The iso­thio­cyanate complex of tri­phenyl­borane forms an unusual coordination polymer with [K(18-crown-6)]+, both in the solid state and in solution

Munro, O.Q.; Pearson, N.

doi:10.1107/S0108270103018262

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 2
Space-filling plot (CPK model) of (I

), illustrating the off-axis tilt of the axial [SCNBPh₃]⁻ ion caused by steric interactions resulting from coordination of one of the BPh₃ phenyl rings to the neighboring [K(18-crown-6]⁺ cation.

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 59| Part 10| October 2003| Pages m407-m412

doi:10.1107/S0108270103018262

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