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The structure of the title compound, [C14H18N2)2Ag2](NO3)2, contains subtle differences in ligand, metal, and counter-anion coordination. One quinoxaline ligand uses one of its quinoxaline N atoms to bond to one silver cation. That silver cation is bound to a second quinoxaline which, in turn, is bound to a second silver atom; thereby using both of its quinoxaline N atoms. A nitrate group bonds with one of its O atoms to the first silver and uses the same oxygen to bond to a silver atom (related by symmetry to the second), thereby forming an extended network. The second nitrate group on the other silver bonds via two nitrate O atoms; one silver cation therefore has a coordination number of three whereas the second has a coordination number of four. One of the quinoxaline ligands has a disordered ethyl group.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S2414314624002475/zl4069sup1.cif
Contains datablock I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2414314624002475/zl4069Isup2.hkl
Contains datablock I

CCDC reference: 2340469

Key indicators

Structure: I
  • Single-crystal X-ray study
  • T = 293 K
  • Mean [sigma](C-C) = 0.003 Å
  • Disorder in main residue
  • R factor = 0.039
  • wR factor = 0.096
  • Data-to-parameter ratio = 27.6

checkCIF/PLATON results

No syntax errors found



Alert level C PLAT220_ALERT_2_C NonSolvent Resd 1 C Ueq(max)/Ueq(min) Range 3.1 Ratio PLAT234_ALERT_4_C Large Hirshfeld Difference C27 --C28 . 0.17 Ang. PLAT241_ALERT_2_C High 'MainMol' Ueq as Compared to Neighbors of O1 Check PLAT241_ALERT_2_C High 'MainMol' Ueq as Compared to Neighbors of O4 Check PLAT242_ALERT_2_C Low 'MainMol' Ueq as Compared to Neighbors of N5 Check PLAT242_ALERT_2_C Low 'MainMol' Ueq as Compared to Neighbors of N6 Check PLAT906_ALERT_3_C Large K Value in the Analysis of Variance ...... 5.814 Check PLAT910_ALERT_3_C Missing # of FCF Reflection(s) Below Theta(Min). 8 Note 1 1 0, 0 2 0, 1 2 0, -1 0 1, 1 0 1, -1 1 1, 0 1 1, 0 2 1,
Alert level G PLAT003_ALERT_2_G Number of Uiso or Uij Restrained non-H Atoms ... 16 Report PLAT004_ALERT_5_G Polymeric Structure Found with Maximum Dimension 2 Info PLAT178_ALERT_4_G The CIF-Embedded .res File Contains SIMU Records 3 Report PLAT188_ALERT_3_G A Non-default SIMU Restraint Value has been used 0.0100 Report PLAT188_ALERT_3_G A Non-default SIMU Restraint Value has been used 0.0100 Report PLAT188_ALERT_3_G A Non-default SIMU Restraint Value has been used 0.0100 Report PLAT199_ALERT_1_G Reported _cell_measurement_temperature ..... (K) 293 Check PLAT200_ALERT_1_G Reported _diffrn_ambient_temperature ..... (K) 293 Check PLAT232_ALERT_2_G Hirshfeld Test Diff (M-X) Ag1 --O1 . 12.6 s.u. PLAT232_ALERT_2_G Hirshfeld Test Diff (M-X) Ag1 --O2 . 7.6 s.u. PLAT232_ALERT_2_G Hirshfeld Test Diff (M-X) Ag1 --N1 . 6.7 s.u. PLAT232_ALERT_2_G Hirshfeld Test Diff (M-X) Ag2 --O4 . 7.8 s.u. PLAT301_ALERT_3_G Main Residue Disorder ..............(Resd 1) 5% Note PLAT410_ALERT_2_G Short Intra H...H Contact H25A ..H27B . 2.13 Ang. x,y,z = 1_555 Check PLAT432_ALERT_2_G Short Inter X...Y Contact O3 ..C28B . 3.00 Ang. 1/2-x,1/2+y,3/2-z = 2_556 Check PLAT860_ALERT_3_G Number of Least-Squares Restraints ............. 102 Note PLAT912_ALERT_4_G Missing # of FCF Reflections Above STh/L= 0.600 916 Note PLAT941_ALERT_3_G Average HKL Measurement Multiplicity ........... 3.3 Low PLAT969_ALERT_5_G The 'Henn et al.' R-Factor-gap value ........... 3.15 Note Predicted wR2: Based on SigI   2 3.04 or SHELX Weight 9.71 PLAT978_ALERT_2_G Number C-C Bonds with Positive Residual Density. 1 Info PLAT992_ALERT_5_G Repd & Actual _reflns_number_gt Values Differ by 2 Check
0 ALERT level A = Most likely a serious problem - resolve or explain 0 ALERT level B = A potentially serious problem, consider carefully 8 ALERT level C = Check. Ensure it is not caused by an omission or oversight 21 ALERT level G = General information/check it is not something unexpected 2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 13 ALERT type 2 Indicator that the structure model may be wrong or deficient 8 ALERT type 3 Indicator that the structure quality may be low 3 ALERT type 4 Improvement, methodology, query or suggestion 3 ALERT type 5 Informative message, check

Computing details top

Poly[(µ-2,3-diethyl-7,8-dimethylquinoxaline-κ2N:N)(2,3-diethyl-7,8-dimethylquinoxaline-κN)-µ-nitrato-κ2O:O'-nitrato-κ2O,O'-disilver(I)] top
Crystal data top
[Ag2(NO3)2(C14H18N2)2]F(000) = 1552
Mr = 768.37Dx = 1.655 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
a = 10.3048 (2) ÅCell parameters from 7239 reflections
b = 24.1140 (6) Åθ = 3.2–31.2°
c = 12.6416 (4) ŵ = 1.32 mm1
β = 100.911 (3)°T = 293 K
V = 3084.53 (13) Å3Block, colorless
Z = 40.41 × 0.33 × 0.25 mm
Data collection top
Xcalibur, Sapphire3
diffractometer
11225 independent reflections
Radiation source: fine-focus sealed X-ray tube, Enhance (Mo) X-ray Source6825 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.030
Detector resolution: 16.1790 pixels mm-1θmax = 33.6°, θmin = 2.9°
ω scansh = 1216
Absorption correction: multi-scan
(CrysAlisPro; Rigaku OD, 2019)
k = 3637
Tmin = 0.775, Tmax = 1.000l = 1919
36657 measured reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.039H-atom parameters constrained
wR(F2) = 0.096 w = 1/[σ2(Fo2) + (0.0359P)2 + 0.7322P]
where P = (Fo2 + 2Fc2)/3
S = 1.00(Δ/σ)max = 0.001
11225 reflectionsΔρmax = 0.36 e Å3
407 parametersΔρmin = 0.49 e Å3
102 restraints
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Hydrogen atoms on sp2 and sp3 carbons were placed at calculated positions with a C—H distance of 0.93 Å and 0.96 Å and were included in the refinement in riding motion approximation with Uiso = 1.2Ueq or 1.5Ueq of the carrier atom, respectively.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ag10.14525 (2)0.20877 (2)0.97995 (2)0.07499 (8)
Ag20.46103 (2)0.14066 (2)0.79131 (2)0.05543 (7)
O10.2455 (3)0.30344 (10)0.96797 (18)0.0987 (8)
O20.1200 (2)0.28503 (9)1.11773 (16)0.0775 (6)
O30.2180 (3)0.36261 (12)1.0993 (2)0.1337 (12)
O40.65506 (19)0.16154 (10)0.94950 (16)0.0773 (6)
O50.7486 (3)0.13377 (12)1.1028 (2)0.1105 (9)
O60.5601 (3)0.09973 (12)1.0286 (2)0.1210 (9)
N10.04723 (17)0.18545 (7)0.93064 (14)0.0420 (4)
N20.28512 (17)0.15893 (7)0.86719 (14)0.0432 (4)
N30.63183 (17)0.11208 (7)0.71683 (14)0.0456 (4)
N40.8581 (2)0.07533 (9)0.64542 (19)0.0641 (5)
N50.1946 (3)0.31748 (11)1.0619 (2)0.0733 (6)
N60.6550 (2)0.12997 (11)1.0286 (2)0.0679 (6)
C10.0822 (2)0.13332 (8)0.92080 (17)0.0427 (4)
C20.2046 (2)0.11947 (9)0.88956 (18)0.0446 (5)
C30.2505 (2)0.21320 (8)0.87823 (16)0.0395 (4)
C40.3359 (2)0.25626 (9)0.85985 (17)0.0488 (5)
H40.4164240.2474540.8410480.059*
C50.3027 (2)0.31103 (9)0.86910 (17)0.0502 (5)
C60.1787 (2)0.32432 (9)0.89600 (17)0.0507 (5)
C70.0972 (2)0.28286 (9)0.91814 (17)0.0472 (5)
H70.0180400.2919690.9391030.057*
C80.1309 (2)0.22665 (8)0.90976 (16)0.0397 (4)
C90.3989 (3)0.35595 (11)0.8517 (2)0.0707 (8)
H9A0.4810810.3393710.8434800.106*
H9B0.4136600.3804710.9125740.106*
H9C0.3628480.3765250.7878260.106*
C100.1338 (3)0.38397 (10)0.8971 (3)0.0752 (8)
H10A0.2012480.4056020.9413530.113*
H10B0.0539140.3858280.9255880.113*
H10C0.1176780.3983470.8249580.113*
C110.0104 (2)0.08953 (10)0.9478 (2)0.0578 (6)
H11A0.0028090.0565450.9055280.069*
H11B0.1005950.1028730.9286720.069*
C120.0193 (3)0.07459 (12)1.0669 (2)0.0775 (8)
H12A0.0440230.0478371.0815790.116*
H12B0.0140140.1073201.1091460.116*
H12C0.1065520.0591821.0852050.116*
C130.2465 (2)0.06016 (9)0.8794 (2)0.0554 (6)
H13A0.2163300.0380350.9340570.066*
H13B0.3422990.0584250.8927420.066*
C140.1930 (3)0.03547 (11)0.7699 (2)0.0715 (7)
H14A0.2256520.0562050.7155900.107*
H14B0.0982370.0369480.7561650.107*
H14C0.2212570.0024130.7684220.107*
C150.6497 (2)0.05903 (10)0.6971 (2)0.0540 (5)
C160.7649 (3)0.04099 (11)0.6597 (2)0.0690 (7)
C170.8409 (2)0.13033 (10)0.66478 (18)0.0502 (5)
C180.9360 (2)0.16915 (11)0.64532 (19)0.0557 (6)
H181.0124290.1565290.6240600.067*
C190.9188 (2)0.22453 (11)0.65687 (17)0.0532 (6)
C200.8031 (2)0.24404 (9)0.69231 (17)0.0485 (5)
C210.7112 (2)0.20651 (9)0.71427 (18)0.0476 (5)
H210.6371170.2192010.7391080.057*
C220.7273 (2)0.14926 (9)0.69975 (17)0.0430 (5)
C231.0185 (3)0.26514 (13)0.6288 (2)0.0705 (8)
H23A1.0906850.2451820.6086500.106*
H23B1.0510320.2880950.6901120.106*
H23C0.9771480.2879680.5697130.106*
C240.7797 (3)0.30509 (11)0.7034 (2)0.0699 (7)
H24A0.8493400.3205290.7565300.105*
H24B0.6964770.3107170.7253580.105*
H24C0.7784440.3230400.6354320.105*
C250.5457 (3)0.01907 (11)0.7192 (2)0.0708 (7)
H25A0.5343150.0100840.6654010.085*
H25B0.4621540.0384690.7132750.085*
C260.5819 (4)0.00665 (15)0.8302 (3)0.1045 (12)
H26A0.6598520.0289570.8340560.157*
H26B0.5103430.0294520.8434950.157*
H26C0.5985970.0221600.8834860.157*
C270.7664 (9)0.0197 (4)0.6193 (9)0.088 (2)0.596 (10)
H27A0.7773630.0446310.6805280.105*0.596 (10)
H27B0.6822080.0279630.5731770.105*0.596 (10)
C280.8758 (9)0.0294 (3)0.5578 (7)0.125 (3)0.596 (10)
H28A0.8528520.0127330.4878170.187*0.596 (10)
H28B0.8883760.0685230.5502610.187*0.596 (10)
H28C0.9560430.0130870.5962360.187*0.596 (10)
C27B0.8116 (14)0.0203 (7)0.6527 (12)0.082 (3)0.404 (10)
H27C0.9071710.0231510.6698580.099*0.404 (10)
H27D0.7738390.0442870.7006210.099*0.404 (10)
C28B0.7591 (16)0.0344 (5)0.5362 (10)0.123 (4)0.404 (10)
H28D0.7775080.0726230.5235810.185*0.404 (10)
H28E0.8011200.0112600.4908950.185*0.404 (10)
H28F0.6654000.0283410.5201120.185*0.404 (10)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.05433 (12)0.06584 (14)0.1134 (2)0.00078 (9)0.03772 (12)0.00521 (12)
Ag20.04237 (10)0.05675 (11)0.07309 (13)0.00201 (7)0.02599 (8)0.00126 (9)
O10.1078 (18)0.1112 (18)0.0684 (13)0.0367 (14)0.0053 (12)0.0201 (12)
O20.0752 (13)0.0839 (14)0.0710 (12)0.0089 (11)0.0079 (10)0.0057 (11)
O30.163 (3)0.108 (2)0.115 (2)0.0615 (19)0.0098 (19)0.0460 (16)
O40.0605 (11)0.1091 (16)0.0630 (12)0.0214 (11)0.0131 (9)0.0019 (11)
O50.0779 (16)0.168 (3)0.0800 (15)0.0122 (16)0.0001 (13)0.0222 (16)
O60.105 (2)0.120 (2)0.142 (2)0.0468 (17)0.0317 (17)0.0218 (18)
N10.0381 (9)0.0437 (9)0.0460 (10)0.0011 (7)0.0125 (7)0.0001 (7)
N20.0389 (9)0.0446 (9)0.0483 (10)0.0020 (7)0.0138 (7)0.0011 (8)
N30.0433 (9)0.0449 (10)0.0517 (10)0.0019 (8)0.0170 (8)0.0005 (8)
N40.0604 (13)0.0612 (13)0.0779 (15)0.0082 (10)0.0314 (11)0.0059 (11)
N50.0711 (15)0.0812 (16)0.0682 (15)0.0140 (13)0.0150 (12)0.0149 (13)
N60.0596 (14)0.0778 (16)0.0700 (15)0.0021 (11)0.0220 (12)0.0061 (12)
C10.0392 (10)0.0417 (11)0.0489 (12)0.0019 (8)0.0125 (9)0.0015 (9)
C20.0404 (11)0.0440 (11)0.0511 (12)0.0006 (9)0.0131 (9)0.0010 (9)
C30.0396 (10)0.0424 (11)0.0369 (10)0.0036 (8)0.0081 (8)0.0008 (8)
C40.0483 (12)0.0527 (13)0.0467 (12)0.0096 (10)0.0124 (9)0.0004 (10)
C50.0594 (14)0.0473 (12)0.0415 (12)0.0128 (10)0.0035 (10)0.0030 (9)
C60.0647 (15)0.0406 (11)0.0427 (12)0.0022 (10)0.0002 (10)0.0009 (9)
C70.0505 (12)0.0447 (12)0.0465 (12)0.0031 (9)0.0092 (10)0.0007 (9)
C80.0397 (10)0.0418 (10)0.0375 (10)0.0006 (8)0.0072 (8)0.0014 (8)
C90.0795 (19)0.0568 (15)0.0760 (18)0.0250 (14)0.0152 (15)0.0048 (13)
C100.092 (2)0.0421 (13)0.088 (2)0.0035 (14)0.0079 (17)0.0009 (13)
C110.0519 (13)0.0433 (12)0.0850 (18)0.0076 (10)0.0303 (12)0.0016 (11)
C120.084 (2)0.0665 (17)0.092 (2)0.0005 (15)0.0425 (17)0.0214 (15)
C130.0517 (13)0.0430 (12)0.0767 (16)0.0006 (10)0.0256 (12)0.0024 (11)
C140.0704 (17)0.0570 (15)0.091 (2)0.0047 (13)0.0242 (15)0.0164 (14)
C150.0548 (13)0.0485 (12)0.0611 (14)0.0027 (10)0.0172 (11)0.0005 (10)
C160.0757 (17)0.0535 (14)0.0841 (18)0.0063 (13)0.0315 (15)0.0099 (13)
C170.0448 (12)0.0623 (14)0.0462 (12)0.0015 (10)0.0155 (9)0.0012 (10)
C180.0415 (12)0.0792 (18)0.0498 (13)0.0044 (11)0.0169 (10)0.0004 (12)
C190.0478 (12)0.0741 (16)0.0376 (11)0.0157 (11)0.0075 (9)0.0038 (11)
C200.0510 (12)0.0516 (13)0.0418 (11)0.0075 (10)0.0059 (9)0.0057 (9)
C210.0449 (11)0.0492 (12)0.0514 (13)0.0006 (9)0.0159 (10)0.0003 (10)
C220.0390 (10)0.0485 (12)0.0434 (11)0.0017 (8)0.0127 (8)0.0012 (9)
C230.0617 (16)0.093 (2)0.0579 (15)0.0292 (15)0.0132 (12)0.0092 (14)
C240.0794 (19)0.0534 (15)0.0748 (18)0.0118 (13)0.0093 (15)0.0089 (13)
C250.0675 (17)0.0489 (14)0.101 (2)0.0106 (12)0.0276 (15)0.0025 (14)
C260.111 (3)0.086 (2)0.128 (3)0.000 (2)0.051 (2)0.033 (2)
C270.093 (5)0.059 (3)0.116 (6)0.014 (4)0.030 (4)0.026 (4)
C280.095 (5)0.105 (5)0.170 (6)0.020 (4)0.018 (5)0.073 (4)
C27B0.081 (6)0.070 (4)0.096 (6)0.006 (5)0.018 (5)0.015 (5)
C28B0.148 (9)0.094 (6)0.122 (7)0.016 (6)0.011 (7)0.039 (6)
Geometric parameters (Å, º) top
Ag1—O12.498 (2)C12—H12C0.9600
Ag1—O22.512 (2)C13—H13A0.9700
Ag1—O4i2.3195 (19)C13—H13B0.9700
Ag1—N12.2600 (17)C13—C141.512 (4)
Ag2—O42.5956 (19)C14—H14A0.9600
Ag2—N22.2492 (17)C14—H14B0.9600
Ag2—N32.2552 (17)C14—H14C0.9600
O1—N51.251 (3)C15—C161.427 (4)
O2—N51.223 (3)C15—C251.506 (3)
O3—N51.229 (3)C16—C271.550 (10)
O4—N61.257 (3)C16—C27B1.563 (17)
O5—N61.215 (3)C17—C181.410 (3)
O6—N61.220 (3)C17—C221.403 (3)
N1—C11.320 (3)C18—H180.9300
N1—C81.373 (3)C18—C191.359 (4)
N2—C21.328 (3)C19—C201.430 (3)
N2—C31.371 (3)C19—C231.510 (3)
N3—C151.323 (3)C20—C211.376 (3)
N3—C221.378 (3)C20—C241.503 (3)
N4—C161.306 (3)C21—H210.9300
N4—C171.366 (3)C21—C221.407 (3)
C1—C21.430 (3)C23—H23A0.9600
C1—C111.505 (3)C23—H23B0.9600
C2—C131.507 (3)C23—H23C0.9600
C3—C41.408 (3)C24—H24A0.9600
C3—C81.403 (3)C24—H24B0.9600
C4—H40.9300C24—H24C0.9600
C4—C51.375 (3)C25—H25A0.9700
C5—C61.421 (3)C25—H25B0.9700
C5—C91.512 (3)C25—C261.515 (4)
C6—C71.368 (3)C26—H26A0.9600
C6—C101.512 (3)C26—H26B0.9600
C7—H70.9300C26—H26C0.9600
C7—C81.408 (3)C27—H27A0.9700
C9—H9A0.9600C27—H27B0.9700
C9—H9B0.9600C27—C281.504 (13)
C9—H9C0.9600C28—H28A0.9600
C10—H10A0.9600C28—H28B0.9600
C10—H10B0.9600C28—H28C0.9600
C10—H10C0.9600C27B—H27C0.9700
C11—H11A0.9700C27B—H27D0.9700
C11—H11B0.9700C27B—C28B1.508 (19)
C11—C121.522 (4)C28B—H28D0.9600
C12—H12A0.9600C28B—H28E0.9600
C12—H12B0.9600C28B—H28F0.9600
O1—Ag1—O250.25 (7)C14—C13—H13A109.0
O4i—Ag1—O195.46 (9)C14—C13—H13B109.0
O4i—Ag1—O2116.53 (7)C13—C14—H14A109.5
N1—Ag1—O1125.80 (8)C13—C14—H14B109.5
N1—Ag1—O2113.10 (7)C13—C14—H14C109.5
N1—Ag1—O4i129.00 (7)H14A—C14—H14B109.5
N2—Ag2—O4101.47 (6)H14A—C14—H14C109.5
N2—Ag2—N3173.50 (6)H14B—C14—H14C109.5
N3—Ag2—O480.37 (7)N3—C15—C16120.8 (2)
N5—O1—Ag195.48 (17)N3—C15—C25117.0 (2)
N5—O2—Ag195.56 (16)C16—C15—C25122.2 (2)
Ag1ii—O4—Ag2138.85 (9)N4—C16—C15122.2 (2)
N6—O4—Ag1ii107.43 (16)N4—C16—C27120.0 (4)
N6—O4—Ag2112.28 (16)N4—C16—C27B110.5 (6)
C1—N1—Ag1122.18 (13)C15—C16—C27117.2 (4)
C1—N1—C8118.57 (18)C15—C16—C27B126.3 (6)
C8—N1—Ag1119.25 (14)N4—C17—C18119.7 (2)
C2—N2—Ag2122.50 (14)N4—C17—C22121.1 (2)
C2—N2—C3118.51 (18)C22—C17—C18119.2 (2)
C3—N2—Ag2118.47 (13)C17—C18—H18119.2
C15—N3—Ag2121.44 (15)C19—C18—C17121.6 (2)
C15—N3—C22118.08 (19)C19—C18—H18119.2
C22—N3—Ag2120.23 (14)C18—C19—C20119.4 (2)
C16—N4—C17117.8 (2)C18—C19—C23120.2 (2)
O2—N5—O1118.7 (2)C20—C19—C23120.3 (2)
O2—N5—O3119.5 (3)C19—C20—C24120.6 (2)
O3—N5—O1121.8 (3)C21—C20—C19119.6 (2)
O5—N6—O4116.6 (2)C21—C20—C24119.8 (2)
O5—N6—O6124.3 (3)C20—C21—H21119.5
O6—N6—O4118.9 (3)C20—C21—C22121.0 (2)
N1—C1—C2121.28 (18)C22—C21—H21119.5
N1—C1—C11116.77 (19)N3—C22—C17120.0 (2)
C2—C1—C11121.92 (19)N3—C22—C21120.81 (19)
N2—C2—C1120.71 (19)C17—C22—C21119.1 (2)
N2—C2—C13117.43 (19)C19—C23—H23A109.5
C1—C2—C13121.85 (19)C19—C23—H23B109.5
N2—C3—C4120.30 (19)C19—C23—H23C109.5
N2—C3—C8120.60 (18)H23A—C23—H23B109.5
C8—C3—C4119.09 (19)H23A—C23—H23C109.5
C3—C4—H4119.3H23B—C23—H23C109.5
C5—C4—C3121.4 (2)C20—C24—H24A109.5
C5—C4—H4119.3C20—C24—H24B109.5
C4—C5—C6119.1 (2)C20—C24—H24C109.5
C4—C5—C9119.7 (2)H24A—C24—H24B109.5
C6—C5—C9121.2 (2)H24A—C24—H24C109.5
C5—C6—C10120.5 (2)H24B—C24—H24C109.5
C7—C6—C5120.0 (2)C15—C25—H25A109.2
C7—C6—C10119.5 (2)C15—C25—H25B109.2
C6—C7—H7119.4C15—C25—C26112.0 (3)
C6—C7—C8121.2 (2)H25A—C25—H25B107.9
C8—C7—H7119.4C26—C25—H25A109.2
N1—C8—C3120.29 (18)C26—C25—H25B109.2
N1—C8—C7120.59 (19)C25—C26—H26A109.5
C3—C8—C7119.11 (19)C25—C26—H26B109.5
C5—C9—H9A109.5C25—C26—H26C109.5
C5—C9—H9B109.5H26A—C26—H26B109.5
C5—C9—H9C109.5H26A—C26—H26C109.5
H9A—C9—H9B109.5H26B—C26—H26C109.5
H9A—C9—H9C109.5C16—C27—H27A109.2
H9B—C9—H9C109.5C16—C27—H27B109.2
C6—C10—H10A109.5H27A—C27—H27B107.9
C6—C10—H10B109.5C28—C27—C16111.8 (7)
C6—C10—H10C109.5C28—C27—H27A109.2
H10A—C10—H10B109.5C28—C27—H27B109.2
H10A—C10—H10C109.5C27—C28—H28A109.5
H10B—C10—H10C109.5C27—C28—H28B109.5
C1—C11—H11A109.2C27—C28—H28C109.5
C1—C11—H11B109.2H28A—C28—H28B109.5
C1—C11—C12111.9 (2)H28A—C28—H28C109.5
H11A—C11—H11B107.9H28B—C28—H28C109.5
C12—C11—H11A109.2C16—C27B—H27C111.3
C12—C11—H11B109.2C16—C27B—H27D111.3
C11—C12—H12A109.5H27C—C27B—H27D109.2
C11—C12—H12B109.5C28B—C27B—C16102.2 (10)
C11—C12—H12C109.5C28B—C27B—H27C111.3
H12A—C12—H12B109.5C28B—C27B—H27D111.3
H12A—C12—H12C109.5C27B—C28B—H28D109.5
H12B—C12—H12C109.5C27B—C28B—H28E109.5
C2—C13—H13A109.0C27B—C28B—H28F109.5
C2—C13—H13B109.0H28D—C28B—H28E109.5
C2—C13—C14113.0 (2)H28D—C28B—H28F109.5
H13A—C13—H13B107.8H28E—C28B—H28F109.5
Ag1—O1—N5—O22.3 (3)C3—C4—C5—C9178.3 (2)
Ag1—O1—N5—O3177.4 (3)C4—C3—C8—N1178.48 (18)
Ag1—O2—N5—O12.2 (3)C4—C3—C8—C72.4 (3)
Ag1—O2—N5—O3177.4 (3)C4—C5—C6—C73.6 (3)
Ag1ii—O4—N6—O55.1 (3)C4—C5—C6—C10174.5 (2)
Ag1ii—O4—N6—O6178.1 (2)C5—C6—C7—C83.1 (3)
Ag1—N1—C1—C2179.96 (15)C6—C7—C8—N1179.0 (2)
Ag1—N1—C1—C112.1 (3)C6—C7—C8—C30.1 (3)
Ag1—N1—C8—C3179.52 (14)C8—N1—C1—C20.2 (3)
Ag1—N1—C8—C70.4 (3)C8—N1—C1—C11178.1 (2)
Ag2—O4—N6—O5174.1 (2)C8—C3—C4—C51.9 (3)
Ag2—O4—N6—O69.1 (3)C9—C5—C6—C7175.8 (2)
Ag2—N2—C2—C1169.46 (15)C9—C5—C6—C106.1 (3)
Ag2—N2—C2—C139.8 (3)C10—C6—C7—C8175.0 (2)
Ag2—N2—C3—C410.8 (3)C11—C1—C2—N2179.3 (2)
Ag2—N2—C3—C8170.33 (14)C11—C1—C2—C131.4 (3)
Ag2—N3—C15—C16173.9 (2)C15—N3—C22—C171.4 (3)
Ag2—N3—C15—C254.2 (3)C15—N3—C22—C21176.9 (2)
Ag2—N3—C22—C17172.84 (16)C15—C16—C27—C28166.0 (6)
Ag2—N3—C22—C218.8 (3)C15—C16—C27B—C28B97.3 (11)
N1—C1—C2—N21.5 (3)C16—N4—C17—C18176.9 (2)
N1—C1—C2—C13179.2 (2)C16—N4—C17—C220.5 (4)
N1—C1—C11—C1288.0 (3)C16—C15—C25—C2683.2 (3)
N2—C2—C13—C1492.9 (3)C17—N4—C16—C151.7 (4)
N2—C3—C4—C5179.20 (19)C17—N4—C16—C27168.7 (5)
N2—C3—C8—N10.4 (3)C17—N4—C16—C27B170.5 (6)
N2—C3—C8—C7178.69 (19)C17—C18—C19—C201.7 (3)
N3—C15—C16—N41.3 (4)C17—C18—C19—C23176.2 (2)
N3—C15—C16—C27169.3 (5)C18—C17—C22—N3178.5 (2)
N3—C15—C16—C27B168.4 (6)C18—C17—C22—C210.1 (3)
N3—C15—C25—C2694.9 (3)C18—C19—C20—C210.1 (3)
N4—C16—C27—C284.8 (10)C18—C19—C20—C24178.6 (2)
N4—C16—C27B—C28B94.4 (11)C19—C20—C21—C221.7 (3)
N4—C17—C18—C19175.7 (2)C20—C21—C22—N3176.8 (2)
N4—C17—C22—N31.1 (3)C20—C21—C22—C171.6 (3)
N4—C17—C22—C21177.3 (2)C22—N3—C15—C160.3 (4)
C1—N1—C8—C30.3 (3)C22—N3—C15—C25178.4 (2)
C1—N1—C8—C7179.36 (19)C22—C17—C18—C191.8 (3)
C1—C2—C13—C1486.4 (3)C23—C19—C20—C21177.9 (2)
C2—N2—C3—C4177.23 (19)C23—C19—C20—C240.7 (3)
C2—N2—C3—C81.6 (3)C24—C20—C21—C22177.0 (2)
C2—C1—C11—C1289.8 (3)C25—C15—C16—N4176.7 (3)
C3—N2—C2—C12.2 (3)C25—C15—C16—C2712.7 (6)
C3—N2—C2—C13178.54 (19)C25—C15—C16—C27B9.7 (7)
C3—C4—C5—C61.1 (3)
Symmetry codes: (i) x1, y, z; (ii) x+1, y, z.
 

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