Figure 3
The interrelationships between the organic cations of (I) along the [101] direction. Five-membered sequences, consisting of two naphthalene-1,5-diaminium (5) cations on general positions, two 5-aminonaphthalen-1-aminium (6) cations and one centrosymmetric naphthalene-1,5-diaminium cation (7), are formed via FF interactions, and these sequences are further extended into a one-dimensional array by both FF and OFF interactions. Hydrogen bonds are shown as dashed lines. The (C)H atoms of the naphthalene rings have been omitted. [Symmetry codes: (iii) −x + 1, −y + 1, −z; (v) −x + 2, −y + 1, −z + 1.] |