Figure 2
Schematic representations of the different hydrogen-bonding synthons between the carboxylic acid substituents. (a) The R22(8) pattern encountered in a variety of TCPP-based hydrogen-bonded networks (Dastidar et al., 1996; Diskin-Posner & Goldberg, 1999; George & Goldberg, 2006; George et al., 2006; Lipstman, Muniappan & Goldberg, 2007). (b) The R33(10) pattern observed in (I). (c) The solvation pattern of the carboxylic acid groups in (II) (see Comment). |