Two polyoxometallate-based supra­molecular compounds influenced by the ratio between the polyoxometallate anion and organic cation

Zhang, Q.; Liu, J.; Lu, J.; Gong, S.-W.

doi:10.1107/S0108270113011554

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 3
For (I)

, the doubly protonated BIM ligands link the POM anions to form (a) a one-dimensional supramolecular chain along the [01 $[\overline{1}]$ ] direction and (b) a two-dimensional layer parallel to the ac plane. (c) These layers and chains cross each other to form a three-dimensional supramolecular network. [Symmetry codes: (i) x, y − 1, z + 1; (ii) −x + 1, −y + 1, −z + 1; (iii) x − 1, y, z; (iv) −x + 1, −y + 1, −z.]

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 69| Part 6| May 2013| Pages 588-593

doi:10.1107/S0108270113011554

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