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Figure 3
(a) Low-symmetry 1:3 A-site-ordered perovskite structures with space group [Im{\bar 3}]. (b) Square-planar coordination of A6b cations. (c) The nearest environment of A6b cations in [Im{\bar 3}m] (left) and [Im{\bar 3}] (right) structures. Short A6bX24h/g bonds are highlighted in red, medium in black, long in blue.

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