Synchrotron structure determination of an α-Keggin doubly PtIV-substituted silicotungstate, (CH6N3)8[α-SiPt2W10O40]·6H2O

Lee, U.; Joo, H.-C.; Park, K.-M.; Ozeki, T.

doi:10.1107/S0108270103004517

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 2
The crystal packing of (I

), with the [α-SiPt₂M₁₀O₄₀]⁸⁻ anions shown as a polyhedral model. Possible hydrogen bonds are indicated by broken lines. [Symmetry codes: (i) $[{1\over2}+y,{1\over2}-x, {1\over2}-z]$ ; (ii) y,1-x,1-z; (iii) $[{1\over2}+x,{1\over2}+y, {1\over2}+z]$ ; (iv) $[{1\over2}-x, {3\over2}-y,{1\over2}+z]$ ; (v) $[-{1\over2}+x, {1\over2}+y, {1\over2}+z]$ ; (vi) $[{3\over2}-y, {1\over2}+x, {3\over2}-z]$ ; (vii) $[-{1\over2}+y, {1\over2}-x, {3\over2}-z]$ ; (viii) $[{1\over2}+x,-{1\over2}+y,{1\over2}+z]$ ; (ix) 1-y,x,1-z; (x) $[{1\over2}-x,{1\over2}-y, {1\over2}+z]$ .]

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 59| Part 4| March 2003| Pages m152-m155

doi:10.1107/S0108270103004517

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