Figure 3
The environments of the aromatic rings in the crystal structures of (1)–(4). (a) Aromatic–aromatic interactions (blue lines) between molecules within the hydrogen-bonded chain [centroid–centroid distance = 4.952 (3) Å] and the interactions (blue lines) between molecules of 21-screw related chains [centroid–centroid distance = 4.985 (2) Å] in the halogenated derivatives (3) and (4). (b)/(c) The shortest intermolecular contacts (blue lines) from the centroids of the aromatic rings in (1) and (2), respectively. In all three plots, distances are in Ångströms. |