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Figure 7
Typical temperature dependence and phase transitions leading to an incommensurately modulated phase. Starting from the high-temperature periodic phase, the incommensurately modulated phase forms below Ti. As the temperature is decreased, the wavevector modulus changes. At the same time the modulation becomes more anharmonic, leading to higher Fourier components. At Tc the phase `locks in' into a periodic approximant, the modulation wavevector being a rational value of the high-temperature periodic phase lattice constant.

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