The structure of the title compound, [C14H18N2)2Ag2](NO3)2, contains subtle differences in ligand, metal, and counter-anion coordination. One quinoxaline ligand uses one of its quinoxaline N atoms to bond to one silver cation. That silver cation is bound to a second quinoxaline which, in turn, is bound to a second silver atom; thereby using both of its quinoxaline N atoms. A nitrate group bonds with one of its O atoms to the first silver and uses the same oxygen to bond to a silver atom (related by symmetry to the second), thereby forming an extended network. The second nitrate group on the other silver bonds via two nitrate O atoms; one silver cation therefore has a coordination number of three whereas the second has a coordination number of four. One of the quinoxaline ligands has a disordered ethyl group.
Supporting information
CCDC reference: 2340469
Key indicators
Structure: I
- Single-crystal X-ray study
- T = 293 K
- Mean
(C-C) = 0.003 Å
- Disorder in main residue
- R factor = 0.039
- wR factor = 0.096
- Data-to-parameter ratio = 27.6
checkCIF/PLATON results
No syntax errors found
Alert level C
PLAT220_ALERT_2_C NonSolvent Resd 1 C Ueq(max)/Ueq(min) Range 3.1 Ratio
PLAT234_ALERT_4_C Large Hirshfeld Difference C27 --C28 . 0.17 Ang.
PLAT241_ALERT_2_C High 'MainMol' Ueq as Compared to Neighbors of O1 Check
PLAT241_ALERT_2_C High 'MainMol' Ueq as Compared to Neighbors of O4 Check
PLAT242_ALERT_2_C Low 'MainMol' Ueq as Compared to Neighbors of N5 Check
PLAT242_ALERT_2_C Low 'MainMol' Ueq as Compared to Neighbors of N6 Check
PLAT906_ALERT_3_C Large K Value in the Analysis of Variance ...... 5.814 Check
PLAT910_ALERT_3_C Missing # of FCF Reflection(s) Below Theta(Min). 8 Note
1 1 0, 0 2 0, 1 2 0, -1 0 1, 1 0 1, -1 1 1,
0 1 1, 0 2 1,
Alert level G
PLAT003_ALERT_2_G Number of Uiso or Uij Restrained non-H Atoms ... 16 Report
PLAT004_ALERT_5_G Polymeric Structure Found with Maximum Dimension 2 Info
PLAT178_ALERT_4_G The CIF-Embedded .res File Contains SIMU Records 3 Report
PLAT188_ALERT_3_G A Non-default SIMU Restraint Value has been used 0.0100 Report
PLAT188_ALERT_3_G A Non-default SIMU Restraint Value has been used 0.0100 Report
PLAT188_ALERT_3_G A Non-default SIMU Restraint Value has been used 0.0100 Report
PLAT199_ALERT_1_G Reported _cell_measurement_temperature ..... (K) 293 Check
PLAT200_ALERT_1_G Reported _diffrn_ambient_temperature ..... (K) 293 Check
PLAT232_ALERT_2_G Hirshfeld Test Diff (M-X) Ag1 --O1 . 12.6 s.u.
PLAT232_ALERT_2_G Hirshfeld Test Diff (M-X) Ag1 --O2 . 7.6 s.u.
PLAT232_ALERT_2_G Hirshfeld Test Diff (M-X) Ag1 --N1 . 6.7 s.u.
PLAT232_ALERT_2_G Hirshfeld Test Diff (M-X) Ag2 --O4 . 7.8 s.u.
PLAT301_ALERT_3_G Main Residue Disorder ..............(Resd 1) 5% Note
PLAT410_ALERT_2_G Short Intra H...H Contact H25A ..H27B . 2.13 Ang.
x,y,z = 1_555 Check
PLAT432_ALERT_2_G Short Inter X...Y Contact O3 ..C28B . 3.00 Ang.
1/2-x,1/2+y,3/2-z = 2_556 Check
PLAT860_ALERT_3_G Number of Least-Squares Restraints ............. 102 Note
PLAT912_ALERT_4_G Missing # of FCF Reflections Above STh/L= 0.600 916 Note
PLAT941_ALERT_3_G Average HKL Measurement Multiplicity ........... 3.3 Low
PLAT969_ALERT_5_G The 'Henn et al.' R-Factor-gap value ........... 3.15 Note
Predicted wR2: Based on SigI 2 3.04 or SHELX Weight 9.71
PLAT978_ALERT_2_G Number C-C Bonds with Positive Residual Density. 1 Info
PLAT992_ALERT_5_G Repd & Actual _reflns_number_gt Values Differ by 2 Check
0 ALERT level A = Most likely a serious problem - resolve or explain
0 ALERT level B = A potentially serious problem, consider carefully
8 ALERT level C = Check. Ensure it is not caused by an omission or oversight
21 ALERT level G = General information/check it is not something unexpected
2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
13 ALERT type 2 Indicator that the structure model may be wrong or deficient
8 ALERT type 3 Indicator that the structure quality may be low
3 ALERT type 4 Improvement, methodology, query or suggestion
3 ALERT type 5 Informative message, check
Poly[(µ-2,3-diethyl-7,8-dimethylquinoxaline-
κ2N:
N)(2,3-diethyl-7,8-dimethylquinoxaline-
κN)-µ-nitrato-
κ2O:
O'-nitrato-
κ2O,
O'-disilver(I)]
top
Crystal data top
[Ag2(NO3)2(C14H18N2)2] | F(000) = 1552 |
Mr = 768.37 | Dx = 1.655 Mg m−3 |
Monoclinic, P21/n | Mo Kα radiation, λ = 0.71073 Å |
a = 10.3048 (2) Å | Cell parameters from 7239 reflections |
b = 24.1140 (6) Å | θ = 3.2–31.2° |
c = 12.6416 (4) Å | µ = 1.32 mm−1 |
β = 100.911 (3)° | T = 293 K |
V = 3084.53 (13) Å3 | Block, colorless |
Z = 4 | 0.41 × 0.33 × 0.25 mm |
Data collection top
Xcalibur, Sapphire3 diffractometer | 11225 independent reflections |
Radiation source: fine-focus sealed X-ray tube, Enhance (Mo) X-ray Source | 6825 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.030 |
Detector resolution: 16.1790 pixels mm-1 | θmax = 33.6°, θmin = 2.9° |
ω scans | h = −12→16 |
Absorption correction: multi-scan (CrysAlisPro; Rigaku OD, 2019) | k = −36→37 |
Tmin = 0.775, Tmax = 1.000 | l = −19→19 |
36657 measured reflections | |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Hydrogen site location: inferred from neighbouring sites |
R[F2 > 2σ(F2)] = 0.039 | H-atom parameters constrained |
wR(F2) = 0.096 | w = 1/[σ2(Fo2) + (0.0359P)2 + 0.7322P] where P = (Fo2 + 2Fc2)/3 |
S = 1.00 | (Δ/σ)max = 0.001 |
11225 reflections | Δρmax = 0.36 e Å−3 |
407 parameters | Δρmin = −0.49 e Å−3 |
102 restraints | |
Special details top
Geometry. All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes. |
Refinement. Hydrogen atoms on sp2 and sp3 carbons were placed at
calculated positions with a C—H distance of 0.93 Å and 0.96 Å and were
included in the refinement in riding motion approximation with Uiso =
1.2Ueq or 1.5Ueq of the carrier atom, respectively. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | Occ. (<1) |
Ag1 | −0.14525 (2) | 0.20877 (2) | 0.97995 (2) | 0.07499 (8) | |
Ag2 | 0.46103 (2) | 0.14066 (2) | 0.79131 (2) | 0.05543 (7) | |
O1 | −0.2455 (3) | 0.30344 (10) | 0.96797 (18) | 0.0987 (8) | |
O2 | −0.1200 (2) | 0.28503 (9) | 1.11773 (16) | 0.0775 (6) | |
O3 | −0.2180 (3) | 0.36261 (12) | 1.0993 (2) | 0.1337 (12) | |
O4 | 0.65506 (19) | 0.16154 (10) | 0.94950 (16) | 0.0773 (6) | |
O5 | 0.7486 (3) | 0.13377 (12) | 1.1028 (2) | 0.1105 (9) | |
O6 | 0.5601 (3) | 0.09973 (12) | 1.0286 (2) | 0.1210 (9) | |
N1 | 0.04723 (17) | 0.18545 (7) | 0.93064 (14) | 0.0420 (4) | |
N2 | 0.28512 (17) | 0.15893 (7) | 0.86719 (14) | 0.0432 (4) | |
N3 | 0.63183 (17) | 0.11208 (7) | 0.71683 (14) | 0.0456 (4) | |
N4 | 0.8581 (2) | 0.07533 (9) | 0.64542 (19) | 0.0641 (5) | |
N5 | −0.1946 (3) | 0.31748 (11) | 1.0619 (2) | 0.0733 (6) | |
N6 | 0.6550 (2) | 0.12997 (11) | 1.0286 (2) | 0.0679 (6) | |
C1 | 0.0822 (2) | 0.13332 (8) | 0.92080 (17) | 0.0427 (4) | |
C2 | 0.2046 (2) | 0.11947 (9) | 0.88956 (18) | 0.0446 (5) | |
C3 | 0.2505 (2) | 0.21320 (8) | 0.87823 (16) | 0.0395 (4) | |
C4 | 0.3359 (2) | 0.25626 (9) | 0.85985 (17) | 0.0488 (5) | |
H4 | 0.416424 | 0.247454 | 0.841048 | 0.059* | |
C5 | 0.3027 (2) | 0.31103 (9) | 0.86910 (17) | 0.0502 (5) | |
C6 | 0.1787 (2) | 0.32432 (9) | 0.89600 (17) | 0.0507 (5) | |
C7 | 0.0972 (2) | 0.28286 (9) | 0.91814 (17) | 0.0472 (5) | |
H7 | 0.018040 | 0.291969 | 0.939103 | 0.057* | |
C8 | 0.1309 (2) | 0.22665 (8) | 0.90976 (16) | 0.0397 (4) | |
C9 | 0.3989 (3) | 0.35595 (11) | 0.8517 (2) | 0.0707 (8) | |
H9A | 0.481081 | 0.339371 | 0.843480 | 0.106* | |
H9B | 0.413660 | 0.380471 | 0.912574 | 0.106* | |
H9C | 0.362848 | 0.376525 | 0.787826 | 0.106* | |
C10 | 0.1338 (3) | 0.38397 (10) | 0.8971 (3) | 0.0752 (8) | |
H10A | 0.201248 | 0.405602 | 0.941353 | 0.113* | |
H10B | 0.053914 | 0.385828 | 0.925588 | 0.113* | |
H10C | 0.117678 | 0.398347 | 0.824958 | 0.113* | |
C11 | −0.0104 (2) | 0.08953 (10) | 0.9478 (2) | 0.0578 (6) | |
H11A | −0.002809 | 0.056545 | 0.905528 | 0.069* | |
H11B | −0.100595 | 0.102873 | 0.928672 | 0.069* | |
C12 | 0.0193 (3) | 0.07459 (12) | 1.0669 (2) | 0.0775 (8) | |
H12A | −0.044023 | 0.047837 | 1.081579 | 0.116* | |
H12B | 0.014014 | 0.107320 | 1.109146 | 0.116* | |
H12C | 0.106552 | 0.059182 | 1.085205 | 0.116* | |
C13 | 0.2465 (2) | 0.06016 (9) | 0.8794 (2) | 0.0554 (6) | |
H13A | 0.216330 | 0.038035 | 0.934057 | 0.066* | |
H13B | 0.342299 | 0.058425 | 0.892742 | 0.066* | |
C14 | 0.1930 (3) | 0.03547 (11) | 0.7699 (2) | 0.0715 (7) | |
H14A | 0.225652 | 0.056205 | 0.715590 | 0.107* | |
H14B | 0.098237 | 0.036948 | 0.756165 | 0.107* | |
H14C | 0.221257 | −0.002413 | 0.768422 | 0.107* | |
C15 | 0.6497 (2) | 0.05903 (10) | 0.6971 (2) | 0.0540 (5) | |
C16 | 0.7649 (3) | 0.04099 (11) | 0.6597 (2) | 0.0690 (7) | |
C17 | 0.8409 (2) | 0.13033 (10) | 0.66478 (18) | 0.0502 (5) | |
C18 | 0.9360 (2) | 0.16915 (11) | 0.64532 (19) | 0.0557 (6) | |
H18 | 1.012429 | 0.156529 | 0.624060 | 0.067* | |
C19 | 0.9188 (2) | 0.22453 (11) | 0.65687 (17) | 0.0532 (6) | |
C20 | 0.8031 (2) | 0.24404 (9) | 0.69231 (17) | 0.0485 (5) | |
C21 | 0.7112 (2) | 0.20651 (9) | 0.71427 (18) | 0.0476 (5) | |
H21 | 0.637117 | 0.219201 | 0.739108 | 0.057* | |
C22 | 0.7273 (2) | 0.14926 (9) | 0.69975 (17) | 0.0430 (5) | |
C23 | 1.0185 (3) | 0.26514 (13) | 0.6288 (2) | 0.0705 (8) | |
H23A | 1.090685 | 0.245182 | 0.608650 | 0.106* | |
H23B | 1.051032 | 0.288095 | 0.690112 | 0.106* | |
H23C | 0.977148 | 0.287968 | 0.569713 | 0.106* | |
C24 | 0.7797 (3) | 0.30509 (11) | 0.7034 (2) | 0.0699 (7) | |
H24A | 0.849340 | 0.320529 | 0.756530 | 0.105* | |
H24B | 0.696477 | 0.310717 | 0.725358 | 0.105* | |
H24C | 0.778444 | 0.323040 | 0.635432 | 0.105* | |
C25 | 0.5457 (3) | 0.01907 (11) | 0.7192 (2) | 0.0708 (7) | |
H25A | 0.534315 | −0.010084 | 0.665401 | 0.085* | |
H25B | 0.462154 | 0.038469 | 0.713275 | 0.085* | |
C26 | 0.5819 (4) | −0.00665 (15) | 0.8302 (3) | 0.1045 (12) | |
H26A | 0.659852 | −0.028957 | 0.834056 | 0.157* | |
H26B | 0.510343 | −0.029452 | 0.843495 | 0.157* | |
H26C | 0.598597 | 0.022160 | 0.883486 | 0.157* | |
C27 | 0.7664 (9) | −0.0197 (4) | 0.6193 (9) | 0.088 (2) | 0.596 (10) |
H27A | 0.777363 | −0.044631 | 0.680528 | 0.105* | 0.596 (10) |
H27B | 0.682208 | −0.027963 | 0.573177 | 0.105* | 0.596 (10) |
C28 | 0.8758 (9) | −0.0294 (3) | 0.5578 (7) | 0.125 (3) | 0.596 (10) |
H28A | 0.852852 | −0.012733 | 0.487817 | 0.187* | 0.596 (10) |
H28B | 0.888376 | −0.068523 | 0.550261 | 0.187* | 0.596 (10) |
H28C | 0.956043 | −0.013087 | 0.596236 | 0.187* | 0.596 (10) |
C27B | 0.8116 (14) | −0.0203 (7) | 0.6527 (12) | 0.082 (3) | 0.404 (10) |
H27C | 0.907171 | −0.023151 | 0.669858 | 0.099* | 0.404 (10) |
H27D | 0.773839 | −0.044287 | 0.700621 | 0.099* | 0.404 (10) |
C28B | 0.7591 (16) | −0.0344 (5) | 0.5362 (10) | 0.123 (4) | 0.404 (10) |
H28D | 0.777508 | −0.072623 | 0.523581 | 0.185* | 0.404 (10) |
H28E | 0.801120 | −0.011260 | 0.490895 | 0.185* | 0.404 (10) |
H28F | 0.665400 | −0.028341 | 0.520112 | 0.185* | 0.404 (10) |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Ag1 | 0.05433 (12) | 0.06584 (14) | 0.1134 (2) | 0.00078 (9) | 0.03772 (12) | −0.00521 (12) |
Ag2 | 0.04237 (10) | 0.05675 (11) | 0.07309 (13) | −0.00201 (7) | 0.02599 (8) | −0.00126 (9) |
O1 | 0.1078 (18) | 0.1112 (18) | 0.0684 (13) | 0.0367 (14) | −0.0053 (12) | −0.0201 (12) |
O2 | 0.0752 (13) | 0.0839 (14) | 0.0710 (12) | 0.0089 (11) | 0.0079 (10) | −0.0057 (11) |
O3 | 0.163 (3) | 0.108 (2) | 0.115 (2) | 0.0615 (19) | −0.0098 (19) | −0.0460 (16) |
O4 | 0.0605 (11) | 0.1091 (16) | 0.0630 (12) | −0.0214 (11) | 0.0131 (9) | −0.0019 (11) |
O5 | 0.0779 (16) | 0.168 (3) | 0.0800 (15) | 0.0122 (16) | −0.0001 (13) | 0.0222 (16) |
O6 | 0.105 (2) | 0.120 (2) | 0.142 (2) | −0.0468 (17) | 0.0317 (17) | 0.0218 (18) |
N1 | 0.0381 (9) | 0.0437 (9) | 0.0460 (10) | −0.0011 (7) | 0.0125 (7) | 0.0001 (7) |
N2 | 0.0389 (9) | 0.0446 (9) | 0.0483 (10) | −0.0020 (7) | 0.0138 (7) | −0.0011 (8) |
N3 | 0.0433 (9) | 0.0449 (10) | 0.0517 (10) | −0.0019 (8) | 0.0170 (8) | 0.0005 (8) |
N4 | 0.0604 (13) | 0.0612 (13) | 0.0779 (15) | 0.0082 (10) | 0.0314 (11) | −0.0059 (11) |
N5 | 0.0711 (15) | 0.0812 (16) | 0.0682 (15) | 0.0140 (13) | 0.0150 (12) | −0.0149 (13) |
N6 | 0.0596 (14) | 0.0778 (16) | 0.0700 (15) | −0.0021 (11) | 0.0220 (12) | −0.0061 (12) |
C1 | 0.0392 (10) | 0.0417 (11) | 0.0489 (12) | −0.0019 (8) | 0.0125 (9) | 0.0015 (9) |
C2 | 0.0404 (11) | 0.0440 (11) | 0.0511 (12) | −0.0006 (9) | 0.0131 (9) | 0.0010 (9) |
C3 | 0.0396 (10) | 0.0424 (11) | 0.0369 (10) | −0.0036 (8) | 0.0081 (8) | 0.0008 (8) |
C4 | 0.0483 (12) | 0.0527 (13) | 0.0467 (12) | −0.0096 (10) | 0.0124 (9) | −0.0004 (10) |
C5 | 0.0594 (14) | 0.0473 (12) | 0.0415 (12) | −0.0128 (10) | 0.0035 (10) | 0.0030 (9) |
C6 | 0.0647 (15) | 0.0406 (11) | 0.0427 (12) | −0.0022 (10) | −0.0002 (10) | −0.0009 (9) |
C7 | 0.0505 (12) | 0.0447 (12) | 0.0465 (12) | 0.0031 (9) | 0.0092 (10) | −0.0007 (9) |
C8 | 0.0397 (10) | 0.0418 (10) | 0.0375 (10) | −0.0006 (8) | 0.0072 (8) | 0.0014 (8) |
C9 | 0.0795 (19) | 0.0568 (15) | 0.0760 (18) | −0.0250 (14) | 0.0152 (15) | 0.0048 (13) |
C10 | 0.092 (2) | 0.0421 (13) | 0.088 (2) | 0.0035 (14) | 0.0079 (17) | 0.0009 (13) |
C11 | 0.0519 (13) | 0.0433 (12) | 0.0850 (18) | −0.0076 (10) | 0.0303 (12) | −0.0016 (11) |
C12 | 0.084 (2) | 0.0665 (17) | 0.092 (2) | −0.0005 (15) | 0.0425 (17) | 0.0214 (15) |
C13 | 0.0517 (13) | 0.0430 (12) | 0.0767 (16) | 0.0006 (10) | 0.0256 (12) | 0.0024 (11) |
C14 | 0.0704 (17) | 0.0570 (15) | 0.091 (2) | −0.0047 (13) | 0.0242 (15) | −0.0164 (14) |
C15 | 0.0548 (13) | 0.0485 (12) | 0.0611 (14) | −0.0027 (10) | 0.0172 (11) | −0.0005 (10) |
C16 | 0.0757 (17) | 0.0535 (14) | 0.0841 (18) | 0.0063 (13) | 0.0315 (15) | −0.0099 (13) |
C17 | 0.0448 (12) | 0.0623 (14) | 0.0462 (12) | 0.0015 (10) | 0.0155 (9) | −0.0012 (10) |
C18 | 0.0415 (12) | 0.0792 (18) | 0.0498 (13) | −0.0044 (11) | 0.0169 (10) | 0.0004 (12) |
C19 | 0.0478 (12) | 0.0741 (16) | 0.0376 (11) | −0.0157 (11) | 0.0075 (9) | 0.0038 (11) |
C20 | 0.0510 (12) | 0.0516 (13) | 0.0418 (11) | −0.0075 (10) | 0.0059 (9) | 0.0057 (9) |
C21 | 0.0449 (11) | 0.0492 (12) | 0.0514 (13) | −0.0006 (9) | 0.0159 (10) | 0.0003 (10) |
C22 | 0.0390 (10) | 0.0485 (12) | 0.0434 (11) | −0.0017 (8) | 0.0127 (8) | 0.0012 (9) |
C23 | 0.0617 (16) | 0.093 (2) | 0.0579 (15) | −0.0292 (15) | 0.0132 (12) | 0.0092 (14) |
C24 | 0.0794 (19) | 0.0534 (15) | 0.0748 (18) | −0.0118 (13) | 0.0093 (15) | 0.0089 (13) |
C25 | 0.0675 (17) | 0.0489 (14) | 0.101 (2) | −0.0106 (12) | 0.0276 (15) | −0.0025 (14) |
C26 | 0.111 (3) | 0.086 (2) | 0.128 (3) | 0.000 (2) | 0.051 (2) | 0.033 (2) |
C27 | 0.093 (5) | 0.059 (3) | 0.116 (6) | 0.014 (4) | 0.030 (4) | −0.026 (4) |
C28 | 0.095 (5) | 0.105 (5) | 0.170 (6) | 0.020 (4) | 0.018 (5) | −0.073 (4) |
C27B | 0.081 (6) | 0.070 (4) | 0.096 (6) | −0.006 (5) | 0.018 (5) | −0.015 (5) |
C28B | 0.148 (9) | 0.094 (6) | 0.122 (7) | 0.016 (6) | 0.011 (7) | −0.039 (6) |
Geometric parameters (Å, º) top
Ag1—O1 | 2.498 (2) | C12—H12C | 0.9600 |
Ag1—O2 | 2.512 (2) | C13—H13A | 0.9700 |
Ag1—O4i | 2.3195 (19) | C13—H13B | 0.9700 |
Ag1—N1 | 2.2600 (17) | C13—C14 | 1.512 (4) |
Ag2—O4 | 2.5956 (19) | C14—H14A | 0.9600 |
Ag2—N2 | 2.2492 (17) | C14—H14B | 0.9600 |
Ag2—N3 | 2.2552 (17) | C14—H14C | 0.9600 |
O1—N5 | 1.251 (3) | C15—C16 | 1.427 (4) |
O2—N5 | 1.223 (3) | C15—C25 | 1.506 (3) |
O3—N5 | 1.229 (3) | C16—C27 | 1.550 (10) |
O4—N6 | 1.257 (3) | C16—C27B | 1.563 (17) |
O5—N6 | 1.215 (3) | C17—C18 | 1.410 (3) |
O6—N6 | 1.220 (3) | C17—C22 | 1.403 (3) |
N1—C1 | 1.320 (3) | C18—H18 | 0.9300 |
N1—C8 | 1.373 (3) | C18—C19 | 1.359 (4) |
N2—C2 | 1.328 (3) | C19—C20 | 1.430 (3) |
N2—C3 | 1.371 (3) | C19—C23 | 1.510 (3) |
N3—C15 | 1.323 (3) | C20—C21 | 1.376 (3) |
N3—C22 | 1.378 (3) | C20—C24 | 1.503 (3) |
N4—C16 | 1.306 (3) | C21—H21 | 0.9300 |
N4—C17 | 1.366 (3) | C21—C22 | 1.407 (3) |
C1—C2 | 1.430 (3) | C23—H23A | 0.9600 |
C1—C11 | 1.505 (3) | C23—H23B | 0.9600 |
C2—C13 | 1.507 (3) | C23—H23C | 0.9600 |
C3—C4 | 1.408 (3) | C24—H24A | 0.9600 |
C3—C8 | 1.403 (3) | C24—H24B | 0.9600 |
C4—H4 | 0.9300 | C24—H24C | 0.9600 |
C4—C5 | 1.375 (3) | C25—H25A | 0.9700 |
C5—C6 | 1.421 (3) | C25—H25B | 0.9700 |
C5—C9 | 1.512 (3) | C25—C26 | 1.515 (4) |
C6—C7 | 1.368 (3) | C26—H26A | 0.9600 |
C6—C10 | 1.512 (3) | C26—H26B | 0.9600 |
C7—H7 | 0.9300 | C26—H26C | 0.9600 |
C7—C8 | 1.408 (3) | C27—H27A | 0.9700 |
C9—H9A | 0.9600 | C27—H27B | 0.9700 |
C9—H9B | 0.9600 | C27—C28 | 1.504 (13) |
C9—H9C | 0.9600 | C28—H28A | 0.9600 |
C10—H10A | 0.9600 | C28—H28B | 0.9600 |
C10—H10B | 0.9600 | C28—H28C | 0.9600 |
C10—H10C | 0.9600 | C27B—H27C | 0.9700 |
C11—H11A | 0.9700 | C27B—H27D | 0.9700 |
C11—H11B | 0.9700 | C27B—C28B | 1.508 (19) |
C11—C12 | 1.522 (4) | C28B—H28D | 0.9600 |
C12—H12A | 0.9600 | C28B—H28E | 0.9600 |
C12—H12B | 0.9600 | C28B—H28F | 0.9600 |
| | | |
O1—Ag1—O2 | 50.25 (7) | C14—C13—H13A | 109.0 |
O4i—Ag1—O1 | 95.46 (9) | C14—C13—H13B | 109.0 |
O4i—Ag1—O2 | 116.53 (7) | C13—C14—H14A | 109.5 |
N1—Ag1—O1 | 125.80 (8) | C13—C14—H14B | 109.5 |
N1—Ag1—O2 | 113.10 (7) | C13—C14—H14C | 109.5 |
N1—Ag1—O4i | 129.00 (7) | H14A—C14—H14B | 109.5 |
N2—Ag2—O4 | 101.47 (6) | H14A—C14—H14C | 109.5 |
N2—Ag2—N3 | 173.50 (6) | H14B—C14—H14C | 109.5 |
N3—Ag2—O4 | 80.37 (7) | N3—C15—C16 | 120.8 (2) |
N5—O1—Ag1 | 95.48 (17) | N3—C15—C25 | 117.0 (2) |
N5—O2—Ag1 | 95.56 (16) | C16—C15—C25 | 122.2 (2) |
Ag1ii—O4—Ag2 | 138.85 (9) | N4—C16—C15 | 122.2 (2) |
N6—O4—Ag1ii | 107.43 (16) | N4—C16—C27 | 120.0 (4) |
N6—O4—Ag2 | 112.28 (16) | N4—C16—C27B | 110.5 (6) |
C1—N1—Ag1 | 122.18 (13) | C15—C16—C27 | 117.2 (4) |
C1—N1—C8 | 118.57 (18) | C15—C16—C27B | 126.3 (6) |
C8—N1—Ag1 | 119.25 (14) | N4—C17—C18 | 119.7 (2) |
C2—N2—Ag2 | 122.50 (14) | N4—C17—C22 | 121.1 (2) |
C2—N2—C3 | 118.51 (18) | C22—C17—C18 | 119.2 (2) |
C3—N2—Ag2 | 118.47 (13) | C17—C18—H18 | 119.2 |
C15—N3—Ag2 | 121.44 (15) | C19—C18—C17 | 121.6 (2) |
C15—N3—C22 | 118.08 (19) | C19—C18—H18 | 119.2 |
C22—N3—Ag2 | 120.23 (14) | C18—C19—C20 | 119.4 (2) |
C16—N4—C17 | 117.8 (2) | C18—C19—C23 | 120.2 (2) |
O2—N5—O1 | 118.7 (2) | C20—C19—C23 | 120.3 (2) |
O2—N5—O3 | 119.5 (3) | C19—C20—C24 | 120.6 (2) |
O3—N5—O1 | 121.8 (3) | C21—C20—C19 | 119.6 (2) |
O5—N6—O4 | 116.6 (2) | C21—C20—C24 | 119.8 (2) |
O5—N6—O6 | 124.3 (3) | C20—C21—H21 | 119.5 |
O6—N6—O4 | 118.9 (3) | C20—C21—C22 | 121.0 (2) |
N1—C1—C2 | 121.28 (18) | C22—C21—H21 | 119.5 |
N1—C1—C11 | 116.77 (19) | N3—C22—C17 | 120.0 (2) |
C2—C1—C11 | 121.92 (19) | N3—C22—C21 | 120.81 (19) |
N2—C2—C1 | 120.71 (19) | C17—C22—C21 | 119.1 (2) |
N2—C2—C13 | 117.43 (19) | C19—C23—H23A | 109.5 |
C1—C2—C13 | 121.85 (19) | C19—C23—H23B | 109.5 |
N2—C3—C4 | 120.30 (19) | C19—C23—H23C | 109.5 |
N2—C3—C8 | 120.60 (18) | H23A—C23—H23B | 109.5 |
C8—C3—C4 | 119.09 (19) | H23A—C23—H23C | 109.5 |
C3—C4—H4 | 119.3 | H23B—C23—H23C | 109.5 |
C5—C4—C3 | 121.4 (2) | C20—C24—H24A | 109.5 |
C5—C4—H4 | 119.3 | C20—C24—H24B | 109.5 |
C4—C5—C6 | 119.1 (2) | C20—C24—H24C | 109.5 |
C4—C5—C9 | 119.7 (2) | H24A—C24—H24B | 109.5 |
C6—C5—C9 | 121.2 (2) | H24A—C24—H24C | 109.5 |
C5—C6—C10 | 120.5 (2) | H24B—C24—H24C | 109.5 |
C7—C6—C5 | 120.0 (2) | C15—C25—H25A | 109.2 |
C7—C6—C10 | 119.5 (2) | C15—C25—H25B | 109.2 |
C6—C7—H7 | 119.4 | C15—C25—C26 | 112.0 (3) |
C6—C7—C8 | 121.2 (2) | H25A—C25—H25B | 107.9 |
C8—C7—H7 | 119.4 | C26—C25—H25A | 109.2 |
N1—C8—C3 | 120.29 (18) | C26—C25—H25B | 109.2 |
N1—C8—C7 | 120.59 (19) | C25—C26—H26A | 109.5 |
C3—C8—C7 | 119.11 (19) | C25—C26—H26B | 109.5 |
C5—C9—H9A | 109.5 | C25—C26—H26C | 109.5 |
C5—C9—H9B | 109.5 | H26A—C26—H26B | 109.5 |
C5—C9—H9C | 109.5 | H26A—C26—H26C | 109.5 |
H9A—C9—H9B | 109.5 | H26B—C26—H26C | 109.5 |
H9A—C9—H9C | 109.5 | C16—C27—H27A | 109.2 |
H9B—C9—H9C | 109.5 | C16—C27—H27B | 109.2 |
C6—C10—H10A | 109.5 | H27A—C27—H27B | 107.9 |
C6—C10—H10B | 109.5 | C28—C27—C16 | 111.8 (7) |
C6—C10—H10C | 109.5 | C28—C27—H27A | 109.2 |
H10A—C10—H10B | 109.5 | C28—C27—H27B | 109.2 |
H10A—C10—H10C | 109.5 | C27—C28—H28A | 109.5 |
H10B—C10—H10C | 109.5 | C27—C28—H28B | 109.5 |
C1—C11—H11A | 109.2 | C27—C28—H28C | 109.5 |
C1—C11—H11B | 109.2 | H28A—C28—H28B | 109.5 |
C1—C11—C12 | 111.9 (2) | H28A—C28—H28C | 109.5 |
H11A—C11—H11B | 107.9 | H28B—C28—H28C | 109.5 |
C12—C11—H11A | 109.2 | C16—C27B—H27C | 111.3 |
C12—C11—H11B | 109.2 | C16—C27B—H27D | 111.3 |
C11—C12—H12A | 109.5 | H27C—C27B—H27D | 109.2 |
C11—C12—H12B | 109.5 | C28B—C27B—C16 | 102.2 (10) |
C11—C12—H12C | 109.5 | C28B—C27B—H27C | 111.3 |
H12A—C12—H12B | 109.5 | C28B—C27B—H27D | 111.3 |
H12A—C12—H12C | 109.5 | C27B—C28B—H28D | 109.5 |
H12B—C12—H12C | 109.5 | C27B—C28B—H28E | 109.5 |
C2—C13—H13A | 109.0 | C27B—C28B—H28F | 109.5 |
C2—C13—H13B | 109.0 | H28D—C28B—H28E | 109.5 |
C2—C13—C14 | 113.0 (2) | H28D—C28B—H28F | 109.5 |
H13A—C13—H13B | 107.8 | H28E—C28B—H28F | 109.5 |
| | | |
Ag1—O1—N5—O2 | 2.3 (3) | C3—C4—C5—C9 | 178.3 (2) |
Ag1—O1—N5—O3 | −177.4 (3) | C4—C3—C8—N1 | −178.48 (18) |
Ag1—O2—N5—O1 | −2.2 (3) | C4—C3—C8—C7 | 2.4 (3) |
Ag1—O2—N5—O3 | 177.4 (3) | C4—C5—C6—C7 | 3.6 (3) |
Ag1ii—O4—N6—O5 | 5.1 (3) | C4—C5—C6—C10 | −174.5 (2) |
Ag1ii—O4—N6—O6 | −178.1 (2) | C5—C6—C7—C8 | −3.1 (3) |
Ag1—N1—C1—C2 | −179.96 (15) | C6—C7—C8—N1 | −179.0 (2) |
Ag1—N1—C1—C11 | −2.1 (3) | C6—C7—C8—C3 | 0.1 (3) |
Ag1—N1—C8—C3 | −179.52 (14) | C8—N1—C1—C2 | 0.2 (3) |
Ag1—N1—C8—C7 | −0.4 (3) | C8—N1—C1—C11 | 178.1 (2) |
Ag2—O4—N6—O5 | 174.1 (2) | C8—C3—C4—C5 | −1.9 (3) |
Ag2—O4—N6—O6 | −9.1 (3) | C9—C5—C6—C7 | −175.8 (2) |
Ag2—N2—C2—C1 | −169.46 (15) | C9—C5—C6—C10 | 6.1 (3) |
Ag2—N2—C2—C13 | 9.8 (3) | C10—C6—C7—C8 | 175.0 (2) |
Ag2—N2—C3—C4 | −10.8 (3) | C11—C1—C2—N2 | −179.3 (2) |
Ag2—N2—C3—C8 | 170.33 (14) | C11—C1—C2—C13 | 1.4 (3) |
Ag2—N3—C15—C16 | −173.9 (2) | C15—N3—C22—C17 | −1.4 (3) |
Ag2—N3—C15—C25 | 4.2 (3) | C15—N3—C22—C21 | 176.9 (2) |
Ag2—N3—C22—C17 | 172.84 (16) | C15—C16—C27—C28 | 166.0 (6) |
Ag2—N3—C22—C21 | −8.8 (3) | C15—C16—C27B—C28B | 97.3 (11) |
N1—C1—C2—N2 | −1.5 (3) | C16—N4—C17—C18 | −176.9 (2) |
N1—C1—C2—C13 | 179.2 (2) | C16—N4—C17—C22 | 0.5 (4) |
N1—C1—C11—C12 | −88.0 (3) | C16—C15—C25—C26 | 83.2 (3) |
N2—C2—C13—C14 | −92.9 (3) | C17—N4—C16—C15 | −1.7 (4) |
N2—C3—C4—C5 | 179.20 (19) | C17—N4—C16—C27 | 168.7 (5) |
N2—C3—C8—N1 | 0.4 (3) | C17—N4—C16—C27B | −170.5 (6) |
N2—C3—C8—C7 | −178.69 (19) | C17—C18—C19—C20 | 1.7 (3) |
N3—C15—C16—N4 | 1.3 (4) | C17—C18—C19—C23 | −176.2 (2) |
N3—C15—C16—C27 | −169.3 (5) | C18—C17—C22—N3 | 178.5 (2) |
N3—C15—C16—C27B | 168.4 (6) | C18—C17—C22—C21 | 0.1 (3) |
N3—C15—C25—C26 | −94.9 (3) | C18—C19—C20—C21 | 0.1 (3) |
N4—C16—C27—C28 | −4.8 (10) | C18—C19—C20—C24 | −178.6 (2) |
N4—C16—C27B—C28B | −94.4 (11) | C19—C20—C21—C22 | −1.7 (3) |
N4—C17—C18—C19 | 175.7 (2) | C20—C21—C22—N3 | −176.8 (2) |
N4—C17—C22—N3 | 1.1 (3) | C20—C21—C22—C17 | 1.6 (3) |
N4—C17—C22—C21 | −177.3 (2) | C22—N3—C15—C16 | 0.3 (4) |
C1—N1—C8—C3 | 0.3 (3) | C22—N3—C15—C25 | 178.4 (2) |
C1—N1—C8—C7 | 179.36 (19) | C22—C17—C18—C19 | −1.8 (3) |
C1—C2—C13—C14 | 86.4 (3) | C23—C19—C20—C21 | 177.9 (2) |
C2—N2—C3—C4 | 177.23 (19) | C23—C19—C20—C24 | −0.7 (3) |
C2—N2—C3—C8 | −1.6 (3) | C24—C20—C21—C22 | 177.0 (2) |
C2—C1—C11—C12 | 89.8 (3) | C25—C15—C16—N4 | −176.7 (3) |
C3—N2—C2—C1 | 2.2 (3) | C25—C15—C16—C27 | 12.7 (6) |
C3—N2—C2—C13 | −178.54 (19) | C25—C15—C16—C27B | −9.7 (7) |
C3—C4—C5—C6 | −1.1 (3) | | |
Symmetry codes: (i) x−1, y, z; (ii) x+1, y, z. |