Figure 3
The asymmetric unit of (II), showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 40% probability level. All C-bound H atoms have been omitted for clarity. The two independent L-ecgonine cations and their tetrachloridoaurate(III) counter-ions are shown. Three symmetry-related atoms are included to show the hydrogen bonding or close contacts. Heavy dashed lines indicate the intramolecular hydrogen bond in each cation and thin solid lines indicate intermolecular hydrogen bonding involving various acceptors. [Symmetry codes: (i) −x + 1, y + , −z + ; (ii) −x + 1, y − , −z + .] |