A centrosymmetric polymorph of chloridotris(triphenyl­phosphine-κP)copper(I) at 150 K

Machado, A.; Manzoni de Oliveira, G.N.; Fenner, H.; Burrow, R.A.

doi:10.1107/S0108270108011232

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 2
A close-up view of the hydrogen-bond interactions of (a) molecule 1 and (b) molecule 2 of (I)

. C—H⋯Cl interactions are indicated with filled dashed lines and C—H⋯π interactions by unfilled dashed lines. Cg₂₁ is the centroid of the C211–C216 ring, Cg₅₁ of ring C511–C516, Cg₂₃ of ring C231–C236 and Cg₁₃ of ring C131–C136. [Symmetry codes: (i) x, y + 1, z; (ii) −x + $[{3\over 2}]$ , y + $[{1\over 2}]$ , −z + $[{1\over 2}]$ ; (iii) −x + $[{1\over 2}]$ , −y + $[{1\over 2}]$ , −z; (iv) −x + $[{3\over 2}]$ , y − $[{1\over 2}]$ , −z + $[{1\over 2}]$ ; (v) −x + 1, y, −z + $[{1\over 2}]$ ; (vi) −x + 1, −y + 1, −z; (vii) x, y − 1, z.]

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 64| Part 6| May 2008| Pages m233-m236

doi:10.1107/S0108270108011232

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