Crystal structure of (2,11-di­aza­[3.3](2,6)pyridino­phane-κ⁴N,N′,N′′,N′′′)(1,6,7,12-tetra­aza­perylene-κ²N¹,N¹²)ruthenium(II) bis­(hexa­fluorido­phosphate) aceto­nitrile 1.422-solvate

The highlighted ruthenium complex forms discrete dimers by π–π stacking inter­actions and hydrogen bonds. This combination of inter­actions results in an unusual nearly face-to-face π–π stacking mode.

Key indicators

• Single-crystal X-ray study
• T = 150 K
• Mean [sigma](C-C) = 0.004 Å
• Disorder in solvent or counterion
• R factor = 0.048
• wR factor = 0.146
• Data-to-parameter ratio = 14.5

checkCIF/PLATON results

No syntax errors found



Alert level B
CRYSS02_ALERT_3_B  The value of _exptl_crystal_size_max is > 1.0
   Maximum crystal size given =   1.300
            Crystal system given = monoclinic

Alert level C
PLAT250_ALERT_2_C Large U3/U1 Ratio for Average U(i,j) Tensor ....        2.2 Note
PLAT250_ALERT_2_C Large U3/U1 Ratio for Average U(i,j) Tensor ....        2.6 Note
PLAT480_ALERT_4_C Long H...A H-Bond Reported H5N    ..  N8      ..       2.69 Ang.
PLAT480_ALERT_4_C Long H...A H-Bond Reported H3     ..  F12A_A  ..       2.60 Ang.
PLAT480_ALERT_4_C Long H...A H-Bond Reported H17A   ..  N9_A    ..       2.65 Ang.
PLAT480_ALERT_4_C Long H...A H-Bond Reported H19    ..  F9B_B   ..       2.61 Ang.
PLAT480_ALERT_4_C Long H...A H-Bond Reported H32C_A ..  F1A_A   ..       2.58 Ang.
PLAT906_ALERT_3_C Large K value in the Analysis of Variance ......      2.297 Check
PLAT971_ALERT_2_C Check Calcd Residual Density  1.00A From     Ru1       1.86 eA-3

Alert level G
PLAT002_ALERT_2_G Number of Distance or Angle Restraints on AtSite         34 Note
PLAT003_ALERT_2_G Number of Uiso or Uij Restrained non-H Atoms ...         17 Report
PLAT007_ALERT_5_G Number of Unrefined Donor-H Atoms ..............          2 Report
PLAT042_ALERT_1_G Calc. and Reported MoietyFormula Strings  Differ     Please Check
PLAT063_ALERT_4_G Crystal Size Likely too Large for Beam Size ....       1.30 mm
PLAT171_ALERT_4_G The CIF-Embedded .res File Contains EADP Records          2 Report
PLAT175_ALERT_4_G The CIF-Embedded .res File Contains SAME Records          3 Report
PLAT178_ALERT_4_G The CIF-Embedded .res File Contains SIMU Records          1 Report
PLAT302_ALERT_4_G Anion/Solvent Disorder ............ Percentage =        100 Note
PLAT333_ALERT_2_G Check Large Av C6-Ring C-C Dist. C9     -C14           1.42 Ang.
PLAT432_ALERT_2_G Short Inter X...Y Contact  F10B_B ..  C26     ..       2.97 Ang.
PLAT432_ALERT_2_G Short Inter X...Y Contact  F3B_B  ..  C10     ..       2.93 Ang.
PLAT432_ALERT_2_G Short Inter X...Y Contact  F3B_B  ..  C9      ..       2.94 Ang.
PLAT432_ALERT_2_G Short Inter X...Y Contact  F6B_B  ..  C15     ..       2.94 Ang.
PLAT720_ALERT_4_G Number of Unusual/Non-Standard Labels ..........         34 Note
PLAT793_ALERT_4_G The Model has Chirality at N3      .............          S Verify
PLAT793_ALERT_4_G The Model has Chirality at N5      .............          S Verify
PLAT811_ALERT_5_G No ADDSYM Analysis: Too Many Excluded Atoms ....          ! Info
PLAT860_ALERT_3_G Number of Least-Squares Restraints .............        183 Note
PLAT912_ALERT_4_G Missing # of FCF Reflections Above STh/L=  0.600        132 Note

   0 ALERT level A = Most likely a serious problem - resolve or explain
   1 ALERT level B = A potentially serious problem, consider carefully
   9 ALERT level C = Check. Ensure it is not caused by an omission or oversight
  20 ALERT level G = General information/check it is not something unexpected

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  10 ALERT type 2 Indicator that the structure model may be wrong or deficient
   3 ALERT type 3 Indicator that the structure quality may be low
  14 ALERT type 4 Improvement, methodology, query or suggestion
   2 ALERT type 5 Informative message, check

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S1. Chemical context

Heteroaromatic ligands with more than three fused rings are commonly called large-surface ligands. These ligand have attracted attention due to their use as connecting building blocks for supra­molecular assemblies. If large-surface ligands feature more than one ligand donor site, connection between neighboring complexes can be realized through normal metal coordination, (Ishow et al., 1998), but the large π system also allows for strong π–π stacking inter­actions. (Kammer et al., 2006; Gut et al., 2002). In order to study the properties of ruthenium complexes containing large-surface ligands, we have recently reported an easy entry to such complexes (Brietzke, Mickler, Kelling, Schilde et al., 2012). Therein, we formulated the advantages of the macrocycle 2,11-di­methyl-2,11-di­aza­[3.3](2,6)-pyridino­phane (L–N₄Me₂) over bi­pyridine (bpy)-type ligands in saturating the coordination sphere of an o­cta­hedral ruthenium complex containing the large-surface ligand of inter­est. The microwave-assisted synthesis of the precursor [Ru(L–N₄Me₂)]²⁺, starting from [Ru(DMSO)₄Cl₂] and L–N₄Me₂, in an ethano­lic solution finished within 30 min. It is not only fast, but also reproducible with only few byproducts, and hence requires no labor-intensive workup. Moreover, using the C_2v symmetric macrocycle rather than bi­pyridine-type ligands avoids the formation of mono- and dinuclear complexes with multiple stereoisomeric forms (Brietzke, Mickler, Kelling & Holdt, 2012; Brietzke et al., 2014). To test the applicability of our microwave-assisted synthetic strategy for use with other related macrocyclic ligands, we choose the unmethyl­ated parent compound of L–N₄Me₂, 2,11-di­aza­[3.3](2,6)-pyridino­phane (L–N₄H₂) as a new ligand for Ru^II. Herein, we present the structure of the complex [Ru(L–N₄H₂)tape](PF₆)₂, (L–N₄H₂ = 2,11-di­aza­[3.3](2,6)pyridino­phane; tape = 1,6,7,12-tetra­aza­perylene), obtained as its aceto­nitrile solvate.

S2. Structural commentary

Fig. 1 illustrates the molecular structure of the complex [Ru(L–N₄H₂)tape]²⁺ in [Ru(C₁₄H₁₆N₄)(C₁₆H₈N₄](PF₆)₂·1.422 C₂H₃N. The Ru—N bond lengths formed by the tape ligand (Table 1) are very close to those reported earlier for [Ru(L–N₄Me₂)tape]²⁺ (Brietzke, Mickler, Kelling, Schilde et al., 2012). The deviation of the N_amine—Ru—N_amine angle [153.79 (10)°] from the idealized value of 180° is slightly larger than for analogous ruthenium L–N₄Me₂ complexes [155.46 (9)–155.93 (17)°; Brietzke, Mickler, Kelling, Schilde et al., 2012].

S3. Supra­molecular features

In the solid state, the cations form discrete centrosymmetric dimers, similar to those seen previously in mononuclear ruthenium–tape complexes. The dimers are held together by π–π stacking inter­actions via the planar tetra­aza­perylene units, with a typical inter­planar distance of 3.39 Å. For the tape ligand, the root-mean-square deviation from planarity was calculated to be 0.0211 Å. However, in the case of [Ru(L–N₄H₂)tape]²⁺, the dimers are also connected through bifurcated hydrogen bonds between one of the two L–N₄H₂ ligand amine protons and both nitro­gen atoms of the uncoordinated tape ligand α,α'-di­imine unit of the second complex cation of the dimer. In the solid state, these additional hydrogen bonds result in a short Ru···Ru distance of 8.8306 (2) Å, a tape ligand centroid–centroid distance of 3.49 (2) Å and an angle of 13.7 (1.4)° between the ring normal and the centroid-to-centroid vector. Therefore, the π–π stacking motif can be described as parallel-displaced, but near to face-to-face (Fig. 2). In metal complexes, a near face-to-face alignment of the polycyclic units is extremely rare (Janiak, 2000). Furthermore, a large number of weak hydrogen bonds connect cations, anions and solvent molecules, stabilizing the crystal packing (Table 2), supported by P—F···π-ring (tape, py) inter­actions [please provide some numerical details]. In the packing, the dimers are oriented in a herringbone-like motif, surrounded by hexafluoridophosphate anions. The solvent aceto­nitrile molecules fill the space between complex moieties (Fig. 3). For a description of the disorder of the anions and solvent molecules, see the Refinement section.

S4. Database survey

For related Ru^II complexes with 2,11-di­methyl-2,11-di­aza­[3.3](2,6)-pyridino­phane, see Brietzke, Mickler, Kelling, Schilde et al. (2012); Brietzke et al. (2014). For Ru^II tetra­aza­perylene complexes containing bi­pyridine-type ligands, see: Brietzke, Mickler, Kelling & Holdt (2012).

S5. Synthesis and crystallization

The synthesis of the ligands L–N₄H₂ (Bottino et al., 1988) and tape (Brietzke, Mickler, Kelling & Holdt, 2012) have been reported previously. [Ru(L–N₄H₂)tape](PF₆)₂ was synthesized as reported for [Ru(L–N₄Me₂)tape](PF₆)₂ (Brietzke, Mickler, Kelling, Schilde et al., 2012), using L–N₄H₂ (73.5 mg, 306 µmol) instead of L–N₄Me₂. A yield of 44% (120.0 mg, 135 µmol) was obtained; m.p. > 573 K. ¹H NMR = (MeCN–d₃): δ = 8.69 (d, J = 5.5 Hz, 2H, C^d—H), 8.56 (d, J = 6.6 Hz, 2H, C^a—H), 8.01 (t, J = 8.0 Hz, 2H, C⁴—H), 7.77 (d, J = 5.5 Hz, 2H, C^c—H), 7.72 (d, J = 6.6 Hz, 2H, C^b—H), 7.65 (d, J = 8.0 Hz, 4H, C³—H + C⁵—H), 5.6 (bs, 2H, N—H), 4.83 (bd, J = 14.0 Hz, 4H, CH₂), 4.47 (d, J = 17.4 Hz, 4H, CH₂) p.p.m. ¹³C NMR = (MeCN-d₃): δ = 160.0 (C² + C⁶), 152.4 (C^e), 150.28 (C^d), 150.24 (C^a), 145.7 (C^f), 138.9 (C⁴), 136.7 (C^b'), 123.5 (C^b), 122.7 (C³ + C⁵), 122.0 (C^c), 119.3 (C^e'), 64.8 (CH₂) p.p.m.. ESI=-MS: calculated for [M–PF₆]⁺ 743.0809; found 743.0778.

Crystals suitable for X-ray structure analysis were obtained by vapor diffusion of di­ethyl ether into a saturated aceto­nitrile solution of [Ru(L–N₄H₂)tape](PF₆)₂. The solution was filled into a test tube, which was placed into a di­ethyl ether-containing bottle. Dark-green crystals began to form at ambient temperature within a few days.

S6. Refinement

Disorder was observed for both the hexafluoridophosphate anions as well as the aceto­nitrile solvate molecules. Both PF₆ anions were refined as disordered over one major and one minor moiety each. The geometry of the minor moieties were each restrained to be similar to that of the major moieties (within an estimated standard deviation of 0.02 Å). The minor moieties were subjected to a rigid bond restraint (RIGU command of SHELX2014, estimated standard deviation 0.004 Ų), and the anisotropic displacement parameters of the major and minor phospho­rus atoms were each constrained to be identical. Associated with the major moiety of the PF₆ anion of P1 is an aceto­nitrile molecule that is absent for the minor moiety. Subject to the restraints and constraints used, the occupancy ratios refined to 0.9215 (17) to 0.0785 (17) for the PF₆ units of P1A and P1B, and to 0.801 (6) and 0.1999 (6) for those of P2A and P2B.

A second aceto­nitrile molecule is disordered across a crystallographic inversion center, with substantial overlap for the two carbon atoms of symmetry-related molecules. The geometry of the molecule was restrained to be similar to that of the first aceto­nitrile molecule, and the ADPs of its C and N atoms were restrained to be have similar U^ij components to their neighbors closer than 2 Å, including those of symmetry-related atoms (SIMU restraint in SHELX2014, estimated standard deviation 0.01 Ų).

All hydrogen atoms connected to C and N atoms were placed in their expected calculated positions and refined as riding with C—H = 0.98 (CH₃), 0.99 (CH₂), 0.95 (C_arom), N—H = 1.0 Å, and with U_iso(H) = 1.2U_eq(C) with the exception of methyl hydrogen atoms, which were refined with U_iso(H) = 1.5U_eq(C).

Crystal data, data collection and structure refinement details are summarized in Table 3.

Related literature

For related literature, see: Bottino et al. (1988); Brietzke et al. (2014); Brietzke, Mickler, Kelling & Holdt (2012); Brietzke, Mickler, Kelling, Schilde, Krüger & Holdt (2012); Janiak (2000).

Computing details

Data collection: X-AREA (Stoe & Cie, 2011); cell refinement: X-AREA (Stoe & Cie, 2011); data reduction: X-RED (Stoe & Cie, 2011); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL2014 (Sheldrick, 2008); molecular graphics: Mercury (Macrae et al., 2006), ORTEP-3 for Windows (Farrugia, 2012); software used to prepare material for publication: SHELXL2014 (Sheldrick, 2008), SHELXLE (Hübschle et al., 2011), publCIF (Westrip, 2010).

Figures

	Fig. 1. The molecular structure of [Ru(L–N4H2)tape]^2+ in [Ru(L–N4H2)tape](PF6)2·1.422 C2H3N with the atomic numbering scheme and 30% probability displacement ellipsoids. Anions and solvent molecules are omitted for clarity.
	Fig. 2. (a) Illustration of the asymmetric unit rendering the disorder of the hexafluoridophosphate anions and acetonitrile solvate molecules (see Refinement section for details). An additional π–π stacked [Ru(L–N4H2)tape]^2+ cation demonstrates, due to the view along the normal of the tape ligand's r.m.s. plane, the nearly face-to-face π–π stacking motif between the tape ligand moieties. The atomic numbering is shown for the anions and solvent molecules as well as for the ruthenium atoms. Hydrogen atoms are omitted for clarity. [Symmetry codes: (ii) 1-x, -y, 1-z, (ix) 1-x, 1-y, -z.] (b) A side view of the dimer formed by two [Ru(L–N4H2)tape]^2+ in [Ru(L–N4H2)tape](PF6)2·1.422 C2H3N, featuring the stacking interactions via planar tape ligand moieties. Only H atoms essential for illustration of the hydrogen bonds, shown as orange dashed lines, are included.
	Fig. 3. A packing diagram of the title compound is displayed along the c axis, illustrating the herringbone-type motif formed by two [Ru(L–N4H2)tape]^2+ dimers. The disordered minor atoms are omitted for clarity.

(2,11-Diaza[3.3](2,6)pyridinophane-κ⁴N,N',N'',N''')(1,6,7,12-tetraazaperylene-κ²N¹,N¹²)ruthenium(II) bis(hexafluoridophosphate) acetonitrile 1.422-solvate

Crystal data

[Ru(C14H16N4)(C16H8N4)](PF6)2·1.422C2H3N	F(000) = 1893.4
Mr = 946.11	Dx = 1.791 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
a = 11.7027 (3) Å	Cell parameters from 63561 reflections
b = 21.7157 (7) Å	θ = 1.5–29.6°
c = 13.9377 (4) Å	µ = 0.65 mm^−1
β = 97.938 (2)°	T = 150 K
V = 3508.08 (18) Å^3	Prism, dark green
Z = 4	1.30 × 0.65 × 0.31 mm

Data collection

STOE IPDS 2 diffractometer	9454 independent reflections
Radiation source: sealed X-ray tube	7744 reflections with I > 2σ(I)
Plane graphite monochromator	Rint = 0.087
Detector resolution: 6.67 pixels mm^-1	θmax = 29.3°, θmin = 1.8°
rotation method scans	h = −16→14
Absorption correction: integration (X-RED; Stoe & Cie, 2011)	k = −29→29
Tmin = 0.613, Tmax = 0.843	l = −19→19
60767 measured reflections

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: mixed
R[F^2 > 2σ(F^2)] = 0.048	H-atom parameters constrained
wR(F^2) = 0.146	w = 1/[σ^2(Fo^2) + (0.0787P)^2 + 2.127P] where P = (Fo^2 + 2Fc^2)/3
S = 1.09	(Δ/σ)max = 0.002
9454 reflections	Δρmax = 1.84 e Å^−3
651 parameters	Δρmin = −1.22 e Å^−3
183 restraints	Extinction correction: SHELXL, Fc^*=kFc[1+0.001xFc^2λ^3/sin(2θ)]^-1/4
Primary atom site location: structure-invariant direct methods	Extinction coefficient: 0.0041 (4)

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ru1	0.40042 (2)	0.19157 (2)	0.58944 (2)	0.03723 (9)
N1	0.49654 (19)	0.11825 (11)	0.64626 (15)	0.0367 (5)
N2	0.46354 (19)	0.15956 (11)	0.46830 (16)	0.0368 (4)
N3	0.5182 (2)	0.26652 (13)	0.6188 (2)	0.0537 (7)
H3N	0.5905	0.2585	0.6061	0.064*
N4	0.3005 (2)	0.26143 (11)	0.53082 (16)	0.0398 (5)
N5	0.2354 (2)	0.14885 (11)	0.58215 (17)	0.0411 (5)
H5N	0.2357	0.1112	0.5582	0.049*
N6	0.3522 (2)	0.22164 (12)	0.71383 (17)	0.0458 (6)
N7	0.7375 (2)	−0.04526 (12)	0.55594 (17)	0.0410 (5)
N8	0.7102 (2)	0.00109 (12)	0.36755 (17)	0.0431 (5)
C1	0.5101 (2)	0.09624 (14)	0.73954 (19)	0.0419 (6)
H1	0.4729	0.1176	0.7861	0.050*
C2	0.5738 (2)	0.04565 (14)	0.76894 (18)	0.0403 (6)
H2	0.5793	0.0321	0.8342	0.048*
C3	0.7009 (3)	−0.03870 (14)	0.72236 (19)	0.0416 (6)
H3	0.7137	−0.0553	0.7860	0.050*
C4	0.7498 (3)	−0.06536 (15)	0.6482 (2)	0.0464 (7)
H4	0.7961	−0.1009	0.6634	0.056*
C5	0.6950 (3)	0.02554 (16)	0.2771 (2)	0.0489 (7)
H5	0.7336	0.0061	0.2296	0.059*
C6	0.6285 (3)	0.07603 (15)	0.2488 (2)	0.0465 (7)
H6	0.6210	0.0904	0.1839	0.056*
C7	0.4978 (3)	0.15793 (14)	0.3018 (2)	0.0435 (6)
H7	0.4836	0.1756	0.2390	0.052*
C8	0.4473 (3)	0.18253 (14)	0.3751 (2)	0.0433 (6)
H8	0.3983	0.2173	0.3615	0.052*
C9	0.5501 (2)	0.08765 (12)	0.58204 (17)	0.0330 (5)
C10	0.6189 (2)	0.03545 (12)	0.60524 (17)	0.0327 (5)
C11	0.6734 (2)	0.00476 (12)	0.53437 (18)	0.0339 (5)
C12	0.6582 (2)	0.02915 (12)	0.43437 (18)	0.0349 (5)
C13	0.5882 (2)	0.08220 (13)	0.41366 (17)	0.0341 (5)
C14	0.5334 (2)	0.11075 (12)	0.48493 (18)	0.0335 (5)
C15	0.6323 (2)	0.01304 (13)	0.70162 (18)	0.0357 (5)
C16	0.5714 (2)	0.10613 (14)	0.31837 (19)	0.0392 (6)
C17	0.4761 (3)	0.31805 (17)	0.5503 (3)	0.0596 (9)
H17A	0.5040	0.3580	0.5787	0.072*
H17B	0.5074	0.3126	0.4884	0.072*
C18	0.3465 (3)	0.31816 (15)	0.5318 (3)	0.0486 (7)
C19	0.2756 (3)	0.36940 (16)	0.5145 (2)	0.0534 (7)
H19	0.3077	0.4096	0.5146	0.064*
C20	0.1575 (3)	0.36070 (16)	0.4970 (2)	0.0499 (7)
H20	0.1076	0.3952	0.4850	0.060*
C21	0.1115 (3)	0.30167 (15)	0.4970 (2)	0.0467 (7)
H21	0.0304	0.2953	0.4854	0.056*
C22	0.1864 (2)	0.25246 (14)	0.51419 (18)	0.0406 (6)
C23	0.1520 (3)	0.18614 (14)	0.5144 (2)	0.0447 (6)
H23A	0.1483	0.1693	0.4480	0.054*
H23B	0.0741	0.1828	0.5340	0.054*
C24	0.2034 (3)	0.14619 (16)	0.6821 (2)	0.0505 (7)
H24A	0.2333	0.1076	0.7143	0.061*
H24B	0.1183	0.1462	0.6788	0.061*
C25	0.2531 (3)	0.20074 (15)	0.7401 (2)	0.0486 (7)
C26	0.2081 (4)	0.22746 (19)	0.8173 (2)	0.0605 (10)
H26	0.1382	0.2129	0.8367	0.073*
C27	0.2687 (4)	0.2763 (2)	0.8653 (2)	0.0725 (13)
H27	0.2399	0.2952	0.9186	0.087*
C28	0.3680 (4)	0.2973 (2)	0.8372 (3)	0.0711 (13)
H28	0.4082	0.3308	0.8703	0.085*
C29	0.4110 (3)	0.26922 (17)	0.7592 (2)	0.0578 (9)
C30	0.5223 (3)	0.2836 (2)	0.7230 (3)	0.0664 (11)
H30A	0.5388	0.3281	0.7309	0.080*
H30B	0.5856	0.2607	0.7620	0.080*
P2A_a	0.8068 (3)	0.42105 (13)	0.4826 (2)	0.0447 (4)	0.801 (6)
F7A_a	0.7169 (3)	0.4256 (2)	0.3859 (2)	0.0686 (11)	0.801 (6)
F8A_a	0.8952 (6)	0.4132 (4)	0.5788 (4)	0.073 (2)	0.801 (6)
F9A_a	0.8867 (5)	0.4699 (2)	0.4427 (3)	0.119 (2)	0.801 (6)
F10A_a	0.7290 (3)	0.3697 (2)	0.5217 (3)	0.1071 (18)	0.801 (6)
F11A_a	0.8748 (3)	0.3704 (2)	0.4319 (2)	0.0715 (11)	0.801 (6)
F12A_a	0.7436 (5)	0.4740 (2)	0.5315 (3)	0.122 (2)	0.801 (6)
P2B_b	0.7944 (11)	0.4130 (6)	0.4882 (10)	0.0447 (4)	0.199 (6)
F7B_b	0.6911 (14)	0.4026 (9)	0.4033 (11)	0.076 (4)	0.199 (6)
F8B_b	0.8948 (19)	0.4222 (13)	0.5756 (15)	0.053 (4)	0.199 (6)
F9B_b	0.7949 (14)	0.4848 (5)	0.4693 (10)	0.075 (4)	0.199 (6)
F10B_b	0.8082 (15)	0.3414 (5)	0.4931 (10)	0.090 (4)	0.199 (6)
F11B_b	0.8886 (12)	0.4117 (9)	0.4167 (9)	0.081 (4)	0.199 (6)
F12B_b	0.6988 (9)	0.4239 (8)	0.5536 (8)	0.068 (3)	0.199 (6)
P1A_a	0.33081 (8)	0.31111 (5)	0.17529 (8)	0.0538 (3)	0.9215 (17)
F1A_a	0.4320 (3)	0.31248 (12)	0.2642 (3)	0.0900 (11)	0.9215 (17)
F2A_a	0.2279 (2)	0.30908 (12)	0.08663 (17)	0.0644 (6)	0.9215 (17)
F3A_a	0.3730 (4)	0.37384 (18)	0.1391 (4)	0.1430 (19)	0.9215 (17)
F4A_a	0.2860 (2)	0.24711 (14)	0.2119 (2)	0.0810 (8)	0.9215 (17)
F5A_a	0.2477 (3)	0.3457 (2)	0.2363 (2)	0.1186 (15)	0.9215 (17)
F6A_a	0.4133 (3)	0.2749 (2)	0.1160 (3)	0.1041 (11)	0.9215 (17)
P1B_b	0.3791 (8)	0.3534 (5)	0.2328 (8)	0.0538 (3)	0.0785 (17)
F1B_b	0.2932 (17)	0.3068 (10)	0.2780 (18)	0.061 (5)	0.0785 (17)
F2B_b	0.4610 (19)	0.3981 (11)	0.185 (2)	0.082 (6)	0.0785 (17)
F3B_b	0.2821 (18)	0.3626 (12)	0.1461 (17)	0.073 (5)	0.0785 (17)
F4B_b	0.4705 (19)	0.3486 (12)	0.3286 (16)	0.076 (5)	0.0785 (17)
F5B_b	0.433 (2)	0.2970 (9)	0.187 (2)	0.065 (5)	0.0785 (17)
F6B_b	0.324 (2)	0.4083 (11)	0.288 (2)	0.085 (6)	0.0785 (17)
N9_a	0.5253 (5)	0.5581 (3)	0.2892 (6)	0.135 (3)	0.9215 (17)
C31_a	0.4952 (4)	0.5135 (3)	0.3184 (5)	0.0832 (15)	0.9215 (17)
C32_a	0.4527 (5)	0.4596 (3)	0.3578 (6)	0.105 (2)	0.9215 (17)
H32A_a	0.3799	0.4689	0.3821	0.158*	0.9215 (17)
H32B_a	0.5092	0.4446	0.4111	0.158*	0.9215 (17)
H32C_a	0.4394	0.4279	0.3074	0.158*	0.9215 (17)
N10	0.4690 (12)	0.4178 (5)	−0.0541 (15)	0.189 (6)	0.5
C33	0.482 (2)	0.4656 (7)	−0.023 (2)	0.151 (6)	0.5
C34	0.5079 (14)	0.5265 (5)	0.0086 (15)	0.088 (4)	0.5
H34A	0.4426	0.5534	−0.0144	0.132*	0.5
H34B	0.5769	0.5410	−0.0172	0.132*	0.5
H34C	0.5219	0.5273	0.0796	0.132*	0.5

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ru1	0.03631 (13)	0.04128 (15)	0.03304 (13)	0.00739 (8)	0.00104 (8)	−0.00181 (8)
N1	0.0365 (11)	0.0423 (12)	0.0302 (10)	0.0077 (9)	0.0011 (8)	−0.0006 (8)
N2	0.0355 (10)	0.0411 (12)	0.0333 (10)	0.0032 (9)	0.0029 (8)	0.0002 (9)
N3	0.0371 (12)	0.0515 (15)	0.0704 (18)	0.0019 (11)	−0.0005 (12)	−0.0090 (13)
N4	0.0406 (12)	0.0421 (12)	0.0352 (10)	0.0084 (10)	−0.0001 (9)	0.0012 (9)
N5	0.0420 (12)	0.0401 (12)	0.0417 (12)	0.0047 (10)	0.0078 (9)	−0.0039 (9)
N6	0.0511 (14)	0.0498 (14)	0.0344 (11)	0.0186 (11)	−0.0018 (10)	−0.0052 (10)
N7	0.0402 (12)	0.0447 (13)	0.0363 (11)	0.0072 (10)	−0.0011 (9)	−0.0051 (9)
N8	0.0434 (12)	0.0516 (14)	0.0348 (11)	0.0036 (10)	0.0076 (9)	−0.0061 (10)
C1	0.0432 (14)	0.0517 (16)	0.0308 (12)	0.0084 (12)	0.0055 (10)	−0.0032 (11)
C2	0.0434 (14)	0.0486 (15)	0.0282 (11)	0.0044 (12)	0.0024 (10)	0.0005 (10)
C3	0.0447 (14)	0.0463 (15)	0.0318 (12)	0.0063 (12)	−0.0018 (10)	−0.0003 (10)
C4	0.0505 (16)	0.0466 (16)	0.0394 (14)	0.0125 (13)	−0.0029 (12)	−0.0025 (12)
C5	0.0502 (16)	0.0620 (19)	0.0362 (13)	0.0018 (14)	0.0122 (12)	−0.0040 (13)
C6	0.0510 (16)	0.0565 (18)	0.0329 (12)	−0.0012 (14)	0.0093 (11)	0.0022 (12)
C7	0.0464 (15)	0.0485 (16)	0.0349 (12)	−0.0006 (12)	0.0029 (11)	0.0080 (11)
C8	0.0422 (14)	0.0469 (15)	0.0394 (14)	0.0027 (12)	0.0010 (11)	0.0070 (11)
C9	0.0286 (10)	0.0381 (13)	0.0316 (11)	0.0003 (9)	0.0015 (9)	−0.0022 (9)
C10	0.0302 (11)	0.0356 (12)	0.0311 (11)	−0.0008 (9)	0.0000 (9)	−0.0022 (9)
C11	0.0300 (11)	0.0376 (12)	0.0331 (11)	−0.0031 (9)	0.0006 (9)	−0.0044 (9)
C12	0.0321 (11)	0.0410 (13)	0.0312 (11)	−0.0022 (10)	0.0033 (9)	−0.0039 (10)
C13	0.0305 (11)	0.0400 (13)	0.0314 (11)	−0.0034 (9)	0.0026 (9)	−0.0015 (9)
C14	0.0296 (11)	0.0380 (12)	0.0321 (11)	−0.0008 (9)	0.0015 (9)	−0.0012 (9)
C15	0.0353 (12)	0.0402 (13)	0.0303 (11)	0.0002 (10)	0.0006 (9)	−0.0018 (10)
C16	0.0389 (13)	0.0461 (15)	0.0327 (12)	−0.0044 (11)	0.0053 (10)	0.0006 (10)
C17	0.0472 (17)	0.0492 (18)	0.081 (3)	−0.0014 (14)	0.0055 (17)	0.0021 (17)
C18	0.0466 (16)	0.0450 (15)	0.0534 (17)	0.0032 (13)	0.0043 (13)	0.0038 (13)
C19	0.0590 (19)	0.0432 (16)	0.0572 (18)	0.0068 (14)	0.0060 (15)	0.0073 (14)
C20	0.0555 (18)	0.0518 (17)	0.0414 (14)	0.0147 (14)	0.0025 (13)	0.0042 (13)
C21	0.0440 (15)	0.0586 (18)	0.0354 (13)	0.0153 (13)	−0.0018 (11)	−0.0015 (12)
C22	0.0407 (13)	0.0492 (15)	0.0303 (11)	0.0089 (12)	−0.0002 (10)	−0.0032 (10)
C23	0.0376 (14)	0.0517 (17)	0.0433 (15)	0.0064 (12)	0.0005 (11)	−0.0073 (12)
C24	0.0557 (18)	0.0502 (17)	0.0493 (16)	0.0112 (14)	0.0208 (14)	0.0039 (13)
C25	0.0599 (18)	0.0540 (17)	0.0324 (13)	0.0250 (14)	0.0081 (12)	0.0026 (11)
C26	0.074 (2)	0.072 (2)	0.0370 (14)	0.0348 (19)	0.0137 (14)	0.0020 (14)
C27	0.088 (3)	0.088 (3)	0.0377 (15)	0.049 (2)	−0.0052 (17)	−0.0161 (17)
C28	0.072 (3)	0.079 (3)	0.0531 (19)	0.037 (2)	−0.0241 (18)	−0.0289 (18)
C29	0.0607 (19)	0.0594 (19)	0.0465 (16)	0.0259 (16)	−0.0171 (14)	−0.0149 (14)
C30	0.0500 (18)	0.068 (2)	0.074 (2)	0.0122 (17)	−0.0178 (17)	−0.0264 (19)
P2A_a	0.0495 (8)	0.0536 (9)	0.0305 (5)	0.0068 (6)	0.0035 (5)	−0.0021 (6)
F7A_a	0.0612 (19)	0.095 (3)	0.0446 (14)	0.0162 (18)	−0.0104 (13)	0.0000 (16)
F8A_a	0.074 (3)	0.103 (5)	0.038 (2)	0.017 (3)	−0.0093 (19)	−0.001 (2)
F9A_a	0.144 (4)	0.119 (4)	0.087 (3)	−0.066 (3)	−0.012 (3)	0.035 (2)
F10A_a	0.065 (2)	0.146 (4)	0.111 (3)	−0.030 (2)	0.017 (2)	0.056 (3)
F11A_a	0.0552 (16)	0.095 (3)	0.0623 (18)	0.0215 (17)	−0.0006 (13)	−0.0264 (18)
F12A_a	0.166 (5)	0.118 (4)	0.070 (2)	0.093 (4)	−0.020 (3)	−0.035 (2)
P2B_b	0.0495 (8)	0.0536 (9)	0.0305 (5)	0.0068 (6)	0.0035 (5)	−0.0021 (6)
F7B_b	0.075 (7)	0.082 (9)	0.067 (7)	0.024 (5)	−0.008 (5)	−0.032 (6)
F8B_b	0.056 (7)	0.062 (8)	0.042 (7)	−0.006 (5)	0.008 (5)	−0.015 (5)
F9B_b	0.101 (8)	0.057 (5)	0.070 (7)	0.003 (4)	0.015 (6)	−0.008 (4)
F10B_b	0.115 (10)	0.067 (5)	0.080 (7)	0.016 (5)	−0.020 (6)	−0.016 (4)
F11B_b	0.085 (7)	0.110 (10)	0.050 (5)	0.029 (6)	0.021 (5)	−0.011 (6)
F12B_b	0.052 (5)	0.097 (9)	0.056 (5)	−0.012 (5)	0.011 (4)	−0.038 (5)
P1A_a	0.0385 (4)	0.0567 (6)	0.0637 (6)	0.0047 (4)	−0.0018 (4)	0.0080 (4)
F1A_a	0.0674 (17)	0.0674 (17)	0.119 (3)	−0.0021 (13)	−0.0435 (18)	0.0102 (16)
F2A_a	0.0545 (13)	0.0872 (18)	0.0500 (12)	0.0095 (11)	0.0013 (10)	0.0056 (10)
F3A_a	0.107 (3)	0.093 (2)	0.210 (5)	−0.032 (2)	−0.046 (3)	0.080 (3)
F4A_a	0.0538 (13)	0.0899 (19)	0.0937 (19)	−0.0141 (13)	−0.0099 (13)	0.0333 (16)
F5A_a	0.104 (2)	0.160 (4)	0.082 (2)	0.069 (3)	−0.0224 (18)	−0.049 (2)
F6A_a	0.0612 (17)	0.136 (3)	0.121 (3)	0.0272 (19)	0.0349 (17)	0.007 (2)
P1B_b	0.0385 (4)	0.0567 (6)	0.0637 (6)	0.0047 (4)	−0.0018 (4)	0.0080 (4)
F1B_b	0.040 (7)	0.061 (9)	0.078 (10)	0.011 (6)	−0.008 (7)	0.022 (7)
F2B_b	0.054 (9)	0.066 (9)	0.123 (12)	0.009 (7)	0.004 (8)	0.029 (8)
F3B_b	0.050 (8)	0.063 (11)	0.103 (8)	0.001 (7)	−0.004 (6)	0.033 (7)
F4B_b	0.052 (8)	0.066 (11)	0.103 (8)	0.006 (7)	−0.014 (6)	0.008 (7)
F5B_b	0.047 (9)	0.058 (7)	0.087 (10)	0.002 (6)	−0.001 (8)	0.020 (7)
F6B_b	0.061 (10)	0.073 (8)	0.119 (11)	0.012 (7)	0.002 (8)	0.005 (7)
N9_a	0.069 (3)	0.072 (3)	0.264 (9)	0.004 (3)	0.021 (4)	−0.011 (4)
C31_a	0.047 (2)	0.073 (3)	0.127 (5)	0.007 (2)	0.005 (3)	−0.018 (3)
C32_a	0.064 (3)	0.099 (4)	0.152 (6)	0.001 (3)	0.010 (3)	0.007 (4)
N10	0.114 (9)	0.095 (8)	0.335 (18)	−0.005 (7)	−0.052 (11)	−0.012 (11)
C33	0.079 (9)	0.113 (10)	0.247 (15)	−0.004 (9)	−0.025 (10)	−0.005 (11)
C34	0.039 (5)	0.085 (6)	0.142 (10)	0.010 (5)	0.018 (6)	0.025 (7)

Geometric parameters (Å, º)

Ru1—N6	2.005 (2)	C20—C21	1.390 (5)
Ru1—N4	2.018 (2)	C20—H20	0.9500
Ru1—N1	2.045 (2)	C21—C22	1.382 (4)
Ru1—N2	2.055 (2)	C21—H21	0.9500
Ru1—N5	2.132 (3)	C22—C23	1.495 (4)
Ru1—N3	2.135 (3)	C23—H23A	0.9900
N1—C9	1.338 (3)	C23—H23B	0.9900
N1—C1	1.374 (3)	C24—C25	1.505 (5)
N2—C14	1.339 (3)	C24—H24A	0.9900
N2—C8	1.380 (4)	C24—H24B	0.9900
N3—C30	1.492 (5)	C25—C26	1.388 (4)
N3—C17	1.509 (5)	C26—C27	1.395 (6)
N3—H3N	0.9051	C26—H26	0.9500
N4—C22	1.338 (4)	C27—C28	1.356 (7)
N4—C18	1.343 (4)	C27—H27	0.9500
N5—C24	1.493 (4)	C28—C29	1.400 (5)
N5—C23	1.499 (4)	C28—H28	0.9500
N5—H5N	0.8825	C29—C30	1.494 (6)
N6—C25	1.342 (5)	C30—H30A	0.9900
N6—C29	1.349 (5)	C30—H30B	0.9900
N7—C11	1.330 (4)	P2A_a—F9A_a	1.566 (4)
N7—C4	1.347 (4)	P2A_a—F12A_a	1.573 (4)
N8—C12	1.328 (3)	P2A_a—F11A_a	1.581 (4)
N8—C5	1.356 (4)	P2A_a—F10A_a	1.583 (4)
C1—C2	1.359 (4)	P2A_a—F8A_a	1.585 (4)
C1—H1	0.9500	P2A_a—F7A_a	1.594 (4)
C2—C15	1.424 (4)	P2B_b—F12B_b	1.556 (13)
C2—H2	0.9500	P2B_b—F10B_b	1.565 (14)
C3—C4	1.376 (4)	P2B_b—F9B_b	1.581 (14)
C3—C15	1.388 (4)	P2B_b—F8B_b	1.584 (14)
C3—H3	0.9500	P2B_b—F11B_b	1.585 (13)
C4—H4	0.9500	P2B_b—F7B_b	1.586 (14)
C5—C6	1.371 (5)	P1A_a—F3A_a	1.556 (3)
C5—H5	0.9500	P1A_a—F6A_a	1.566 (3)
C6—C16	1.411 (4)	P1A_a—F5A_a	1.569 (3)
C6—H6	0.9500	P1A_a—F1A_a	1.592 (3)
C7—C8	1.358 (4)	P1A_a—F4A_a	1.594 (3)
C7—C16	1.416 (4)	P1A_a—F2A_a	1.603 (3)
C7—H7	0.9500	P1B_b—F3B_b	1.552 (15)
C8—H8	0.9500	P1B_b—F5B_b	1.555 (16)
C9—C10	1.402 (4)	P1B_b—F2B_b	1.576 (15)
C9—C14	1.431 (3)	P1B_b—F4B_b	1.594 (15)
C10—C11	1.415 (3)	P1B_b—F6B_b	1.601 (16)
C10—C15	1.417 (3)	P1B_b—F1B_b	1.614 (15)
C11—C12	1.479 (4)	N9_a—C31_a	1.125 (8)
C12—C13	1.420 (4)	C31_a—C32_a	1.413 (8)
C13—C14	1.400 (3)	C32_a—H32A_a	0.9800
C13—C16	1.414 (4)	C32_a—H32B_a	0.9800
C17—C18	1.504 (5)	C32_a—H32C_a	0.9800
C17—H17A	0.9900	N10—C33	1.125 (8)
C17—H17B	0.9900	C33—C34	1.413 (8)
C18—C19	1.389 (5)	C34—H34A	0.9800
C19—C20	1.383 (5)	C34—H34B	0.9800
C19—H19	0.9500	C34—H34C	0.9800
N6—Ru1—N4	83.61 (9)	C21—C22—C23	125.5 (3)
N6—Ru1—N1	97.14 (9)	C22—C23—N5	111.7 (2)
N4—Ru1—N1	177.60 (10)	C22—C23—H23A	109.3
N6—Ru1—N2	175.16 (9)	N5—C23—H23A	109.3
N4—Ru1—N2	100.11 (9)	C22—C23—H23B	109.3
N1—Ru1—N2	79.27 (9)	N5—C23—H23B	109.3
N6—Ru1—N5	79.72 (10)	H23A—C23—H23B	107.9
N4—Ru1—N5	80.65 (10)	N5—C24—C25	110.0 (3)
N1—Ru1—N5	97.22 (9)	N5—C24—H24A	109.7
N2—Ru1—N5	103.86 (9)	C25—C24—H24A	109.7
N6—Ru1—N3	80.65 (12)	N5—C24—H24B	109.7
N4—Ru1—N3	80.06 (11)	C25—C24—H24B	109.7
N1—Ru1—N3	102.31 (11)	H24A—C24—H24B	108.2
N2—Ru1—N3	96.87 (11)	N6—C25—C26	120.3 (3)
N5—Ru1—N3	153.79 (10)	N6—C25—C24	113.8 (3)
C9—N1—C1	117.2 (2)	C26—C25—C24	125.8 (4)
C9—N1—Ru1	114.26 (17)	C25—C26—C27	117.8 (4)
C1—N1—Ru1	128.52 (18)	C25—C26—H26	121.1
C14—N2—C8	116.8 (2)	C27—C26—H26	121.1
C14—N2—Ru1	113.92 (17)	C28—C27—C26	121.2 (3)
C8—N2—Ru1	129.2 (2)	C28—C27—H27	119.4
C30—N3—C17	113.3 (3)	C26—C27—H27	119.4
C30—N3—Ru1	108.0 (2)	C27—C28—C29	119.4 (4)
C17—N3—Ru1	107.4 (2)	C27—C28—H28	120.3
C30—N3—H3N	109.4	C29—C28—H28	120.3
C17—N3—H3N	104.6	N6—C29—C28	118.9 (4)
Ru1—N3—H3N	114.3	N6—C29—C30	114.4 (3)
C22—N4—C18	121.6 (3)	C28—C29—C30	126.5 (4)
C22—N4—Ru1	118.0 (2)	N3—C30—C29	111.4 (3)
C18—N4—Ru1	118.4 (2)	N3—C30—H30A	109.3
C24—N5—C23	112.5 (2)	C29—C30—H30A	109.3
C24—N5—Ru1	108.35 (19)	N3—C30—H30B	109.3
C23—N5—Ru1	107.56 (18)	C29—C30—H30B	109.3
C24—N5—H5N	109.4	H30A—C30—H30B	108.0
C23—N5—H5N	107.3	F9A_a—P2A_a—F12A_a	89.9 (4)
Ru1—N5—H5N	111.7	F9A_a—P2A_a—F11A_a	87.2 (3)
C25—N6—C29	122.3 (3)	F12A_a—P2A_a—F11A_a	177.0 (4)
C25—N6—Ru1	118.9 (2)	F9A_a—P2A_a—F10A_a	177.8 (4)
C29—N6—Ru1	117.9 (2)	F12A_a—P2A_a—F10A_a	92.3 (4)
C11—N7—C4	117.6 (2)	F11A_a—P2A_a—F10A_a	90.7 (3)
C12—N8—C5	117.3 (3)	F9A_a—P2A_a—F8A_a	91.2 (4)
C2—C1—N1	123.6 (2)	F12A_a—P2A_a—F8A_a	90.2 (4)
C2—C1—H1	118.2	F11A_a—P2A_a—F8A_a	89.6 (3)
N1—C1—H1	118.2	F10A_a—P2A_a—F8A_a	88.4 (4)
C1—C2—C15	119.8 (2)	F9A_a—P2A_a—F7A_a	90.8 (3)
C1—C2—H2	120.1	F12A_a—P2A_a—F7A_a	91.5 (3)
C15—C2—H2	120.1	F11A_a—P2A_a—F7A_a	88.8 (2)
C4—C3—C15	118.2 (3)	F10A_a—P2A_a—F7A_a	89.5 (2)
C4—C3—H3	120.9	F8A_a—P2A_a—F7A_a	177.3 (4)
C15—C3—H3	120.9	F12B_b—P2B_b—F10B_b	101.7 (11)
N7—C4—C3	125.4 (3)	F12B_b—P2B_b—F9B_b	88.2 (10)
N7—C4—H4	117.3	F10B_b—P2B_b—F9B_b	170.0 (12)
C3—C4—H4	117.3	F12B_b—P2B_b—F8B_b	92.7 (12)
N8—C5—C6	125.2 (3)	F10B_b—P2B_b—F8B_b	91.7 (13)
N8—C5—H5	117.4	F9B_b—P2B_b—F8B_b	89.2 (12)
C6—C5—H5	117.4	F12B_b—P2B_b—F11B_b	171.9 (13)
C5—C6—C16	118.5 (3)	F10B_b—P2B_b—F11B_b	86.2 (11)
C5—C6—H6	120.8	F9B_b—P2B_b—F11B_b	83.9 (10)
C16—C6—H6	120.8	F8B_b—P2B_b—F11B_b	88.8 (12)
C8—C7—C16	120.6 (3)	F12B_b—P2B_b—F7B_b	85.6 (9)
C8—C7—H7	119.7	F10B_b—P2B_b—F7B_b	87.3 (10)
C16—C7—H7	119.7	F9B_b—P2B_b—F7B_b	92.1 (10)
C7—C8—N2	123.2 (3)	F8B_b—P2B_b—F7B_b	177.8 (14)
C7—C8—H8	118.4	F11B_b—P2B_b—F7B_b	93.0 (11)
N2—C8—H8	118.4	F3A_a—P1A_a—F6A_a	91.3 (3)
N1—C9—C10	123.7 (2)	F3A_a—P1A_a—F5A_a	90.3 (3)
N1—C9—C14	116.3 (2)	F6A_a—P1A_a—F5A_a	178.4 (3)
C10—C9—C14	120.0 (2)	F3A_a—P1A_a—F1A_a	90.06 (19)
C9—C10—C11	121.3 (2)	F6A_a—P1A_a—F1A_a	88.5 (2)
C9—C10—C15	118.8 (2)	F5A_a—P1A_a—F1A_a	91.1 (2)
C11—C10—C15	119.9 (2)	F3A_a—P1A_a—F4A_a	179.29 (18)
N7—C11—C10	121.4 (2)	F6A_a—P1A_a—F4A_a	89.1 (2)
N7—C11—C12	119.8 (2)	F5A_a—P1A_a—F4A_a	89.3 (2)
C10—C11—C12	118.8 (2)	F1A_a—P1A_a—F4A_a	90.53 (15)
N8—C12—C13	122.5 (2)	F3A_a—P1A_a—F2A_a	90.70 (18)
N8—C12—C11	119.3 (2)	F6A_a—P1A_a—F2A_a	91.83 (18)
C13—C12—C11	118.2 (2)	F5A_a—P1A_a—F2A_a	88.55 (15)
C14—C13—C16	119.1 (2)	F1A_a—P1A_a—F2A_a	179.18 (18)
C14—C13—C12	121.6 (2)	F4A_a—P1A_a—F2A_a	88.72 (14)
C16—C13—C12	119.3 (2)	F3B_b—P1B_b—F5B_b	94.2 (14)
N2—C14—C13	123.8 (2)	F3B_b—P1B_b—F2B_b	90.7 (13)
N2—C14—C9	116.2 (2)	F5B_b—P1B_b—F2B_b	90.3 (13)
C13—C14—C9	120.0 (2)	F3B_b—P1B_b—F4B_b	173.7 (15)
C3—C15—C10	117.4 (2)	F5B_b—P1B_b—F4B_b	91.9 (13)
C3—C15—C2	125.6 (2)	F2B_b—P1B_b—F4B_b	91.0 (13)
C10—C15—C2	117.0 (2)	F3B_b—P1B_b—F6B_b	88.9 (13)
C6—C16—C13	117.2 (3)	F5B_b—P1B_b—F6B_b	175.5 (15)
C6—C16—C7	126.2 (3)	F2B_b—P1B_b—F6B_b	92.9 (14)
C13—C16—C7	116.5 (2)	F4B_b—P1B_b—F6B_b	85.0 (13)
C18—C17—N3	110.1 (3)	F3B_b—P1B_b—F1B_b	87.5 (12)
C18—C17—H17A	109.6	F5B_b—P1B_b—F1B_b	88.8 (12)
N3—C17—H17A	109.6	F2B_b—P1B_b—F1B_b	178.0 (15)
C18—C17—H17B	109.6	F4B_b—P1B_b—F1B_b	90.9 (12)
N3—C17—H17B	109.6	F6B_b—P1B_b—F1B_b	88.1 (13)
H17A—C17—H17B	108.2	N9_a—C31_a—C32_a	176.6 (7)
N4—C18—C19	120.3 (3)	C31_a—C32_a—H32A_a	109.5
N4—C18—C17	113.2 (3)	C31_a—C32_a—H32B_a	109.5
C19—C18—C17	126.5 (3)	H32A_a—C32_a—H32B_a	109.5
C20—C19—C18	118.6 (3)	C31_a—C32_a—H32C_a	109.5
C20—C19—H19	120.7	H32A_a—C32_a—H32C_a	109.5
C18—C19—H19	120.7	H32B_a—C32_a—H32C_a	109.5
C19—C20—C21	120.3 (3)	N10—C33—C34	174.0 (19)
C19—C20—H20	119.9	C33—C34—H34A	109.5
C21—C20—H20	119.9	C33—C34—H34B	109.5
C22—C21—C20	118.4 (3)	H34A—C34—H34B	109.5
C22—C21—H21	120.8	C33—C34—H34C	109.5
C20—C21—H21	120.8	H34A—C34—H34C	109.5
N4—C22—C21	120.8 (3)	H34B—C34—H34C	109.5
N4—C22—C23	113.7 (2)
C9—N1—C1—C2	−0.3 (4)	C1—C2—C15—C10	−0.9 (4)
Ru1—N1—C1—C2	177.9 (2)	C5—C6—C16—C13	0.7 (4)
N1—C1—C2—C15	1.0 (5)	C5—C6—C16—C7	−178.7 (3)
C11—N7—C4—C3	0.5 (5)	C14—C13—C16—C6	179.9 (3)
C15—C3—C4—N7	0.4 (5)	C12—C13—C16—C6	−1.4 (4)
C12—N8—C5—C6	−1.5 (5)	C14—C13—C16—C7	−0.7 (4)
N8—C5—C6—C16	0.8 (5)	C12—C13—C16—C7	178.1 (2)
C16—C7—C8—N2	0.0 (5)	C8—C7—C16—C6	179.6 (3)
C14—N2—C8—C7	0.3 (4)	C8—C7—C16—C13	0.2 (4)
Ru1—N2—C8—C7	177.6 (2)	C30—N3—C17—C18	−85.1 (4)
C1—N1—C9—C10	−0.5 (4)	Ru1—N3—C17—C18	34.0 (4)
Ru1—N1—C9—C10	−178.98 (19)	C22—N4—C18—C19	−0.6 (5)
C1—N1—C9—C14	179.0 (2)	Ru1—N4—C18—C19	−164.4 (3)
Ru1—N1—C9—C14	0.6 (3)	C22—N4—C18—C17	−179.1 (3)
N1—C9—C10—C11	179.9 (2)	Ru1—N4—C18—C17	17.1 (4)
C14—C9—C10—C11	0.3 (4)	N3—C17—C18—N4	−34.3 (4)
N1—C9—C10—C15	0.6 (4)	N3—C17—C18—C19	147.3 (3)
C14—C9—C10—C15	−179.0 (2)	N4—C18—C19—C20	0.5 (5)
C4—N7—C11—C10	−0.8 (4)	C17—C18—C19—C20	178.8 (3)
C4—N7—C11—C12	179.3 (3)	C18—C19—C20—C21	0.0 (5)
C9—C10—C11—N7	−179.1 (2)	C19—C20—C21—C22	−0.4 (5)
C15—C10—C11—N7	0.2 (4)	C18—N4—C22—C21	0.3 (4)
C9—C10—C11—C12	0.8 (4)	Ru1—N4—C22—C21	164.1 (2)
C15—C10—C11—C12	−179.9 (2)	C18—N4—C22—C23	179.1 (3)
C5—N8—C12—C13	0.7 (4)	Ru1—N4—C22—C23	−17.1 (3)
C5—N8—C12—C11	−179.1 (3)	C20—C21—C22—N4	0.2 (4)
N7—C11—C12—N8	−0.9 (4)	C20—C21—C22—C23	−178.4 (3)
C10—C11—C12—N8	179.2 (2)	N4—C22—C23—N5	31.3 (3)
N7—C11—C12—C13	179.3 (2)	C21—C22—C23—N5	−150.0 (3)
C10—C11—C12—C13	−0.6 (4)	C24—N5—C23—C22	90.0 (3)
N8—C12—C13—C14	179.4 (2)	Ru1—N5—C23—C22	−29.3 (3)
C11—C12—C13—C14	−0.7 (4)	C23—N5—C24—C25	−86.8 (3)
N8—C12—C13—C16	0.7 (4)	Ru1—N5—C24—C25	32.0 (3)
C11—C12—C13—C16	−179.5 (2)	C29—N6—C25—C26	−0.9 (4)
C8—N2—C14—C13	−0.8 (4)	Ru1—N6—C25—C26	−169.9 (2)
Ru1—N2—C14—C13	−178.5 (2)	C29—N6—C25—C24	−178.3 (3)
C8—N2—C14—C9	179.6 (2)	Ru1—N6—C25—C24	12.7 (3)
Ru1—N2—C14—C9	1.9 (3)	N5—C24—C25—N6	−30.1 (4)
C16—C13—C14—N2	1.0 (4)	N5—C24—C25—C26	152.7 (3)
C12—C13—C14—N2	−177.7 (2)	N6—C25—C26—C27	0.3 (5)
C16—C13—C14—C9	−179.4 (2)	C24—C25—C26—C27	177.3 (3)
C12—C13—C14—C9	1.9 (4)	C25—C26—C27—C28	0.4 (5)
N1—C9—C14—N2	−1.7 (3)	C26—C27—C28—C29	−0.5 (6)
C10—C9—C14—N2	177.9 (2)	C25—N6—C29—C28	0.8 (5)
N1—C9—C14—C13	178.7 (2)	Ru1—N6—C29—C28	170.0 (2)
C10—C9—C14—C13	−1.7 (4)	C25—N6—C29—C30	176.9 (3)
C4—C3—C15—C10	−0.9 (4)	Ru1—N6—C29—C30	−13.9 (4)
C4—C3—C15—C2	178.9 (3)	C27—C28—C29—N6	−0.1 (5)
C9—C10—C15—C3	180.0 (2)	C27—C28—C29—C30	−175.7 (4)
C11—C10—C15—C3	0.7 (4)	C17—N3—C30—C29	90.1 (4)
C9—C10—C15—C2	0.1 (4)	Ru1—N3—C30—C29	−28.7 (4)
C11—C10—C15—C2	−179.2 (2)	N6—C29—C30—N3	28.9 (4)
C1—C2—C15—C3	179.3 (3)	C28—C29—C30—N3	−155.4 (3)

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
N3—H3N···F2A_a^i	0.91	2.22	3.037 (4)	150
N3—H3N···F4A_a^i	0.91	2.55	3.236 (4)	133
N5—H5N···N7^ii	0.88	2.20	3.006 (3)	153
N5—H5N···N8^ii	0.88	2.69	3.373 (4)	135
C1—H1···F11A_a^iii	0.95	2.48	3.376 (5)	157
C1—H1···F11B_b^iii	0.95	2.28	3.019 (11)	134
C3—H3···F8A_a^iv	0.95	2.51	3.301 (8)	141
C3—H3···F12A_a^iv	0.95	2.60	3.414 (5)	144
C3—H3···F8B_b^iv	0.95	2.50	3.28 (3)	140
C3—H3···F12B_b^iv	0.95	2.37	3.283 (10)	161
C5—H5···F7A_a^v	0.95	2.50	3.404 (5)	159
C8—H8···F1A_a	0.95	2.53	3.211 (4)	128
C8—H8···F4A_a	0.95	2.40	3.085 (4)	129
C8—H8···F1B_b	0.95	2.50	3.42 (2)	163
C17—H17A···N9_a^vi	0.99	2.65	3.500 (8)	145
C17—H17B···F4B_b	0.99	2.34	3.15 (2)	138
C19—H19···F9B_b^vi	0.95	2.61	3.287 (12)	128
C21—H21···F11A_a^vii	0.95	2.48	3.166 (4)	129
C23—H23B···F6A_a^iii	0.99	2.51	3.409 (4)	151
C24—H24A···F7A_a^iii	0.99	2.53	3.224 (5)	127
C24—H24B···F2B_b^iii	0.99	2.09	3.00 (2)	152
C24—H24B···F5B_b^iii	0.99	2.51	3.41 (3)	150
C26—H26···F1A_a^iii	0.95	2.55	3.328 (5)	140
C26—H26···F4B_b^iii	0.95	2.36	3.26 (3)	156
C28—H28···N10^viii	0.95	2.23	3.169 (12)	169
C30—H30A···N9_a^vi	0.99	2.59	3.484 (7)	151
C30—H30B···F4A_a^i	0.99	2.54	3.182 (5)	122
C32_a—H32A_a···F12A_a^vi	0.98	2.36	3.273 (8)	155
C32_a—H32B_a···F7A_a	0.98	2.54	3.150 (7)	121
C32_a—H32C_a···F1A_a	0.98	2.58	3.446 (8)	148

Symmetry codes: (i) x+1/2, −y+1/2, z+1/2; (ii) −x+1, −y, −z+1; (iii) x−1/2, −y+1/2, z+1/2; (iv) −x+3/2, y−1/2, −z+3/2; (v) −x+3/2, y−1/2, −z+1/2; (vi) −x+1, −y+1, −z+1; (vii) x−1, y, z; (viii) x, y, z+1.