Figure 8
Projection drawings showing the π–π stackings in the Fe(OEP-π-cation radical)Cl lattice: (a) viewed parallel to the porphyrin planes, showing the four packing/stacking interactions to the porphyrin planes (the lower interaction is the tight face-to-face dimer interaction; Scheidt et al., 1992); (b) viewed perpendicular to the porphyrin plane, showing adjacent parallel molecules with Me⋯plane contacts. Atoms are represented by spheres of arbitrary radii. |