Figure 6
Schematic representations of the intramolecular hydrogen-bond network presented by (A) (I) in both polymorphic forms and (B) the 4-oxo-N-methoxyphenyl-4H-chromene-2-carboxamide isomer. As can be seen, the amidic substitution at the 3-position of the chromone (A) `inverts' the relative position of atoms O1 and O4 of the chromone ring with respect to the N-phenylcarboxamide group, compared with the structure of the 2-carboxamide (B). |