Decaaqua­bis­(μ3-4-hy­droxy­pyridine-2,6-dicarboxyl­ato)bis­(4-hy­droxy­pyridine-2,6-dicarboxyl­ato)tetra­manganese(II) 3.34-hydrate: a new three-dimensional open metal–organic framework based on a tetra­nuclear MnII complex of chelidamic acid and undecameric stitching water clusters

Mirzaei, M.; Lippolis, V.; Eshtiagh-Hosseini, H.; Mahjoobizadeh, M.

doi:10.1107/S0108270111050293

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 3
A partial view of the tetranuclear Mn^II clusters in the title compound stacking along the a axis and interacting via hydrogen bonds at the axially coordinated water molecules. Displacement ellipsoids are drawn at the 50% probability level. Two very close fused R₂²(8) hydrogen-bonding motifs can be envisaged in the hydrogen-bonding pattern responsible for the stacking. [Symmetry code: (vii) x − 1, y, z.]

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 68| Part 1| December 2012| Pages m7-m11

doi:10.1107/S0108270111050293

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