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In the disolvated title salt, (C13H10NO)[SnCl4(C10H8NO)]·2CH3OH, the SnIV atom is chelated by the N,O-bidentate 2-methyl­quinolin-8-olate ion and is further coordinated by four chloride ions, showing a distorted octa­hedral SnNOCl4 geometry. In the crystal, the cation and anion are linked to the methanol mol­ecules by O—H...O and N—H...O hydrogen bonds.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536811031461/xu5283sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536811031461/xu5283Isup2.hkl
Contains datablock I

CCDC reference: 845226

Key indicators

  • Single-crystal X-ray study
  • T = 100 K
  • Mean [sigma](C-C) = 0.005 Å
  • R factor = 0.041
  • wR factor = 0.095
  • Data-to-parameter ratio = 17.3

checkCIF/PLATON results

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Alert level C PLAT029_ALERT_3_C _diffrn_measured_fraction_theta_full Low ....... 0.965 PLAT042_ALERT_1_C Calc. and Reported MoietyFormula Strings Differ ? PLAT910_ALERT_3_C Missing # of FCF Reflections Below Th(Min) ..... 4 PLAT912_ALERT_4_C Missing # of FCF Reflections Above STh/L= 0.600 194
Alert level G PLAT002_ALERT_2_G Number of Distance or Angle Restraints on AtSite 8 PLAT005_ALERT_5_G No _iucr_refine_instructions_details in CIF .... ? PLAT154_ALERT_1_G The su's on the Cell Angles are Equal .......... 0.00300 Deg. PLAT432_ALERT_2_G Short Inter X...Y Contact O4 .. C23 .. 2.93 Ang. PLAT860_ALERT_3_G Note: Number of Least-Squares Restraints ....... 4
0 ALERT level A = Most likely a serious problem - resolve or explain 0 ALERT level B = A potentially serious problem, consider carefully 4 ALERT level C = Check. Ensure it is not caused by an omission or oversight 5 ALERT level G = General information/check it is not something unexpected 2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 2 ALERT type 2 Indicator that the structure model may be wrong or deficient 3 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion 1 ALERT type 5 Informative message, check

Comment top

We have been attempting to synthesize mixed-chelate tin(IV) compounds; in a recent study, we reacted stannic chloride with 8-hydroxyquinoline and 2-methyl-8-hydroxyquinoline (Vafaee et al., 2010). However, the reaction yielded 2-methyl-8-hydroxyquinolinium tetrachlorido(quinolin-8-olato)stannate as an acetonitrile solvate. The ligand that enages in coordination is the one that is less sterically crowded. A similar synthesis but with 10-hydroxybenzo[h]quinoline and 2-methyl-8-hydroxyquinoline in methanol medium yielded the di-solvated title salt (Scheme I, Fig. 1). Similarly, the less sterically crowded ligand engages in chelation, so that the more crowded ligand is now protonated. The SnIV atom shows octahedral SnNOCl4 coordination. The cation and anion are linked to the methanol molecules by O–H···O and N–H···O hydrogen bonds. One of the solvent molecules functions only as acceptor whereas the other functions both as a donor as well as acceptor.

Related literature top

For the related compound, solvated 2-methyl-8-hydroxyquinolinium tetrachlorido(quinolin-8-olato)stannate, see: Vafaee et al. (2010).

Experimental top

Stannic chloride pentahydrate (0.35 g, 1 mmol), 10-hydroxybenzo[h]quinoline (0.20 g, 1 mmol) and 2-methyl-8-hydroxyquinoline (0.16 g, 1 mmol) were loaded into a convection tube and the tube was filled with dry methanol and kept at 333 K. Yellow crystals were collected from the side arm after several days (in approximately yield 80%, m.p. 538 K).

Refinement top

Carbon-bound H-atoms were placed in calculated positions [C—H 0.95 to 0.98 Å, Uiso(H) 1.2 to 1.5Ueq(C)] and were included in the refinement in the riding model approximation.

The ammonium and hydroxy H-atoms were located in a difference Fourier map, and were refined with distance restraints of N–H 0.88±0.01, O–H 0.84±0.01 Å; their temperature factors were refined.

The final difference Fourier map had a peak as well as a hole in the vicinity ot Sn1.

Omitted from the refinement was the (0 0 2) reflection.

Computing details top

Data collection: CrysAlis PRO (Agilent, 2010); cell refinement: CrysAlis PRO (Agilent, 2010); data reduction: CrysAlis PRO (Agilent, 2010); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: X-SEED (Barbour, 2001); software used to prepare material for publication: publCIF (Westrip, 2010).

Figures top
[Figure 1] Fig. 1. Thermal ellipsoid plot (Barbour, 2001) of (C14H10NO)[SnCl4(C10H8NO)].2CH3OH, at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
10-Hydroxybenzo[h]quinolinium tetrachlorido(2-methylquinolin-8-olato-κ2N,O)stannate(IV) methanol disolvate top
Crystal data top
(C13H10NO)[SnCl4(C10H8NO)]·2CH4OZ = 2
Mr = 678.97F(000) = 680
Triclinic, P1Dx = 1.701 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 7.5645 (2) ÅCell parameters from 6565 reflections
b = 10.1112 (3) Åθ = 2.3–29.3°
c = 17.7837 (5) ŵ = 1.40 mm1
α = 98.105 (3)°T = 100 K
β = 95.653 (3)°Prism, yellow
γ = 97.509 (3)°0.30 × 0.30 × 0.10 mm
V = 1325.56 (6) Å3
Data collection top
Agilent SuperNova Dual
diffractometer with an Atlas detector
5871 independent reflections
Radiation source: SuperNova (Mo) X-ray Source5239 reflections with I > 2σ(I)
Mirror monochromatorRint = 0.056
Detector resolution: 10.4041 pixels mm-1θmax = 27.5°, θmin = 2.5°
ω scansh = 99
Absorption correction: multi-scan
(CrysAlis PRO; Agilent, 2010)
k = 1012
Tmin = 0.678, Tmax = 0.873l = 2223
10548 measured reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.041Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.095H atoms treated by a mixture of independent and constrained refinement
S = 1.11 w = 1/[σ2(Fo2) + (0.0329P)2 + 1.5116P]
where P = (Fo2 + 2Fc2)/3
5871 reflections(Δ/σ)max = 0.001
340 parametersΔρmax = 1.23 e Å3
4 restraintsΔρmin = 1.14 e Å3
Crystal data top
(C13H10NO)[SnCl4(C10H8NO)]·2CH4Oγ = 97.509 (3)°
Mr = 678.97V = 1325.56 (6) Å3
Triclinic, P1Z = 2
a = 7.5645 (2) ÅMo Kα radiation
b = 10.1112 (3) ŵ = 1.40 mm1
c = 17.7837 (5) ÅT = 100 K
α = 98.105 (3)°0.30 × 0.30 × 0.10 mm
β = 95.653 (3)°
Data collection top
Agilent SuperNova Dual
diffractometer with an Atlas detector
5871 independent reflections
Absorption correction: multi-scan
(CrysAlis PRO; Agilent, 2010)
5239 reflections with I > 2σ(I)
Tmin = 0.678, Tmax = 0.873Rint = 0.056
10548 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.0414 restraints
wR(F2) = 0.095H atoms treated by a mixture of independent and constrained refinement
S = 1.11Δρmax = 1.23 e Å3
5871 reflectionsΔρmin = 1.14 e Å3
340 parameters
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Sn10.86883 (3)0.09428 (2)0.789295 (13)0.01747 (8)
Cl10.86363 (16)0.14417 (9)0.78823 (6)0.0417 (3)
Cl20.63271 (12)0.06051 (9)0.68485 (5)0.02469 (19)
Cl30.66698 (12)0.09658 (10)0.88638 (5)0.0303 (2)
Cl41.10456 (13)0.09761 (11)0.70839 (5)0.0340 (2)
O10.8665 (3)0.2980 (2)0.78929 (13)0.0164 (5)
O20.3798 (4)0.4948 (3)0.64356 (15)0.0274 (6)
H20.453 (5)0.464 (4)0.672 (2)0.041*
O30.5605 (3)0.4044 (3)0.75020 (15)0.0261 (6)
H30.649 (4)0.363 (4)0.752 (3)0.039*
O40.4163 (4)0.7760 (3)0.73826 (19)0.0459 (8)
H40.507 (5)0.836 (4)0.749 (3)0.069*
N11.0833 (4)0.1902 (3)0.88721 (15)0.0165 (6)
N20.2612 (4)0.6931 (3)0.58555 (18)0.0226 (6)
H10.304 (5)0.673 (4)0.6302 (12)0.027*
C11.0870 (4)0.3279 (3)0.89787 (19)0.0164 (7)
C20.9706 (4)0.3813 (3)0.84513 (19)0.0165 (7)
C30.9725 (5)0.5190 (3)0.8541 (2)0.0210 (7)
H3A0.89640.55640.81970.025*
C41.0860 (5)0.6053 (4)0.9140 (2)0.0240 (8)
H4A1.08430.69990.91910.029*
C51.1982 (5)0.5561 (4)0.9646 (2)0.0229 (7)
H51.27400.61591.00430.028*
C61.2003 (4)0.4154 (3)0.95736 (19)0.0192 (7)
C71.3109 (5)0.3538 (4)1.0069 (2)0.0234 (8)
H71.38810.40781.04840.028*
C81.3067 (5)0.2178 (4)0.9950 (2)0.0254 (8)
H81.38210.17731.02810.031*
C91.1914 (5)0.1355 (4)0.9339 (2)0.0213 (7)
C101.1918 (6)0.0137 (4)0.9208 (2)0.0320 (9)
H10A1.20770.04330.86730.048*
H10B1.07750.05960.93210.048*
H10C1.29070.03600.95430.048*
C110.2292 (4)0.6061 (4)0.5177 (2)0.0189 (7)
C120.2715 (4)0.4711 (4)0.5116 (2)0.0202 (7)
C130.3479 (4)0.4138 (4)0.5739 (2)0.0215 (7)
C140.3861 (5)0.2837 (4)0.5632 (2)0.0245 (8)
H140.43540.24650.60530.029*
C150.3524 (5)0.2065 (4)0.4906 (2)0.0256 (8)
H150.38100.11710.48350.031*
C160.2783 (5)0.2574 (4)0.4289 (2)0.0256 (8)
H160.25630.20320.37980.031*
C170.2354 (4)0.3891 (4)0.4384 (2)0.0214 (7)
C180.1589 (5)0.4437 (4)0.3745 (2)0.0263 (8)
H180.13620.38890.32560.032*
C190.1186 (5)0.5699 (4)0.3819 (2)0.0262 (8)
H190.06540.60170.33850.031*
C200.1542 (4)0.6568 (4)0.4535 (2)0.0222 (7)
C210.1174 (5)0.7900 (4)0.4624 (2)0.0295 (9)
H210.06810.82460.41930.035*
C220.1518 (5)0.8716 (4)0.5327 (2)0.0288 (8)
H220.12530.96150.53880.035*
C230.2259 (5)0.8189 (4)0.5943 (2)0.0290 (8)
H230.25170.87350.64320.035*
C240.4551 (6)0.3602 (4)0.8063 (2)0.0329 (9)
H24A0.52700.38070.85660.049*
H24B0.41630.26260.79350.049*
H24C0.34960.40690.80750.049*
C250.4131 (7)0.7114 (5)0.8025 (2)0.0414 (10)
H25A0.52180.66910.80940.062*
H25B0.30700.64200.79550.062*
H25C0.40830.77770.84790.062*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Sn10.02318 (13)0.01235 (12)0.01641 (13)0.00327 (9)0.00053 (9)0.00207 (8)
Cl10.0566 (7)0.0134 (4)0.0472 (6)0.0041 (4)0.0256 (5)0.0014 (4)
Cl20.0283 (4)0.0200 (4)0.0237 (4)0.0035 (3)0.0062 (4)0.0027 (3)
Cl30.0279 (5)0.0373 (5)0.0282 (5)0.0008 (4)0.0084 (4)0.0156 (4)
Cl40.0331 (5)0.0530 (6)0.0187 (4)0.0224 (5)0.0053 (4)0.0007 (4)
O10.0193 (11)0.0139 (11)0.0167 (11)0.0049 (9)0.0023 (9)0.0027 (9)
O20.0339 (15)0.0294 (15)0.0213 (14)0.0096 (12)0.0004 (12)0.0102 (11)
O30.0230 (13)0.0351 (15)0.0266 (14)0.0133 (11)0.0089 (11)0.0143 (11)
O40.0452 (18)0.049 (2)0.0390 (18)0.0141 (15)0.0075 (15)0.0209 (15)
N10.0194 (13)0.0164 (14)0.0144 (14)0.0025 (11)0.0040 (11)0.0031 (11)
N20.0192 (14)0.0256 (16)0.0242 (16)0.0015 (13)0.0018 (13)0.0104 (13)
C10.0184 (15)0.0135 (15)0.0180 (16)0.0004 (13)0.0074 (13)0.0036 (12)
C20.0167 (15)0.0177 (16)0.0167 (16)0.0029 (13)0.0083 (13)0.0039 (12)
C30.0242 (17)0.0179 (17)0.0240 (18)0.0047 (14)0.0099 (15)0.0078 (14)
C40.0272 (18)0.0135 (16)0.032 (2)0.0002 (14)0.0135 (16)0.0024 (14)
C50.0218 (17)0.0196 (18)0.0244 (19)0.0027 (14)0.0071 (15)0.0042 (14)
C60.0171 (16)0.0209 (17)0.0186 (17)0.0020 (13)0.0088 (14)0.0001 (13)
C70.0196 (17)0.029 (2)0.0192 (18)0.0016 (15)0.0024 (14)0.0036 (14)
C80.0246 (18)0.029 (2)0.0218 (18)0.0049 (16)0.0029 (15)0.0050 (15)
C90.0249 (17)0.0204 (18)0.0192 (17)0.0047 (14)0.0020 (14)0.0047 (13)
C100.040 (2)0.0217 (19)0.032 (2)0.0077 (17)0.0115 (18)0.0049 (16)
C110.0128 (15)0.0243 (18)0.0214 (18)0.0013 (13)0.0046 (13)0.0090 (14)
C120.0129 (15)0.0285 (19)0.0222 (18)0.0034 (14)0.0064 (14)0.0109 (14)
C130.0182 (16)0.0268 (19)0.0217 (18)0.0034 (14)0.0051 (14)0.0089 (14)
C140.0200 (17)0.029 (2)0.029 (2)0.0058 (15)0.0065 (15)0.0139 (15)
C150.0227 (18)0.0247 (19)0.033 (2)0.0053 (15)0.0108 (16)0.0089 (15)
C160.0238 (18)0.031 (2)0.0235 (19)0.0039 (16)0.0095 (15)0.0048 (15)
C170.0166 (16)0.0291 (19)0.0215 (18)0.0039 (14)0.0079 (14)0.0100 (14)
C180.0283 (19)0.036 (2)0.0170 (17)0.0049 (16)0.0064 (15)0.0081 (15)
C190.0215 (17)0.040 (2)0.0220 (19)0.0068 (16)0.0067 (15)0.0156 (16)
C200.0170 (16)0.030 (2)0.0236 (18)0.0041 (14)0.0071 (14)0.0135 (15)
C210.0214 (18)0.038 (2)0.035 (2)0.0083 (17)0.0081 (17)0.0216 (18)
C220.0288 (19)0.027 (2)0.034 (2)0.0071 (16)0.0080 (17)0.0113 (16)
C230.0278 (19)0.024 (2)0.036 (2)0.0037 (16)0.0039 (17)0.0075 (16)
C240.037 (2)0.034 (2)0.034 (2)0.0086 (18)0.0181 (18)0.0113 (17)
C250.055 (3)0.037 (2)0.033 (2)0.006 (2)0.009 (2)0.0052 (19)
Geometric parameters (Å, º) top
Sn1—O12.063 (2)C9—C101.494 (5)
Sn1—N12.272 (3)C10—H10A0.9800
Sn1—Cl42.3988 (10)C10—H10B0.9800
Sn1—Cl22.4011 (8)C10—H10C0.9800
Sn1—Cl12.4036 (9)C11—C201.414 (5)
Sn1—Cl32.4145 (9)C11—C121.435 (5)
O1—C21.324 (4)C12—C171.422 (5)
O2—C131.366 (4)C12—C131.429 (5)
O2—H20.843 (10)C13—C141.375 (5)
O3—C241.421 (5)C14—C151.393 (5)
O3—H30.835 (10)C14—H140.9500
O4—C251.395 (5)C15—C161.376 (5)
O4—H40.838 (10)C15—H150.9500
N1—C91.333 (4)C16—C171.403 (5)
N1—C11.374 (4)C16—H160.9500
N2—C231.325 (5)C17—C181.436 (5)
N2—C111.369 (5)C18—C191.342 (5)
N2—H10.888 (10)C18—H180.9500
C1—C61.413 (5)C19—C201.423 (5)
C1—C21.433 (5)C19—H190.9500
C2—C31.377 (5)C20—C211.401 (5)
C3—C41.412 (5)C21—C221.380 (6)
C3—H3A0.9500C21—H210.9500
C4—C51.366 (5)C22—C231.385 (5)
C4—H4A0.9500C22—H220.9500
C5—C61.413 (5)C23—H230.9500
C5—H50.9500C24—H24A0.9800
C6—C71.418 (5)C24—H24B0.9800
C7—C81.358 (5)C24—H24C0.9800
C7—H70.9500C25—H25A0.9800
C8—C91.415 (5)C25—H25B0.9800
C8—H80.9500C25—H25C0.9800
O1—Sn1—N177.28 (9)C9—C10—H10C109.5
O1—Sn1—Cl490.31 (7)H10A—C10—H10C109.5
N1—Sn1—Cl486.85 (7)H10B—C10—H10C109.5
O1—Sn1—Cl286.01 (6)N2—C11—C20116.6 (3)
N1—Sn1—Cl2163.26 (7)N2—C11—C12121.9 (3)
Cl4—Sn1—Cl294.22 (3)C20—C11—C12121.5 (3)
O1—Sn1—Cl1178.56 (7)C17—C12—C13117.9 (3)
N1—Sn1—Cl1103.94 (7)C17—C12—C11117.7 (3)
Cl4—Sn1—Cl190.53 (4)C13—C12—C11124.4 (3)
Cl2—Sn1—Cl192.77 (3)O2—C13—C14122.6 (3)
O1—Sn1—Cl390.14 (7)O2—C13—C12116.5 (3)
N1—Sn1—Cl384.93 (7)C14—C13—C12120.8 (3)
Cl4—Sn1—Cl3171.46 (3)C13—C14—C15120.0 (3)
Cl2—Sn1—Cl394.32 (3)C13—C14—H14120.0
Cl1—Sn1—Cl389.20 (4)C15—C14—H14120.0
C2—O1—Sn1116.63 (19)C16—C15—C14121.1 (3)
C13—O2—H2109 (3)C16—C15—H15119.5
C24—O3—H3105 (3)C14—C15—H15119.5
C25—O4—H4104 (4)C15—C16—C17120.2 (3)
C9—N1—C1119.5 (3)C15—C16—H16119.9
C9—N1—Sn1131.3 (2)C17—C16—H16119.9
C1—N1—Sn1109.2 (2)C16—C17—C12119.9 (3)
C23—N2—C11124.4 (3)C16—C17—C18120.7 (3)
C23—N2—H1110 (3)C12—C17—C18119.3 (3)
C11—N2—H1126 (3)C19—C18—C17121.8 (3)
N1—C1—C6122.7 (3)C19—C18—H18119.1
N1—C1—C2117.1 (3)C17—C18—H18119.1
C6—C1—C2120.3 (3)C18—C19—C20121.1 (3)
O1—C2—C3122.2 (3)C18—C19—H19119.4
O1—C2—C1119.5 (3)C20—C19—H19119.4
C3—C2—C1118.3 (3)C21—C20—C11119.3 (3)
C2—C3—C4120.8 (3)C21—C20—C19122.2 (3)
C2—C3—H3A119.6C11—C20—C19118.5 (3)
C4—C3—H3A119.6C22—C21—C20121.0 (4)
C5—C4—C3121.7 (3)C22—C21—H21119.5
C5—C4—H4A119.2C20—C21—H21119.5
C3—C4—H4A119.2C21—C22—C23118.2 (4)
C4—C5—C6119.3 (3)C21—C22—H22120.9
C4—C5—H5120.3C23—C22—H22120.9
C6—C5—H5120.3N2—C23—C22120.6 (4)
C1—C6—C5119.6 (3)N2—C23—H23119.7
C1—C6—C7116.4 (3)C22—C23—H23119.7
C5—C6—C7123.9 (3)O3—C24—H24A109.5
C8—C7—C6120.1 (3)O3—C24—H24B109.5
C8—C7—H7120.0H24A—C24—H24B109.5
C6—C7—H7120.0O3—C24—H24C109.5
C7—C8—C9120.8 (3)H24A—C24—H24C109.5
C7—C8—H8119.6H24B—C24—H24C109.5
C9—C8—H8119.6O4—C25—H25A109.5
N1—C9—C8120.5 (3)O4—C25—H25B109.5
N1—C9—C10119.5 (3)H25A—C25—H25B109.5
C8—C9—C10119.9 (3)O4—C25—H25C109.5
C9—C10—H10A109.5H25A—C25—H25C109.5
C9—C10—H10B109.5H25B—C25—H25C109.5
H10A—C10—H10B109.5
N1—Sn1—O1—C25.0 (2)C1—N1—C9—C10178.0 (3)
Cl4—Sn1—O1—C291.7 (2)Sn1—N1—C9—C105.3 (5)
Cl2—Sn1—O1—C2174.1 (2)C7—C8—C9—N10.7 (6)
Cl3—Sn1—O1—C279.8 (2)C7—C8—C9—C10178.6 (4)
O1—Sn1—N1—C9178.4 (3)C23—N2—C11—C200.3 (5)
Cl4—Sn1—N1—C987.4 (3)C23—N2—C11—C12179.5 (3)
Cl2—Sn1—N1—C9178.4 (2)N2—C11—C12—C17179.2 (3)
Cl1—Sn1—N1—C92.4 (3)C20—C11—C12—C170.0 (5)
Cl3—Sn1—N1—C990.3 (3)N2—C11—C12—C130.6 (5)
O1—Sn1—N1—C14.6 (2)C20—C11—C12—C13179.8 (3)
Cl4—Sn1—N1—C195.7 (2)C17—C12—C13—O2179.5 (3)
Cl2—Sn1—N1—C11.5 (4)C11—C12—C13—O20.7 (5)
Cl1—Sn1—N1—C1174.57 (19)C17—C12—C13—C140.3 (5)
Cl3—Sn1—N1—C186.7 (2)C11—C12—C13—C14179.4 (3)
C9—N1—C1—C60.7 (5)O2—C13—C14—C15179.3 (3)
Sn1—N1—C1—C6176.6 (3)C12—C13—C14—C150.8 (5)
C9—N1—C1—C2178.8 (3)C13—C14—C15—C161.0 (5)
Sn1—N1—C1—C23.8 (3)C14—C15—C16—C170.0 (5)
Sn1—O1—C2—C3175.9 (2)C15—C16—C17—C121.2 (5)
Sn1—O1—C2—C14.7 (4)C15—C16—C17—C18179.7 (3)
N1—C1—C2—O10.2 (4)C13—C12—C17—C161.3 (5)
C6—C1—C2—O1179.4 (3)C11—C12—C17—C16178.4 (3)
N1—C1—C2—C3179.6 (3)C13—C12—C17—C18179.9 (3)
C6—C1—C2—C30.0 (5)C11—C12—C17—C180.1 (5)
O1—C2—C3—C4179.5 (3)C16—C17—C18—C19179.2 (3)
C1—C2—C3—C40.2 (5)C12—C17—C18—C190.7 (5)
C2—C3—C4—C50.3 (5)C17—C18—C19—C201.5 (6)
C3—C4—C5—C60.3 (5)N2—C11—C20—C210.1 (5)
N1—C1—C6—C5179.5 (3)C12—C11—C20—C21179.2 (3)
C2—C1—C6—C50.0 (5)N2—C11—C20—C19179.9 (3)
N1—C1—C6—C70.5 (5)C12—C11—C20—C190.8 (5)
C2—C1—C6—C7180.0 (3)C18—C19—C20—C21178.4 (3)
C4—C5—C6—C10.2 (5)C18—C19—C20—C111.6 (5)
C4—C5—C6—C7179.8 (3)C11—C20—C21—C220.6 (5)
C1—C6—C7—C81.2 (5)C19—C20—C21—C22179.4 (4)
C5—C6—C7—C8178.9 (3)C20—C21—C22—C230.9 (6)
C6—C7—C8—C90.6 (5)C11—N2—C23—C220.0 (6)
C1—N1—C9—C81.3 (5)C21—C22—C23—N20.5 (6)
Sn1—N1—C9—C8175.4 (2)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O2—H2···O30.84 (1)1.75 (2)2.570 (3)164 (5)
O3—H3···O10.84 (1)1.94 (2)2.746 (3)162 (4)
N2—H1···O40.89 (1)2.09 (3)2.816 (4)138 (3)

Experimental details

Crystal data
Chemical formula(C13H10NO)[SnCl4(C10H8NO)]·2CH4O
Mr678.97
Crystal system, space groupTriclinic, P1
Temperature (K)100
a, b, c (Å)7.5645 (2), 10.1112 (3), 17.7837 (5)
α, β, γ (°)98.105 (3), 95.653 (3), 97.509 (3)
V3)1325.56 (6)
Z2
Radiation typeMo Kα
µ (mm1)1.40
Crystal size (mm)0.30 × 0.30 × 0.10
Data collection
DiffractometerAgilent SuperNova Dual
diffractometer with an Atlas detector
Absorption correctionMulti-scan
(CrysAlis PRO; Agilent, 2010)
Tmin, Tmax0.678, 0.873
No. of measured, independent and
observed [I > 2σ(I)] reflections
10548, 5871, 5239
Rint0.056
(sin θ/λ)max1)0.649
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.041, 0.095, 1.11
No. of reflections5871
No. of parameters340
No. of restraints4
H-atom treatmentH atoms treated by a mixture of independent and constrained refinement
Δρmax, Δρmin (e Å3)1.23, 1.14

Computer programs: CrysAlis PRO (Agilent, 2010), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), X-SEED (Barbour, 2001), publCIF (Westrip, 2010).

Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O2—H2···O30.84 (1)1.75 (2)2.570 (3)164 (5)
O3—H3···O10.84 (1)1.94 (2)2.746 (3)162 (4)
N2—H1···O40.89 (1)2.09 (3)2.816 (4)138 (3)
 

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