Figure 6
Projection drawings showing the π–π stackings in the (I)·CH2Cl2 lattice: (a) viewed parallel to the porphyrin planes of (I), showing the five packing/stacking interactions to the porphyrin planes; (b) viewed perpendicular to the porphyrin plane of (I), showing adjacent parallel molecules with CH2⋯plane contacts; (c) viewed perpendicular to the porphyrin plane of (I), showing adjacent parallel molecules with Me⋯plane contacts. Atoms are represented by spheres of arbitrary radii. |