Secondary inter­actions in gold(I) complexes with thione ligands. 5. Two ionic compounds of the form bis­(thione)gold(I) bis(4-halobenzene­sulfon­yl)amide

Jones, P.G.; Friedrichs, S.

doi:10.1107/S0108270106044143

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 5
Short contacts (dashed lines) in (I)

to Cl atoms in the region y ≃ $[{1\over 4}]$ , viewed parallel to the b axis. Italic labels correspond to the following contacts: (a) Au⋯Cl1(x + 1, y, z) 3.862 (2) Å; (b) Au⋯Cl1(x + 1, −y + $[{1\over 2}]$ , z − $[{1\over 2}]$ ) 4.005 (2) Å; (c) Au⋯Cl2(−x + 1, y − $[{1\over 2}]$ , −z + $[{1\over 2}]$ ) 3.768 (2) Å; (d) S11⋯Cl2(−x + 1, −y + 1, −z) 3.334 (2) Å; (e) S21⋯Cl1(x + 1, −y + $[{1\over 2}]$ , z − $[{1\over 2}]$ ) 3.539 (2) Å; (f) S21⋯Cl2(−x + 1, −y + 1, −z) 3.649 (2) Å; (g) Cl1⋯Cl2(−x + 1, y − $[{1\over 2}]$ , −z + $[{1\over 2}]$ ) 3.549 (2) Å. For clarity, anions are represented as SO₂C₆H₄Cl fragments.

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 62| Part 12| November 2006| Pages m623-m627

doi:10.1107/S0108270106044143

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