Secondary inter­actions in gold(I) complexes with thione ligands. 5. Two ionic compounds of the form bis­(thione)gold(I) bis(4-halobenzene­sulfon­yl)amide

Jones, P.G.; Friedrichs, S.

doi:10.1107/S0108270106044143

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 6
A packing diagram for (II)

, viewed parallel to the b axis at y ≃ 0. A horizontal row of four dimers (arranged like backslashes) can be recognized across the centre of the diagram, with neighbouring anions top and bottom. Italic labels correspond to the following contacts (see Table 4

for details of hydrogen bonds; details of other interactions are given here): (a) H13A⋯O2; (b) H14C⋯O2; (c) H14B⋯O1; (d) C25⋯O1; (e) H13B⋯I; (f) I⋯I(−x − $[{1\over 2}]$ , −y + $[{1\over 2}]$ , −z + 1) 4.1116 (7) Å; (g) Au⋯I(x, −y + 1, z − $[{1\over 2}]$ ) 3.9467 (6) Å. Classical hydrogen bonds (cf. Fig. 2

) are shown as dashed lines but are not labelled.

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 62| Part 12| November 2006| Pages m623-m627

doi:10.1107/S0108270106044143

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