Figure 2
Perspective drawing showing the overlap of the major- [0.684 (5)] and minor-occupancy [0.316 (5)] molecules of the whole-molecule disorder model. The major difference between the two partial molecules is the positioning of the C27/C28 ethyl group of the major-occupancy molecule to the opposite side of the porphyrinate plane as the axial chloride ligand, while the C27m/C28m ethyl group of the minor-occupancy molecule is to the same side of the porphyrinate plane as the axial chloride ligand. The bonds of the major-occupancy molecule are represented as solid lines and the bonds of the minor-occupancy molecule are represented as open lines. The atoms of the major-occupancy molecule are represented as eighth-cutout spheres and the atoms of the minor-occupancy molecule are represented as open spheres, both of arbitrary radius, for clarity. |