Figure 3
The unit-cell contents in (I), showing some of the supramolecular interactions. The DICNQ fragment labelled (1) is at the symmetry position (x, y, z), that labelled (2) is at (1 − x, 1 − y, 1 − z), that labelled (3) is at (x − , y + , z) and that labelled (4) is at ( − x, − y, 1 − z). The weak hydrogen bonds from primed atom C6′ at (x − , y + , z) to doubly primed atom N23′′ at ( − x, − y, 1 − z) and its inversion-related counterpart are indicated by dotted lines. The π–π stacking interactions between overlapping DICNQ fragments are indicated by arrows. Zn and Cl atoms are denoted by small spheres. H atoms have been omitted for clarity. |