Figure 2
Views of the crystal packing of (Ia) and (Ib), showing (a) hydrogen-bonded layers in (Ia) and (b) double layers in (Ib). Dashed lines represent N—H⋯S hydrogen bonds in dimers of 1-(diaminomethylene)thiouron-1-ium and O—H⋯O bonds in dimers involving HSO4−. |