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Figure 1
The mol­ecular structure of (I)[link], showing (a) discrete [Cd(bpph)4(H2O)2]2+ cations and (b) [Cd2I6]2− anions, with the atom-labelling scheme. Displacement ellipsoids are drawn at the 40% probability level. The aromatic rings labelled A–F provide the key to the inter­molecular inter­actions listed in Table 3[link]. N atoms are shaded grey. Note the disordered mode of the CdII cations within the iodo­cadmate linkage in part (b), denoted by open and solid bonds. [Symmetry codes: (i) −x + 1, −y + 1, −z + 1; (ii) −x, −y + 1, −z + 1; (iii) −x + 2, −y, −z.]

Journal logoSTRUCTURAL
CHEMISTRY
ISSN: 2053-2296
Volume 69| Part 3| February 2013| Pages 219-224
doi:10.1107/S0108270113002801
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