Figure 4
The crystal packing of (V), (VII) and (VIII), viewed parallel to the c axis, with X and Y substituents drawn as spheres. N—H⋯O hydrogen-bonded chains, which propagate parallel to [001], are represented by a single molecule. The layer structure highlighted by dot–dashed lines (left diagram) is the result of the stacking of these chains via a glide operation. Note that OMe/Cl, (VII), and CN/H, (VIII), show the largest differences (dissimilarity index x = 10.1) of all investigated structures. |