Figure 4
(a) The one-dimensional chains of [Mn–(μ-CO2)2–Mn]n. The MII—O bonds of the second coordination spheres are shown as dashed lines. (b) The inorganic MIIO8 SBUs are chains of edge-sharing dodecahedra, in which the C atoms can be connected to form a zigzag ladder. The atom coordinates from (I) were exemplarily used to create the diagram. |