cis-Dichloro­[tris­(2-benzimidazolylmethyl)amine]iron(III) chloride ethanol dihydrate: hydrogen bonding changing the arrangement of tapes built from π–π and C—H⋯π inter­actions

Feng, S.-S.; Lu, L.-P.; Wang, S.-X.; Li, L.; Zhu, M.-L.

doi:10.1107/S0108270106002630

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 2
The face-to-face π–π and edge-to-face C—H⋯π interactions (dotted lines) and the perpendicular arrangement of the tapes in (I)

. Fe atoms are shaded, N atoms have a central dot, Cl atoms are large and cross-hatched, C atoms are plain spheres and H atoms are small circles. The minor disorder components have been omitted for clarity. [Symmetry codes: (i) 3 + x, y, z; (ii) 3 − x, 2 − y, 1 − z; (iii) 2 + x, y, z; (iv) 2 − x, 2 − y, 1 − z; (v) 3 − x, − $[{1\over 2}]$ + y, $[{3\over 2}]$ − z.]

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 62| Part 3| February 2006| Pages m105-m108

doi:10.1107/S0108270106002630

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