A dihydroxidotetra­copper(II) framework supported by 4,4′-(adamantane-1,3-diyl)bis­(1,2,4-triazole) and benzene-1,3,5-tricarboxyl­ate bridges

Senchyk, G.A.; Lysenko, A.B.; Krautscheid, H.; Sieler, J.; Domasevitch, K.V.

doi:10.1107/S0108270108016545

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 3
The interconnection of metal–carboxylate layers (which are orthogonal to the plane of the figure) by tr₂ad ligands in (I)

, showing a set of O—H⋯O, O—H⋯N and C—H⋯O bonds. Note that hydrogen-bonded water molecules (O8) provide additional links between the hydroxide–copper clusters. Dashed lines indicate hydrogen bonding, O atoms are shaded gray, N and Cu atoms are shown as crossed circles, and methylene H atoms have been omitted for clarity. [Symmetry codes: (v) −x + 1, −y, −z + 1; (vi) x, y, z + 1.]

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 64| Part 7| June 2008| Pages m246-m249

doi:10.1107/S0108270108016545

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