9)	0.0368 (11)	0.0211 (10)
C2	0.0475 (11)	0.0378 (10)	0.0696 (14)	0.0139 (8)	0.0207 (10)	0.0197 (10)
C3	0.0679 (15)	0.0365 (10)	0.0662 (15)	0.0200 (10)	0.0193 (12)	0.0108 (10)
C4	0.0924 (19)	0.0481 (13)	0.0720 (17)	0.0325 (13)	0.0450 (15)	0.0100 (12)
C5	0.0654 (14)	0.0451 (11)	0.0606 (13)	0.0210 (10)	0.0344 (11)	0.0150 (10)
C6	0.0390 (9)	0.0567 (11)	0.0375 (9)	0.0219 (8)	0.0214 (7)	0.0220 (8)
C7	0.0685 (14)	0.0859 (18)	0.0451 (11)	0.0377 (13)	0.0361 (11)	0.0348 (12)
C8	0.0371 (8)	0.0506 (10)	0.0391 (9)	0.0195 (8)	0.0206 (7)	0.0201 (8)
C9	0.0382 (10)	0.0688 (15)	0.0622 (13)	0.0222 (10)	0.0211 (9)	0.0270 (11)
Cl2A	0.219 (10)	0.219 (11)	0.261 (16)	0.095 (8)	0.117 (11)	0.061 (12)
C11A	0.159 (9)	0.158 (9)	0.161 (9)	0.072 (7)	0.059 (6)	0.051 (7)
C12A	0.154 (8)	0.153 (9)	0.156 (8)	0.073 (7)	0.061 (6)	0.056 (7)
Cl3A	0.38 (2)	0.29 (2)	0.204 (12)	0.23 (2)	0.084 (16)	0.008 (13)
Cl2B	0.245 (12)	0.171 (9)	0.239 (16)	0.097 (8)	0.135 (10)	0.043 (10)
C11B	0.156 (8)	0.153 (8)	0.158 (9)	0.075 (7)	0.060 (6)	0.053 (6)
C12B	0.156 (9)	0.157 (9)	0.161 (9)	0.076 (7)	0.053 (6)	0.056 (7)
Cl3B	0.34 (2)	0.339 (19)	0.128 (8)	0.22 (2)	0.080 (12)	0.071 (10)

Geometric parameters (Å, º) top

Ru1—O1	2.0204 (14)	C7—H7A	0.9600
Ru1—O2	2.0232 (14)	C7—H7B	0.9600
Ru1—O4	2.0235 (13)	C7—H7C	0.9600
Ru1—O3	2.0256 (13)	C7—H7D	0.9600
Ru1—Ru1ⁱ	2.2738 (3)	C7—H7E	0.9600
Ru1—N1	2.2920 (17)	C7—H7F	0.9600
Cl1—C2	1.730 (3)	C8—C9	1.498 (3)
P1—F2ⁱⁱ	1.5795 (19)	C9—H9A	0.9600
P1—F2	1.5795 (19)	C9—H9B	0.9600
P1—F1ⁱⁱ	1.5896 (18)	C9—H9C	0.9600
P1—F1	1.5896 (18)	C9—H9D	0.9600
P1—F3ⁱⁱ	1.5965 (16)	C9—H9E	0.9600
P1—F3	1.5965 (16)	C9—H9F	0.9600
O1—C6	1.272 (2)	Cl2A—C11A	1.803 (16)
O2—C6ⁱ	1.267 (3)	C11A—C12A	1.493 (13)
O3—C8ⁱ	1.272 (2)	C11A—H11A	0.9700
O4—C8	1.271 (2)	C11A—H11B	0.9700
N1—C5	1.329 (3)	C12A—Cl3A	1.811 (16)
N1—C1	1.331 (3)	C12A—H12A	0.9700
C1—C2	1.379 (3)	C12A—H12B	0.9700
C1—H1	0.9300	Cl2B—C11B	1.826 (16)
C2—C3	1.364 (4)	C11B—C12B	1.476 (13)
C3—C4	1.373 (4)	C11B—H11C	0.9700
C3—H3	0.9300	C11B—H11D	0.9700
C4—C5	1.389 (3)	C12B—Cl3B	1.805 (16)
C4—H4	0.9300	C12B—H12C	0.9700
C5—H5	0.9300	C12B—H12D	0.9700
C6—C7	1.501 (3)

O1—Ru1—O2	178.70 (5)	N1—C5—H5	119.0
O1—Ru1—O4	90.18 (6)	C4—C5—H5	119.0
O2—Ru1—O4	89.69 (6)	O2ⁱ—C6—O1	122.70 (17)
O1—Ru1—O3	89.85 (6)	O2ⁱ—C6—C7	119.34 (19)
O2—Ru1—O3	90.25 (6)	O1—C6—C7	117.96 (19)
O4—Ru1—O3	178.83 (5)	C6—C7—H7A	109.5
O1—Ru1—Ru1ⁱ	89.66 (4)	C6—C7—H7B	109.5
O2—Ru1—Ru1ⁱ	89.04 (4)	H7A—C7—H7B	109.5
O4—Ru1—Ru1ⁱ	89.73 (4)	C6—C7—H7C	109.5
O3—Ru1—Ru1ⁱ	89.11 (4)	H7A—C7—H7C	109.5
O1—Ru1—N1	91.38 (6)	H7B—C7—H7C	109.5
O2—Ru1—N1	89.92 (6)	H7D—C7—H7E	109.5
O4—Ru1—N1	93.63 (6)	H7D—C7—H7F	109.5
O3—Ru1—N1	87.53 (6)	H7E—C7—H7F	109.5
Ru1ⁱ—Ru1—N1	176.48 (4)	O4—C8—O3ⁱ	122.84 (17)
F2ⁱⁱ—P1—F2	180.0	O4—C8—C9	118.51 (18)
F2ⁱⁱ—P1—F1ⁱⁱ	89.08 (12)	O3ⁱ—C8—C9	118.64 (18)
F2—P1—F1ⁱⁱ	90.92 (12)	C8—C9—H9A	109.5
F2ⁱⁱ—P1—F1	90.92 (12)	C8—C9—H9B	109.5
F2—P1—F1	89.08 (12)	H9A—C9—H9B	109.5
F1ⁱⁱ—P1—F1	180.00 (15)	C8—C9—H9C	109.5
F2ⁱⁱ—P1—F3ⁱⁱ	88.89 (11)	H9A—C9—H9C	109.5
F2—P1—F3ⁱⁱ	91.11 (11)	H9B—C9—H9C	109.5
F1ⁱⁱ—P1—F3ⁱⁱ	90.71 (11)	H9D—C9—H9E	109.5
F1—P1—F3ⁱⁱ	89.29 (11)	H9D—C9—H9F	109.5
F2ⁱⁱ—P1—F3	91.11 (11)	H9E—C9—H9F	109.5
F2—P1—F3	88.89 (11)	C12A—C11A—Cl2A	104.0 (18)
F1ⁱⁱ—P1—F3	89.29 (11)	C12A—C11A—H11A	111.0
F1—P1—F3	90.71 (11)	Cl2A—C11A—H11A	110.9
F3ⁱⁱ—P1—F3	180.0	C12A—C11A—H11B	111.0
C6—O1—Ru1	118.99 (13)	Cl2A—C11A—H11B	111.0
C6ⁱ—O2—Ru1	119.58 (12)	H11A—C11A—H11B	109.0
C8ⁱ—O3—Ru1	119.40 (12)	C11A—C12A—Cl3A	99.1 (17)
C8—O4—Ru1	118.90 (12)	C11A—C12A—H12A	112.0
C5—N1—C1	118.17 (19)	Cl3A—C12A—H12A	112.0
C5—N1—Ru1	123.95 (15)	C11A—C12A—H12B	112.0
C1—N1—Ru1	117.87 (15)	Cl3A—C12A—H12B	112.0
N1—C1—C2	122.2 (2)	H12A—C12A—H12B	109.6
N1—C1—H1	118.9	C12B—C11B—Cl2B	114 (2)
C2—C1—H1	118.9	C12B—C11B—H11C	108.8
C3—C2—C1	120.3 (2)	Cl2B—C11B—H11C	108.8
C3—C2—Cl1	121.60 (19)	C12B—C11B—H11D	108.8
C1—C2—Cl1	118.1 (2)	Cl2B—C11B—H11D	108.8
C2—C3—C4	117.6 (2)	H11C—C11B—H11D	107.7
C2—C3—H3	121.2	C11B—C12B—Cl3B	102.6 (18)
C4—C3—H3	121.2	C11B—C12B—H12C	111.3
C3—C4—C5	119.7 (2)	Cl3B—C12B—H12C	111.3
C3—C4—H4	120.2	C11B—C12B—H12D	111.3
C5—C4—H4	120.2	Cl3B—C12B—H12D	111.3
N1—C5—C4	122.1 (2)	H12C—C12B—H12D	109.2

C5—N1—C1—C2	−1.4 (4)	Ru1—N1—C5—C4	−177.7 (2)
Ru1—N1—C1—C2	178.28 (17)	C3—C4—C5—N1	−1.3 (4)
N1—C1—C2—C3	0.2 (4)	Ru1—O1—C6—O2ⁱ	−1.9 (3)
N1—C1—C2—Cl1	−179.25 (19)	Ru1—O1—C6—C7	178.49 (14)
C1—C2—C3—C4	0.5 (4)	Ru1—O4—C8—O3ⁱ	1.7 (3)
Cl1—C2—C3—C4	179.9 (2)	Ru1—O4—C8—C9	−179.58 (14)
C2—C3—C4—C5	0.1 (4)	Cl2A—C11A—C12A—Cl3A	−164 (3)
C1—N1—C5—C4	1.9 (4)	Cl2B—C11B—C12B—Cl3B	−154 (3)

Symmetry codes: (i) −x+1, −y, −z; (ii) −x+2, −y, −z+1.

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Tetra-μ-acetato-κ8O:O′-bis­[(3-chloro­pyridine-κN)ruthenium(II,III)](Ru—Ru) hexa­fluorido­phosphate 1,2-di­chloro­ethane monosolvate

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Tetra-μ-acetato-κ⁸O:O′-bis[(3-chloropyridine-κN)ruthenium(II,III)](Ru—Ru) hexafluoridophosphate 1,2-dichloroethane monosolvate