Ca3ZnGeO2[Ge4O12]: a Ca–Zn germanate related to the mineral taikanite

Redhammer, G.J.

doi:10.1107/S2053229614027466

Acta Crystallographica Section C
Acta Crystallographica
Section C STRUCTURAL CHEMISTRY

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Figure 1
The asymmetric unit and symmetry-related atoms of Ca₃ZnGeO₂[Ge₄O₁₂], shown with 95% probability displacement ellipsoids. Colour code: orange and yellow = Ca²⁺ on Ca1 and Ca2 sites, respectively; cyan and blue = Ge⁴⁺ on Ge1 and Ge2 sites forming the [Ge₄O₁₂] chain and the Ge3 site, respectively; green = Zn²⁺; red = O atoms. [Symmetry codes: (i) x + $[{1\over 2}]$ , y + $[{1\over 2}]$ , z; (ii) −x + $[{1\over 2}]$ , y + $[{1\over 2}]$ , −z; (iii) −x + 1, y, −z; (iv) x, y, z − 1; (v) −x + 1, y, −z + 1; (vi) x + $[{1\over 2}]$ , y + $[{1\over 2}]$ , z − 1; (vii) −x + $[{1\over 2}]$ , y + $[{1\over 2}]$ , −z + 1; (viii) −x + $[{1\over 2}]$ , y − $[{1\over 2}]$ , −z + 1; (ix) −x + $[{1\over 2}]$ , y − $[{1\over 2}]$ , −z; (x) x + $[{1\over 2}]$ , y − $[{1\over 2}]$ , z; (xi) x + $[{1\over 2}]$ , y − $[{1\over 2}]$ , z − 1.]

STRUCTURAL
CHEMISTRY

ISSN: 2053-2296

Volume 71| Part 1| January 2015| Pages 80-83

doi:10.1107/S2053229614027466

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