1,3,5-Triphenyl­adamantane and 1,3,5,7-tetra­phenyl­adamantane

Boldog, I.; Lysenko, A.B.; Rusanov, E.B.; Chernega, A.N.; Domasevitch, K.V.

doi:10.1107/S0108270109013456

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 2
The supramolecular cube formed by two molecules of (I)

by means of concerted C—H⋯π interactions (shown as dashed lines) between six phenyl groups. Atoms C4 and C4^v are situated on the improper threefold axis. [Symmetry codes: (iii) y − $[{1\over 3}]$ , −x + y + $[{1\over 3}]$ , −z + $[{1\over 3}]$ ; (iv) x − y + $[{2\over 3}]$ , x + $[{1\over 3}]$ , −z + $[{1\over 3}]$ ; (v) −x + $[{2\over 3}]$ , −y + $[{4\over3}]$ , −z + $[{1\over 3}]$ .]

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 65| Part 5| April 2009| Pages o248-o252

doi:10.1107/S0108270109013456

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