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Figure 10
Dihedral angles (°) around the aryl–aryl bond in biaryl-fused oxepines, azepines and thiepines (taken from published X-ray data). The numerical values of the exocyclic and endocyclic biaryl dihedral angles are indicated. Symbols: (*) highest of four per unit cell; (†) lowest of four per unit cell; (‡) highest of three per unit cell; (§) lowest of three per unit cell; (¶) highest of two per unit cell; (¥) lowest of two per unit cell. CSD six-letter codes: (17), DIFTAN (Engelhardt et al., 1985BB21); (18), JAFLAE (Bringmann et al., 2003BB12); (19), TICTOO (Roszak et al., 1996BB46); (20), GEDYOD (Schmid et al., 1988BB48); (21), GAVKET (Nyburg et al., 1988BB44); (22), GAVKAP (Nyburg et al., 1988BB44); (23), NUBGOG (Mrvoš-Sermek et al., 1998BB43); (24), XEBNOH (Arroyo et al., 2000BB2); (25), WOBMIJ (Schneider et al., 2000BB49); (26), WOBMEF (Schneider et al., 2000BB49); (27), HOVGEE (Widhalm et al., 1999BB54); (28), XEBNIB (Arroyo et al., 2000BB2); (29), HOVGOO (Widhalm et al., 1999BB54); (30), SIZQOH (Kiupel et al., 1998BB32); (31), YIPREU01 (Miyake et al., 2002BB42); (32), YIPREU (Bandarage et al., 1995BB3); (33), KIRPOQ (Loncar-Tomascovic et al., 2000BB38); (34), KIRKOL (Loncar-Tomascovic et al., 2000BB38).

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