Figure 15
A comparison of apatite unit-cell parameter determinations for the shark tooth and brachiopod fossils (this work) and derived from the ICDD database. The points labelled hydroxylapatite, fluorapatite and chlorapatite [Ca5(PO4)3Cl] are for minerals listed as pure whereas the mixed apatites have the general formula [Ca5(PO4)3(OH,F,Cl)], though they may have a composition close to one of the end-members of the solid solution. Carbonate apatites have the general formula [Ca5(PO4,CO3)3(OH,F,Cl)], but the carbonate content may be very low. Carbonate-containing apatites with relatively high carbonate content tend to have the lowest a unit-cell dimension for the structures in the ICDD database. |