Correlation of the solid-state reactivities of racemic 2,4(6)-di-O-benzoyl-myo-inositol 1,3,5-orthoformate and its 4,4′-bi­pyridine cocrystal with their crystal structures

Tamboli, M.I.; Bahadur, V.; Gonnade, R.G.; Shashidhar, M.S.

doi:10.1107/S2053229614021834

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 5
The helical assembly of molecules of (1)

through O4—H4A⋯O7ⁱ interactions (dashed lines), bringing the nucleophile (O4—H4A) and electrophile (C15=O8) into close proximity with the proper orientation required for benzoyl-group transfer. [Symmetry code: (i) −x + 1, y − $[{1\over 2}]$ , −z + $[{1\over 2}]$ .]

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 70| Part 11| October 2014| Pages 1040-1045

doi:10.1107/S2053229614021834

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