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Figure 2
(a) A scatter plot and (b) a histogram of observed TT separations in all chain-silicate minerals and selected synthetic compounds. All symmetrically unique TT separations up to 6.5 Å in the geometrical repeat unit of each mineral (or synthetic) were incorporated. Red lines represent the set minimum (3.713 Å) TT separations permitted during embedding. In (a), black points represent Si⋯Si separations and the blue, purple, green, red, pink and yellow points represent TT separations that involve the T cations Al, V, Be, B, Fe and Li, respectively.

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